Abstract: Core-sheath filaments comprising a non-tacky sheath, the non-tacky sheath exhibiting a melt flow index of less than 15 grams per 10 minutes and an adhesive core, the adhesive core comprising 10 wt.% to 99 wt.% of a polymer and a phenolic resin, where the polymer comprises an isoprene moiety, the phenolic resin comprises an alkyl-substituted phenol, and the phenolic resin is substantially free of halogens. Cured adhesive composition comprising the disclosed core-sheath filaments and methods of making such core-sheath filaments.

Abstract: A composition is described comprising a styrene-isobutylene block copolymer; and at least one ethylenically unsaturated monomer. After curing the composition comprises polymerized units of the ethylenically unsaturated monomer. In some embodiments the ethylenically unsaturated groups are selected from (meth)acryl or vinyl ether. The composition is suitable for use as a (e.g. pressure sensitive) adhesive. Articles, methods of making an article, and methods of bonding are also described.

Abstract: A composition is described comprising a styrene-isobutylene block copolymer; and at least one ethylenically unsaturated monomer. After curing the composition comprises polymerized units of the ethylenically unsaturated monomer. In some embodiments the ethylenically unsaturated groups are selected from (meth)acryl or vinyl ether. The composition is suitable for use as a (e.g. pressure sensitive) adhesive. Articles, methods of making an article, and methods of bonding are also described.

Abstract: A system including a polymeric sheet. The polymeric sheet comprises a base sheet having a first surface and a second surface opposite the first surface and a multiplicity of spaced rails projecting from the first surface of the base sheet. The rails comprise a stem portion attached to and substantially upright from the first surface of the base sheet and a top portion on the distal end of the stem opposite the base sheet. The top portion comprises a first surface opposite the base sheet and a second surface facing the first surface of the base sheet. Additionally, the rails have a length greater than the width of the stems. The first surface of the base sheet, the second surface of the top portion and the surface of the stem defines a cavity with walls, and an adhesive coated on at least a portion of the cavity wall.

Abstract: Provided are amorphous polyolefin compositions that can be dispensed digitally as the core in a core-sheath construction. These formulations provide dependable adhesion to both polar and non-polar surface in addition to providing a high barrier to air and moisture which is beneficial in many applications. These formulations and the method of processing these formulations provide many benefits, including low VOCs, avoiding die cutting, design flexibility, achieving intricate nonplanar bonding patterns, printing on thin and/or delicate substrates, and printing on an irregular and/or complex topography, no need for release liners or low-adhesion backsize, and no need for a post-processing step.

Abstract: Core-sheath filaments are provided that comprise cores having diene-based rubbers that are crosslinked by multifunctional acrylates, resulting in superior high-temperature performance adhesives. The adhesive compositions have excellent durability against oxygen and moisture, low and stable dielectric properties, and superior high-temperature performance. Methods of making core-sheath filaments having cores including diene-based rubbers that are crosslinked by multifunctional acrylates and uses for such core-sheath filaments.

Abstract: A web. The web includes an array of discrete polymeric tubes; a plurality of spacer segments between at least a plurality of adjacent polymeric tubes; wherein polymeric tubes are hollow polymeric tubes; wherein the web is a continuous web.

Abstract: An adhesive composition is described comprising a polyisobutylene polymer component; and up to 30 wt.-% of at least one aliphatic multifunctional component comprising at least two ethylenically unsaturated groups selected from (meth)acryl or vinyl ether. The monomer comprises a hydrocarbon moiety with greater than 12 contiguous carbon atoms. When the hydrocarbon moiety is branched, the hydrocarbon moiety comprises side chains with at least two carbon atoms. The aliphatic multifunctional component is sufficiently compatible such that crosslinked adhesive composition at a thickness of 20 microns has a haze of less than 3%. Also described are adhesive articles.

Abstract: Compositions are described comprising at least 20 wt. % of block copolymer comprising polyvinyl aromatic end blocks and a polyisoprene midblock and at least one ethylenically unsaturated monomer comprising one or more groups selected from (meth)acryl or vinyl ether. In one embodiment, the monomer has a Log P according to Moriguchi's method of at least 2.2. In another embodiment, the monomer is a multifunctional aromatic ethylenically unsaturated monomer. The composition is typically a (e.g. pressure sensitive) adhesive. Also described are methods of making an article, adhesive articles, and methods of bonding.

Abstract: Coextruded polymeric netting having a machine direction comprising: a plurality of pairs of: first segments each having first and second opposed major surfaces and a thickness, the first segments comprising first material; second segments comprising second material, wherein adjacent first segments are joined together via a second segment, wherein the second segments extend from the second major surface past the first major surface of each first adjacent segment and has a distal end, the second segments having first and second opposed major surfaces, wherein there is a gap between adjacent second segments; and a third material, different from the first and second materials on at least one of the first or second major surfaces of at least every other second segment, wherein the first segments, second segments, and third material each extend continuously for at least 5 mm in the machine direction, and wherein first and second materials of adjacent pairs are periodically bonded together in the machine direction.

Abstract: Dust suppression compositions include at least one cationic or zwitterionic (meth)acrylate-based copolymer and at least one solvent, where the solvent can be water, an aqueous mixture, or one or more non-water solvents. The dust suppression composition can also include a plasticizer, generally glycerol. The dust suppression compositions are suitable for use with sand mixtures, especially silica sand mixtures.

