Patents by Inventor Toshihiko Sugano

Toshihiko Sugano has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9587050
    Abstract: A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity.
    Type: Grant
    Filed: February 13, 2014
    Date of Patent: March 7, 2017
    Assignee: TOHO TITANIUM CO., LTD.
    Inventors: Motoki Hosaka, Noriaki Nakamura, Shingo Yamada, Toshihiko Sugano
  • Publication number: 20160326277
    Abstract: High stereoregularity, highly active catalytic performance, and good hydrogen response can be obtained by homopolymerizing propylene in the presence of a catalyst that includes a solid catalyst component including titanium, magnesium, a halogen, a carbonate compound represented by the following formula, and a diether compound. Excellent polymerization behavior can also be obtained when effecting random copolymerization or block copolymerization. R1—O—C(?O)—O—Z—O—R2??(1) wherein R1 and R2 are a hydrocarbon group or a substituted hydrocarbon group having 1 to 24 carbon atoms, or a heteroatom-containing group, provided that R1 and R2 are either identical or different, and Z is a linking group that links two oxygen atoms through a carbon atom or a carbon chain.
    Type: Application
    Filed: August 4, 2014
    Publication date: November 10, 2016
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Toshihiko SUGANO, Toshiya UOZUMI, Motoki HOSAKA
  • Patent number: 9243081
    Abstract: A solid catalyst component for olefin polymerization includes titanium, magnesium, a halogen, and a compound represented by the following formula (1): R1O—C(?O)—O—Z—OR2, and an olefin polymerization catalyst includes the solid catalyst component, an organoaluminum compound, and an optional external electron donor compound. An olefin polymer that has a moderate molecular weight distribution while maintaining high stereoregularity can be produced by utilizing the solid catalyst component and the olefin polymerization catalyst.
    Type: Grant
    Filed: May 9, 2012
    Date of Patent: January 26, 2016
    Assignee: TOHO TITANIUM CO., LTD.
    Inventors: Toshihiko Sugano, Toshiya Uozumi, Noriaki Nakamura
  • Publication number: 20160009836
    Abstract: A method for producing a propylene-based block copolymer ensures excellent olefin polymerization activity and activity with respect to hydrogen (hydrogen response) during polymerization, and produces a propylene-based block copolymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes copolymerizing propylene and an ?-olefin in the presence of a catalyst that includes (I) a solid catalyst component that includes titanium, magnesium, a halogen, and a compound represented by R1O—C(?O)—O—Z—OR2, and (II) a compound represented by R3pAlQ3-p, to obtain a propylene-based block copolymer.
    Type: Application
    Filed: February 5, 2014
    Publication date: January 14, 2016
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Toshihiko SUGANO, Motoki HOSAKA, Toshiya UOZUMI
  • Patent number: 9206273
    Abstract: A solid catalyst component for olefin polymerization includes titanium, magnesium, a halogen, a compound represented by (R1)kC6H4-k(COOR2)(COOR3), and a compound represented by R4O—C(?O)—O—Z—OR5. The solid catalyst component is a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity.
    Type: Grant
    Filed: February 7, 2014
    Date of Patent: December 8, 2015
    Assignee: TOHO TITANIUM CO., LTD.
    Inventors: Motoki Hosaka, Noriaki Nakamura, Toshihiko Sugano
  • Patent number: 9206265
    Abstract: An olefin polymer that is obtained using an olefin polymerization catalyst that includes a solid catalyst component for olefin polymerization that includes titanium, magnesium, a halogen, and an ester compound (A) represented by the following formula (1): R1R2C?C(COOR3)(COOR4), an organoaluminum compound, and an optional external electron donor compound, exhibits primary properties (e.g., molecular weight distribution and stereoregularity) similar to those of an olefin polymer obtained using a solid catalyst component that includes a phthalic ester as an electron donor.
    Type: Grant
    Filed: April 13, 2012
    Date of Patent: December 8, 2015
    Assignee: TOHO TITANIUM CO., LTD.
    Inventors: Toshiya Uozumi, Shingo Yamada, Noriaki Nakamura, Koichiro Hisano, Motoki Hosaka, Toshihiko Sugano
  • Publication number: 20150240001
    Abstract: A solid catalyst component for olefin polymerization makes it possible to polymerize an olefin with high polymerization activity when used for an olefin polymerization catalyst, and produce an olefin polymer having a low fine powder content, a low coarse powder content, and a low volatile organic compound (VOC) content in high yield. The solid catalyst component for olefin polymerization is produced by suspending (a) a dialkoxymagnesium, and (b) at least one alcohol selected from ethanol, n-propanol, n-butanol, isopropanol, isobutanol, and t-butanol, in an inert organic solvent so that the total amount of the alcohol is 0.5 to 1.5 parts by mass based on 100 parts by mass of the dialkoxymagnesium, to prepare a suspension, and bringing (c) an internal electron donor and (d) a titanium halide compound into contact with the suspension.
