Abstract: Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10?7 to 16×10?7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR?525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.

Abstract: Cordierite ceramic articles with high volume percent porosities of at least 64% but less than 80% have controlled median pore sizes and mean coefficients of thermal expansion that impart substantially improved modulus of rupture strengths (MOR) and thermal shock resistance (TSR) to the ceramic articles.

Abstract: Porous ceramic catalyst supports or filters to be provided with catalyst coatings via oxide washcoating processes are pre-coated with cross-linked polymer barrier layers to prevent washcoat nanoparticle intrusion into the microcracked and/or microporous surfaces of the ceramics, the barrier coatings being formed by thermally cross-linking hydrocarbon polymers that are vaporizable at moderate washcoat stabilization or catalyst activation temperatures and that preferentially block the micropore/microchannel pore volume of the article.

Abstract: Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10?7 to 16×10?7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR?525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.

Abstract: Porous, non-microcracked cordierite ceramic bodies having high strength, high strain tolerance, and high thermal shock resistance are produced from cordierite powder batch mixtures of controlled powder particle size fired according to a schedule that prevents objectionable cordierite grain growth, maintaining a small cordierite crystalline domain size in order to minimize or prevent microcracking in the product.

Abstract: An apparatus and method to passivate porous ceramic articles containing microcracks as described herein. The method includes circulating a fluid including a passivator through the porous ceramic article and depositing at least a portion of the passivator on the porous ceramic article.

Abstract: An apparatus and method to passivate porous ceramic articles containing microcracks as described herein. The method includes circulating a fluid including a passivator through the porous ceramic article and depositing at least a portion of the passivator on the porous ceramic article.

Abstract: Ceramic structures such as catalyst supports or combustion exhaust filters that incorporate combinations of high temperature phase change materials, and methods for determining the thermal history of such ceramic structures, by disposing the phase change materials on or within the structures and subsequently detecting the presence or absence of phase changes in the materials after exposure to high temperatures.

Abstract: A diesel particulate filter comprising a plugged, wall-flow honeycomb filter body composed of cordierite and having a plurality of parallel end-plugged cell channels traversing the body from a frontal inlet end to an outlet end thereof, wherein the filter exhibits a CTE (25-800° C.) of less than 13×10?7/° C., a bulk filter density of less than 0.60 g/cm3, a median pore diameter, d50, of less than 25 micrometers, a porosity and pore size distribution that satisfy the relationship Pm?3.75, wherein Pm is equal to 10.2474{1/[(d50)2(%porosity/100)]}+0.0366183(d90)?0.00040119(d90)2+0.468815(100/%porosity)2+0.0297715(d50)+1.61639(d50?d10)/d50, wherein d10, and d90 are pore diameters at 10% and 90% of the pore size distribution on a volumetric basis, and d10<d50<d90. A method of making the same is also provided.

Abstract: Porous, non-microcracked cordierite ceramic bodies having high strength, high strain tolerance, and high thermal shock resistance are produced from cordierite powder batch mixtures of controlled powder particle size fired according to a schedule that prevents objectionable cordierite grain growth, maintaining a small cordierite crystalline domain size in order to minimize or prevent microcracking in the product.

Abstract: Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10?7 to 16×10?7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR?525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.

Abstract: Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10?7 to 16×10?7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR?525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.

Abstract: Cordierite ceramic articles with high volume percent porosities of at least 64% but less than 80% have controlled median pore sizes and mean coefficients of thermal expansion that impart substantially improved modulus of rupture strengths (MOR) and thermal shock resistance (TSR) to the ceramic articles.

Abstract: Ceramic structures such as catalyst supports or combustion exhaust filters that incorporate combinations of high temperature phase change materials, and methods for determining the thermal history of such ceramic structures, by disposing the phase change materials on or within the structures and subsequently detecting the presence or absence of phase changes in the materials after exposure to high temperatures.

