Patents by Inventor Walter Denzinger

Walter Denzinger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5286263
    Abstract: Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 -C.sub.40 -alkyl vinyl ethers, if necessary as a mixture with not more than 50 mol % of C.sub.8 -C.sub.40 -monoolefins, with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for imparting water repellency to leathers and skins.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: February 15, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Ortwin Schaffer, Herbert Bay, Karl Stork, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5279613
    Abstract: Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 --C.sub.40 -monoolefins with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides by mass polymerization at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for rendering leathers and skins water-repellent.
    Type: Grant
    Filed: February 5, 1992
    Date of Patent: January 18, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Ortwin Schaffer, Herbert Bay, Karl Stork, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5266165
    Abstract: Abstract of the Disclosure: Copolymers of (a) C.sub.12 - to C.sub.24 -monoolefins and (b) maleic anhydride or itaconic anhydride, having molecular weights of from 800 to 100,000 g/mol, in the form of partially or completely neutralized semiamides with morpholine, in aqueous solution or dispersion, can be used as sizes for paper.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: November 30, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Arnold DeClercq, Walter Denzinger, Norbert Greif, Heinrich Hartmann, Knut Oppenlaender, Ulrich Riebeling
  • Patent number: 5232603
    Abstract: Water-soluble copolymers which contain, polymerized in, as characteristic monomers(a) 99 to 50% by weight of monoethylenically unsaturated carboxylic acids with 3 to 8 carbon atoms or their salts and(b) 1 to 50% by weight of N-vinylimidazole or substituted N-vinylimidazoles, their salts or products of quaternization and which have K values of from 10 to 50 are used for water treatment to reduce deposits of scale and sludge in water-conveying systems.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: August 3, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Charalampos Gousetis, Ulrich Goeckel, Alfred Ruland
  • Patent number: 5227446
    Abstract: Graft copolymers obtainable by free radical-initiated copolymerization of(A) a monomer mixture comprising(a) a monoethylenically unsaturated C.sub.4 - to C.sub.8 -dicarboxylic acid, or an anhydride, alkali metal salt or ammonium salt thereof,(b) a monoethylenically unsaturated C.sub.3 - to C.sub.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: July 13, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Alexander Kud, Richard Baur, John Feldmann, Hans-Juergen Raubenheimer
  • Patent number: 5217813
    Abstract: In novel polyethyleneimine and polyvinylamine derivatives, the polyethyleneimines contain the structural elements Ia and/or Ib ##STR1## and the polyvinylamines contain the structural elements II.sub.a, II.sub.b and II.sub.c ##STR2## where, for the degrees of polymerization n, m and p, n.gtoreq.1, m.gtoreq.0 and p.gtoreq.0, and X.sup.1 is CR.sup.1 R.sup.2 PO.sub.3 R.sup.3 R.sup.4 or CR.sup.1 R.sup.2 SO.sub.3 R.sup.3, X.sup.2 independently of X.sup.1 is hydrogen, CR.sup.1 R.sup.2 PO.sub.3 R.sup.3 R.sup.4 or CR.sup.1 R.sup.2 SO.sub.3 R.sup.3, Y.sup.1 and Y.sup.2 independently of one another are each one or more CHR.sup.1 PO.sub.3 R.sup.3 R.sup.4 or CHR.sup.1 SO.sub.3 R.sup.3 groups or hydrogen, Y.sup.3 and Y.sup.4 independently of one another and of Y.sup.1 and Y.sup.2 are each hydrogen, CHR.sup.1 PO.sub.3 R.sup.3 R.sup.4 or CHR.sup.1 SO.sub.3 R.sup.3, and Z.sup.1 -Z.sup.4 are identical or different inorganic and/or organic radicals, wherein R.sup.1 and R.sup.2 independently of one another are each hydrogen, C.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: June 8, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Roser, Juergen Mohr, Armin Lange, Knut Oppenlaender, Walter Denzinger, Thomas Loerzer
  • Patent number: 5175361
    Abstract: A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: December 29, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Wolfgang Trieselt, Albert Hettche, Rolf Schneider, Hans-Juergen Raubenheimer
  • Patent number: 5145559
    Abstract: Paper, board and cardboard are produced by draining a paper stock, containing undesirable substances, in the presence of hydrolyzed homo- and/or copolymers of N-vinylformamide having a degree of hydrolysis of not less than 60% and a cationic retention aid. According to the invention, faster drainage and improved retention are obtained compared with the use of known fixing agents.