    Type: Application
    Filed: September 24, 2013
    Publication date: August 27, 2015
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Motoki Hosaka, Hidetoshi Umebayashi, Toshihiko Sugano
  • Publication number: 20150240002
    Abstract: A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity.
    Type: Application
    Filed: February 13, 2014
    Publication date: August 27, 2015
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Motoki Hosaka, Noriaki Nakamura, Shingo Yamada, Toshihiko Sugano
  • Publication number: 20150240011
    Abstract: A method produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds into contact with each other to effect a reaction, followed by washing; a second step that brings one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction; and a third step that brings a tetravalent titanium halide compound and one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.
    Type: Application
    Filed: February 13, 2014
    Publication date: August 27, 2015
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Motoki Hosaka, Noriaki Nakamura, Shingo Yamada, Toshihiko Sugano
  • Publication number: 20150240003
    Abstract: A solid catalyst component for olefin polymerization includes titanium, magnesium, a halogen, a compound represented by (R1)kC6H4-k(COOR2)(COOR3), and a compound represented by R4O—C(?O)—O—Z—OR5. The solid catalyst component is a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity.
    Type: Application
    Filed: February 7, 2014
    Publication date: August 27, 2015
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Motoki Hosaka, Noriaki Nakamura, Toshihiko Sugano
  • Publication number: 20150166693
    Abstract: A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity.
    Type: Application
    Filed: July 10, 2013
    Publication date: June 18, 2015
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Motoki Hosaka, Noriaki Nakamura, Toshihiko Sugano
  • Publication number: 20140343237
    Abstract: A solid catalyst component for olefin polymerization includes titanium, magnesium, a halogen, and a compound represented by the following formula (1): R1O—C(?O)—O—Z—OR2, and an olefin polymerization catalyst includes the solid catalyst component, an organoaluminum compound, and an optional external electron donor compound. An olefin polymer that has a moderate molecular weight distribution while maintaining high stereoregularity can be produced by utilizing the solid catalyst component and the olefin polymerization catalyst.
    Type: Application
    Filed: May 9, 2012
    Publication date: November 20, 2014
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Toshihiko Sugano, Toshiya Uozumi, Noriaki Nakamura
  • Publication number: 20140221583
    Abstract: An olefin polymer that is obtained using an olefin polymerization catalyst that includes a solid catalyst component for olefin polymerization that includes titanium, magnesium, a halogen, and an ester compound (A) represented by the following formula (1): R1R2C?C(COOR3)(COOR4), an organoaluminum compound, and an optional external electron donor compound, exhibits primary properties (e.g., molecular weight distribution and stereoregularity) similar to those of an olefin polymer obtained using a solid catalyst component that includes a phthalic ester as an electron donor.
    Type: Application
    Filed: April 13, 2012
    Publication date: August 7, 2014
    Applicant: TOHO TITANIUM CO., LTD.
    Inventors: Toshiya Uozumi, Shingo Yamada, Noriaki Nakamura, Koichiro Hisano, Motoki Hosaka, Toshihiko Sugano
  • Patent number: 7276463
    Abstract: A catalyst having a high catalyst activity, which enables the production of an ?-olefin polymer improved in stereoregularity by decreasing an amorphous component, and a production method for the ?-olefin polymer, are developed. Described are a catalyst for polymerizing ?-olefin comprising a combination of (A) a solid catalyst component containing magnesium, titanium and a halogen as an essential component, which may contain if necessary, a silicon compound, an organoaluminum compound, and an electron donor; (B) an organoaluminum compound; and (C) a compound containing a C(?O)N bond such as an amide or an urea; which may further contain if necessary, (D) a silicon compound or a diether compound; and a production method for an ?-olefin polymer using the same.
    Type: Grant
    Filed: September 9, 2003
    Date of Patent: October 2, 2007
    Assignee: Japan Polypropylene Corporation
    Inventors: Toshihiko Sugano, Kouji Nakayama, Shigeyuki Matsunami
  • Publication number: 20060068984
    Abstract: A catalyst having a high catalyst activity, which enables the production of an ?-olefin polymer improved in stereoregularity by decreasing an amorphous component, and a production method for the ?-olefin polymer, are developed. Described are a catalyst for polymerizing ?-olefin comprising a combination of (A) a solid catalyst component containing magnesium, titanium and a halogen as an essential component, which may contain if necessary, a silicon compound, an organoaluminum compound, and an electron donor; (B) an organoaluminum compound; and (C) a compound containing a C(?O)N bond such as an amide or an urea; which may further contain if necessary, (D) a silicon compound or a diether compound; and a production method for an ?-olefin polymer using the same.