Abstract: A diesel particulate filter having a honeycomb body composed of cordierite and exhibiting a CTE (25-800° C.) of less than 13×10?7/° C.; a median pore diameter, d50, of less than 25 ?m; % porosity not less than 53%; and a narrow pore size distribution wherein a value of d50?d10)/d50 is not greater than 0.6; and a value of d90 less than 40 ?m wherein d10, and d90 are pore diameters at 10% and 90% of the pore size distribution on a volumetric basis, and d10<d50<d90. The particulate filter preferably exhibits a plugged, wall-flow honeycomb filter body composed of cordierite and having a plurality of parallel end-plugged cell channels traversing the body from a frontal inlet end to an outlet end thereof.

Abstract: A coated diesel exhaust filter is provided that applies a relatively low pressure drop across the exhaust system despite the buildup of soot deposits. The filter includes a porous ceramic structure having an inlet end, an outlet end, and a plurality of gas inlet and gas outlet channels disposed between the inlet and outlet ends, the channels being separated by porous ceramic walls. A catalyst is distributed at least partly within the porous ceramic walls of the structure, and is distributed at a higher concentration within portions of the ceramic walls adjacent to the outlet surfaces than within portions of the ceramic walls adjacent the inlet surfaces. Both the inlet and outlet surfaces are substantially free of the catalyst in order to maintain a gas-conducting porosity in these surfaces.

Abstract: A diesel particulate filter having a honeycomb body composed of cordierite and exhibiting a CTE (25-800° C.) of less than 13×10?7/° C.; a median pore diameter, d50, of less than 25 ?m; % porosity not less than 53%; and a narrow pore size distribution wherein a value of d50-d10)/d50 is not greater than 0.6; and a value of d90 less than 40 ?m wherein d10, and d90 are pore diameters at 10% and 90% of the pore size distribution on a volumetric basis, and d10<d50<d90. The particulate filter preferably exhibits a plugged, wall-flow honeycomb filter body composed of cordierite and having a plurality of parallel end-plugged cell channels traversing the body from a frontal inlet end to an outlet end thereof.

Abstract: A diesel particulate filter comprising a plugged, wall-flow honeycomb filter body composed of cordierite and having a plurality of parallel end-plugged cell channels traversing the body from a frontal inlet end to an outlet end thereof, wherein the filter exhibits a CTE (25-800° C.) of less than 13×10?7/° C., a bulk filter density of less than 0.60 g/cm3, a median pore diameter, d50, of less than 25 micrometers, a porosity and pore size distribution that satisfy the relationship Pm?3.75, wherein Pm is equal to 10.2474{1/[(d50)2(1/oporosity/100)]}+0.0366183(d90)?0.00040119(d90)2+0.468815(100/% porosity)2+0.0297715(d50)+1.61639(d50?d10)/d50, wherein d10, and d90 are pore diameters at 10% and 90% of the pore size distribution on a volumetric basis, and d10<d50<d90. A method of making the same is also provided.

Abstract: A diesel particulate filter comprising a plugged, wall-flow honeycomb filter body composed of cordierite and having a plurality of parallel end-plugged cell channels traversing the body from a frontal inlet end to an outlet end thereof, wherein the filter exhibits a CTE (25–800° C.) of less than 13×10?7/° C., a bulk filter density of less than 0.60 g/cm3, a median pore diameter, d50, of less than 25 micrometers, a porosity and pore size distribution that satisfy the relationship Pm?3.75, wherein Pm is equal to 10.2474{1/[(d50)2(% porosity/100)]}+0.0366183(d90)?0.00040119(d90)2+0.468815(100/% porosity)2+0.0297715(d50)+1.61639(d50?d10)/d50, wherein d10, and d90 are pore diameters at 10% and 90% of the pore size distribution on a volumetric basis, and d10<d50<d90. A method of making the same is also provided.

Abstract: Porous ceramic catalyst supports or filters to be provided with catalyst coatings via oxide washcoating processes are pre-coated with cross-linked polymer barrier layers to prevent washcoat nanoparticle intrusion into the microcracked and/or microporous surfaces of the ceramics, the barrier coatings being formed by thermally cross-linking hydrocarbon polymers that are vaporizable at moderate washcoat stabilization or catalyst activation temperatures and that preferentially block the micropore/microchannel pore volume of the article.