Patents by Inventor Toshihiro Nishikawa

Toshihiro Nishikawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5290673
    Abstract: An emulsion layer containing silver halide grains reduction-sensitized by an ascorbic acid or at least one of its derivatives and containing a nitrogen-containing heterocyclic compound having a mercapto group is formed on a support.
    Type: Grant
    Filed: October 15, 1991
    Date of Patent: March 1, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshihiro Nishikawa
  • Patent number: 5192656
    Abstract: A silver halide color photographic light-sensitive material comprises at least one silver halide emulsion layer applied onto a substrate, at least one of the layers being formed from a silver halide emulsion containing not less than 7 mole % of silver iodide and the light-sensitive material including a polymer having cationic sites. The light-sensitive material exhibits good graininess, high sensitivity and excellent desilvering properties.
    Type: Grant
    Filed: April 13, 1988
    Date of Patent: March 9, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Shinji Ueda, Hideo Usui
  • Patent number: 5104775
    Abstract: In a method for processing at least 2 kinds of silver halide color photographic light-sensitive materials comprising the steps of development, bleach-fixing, water washing and/or stabilization, the method comprises processing, in a common bleach-fixing bath and a common water washing or stabilization bath directly subsequent thereto, one silver halide color photographic light sensitive material having, applied to a substrate, a silver halide emulsion layer which contains, on average, not less than 3 mole % of silver iodide and another silver halide color photographic light sensitive material having applied to a substrate a silver halide emulsion layer which is substantially free of silver iodide, the water washing or stabilization bath containing at least one nonionic surfactant. The amount of replenisher for the bleach-fixing bath and the water washing or stabilizing bath is reduced to not more than 400 ml/m.sup.2 for color paper or not more than 800 m1/m.sup.2 for color negative film.
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: April 14, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Abe, Shinji Ueda, Toshihiro Nishikawa
  • Patent number: 4968595
    Abstract: A silver halide photographic emulsion containing silver halide grains having (III) faces, at least 50% (by projected area) of which are(a) silver halide grains controlled so that the development thereof is initiated at the corners or in the vicinity of the corners of the grains, and/or(b) silver halide grains controlled so that the development thereof is initiated at the edges or in the vicinity of the edges of the grains.
    Type: Grant
    Filed: June 6, 1988
    Date of Patent: November 6, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sumito Yamada, Tadashi Ito, Hiroyuki Mifune, Keisuke Shiba, Toshihiro Nishikawa, Hideo Ikeda
  • Patent number: 4960689
    Abstract: A silver halide color photographic light-sensitive material includes a support having thereon at least one silver halide emulsion layer, wherein the emulsion layer contains a silver halide emulsion which comprises silver halide grains consisting of at least 50 mol % of silver chloride and contains at least one of the compounds represented by formulas [I] to [III]: ##STR1## wherein Z represents alkyl (the number of carbon atoms is 1 to 18), aryl (the number of carbon atom is 6 to 18), or heterocyclic,Y represents an atom group required for forming heterocyclic or aryl (the number of carbon atoms of the aryl is 6 to 18),M represents metal cation, organic cation, or hydrogen atom, andn represents an integer from 2 to 10.
    Type: Grant
    Filed: June 2, 1988
    Date of Patent: October 2, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Shunji Takada, Kazunori Hasebe
  • Patent number: 4957853
    Abstract: A novel silver halide color photographic light-sensitive material is provided having at least one light-sensitive silver halide emulsion layer provided on a support and said photographic material contains at least one cyan dye-forming coupler represented by formula (I) ##STR1## wherein r represents a substituted or unsubstituted branched alkyl or substituted alkyl group containing 6 or more carbon atoms; X represents a hydrogen atom or a non-photographically-useful group which can be released therefrom upon coupling with an oxidized form of an aromatic primary amine developing agent; R' represents a group which can be substituted at a phenyl nucleus other than a group which can be represented by OR; and n is an integer of from 0 to 4.