Abstract: Article comprising first and second coextruded polymeric nettings, the first and second coextruded polymeric nettings each having a machine direction comprising: a plurality of pairs of: first segments each having first and second opposed major surfaces and a thickness, the first segments comprising first material; second segments comprising second material, wherein adjacent first segments are joined together via a second segment, wherein the second segments extend from the second major surface past the first major surface of each first adjacent segment and has a distal end, the second segments having first and second opposed major surfaces, wherein there is a gap between adjacent second segments; and a third material comprising adhesive, different from the first and second materials on at least one the first or second major surfaces first segment, wherein the first segments, second segments, and third material each extend continuously for at least 5 mm in the machine direction, and wherein first and second m

Abstract: A composition is described comprising a styrene-isobutylene block copolymer; and at least one ethylenically unsaturated monomer. After curing the composition comprises polymerized units of the ethylenically unsaturated monomer. In some embodiments the ethylenically unsaturated groups are selected from (meth)acryl or vinyl ether. The composition is suitable for use as a (e.g. pressure sensitive) adhesive. Articles, methods of making an article, and methods of bonding are also described.

Abstract: Coextruded polymeric article comprising first segments each having first and second opposed major surfaces and a thickness, the first segments comprising first material; second segments comprising second material, wherein adjacent first segments are joined together via a second segment, wherein at least 10 percent by number of the second segments extend from the second major surface past the first major surface of each first adjacent segment and has a distal end, the second segments having first and second opposed major surfaces, wherein there is a gap between adjacent second segments; and adhesive on the first and second major surfaces of at least every other second segment except a portion of the major surface adjacent to the respective distal end is free of the adhesive, wherein the first segments, second segments, and adhesive each extend continuously for at least 5 mm. Uses for coextruded polymeric articles described herein include adhesive articles and household cleaning products (e.g.

Abstract: In one embodiment, an adhesive composition is described comprising a polyisobutylene polymer component, a styrene-isobutylene block copolymer, and optionally a tackifier. The polyisobutylene polymer component comprises one or more polyisobutylene polymers. The polyisobutylene polymer component has an average weight average molecular weight ranging from 100 g/mole to less than 15,000 g/mole. In some embodiments, the adhesive composition is a pressure sensitive adhesive.

Abstract: The present disclosure relates to a curable pressure sensitive adhesive composition comprising: a) a butyl rubber component in an amount greater than 40 wt %; b) a tackifier in an amount greater than 1 wt %; c) a multifunctional crosslinking agent comprising at least two nitroso functional groups; and d) optionally, a hydrocarbon plasticizer; wherein the weight percentages are based on the total weight of the curable pressure sensitive adhesive composition. In another aspect, the present disclosure is directed to a method for protecting an electronic device or an electronic component from moisture and air permeation, wherein the method comprises the step of using a pressure sensitive adhesive composition as described above. According to still another aspect, the present disclosure is directed to the use of a pressure sensitive adhesive composition as described above for manufacturing an electronic device.

Abstract: Coextended polymeric article comprising a layer comprising first and second opposed major surfaces, wherein a plurality of attached projection pairs comprising first and second projections extend from only the first major surface (i.e., the second major surface is free of any projections), wherein each first projection has at least first and second opposed sides and a height from the first major surface to a distal end, wherein each first projection has at least first and second opposed sides and a height from the first major surface to a distal end. Uses for coextruded polymeric articles described herein include adhesive articles and household cleaning products (e.g., a mop, a duster, a brush, a cleaning cloth, or a lint roller).

Abstract: An adhesive composition are articles are described. The adhesive composition comprises a polyisobutylene polymer component; up to 20 wt.-% of a polyolefin copolymer comprising polymerized units of an acidic monomer; and optionally, at least one tackifier. The polyolefin copolymer typically comprises C2-C4 alkylene units. The polyolefin copolymer comprises polymerized units of a carboxylic acid, or unsaturated derivative thereof. In some embodiments, the polyolefin copolymer has a melting temperature ranging from 50 to 150° C. In some embodiments, the polyolefin copolymer has an acid number of less than 40, 35, 30, or 25 mgKOH/g.

Abstract: Coextruded polymeric article comprising first segments each having first and second opposed major surfaces and a thickness, the first segments comprising first material; second segments comprising second material, wherein adjacent first segments are joined together via a second segment, wherein the second segments extend from the second major surface past the first major surface of each first adjacent segment and has a distal end, the second segments having first and second oppose sides; first protrusions each extending from the first side of a second segment and extending no more than to the first major surface of the respective first segment adjacent to the second segment, the first protrusions comprising third material; and second protrusions each extending from the first side of a second segment, contacting the first protrusion extending from the second segment and extending not more than to the distal end of the second segment, the second protrusions comprising fourth material, wherein at least one of th

Abstract: Coextruded polymeric article (100, 200) comprising first and second opposed major surfaces (111, 211), wherein a plurality of projections (114, 117, 214, 214, 217) extend from only the first major surface (111, 112, 211, 212), wherein each projection (214) has at least first and second opposed sides (218) and a height from the first major surface (111, 112, 211, 212) to a distal end (116, 216), wherein at least a majority by number of the projections (114, 117, 214, 214, 217) have a protrusion (117, 217) extending from It only the first side (118, 218) and extending in one direction not more than to the first major surface (111, 112, 211, 212) and extending in an opposite direction to less than the height of the respective projection (214), wherein the projections (114, 117, 214, 214, 217) extend to the second major surface (111, 112, 211, 212), wherein there are regions (119, 120, 220) extending from the first and second major surfaces (111, 211) that are between projections (114, 117, 214, 214, 217), wherei