    Type: Grant
    Filed: January 16, 1991
    Date of Patent: September 8, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Auhorn, Friedrich Linhart, Primoz Lorencak, Michael Kroener, Norbert Sendhoff, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5126069
    Abstract: A detergent composition contains as essential ingredients surfactants and from 0.1 to 15% by weight of water-soluble or -dispersible polymers obtainable by oxidation of polymers containing not less than 10 mol % of carboxyl-containing monoethylenically unsaturated monomers as copolymerized units and having Fikentscher K values of from 8 to 300.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: June 30, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Kud, Richard Baur, Angelika Funhoff, Walter Denzinger, Heinrich Hartmann, Hans-Juergen Raubenheimer
  • Patent number: 5126395
    Abstract: Stable water-in-oil emulsions of a hydrolyzed polymer of an N-vinylamide of the formula ##STR1## where R and R.sup.1 are each H or C.sub.1 -C.sub.6 -alkyl, are prepared by polymerizing a compound of the formula I, alone or as a mixture with other monoethylenically unsaturated monomers, in the form of a water-in-oil emulsion to give a water-in-oil polymer emulsion, and then hydrolyzing the polymer, hydrolysis of the polymer in the form of the water-in-oil polymer emulsion being carried out in the presence of an acid or base, and additives in the form of antioxidants, reducing agents or aldehyde acceptors being added for stabilization.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: June 30, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Lutz End, Walter Denzinger, Michael Kroener, Norbert Sendhoff, Enrique Freudenberg, Friedrich Linhart, Rolf Fikentscher, Heinrich Hartmann
  • Patent number: 5124181
    Abstract: Copolymers which containa) from 50 to 90% by weight of C.sub.8 -C.sub.40 -alkyl methacrylates, vinyl esters of C.sub.8 -C.sub.40 -carboxylic acids or mixtures thereof andb) from 10 to 50% by weight of monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids, monoethylenically unsaturated dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids, amides of C.sub.3 -C.sub.12 -monocarboxylic acids or mixtures thereofas copolymerized units and have molecular masses of from 500 to 30,000 are used in at least partially neutralized form in aqueous solution or dispersion for making leather and furs water repellent.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: June 23, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Ortwin Schaffer, Herbert Bay, Karl Stork, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5098521
    Abstract: Paper, board and cardboard are produced from paper stocks containing foreign substances by drainage in the presence of a polymer which contains, as typical polymerized constituents, units of the formulae ##STR1## where R.sup.1 and R.sup.2 are each H, C.sub.1 -C.sub.3 -alkyl, and which have K values of not less than 130, the polymers containing less than 10 mol % of units of the formula II.
    Type: Grant
    Filed: January 9, 1991
    Date of Patent: March 24, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Enrique Freudenberg, Friedrich Linhart, Rainer Tresch, Heinrich Hartmann, Walter Denzinger, Michael Kroener, Norbert Sendhoff
  • Patent number: 5084535
    Abstract: Pulverulent polymers of acrylic acid and methacrylic acid are prepared by polymerizing (a) from 100 to 70% by weight of acrylic acid, methacrylic acid or a mixture thereof and (b) from 0 to 30% by weight of vinylsulfonic acid or an alkali metal salt thereof in a monohydric C.sub.1 -C.sub.8 -alcohol, water or a mixture thereof in a pulverulent bed in the presence of a polymerization initiator and from 0.05 to 10 mol % of thiocarboxylic acid and/or a mercaptoalcohol and from 0.05 to 10 mol % of propionic acid or formic acid as regulators, each percentage being based on the monomers used in the polymerization, by maintaining the pulverulent state during the polymerization, removing the heat of polymerization by distilling off the solvent and recirculating the reaction mixture.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: January 28, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Hennig, Heinrich Hartmann, Hans-Juergen Raubenheimer, Hermann Fischer, Walter Denzinger
  • Patent number: 5073269
    Abstract: Water-soluble copolymers of maleic acid useful as water treatment agents are prepared by copolymerizing(a) from 99 to 80% by weight of maleic anhydride and(b) from 1 to 20% by weight of a monoethylenically unsaturated monomer copolymerizable therewith and, facultatively,(c) up to 10% by weight of a crosslinker, at from 60.degree. to 200.degree. C. in an aromatic hydrocarbon in the presence of peroxyesters derived from saturated or monoethylenically unsaturated carboxylic acids, and hydrolyzing the anhydride groups of the copolymers following the polymerization.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: December 17, 1991
    Assignee: BASF Corporation
    Inventors: Walter Denzinger, Heinrich Hartmann, Ulrich Goeckel, Felix Richter, Hans-Juergen Raubenheimer, Ekhard Winkler
  • Patent number: 5026494
    Abstract: An amino group containing graft polymer comprising a main chain polymer having allyl amine grafted onto it whereby the main chain polymer is a hydrogenated olefin/diene copolymer and the total nitrogen content of the graft copolymer is from 0.001 to 0.05 weight percent.
    Type: Grant
    Filed: May 8, 1990
    Date of Patent: June 25, 1991
    Assignee: BASF
    Inventors: Walter Denzinger, Helmut Mach, Juergen Mohr, Knut Oppenlaender, Roland Schwen, Hans-Henning Vogel
  • Patent number: 5009805
    Abstract: Liquid detergent formulations contain as essential constituents a surfactant and 0.1-20% by weight of a copolymer which contains(a) 50-99 mol % of units of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, a half ester of a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, an ester of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a C.sub.2 -C.sub.30 -olefin, styrene, a C.sub.1 -C.sub.3 -alkylstyrene, a C.sub.1 -C.sub.28 -alkyl vinyl ether, a vinyl ester of a saturated C.sub.1 -C.sub.8 -monocarboxylic acid or a mixture thereof and(b) 50-1 mol % of units of an amide of a monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acid where the amide groups have the structure ##STR1## where R.sup.1 is C.sub.8 -C.sub.28 -alkyl or preferably ##STR2## R.sup.3 and R.sup.4 are each H, CH.sub.3 or C.sub.2 H.sub.5, R is C.sub.1 -C.sub.28 -alkyl,n is from 2 to 100 andR.sup.2 is H or R.sup.