    Type: Grant
    Filed: January 27, 1988
    Date of Patent: September 18, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Toshihiro Nishikawa
  • Patent number: 4952490
    Abstract: A photographic light-sensitive material comprises a support having thereon at least one silver halide emulsion layer. At least 70% of a total number of silver halide grains contained in the emulsion layer are regular crystal grains not having a twinning plane. At least 50 mol% of the regular grains are silver chloride. The regular crystal grains have a (111) crystal plane on 30% or more of a total grain surface and are chemically sensitized in the presence of a gold compound or sulfur and gold compounds.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: August 28, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunji Takada, Toshihiro Nishikawa, Kei Sakanoue, Akira Abe
  • Patent number: 4952491
    Abstract: A photographic light-sensitive material comprising, on a support, at least one silver halide emulsion layer containing silver halide grains, wherein at least 50% of the total projected surface area of silver halide grains contained in the silver halide emulsion layer is occupied by tabular grains comprising at least about 50 mol% of silver chloride, the tabular grains having been precipitated in the presence of a dye and having an aspect ratio of at least 2.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: August 28, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Shunji Takada
  • Patent number: 4865962
    Abstract: A photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, characterized in that the emulsion layer contains silver chlorobromide prepared in such a manner that silver halide regular crystal grains, having no twinning crystal plane and containing 50 mol % or more of silver chloride, are used as host grains, an organic compound is adsorbed on a surface of each of the host grains, and sulfur-plus-gold sensitization is performed, either during or after halide conversion in the presence of a bromide.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: September 12, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunori Hasebe, Masahiro Asami, Naoto Ohshima, Keisuke Shiba, Toshihiro Nishikawa, Kei Sakanoue, Akira Abe
  • Patent number: 4863841
    Abstract: A silver halide color photographic material comprising a support having thereon at least one photosensitive silver halide emulsion layer, wherein a 5-pyrazolone type 2-equivalent coupler is present in the photosensitive silver halide emulsion layer or a layer adjacent thereto and a hardening agent which acts by activating a carboxy group is present in a photosensitive or non-photosensitive photographic layer of the silver halide color photographic material.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: September 5, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hidetoshi Kobayashi, Toshihiro Nishikawa, Koji Tamoto
  • Patent number: 4857442
    Abstract: The present invention provides an economical method for the processing of silver halide color photographic materials comprising fixing or bleach-fixing of the material followed by the washing thereof with a small amount of a washing replenisher. The present method is characterized in that the silver halide color photographic material to be processed contains at least one cyan dye-forming coupler of the following formula (I) or (II) and that the amount of the washing replenisher in the washing step falls within the range of 30 to 50 times of the amount of the processing solution carried over from a previous bath based on the unit area of the photographic material being processed, ##STR1## wherein, R.sub.1 represents --CONR.sub.5 R.sub.6, --NHCOR.sub.5, --NHCOOR.sub.7, --NHSO.sub.2 R.sub.7, --NHCONR.sub.5 R.sub.6 or --NHSO.sub.2 NR.sub.5 R.sub.6 ;R.sub.2 represents a substituent on the naphthol ring;m is an integer of 0 to 3;R.sub.3 represents a mono-valent organic group;R.sub.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: August 15, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Fujita, Toshihiro Nishikawa
  • Patent number: 4820624
    Abstract: A corner development type silver halide photographic emulsion is disclosed, wherein the silver halide crystals in the silver halide emulsion are cubic or tetradecahedral grains having at least substantial (100) planes and the emulsion is controlled so that at least 70% of developed silver halide crystals (grains), which are observed on applying a light exposure of 1/50 second to the emulsion under the light-exposure condition corresponding to (maximum density --minimum density).times.3/4 of the silver image in the characteristic curve of the emulsion obtained by the developer, developing under the development condition which are used for processing a photographic light-sensitive material formed by coating the emulsion on a support, and stopping the development with an aqueous solution of 5% glacial acetic acid just after the initiation of the development, are developed at the corners of the cubic or tetradecahedral crystals or at the vicinity of the corners.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: April 11, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunori Hasebe, Masahiro Asami, Naoto Ohshima, Keisuke Shiba, Toshihiro Nishikawa
  • Patent number: 4804617
    Abstract: This invention provides a processing method for exposed silver halide color photosensitive materials, which enables sufficient desilverization to be performed in a short time and highly photographic quality to be obtained. The processing method of this invention comprises the steps of: exposing silver halide color photosensitive material containing 5-pyrazolone-type or pyrazoloazole-type 2-equivalent magenta coupler to light; color developing said photosensitive material; and desilverizing said photosensitive material, wherein said desilverizing step uses a bleaching bath containing ferric complex salt aminopolycarboxylate, and thereafter uses a bleaching-and-fixing bath containing ferric complex salt aminopolycarboxylate.
