Patents by Inventor Toshihiko Sugano

Toshihiko Sugano has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5225501
    Abstract: A process for producing a propylene random copolymer comprising the repeating units (I)-(III) in quantities of 70-99.9 molar % of (I), 0-15 molar % and 0.1-30 molar %, respectively, which comprises contacting monomers which afford the following repeating units: ##STR1## m denotes 0 or an integer of 2-10, R.sub..alpha., R.sub..beta. and R.sub..gamma. independently represent a hydrogen atom or a hydrocarbyl group having 1-5 carbon atoms, at least one of R.sub..beta. and R.sub..gamma. being the hydrocarbyl group, and n denotes an integer of 1-5, with a polymerization catalyst to copolymerize, the polymerization catalyst comprising:component (A) which is a transition metal compound represented by the formula:Q.sub.a (C.sub.5 H.sub.5-a-b R.sup.1.sub.b)(C.sub.5 H.sub.5-a-c R.sup.2.sub.c)MeXYwherein R.sup.1 and R.sup.
    Type: Grant
    Filed: May 1, 1992
    Date of Patent: July 6, 1993
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Takashi Fujita, Toshihiko Sugano, Hideshi Uchino
  • Patent number: 5147839
    Abstract: Ziegler polymerization of .alpha.-olefins is disclosed which is characterized by a solid catalyst component. The solid catalyst component, Component (A), comprises Sub-component (i) which is a solid catalyst component for Ziegler catalysts comprising Ti, Mg and a halogen; Sub-component (ii) which is a silicon compound having a plurality of a bond represented by a formula: Si--OR.sup.1R.sup.1.sub.m X.sub.n Si(OR.sup.2).sub.4-n-mwherein R.sup.1 indicates a hydrocarbyl group of 1 to 8 carbon atoms, Sub-component (iii) which is a vinylsilane compound, and Sub-component (iii) which is an organometal compound of a metal of Groups I to IV of the Periodic Table. No need of an outside electron donor may be required, and the polymer produced is improved in its content of a "tacky" polymer.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: September 15, 1992
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Takashi Fujita, Toshihiko Sugano
  • Patent number: 5137995
    Abstract: A process for the preparation of olefin polymers, which comprises polymerizing an olefin in the presence of a catalyst which comprises: (A) a solid catalyst component obtained by contacting a magnesium dihalide such as MgCl.sub.2 with a titanium tetra-alkoxide such as Ti(O-nBu).sub.4 and then with a polymeric silicon compound having a structure represented by the formula ##STR1## wherein R stands for a hydrocarbon residue such as CH.sub.3, and contacting the obtained solid component with a halogen compound of silicon such as SiCl.sub.4 or with a halogen compound of silicon such as SiCl.sub.4 and a halogen compound of titanium such as TiCl.sub.4, (B) an organoaluminum compound such as Al(Et).sub.3 ; and (C) an organic silicon compound having an Si--O--C linkage such as PhSi(OEt).sub.3. According to this process, a polymer having a high stereoregularity, a narrow particle size distribution and a high bulk density can be obtained in a high yield with a high efficiency.
    Type: Grant
    Filed: June 7, 1991
    Date of Patent: August 11, 1992
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Masuzo Yokoyama, Kouichi Katou, Toshihiko Sugano
  • Patent number: 5104838
    Abstract: Disclosed is a titanium-containing solid catalyst component which is a contact reaction product of:(i) a magnesium halide such as MgCl.sub.2,(ii) a titanium compound represented by the formula:Ti(OR.sup.1).sub.a X.sub.4-awherein a is a number of 0.ltoreq.a.ltoreq.4, R.sup.1 represents a hydrocarbon residue having 1 to 20 carbon atoms, and X represents a halogen atom, such as Ti(O--nBu).sub.4, and(iii) a coordination titanium compound represented by the formula:R.sup.2.sub.m R.sup.3.sub.n TiX.sub.4-m-nwherein R.sup.2 represents a cyclopentadienyl group or a substituted cyclopentadienyl group, R.sup.3 represents a hydrogen atom, a hydroxyl group, a hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an amino group or a substituted amino group, X represents a halogen atom, and m is a number of 1.ltoreq.m.ltoreq.4 and n is a number of 0.ltoreq.n.ltoreq.3, with the proviso that the condition of 1.ltoreq.m+n.ltoreq.4 is satisfied, such as Cp.sub.2 TiCl.sub.2, i.e.
    Type: Grant
    Filed: August 2, 1990
    Date of Patent: April 14, 1992
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Takashi Fujita, Toshihiko Sugano, Takashi Niwa
  • Patent number: 5032563
    Abstract: Ziegler polymerization of .alpha.-olefins is disclosed which is characterized by a solid catalyst component used in the Ziegler-type catalyst. The solid catalyst component, Component (A), comprises Component (i) which is a solid catalyst component for a Ziegler-type catalyst comprising Ti, Mg and a halogen; Component (ii) a silicon compound of a formula:R.sup.1 R.sup.2.sub.3-n Si(OR.sup.3).sub.nwherein R.sup.1 -R.sup.3 are each hydrocarbyl group characterized by R.sup.1 which has a branched hydrocarbyl group;Component (iii) a halogen compound of W or Mo; and Component (iv) an organometal compound of a metal of Groups I to IV of the Periodic Table.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: July 16, 1991
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Mitsuyuki Matsuura, Toshihiko Sugano, Kazuo Nakamura
  • Patent number: 4563436
    Abstract: A catalyst component for polymerization of .alpha.-olefins is produced by causing mutual contact of:(A) a magnesium halide containing solid;(B) an electron donating compound, having the structural site as represented by the formula show below in its molecule: ##STR1## and (C) a titanium halide. The catalyst thus produced has high polymerization activity and is capable of producing polymers having excellent stereoregularity.
    Type: Grant
    Filed: December 13, 1984
    Date of Patent: January 7, 1986
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Masuzo Yokoyama, Toshihiko Sugano