    Type: Grant
    Filed: October 19, 1989
    Date of Patent: April 23, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Johannes Perner, Paul Diessel, Heinrich Hartmann, Walter Denzinger, Alfred Oftring, Willibald Schoenleben
  • Patent number: 5009670
    Abstract: Fuels for gasoline engines contain small amounts of copolymers of alkyl (meth)-acrylates where the alkyl radical is of 8 to 40 carbon atoms and/or vinyl esters of carboxylic acids of 8 to 40 carbon atoms and monoethylenically unsaturated mono- and/or dicarboxylic acids of 3 to 12 carbon atoms and/or monoethylenically unsaturated compounds having sulfo and/or phosphonic acid groups, having a total molecular weight of from 500 to 20,000 g per mole, some or all of the carboxyl, sulfo and phosphonic acid groups of the copolymers having been reacted with an alkali or alkaline earth with formation of the alkali metla salts or alkaline earth metal salts and the remainder of the acid groups having been reacted with ammonia and/or amines of not more than 50 carbon atoms to give the corresponding amide groups and/or ammonium salts.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: April 23, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz-Dieter Martischius, Hans-Henning Vogel, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5008032
    Abstract: Liquid, alkaline detergent formulations which contain as essential constituents a surfactant, water and 0.1-20% by weight of partially esterified copolymers are obtainable by the copolymerization of(a) one or more C.sub.4 -C.sub.28 -olefins and(b) ethylenically unsaturated dicarboxylic anhydrides of from 4 to 8 carbon atomsin a molar ratio of 1:1 and subsequent partial esterification of the copolymers of the reaction products(A) C.sub.1 -C.sub.30 -alcohols, C.sub.8 -C.sub.22 fatty acids, C.sub.1 -C.sub.12 -alkylphenols or secondary C.sub.2 -C.sub.30 -amines with(B) one or more C.sub.2 -C.sub.4 -alkylene oxides or tetrahydrofuranin a molar ratio of (A):(B) of from 1:2 to 1:50 and hydrolysis of the anhydride groups of the copolymer to carboxyl groups, the partial esterification of the copolymers being carried on until more than 5 to 50% of the carboxyl groups of the copolymers have been esterified.
    Type: Grant
    Filed: October 5, 1989
    Date of Patent: April 16, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Paul Diessel, Johannes Perner, Walter Denzinger, Heinrich Hartmann, Hans-Juergen Raubenheimer
  • Patent number: 5008321
    Abstract: Stable water-in-oil emulsions of hydrolyzed polymers of N-vinylamides of the formula ##STR1## where R and R.sup.1 are each H or C.sub.1 -C.sub.6 -alkyl are prepared by polymerization of a compound of the formula I alone or as a mixture with other monoethylenically unsaturated monomers, in the form of a water-in-oil emulsion, to give a water-in-oil polymer emulsion, and subsequent hydrolysis of the polymer, by a process in which hydrolysis of the polymer in the form of the water-in-oil polymer emulsion is carried out in the presence of an acid or base and of from 1 to 30% by weight, based on the polymer, of an emulsifier which is obtainable by(A) reacting a C.sub.10 -C.sub.22 -fatty alcohol with epichlorohydrin in a molar ratio of from 1:0.5 to 1:1.5 to give a glycidyl ether,(B) reacting the glycidyl ether with (1) a saturated C.sub.2 -C.sub.6 -alcohol containing from 2 to 6 OH groups or (2) its monoether with a C.sub.10 -C.sub.22 -fatty alcohol, in a molar ratio of glycidyl ether to (1) or (2) of from 1:0.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: April 16, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Norbert Sendhoff, Enrique Freudenberg
  • Patent number: 4978427
    Abstract: Water-soluble copolymers containing copolymerized vinylamine units are prepared by copolymerizing (a) from 95 to 10 mol % of N-vinylformamide and (b) from 5 to 90 mol % of an ethylenically unsaturated monomer from the group consisting of vinyl acetate, vinyl propionate, C.sub.1 -C.sub.4 -alkyl vinyl ethers, the esters, nitriles and amines of acrylic acid and methacrylic acid and N-vinylpyrrolidone, and then eliminating from 30 to 100 mol % of the formyl groups from the copolymer. Preferred copolymers are copolymers of N-vinyl-formamide and vinyl acetate, in which from 30 to 100 mol % of the monomer units are hydrolyzed. The copolymers are used in papermaking to increase the dry strength and wet strength of the paper.
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: December 18, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Sigberg Pfohl, Michael Kroener, Heinrich Hartmann, Walter Denzinger