    Type: Grant
    Filed: July 10, 1987
    Date of Patent: February 14, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Akira Abe
  • Patent number: 4798784
    Abstract: A method for processing a silver halide color photographic material which comprises, after color development of an exposed silver halide color photographic material containing a hydrolyzable type DIR coupler, rapidly processing the developed silver halide color photographic material with a liquid having a bleaching ability and subsequently with a liquid having a bleach-fixing ability, to thereby form a color image.In accordance with the method for processing a silver halide color photographic material, desilveration is completed in a short period of time and color photographic images having excellent color reproducibility and fastness are obtained.
    Type: Grant
    Filed: November 26, 1986
    Date of Patent: January 17, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzo Kishimoto, Toshihiro Nishikawa, Akira Abe, Junya Nakajima
  • Patent number: 4762774
    Abstract: A method for color image formation is disclosed, comprising imagewise exposing to light a silver halide color photographic material having a silver halide emulsion layer containing monodispersed silver halide grains, subjecting the exposed material to color development, and processing the material with a bath primarily having bleaching capacity and then with a bath having bleach-fixing capacity. The method realizes acceleration of desilvering to reduce the processing time.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: August 9, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzo Kishimoto, Toshihiro Nishikawa, Akira Abe, Junya Nakajima
  • Patent number: 4725530
    Abstract: A silver halide color photographic material comprising a support and at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer on the support, which contains at least one cyan dye forming coupler represented by the general formula (I) and at least one cyan dye forming coupler represented by the general formula (II): ##STR1## wherein R.sub.1 represents --CONR.sub.5 R.sub.6, --NHCORhd 5, --NHCOOR.sub.7, --NHSO.sub.2 R.sub.7, --NHCONR.sub.5 R.sub.6 or --NHSO.sub.2 NR.sub.5 R.sub.6, R.sub.2 represents a group which can be substituted in the naphthol ring, m represents 0 or an integer of 1 to 3, R.sub.3 represents a monovalent group, R.sub.4 represents an aromatic group, and X and Y each represents a hydrogen atom or a group capable of leaving through a coupling reaction with an oxidized product of aromatic primary amine developing agent; R.sub.5 and R.sub.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: February 16, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Toshihiro Nishikawa
  • Patent number: 4695529
    Abstract: An image-forming process is disclosed, which comprises exposing a silver halide color photographic material comprising a support having provided thereon at least one silver halide emulsion layer containing tabular silver halide grains having a diameter-to-thickness ratio of 5 or more, subjecting the exposed photographic material to color development processing, then processing the photographic material in a bath mainly having a bleaching ability and successively in a bath having a bleach-fixing ability.
    Type: Grant
    Filed: October 15, 1986
    Date of Patent: September 22, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Abe, Junya Nakajima, Toshihiro Nishikawa
  • Patent number: 4623612
    Abstract: An improved method of developing silver halide photographic light-sensitive materials comprising at least one silver halide emulsion layer on a support is disclosed. In the improvement, said silver halide emulsion layer contains core/shell type silver halide grains having a shell thickness of 25 to 150 .ANG. wherein the surface of the core is subjected to chemical sensitization treatment and the surface of the shell is not subjected to chemical sensitization, and a developing solution contains a solvent for silver halide. It is possible to carry out spectral sensitization without causing a reduction in intrinsic sensitivity and to provide high-speed silver halide light-sensitive materials which are excellent in anti-fading property of latent images and excellent in stabilization with the passage of time using the above-described improved method.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: November 18, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Hatsumi Tanemura
  • Patent number: 4618573
    Abstract: A silver halide color photographic material containing a hardener capable of exerting a hardening effect through activation of a carboxyl group and a magenta coupler of the pyrazoloazole type, whereby lowering of color density of magenta images due to use of rapidly acting hardeners can be prevented.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: October 21, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hidetoshi Kobayashi, Toshihiro Nishikawa, Koji Tamoto