    Type: Application
    Filed: September 9, 2003
    Publication date: March 30, 2006
    Applicant: Japan PolyChem Corporation
    Inventors: Toshihiko Sugano, Kouji Nakayama, Shigeyuki Matsunami
  • Patent number: 6953831
    Abstract: An ethylene polymer excellent in molding processability represented by uniform extensibility, drawdown resistance, swell and extrudability, and mechanical properties represented by rigidity, impact resistance and ESCR, is provided. Particularly, an ethylene polymer remarkably excelent in balance between rigidity and ESCR as compared with a conventionally known ethylene polymer is provided. An ethylene polymer, which is an ethylene homopolymer or a copolymer of ethylene with an ?-olefin having a carbon number of from 3 to 20, and which satisfies the following conditions (1) to (4): (1) the melt index (HLMI) under a load of 21.6 kg at 190° C. is from 0.1 to 1000 g/10 min, (2) the density (d) is from 0.935 to 0.985 g/cm3, (3) the relation between HLMI and d satisfies the following formula (i): d?0.00900×log(HLMI)+0.951, (4) the relation between ESCR and the flexural modulus (M) satisfies the following formula (ii): M??7310×log(ESCR)+32300.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: October 11, 2005
    Assignee: Japan Polychem Corporation
    Inventors: Yoshiyuki Ishihama, Toshihiko Sugano, Masayuki Yamazaki, Kou Obata
  • Patent number: 6943227
    Abstract: The present invention provides a catalyst for olefin polymerization having high olefin polymerization activity without being accompanied by generation of an adhered polymer on the wall of a polymerization reactor and the wall of pipe line and generation of a locking massive polymer, and capable of manufacturing an olefin polymer industrially and stably for a long period of time. That is, the present invention related to a catalyst for olefin polymerization comprising [A1] a hafnium compound or a zirconium compound having at least one conjugated 5-membered ring ligand, [A2] a zirconium compound having at least one conjugated 5-membered ring ligand but different from [A1], and [B] phyllosilicate, and relates to a method of polymerizing or copolymerizing olefin in the presence of the catalyst.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: September 13, 2005
    Assignee: Japan Polypropylene Corporation
    Inventors: Yoshiyuki Ishihama, Toshihiko Sugano
  • Patent number: 6916886
    Abstract: To provide a propylene based block copolymer that, when used as a molding material, exhibits an extremely good stiffness-impact resistance balance and has good heat resistance and excellent moldability, and therefore, in molding, good appearance is revealed. That is, the invention provides a propylene based block copolymer obtained through a preceding stage step of producing a propylene polymer component (PP) and a subsequent stage step of producing a propylene-ethylene copolymer component (EP) using a metallocene catalyst, wherein the block copolymer satisfies specific requisites.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: July 12, 2005
    Assignee: Japan Polypropylene Corporation
    Inventors: Tetsuya Morioka, Kazuya Sakata, Toshihiko Sugano, Masaaki Itou, Yuu Hayakawa
  • Publication number: 20050009993
    Abstract: To provide a propylene based block copolymer that, when used as a molding material, exhibits an extremely good stiffness-impact resistance balance and has good heat. resistance and excellent moldability, and therefore, in molding, good appearance is revealed. That is, the invention provides a propylene based block copolymer obtained through a preceding stage step of producing a propylene polymer component (PP) and a subsequent stage step of producing a propylene-ethylene copolymer component (EP) using a metallocene catalyst, wherein the block copolymer satisfies specific requisites.
    Type: Application
    Filed: September 26, 2002
    Publication date: January 13, 2005
    Inventors: Tetsuya Morioka, Kazuya Sakata, Toshihiko Sugano, Masaaki Itou, Yuu Hayakawa
  • Patent number: 6825371
    Abstract: The present invention relates to a catalyst for polymerization of &agr;-olefin, which comprises: an essential component (A) of a transition metal compound, an essential component (B) of an ion exchangeable layer compound except for silicate, or an inorganic silicate, and an optional component (C) of an organoaluminum compound, said component (A) being represented by the general formula (I):
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: November 30, 2004
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toshihiko Sugano, Masami Kashimoto, Taku Kato