Abstract: The present disclosure relates to a method for making an electrode material of lithium-ion batteries. In the method, a lithium source solution and a plurality of titanium source particles are provided. The lithium source solution and the titanium source particles are mixed, wherein a molar ratio of lithium element to titanium element is in a range from about 4:5 to about 9:10, thereby forming a sol. A carbon source compound is dispersed into the sol to form a sol mixture. The sol mixture is spray dried to form a plurality of precursor particles. The precursor particles are heated to form a lithium titanate composite electrode material.

Abstract: The present disclosure relates to a method for making an electrode material of lithium-ion batteries. In the method, a lithium source solution and a plurality of titanium source particles are provided. The lithium source solution and the titanium source particles are mixed, wherein a molar ratio of lithium element to titanium element is in a range from about 4:5 to about 9:10, thereby forming a sol. A carbon source compound is dispersed into the sol to form a sol mixture. The sol mixture is spray dried to form a plurality of precursor particles. The precursor particles are heated to form a lithium titanate composite electrode material.

Abstract: The present disclosure relates to a method for making an electrode material of lithium-ion batteries. In the method, a lithium source solution and a plurality of titanium source particles are provided. The lithium source solution and the titanium source particles are mixed, wherein a molar ratio of lithium element to titanium element is in a range from about 4:5 to about 9:10, thereby forming a sol. A carbon source compound is dispersed into the sol to form a sol mixture. The sol mixture is spray dried to form a plurality of precursor particles. The precursor particles are heated to form a lithium titanate composite electrode material.

Abstract: This disclosure is related to a method for making a phosphorated polymer for electrochemical reversible lithium storage. A mixture including organic polymer and phosphorus is first heated and then cooled down to room temperature. The mixture is immersed in an alkaline solution after cooling own to room temperature. The pH of the mixture is adjusted to be neutral after immersing in the alkaline solution. The alkaline solution is removed.

Abstract: A method for making a separator of a lithium ion battery is provided. In the method, a modifier, and a porous membrane are provided. The modifier is a mixture of a phosphorus source having a phosphate radical, a trivalent aluminum source, and a metallic oxide provided in a liquid phase solvent. The modifier is coated on a surface of the porous membrane to form a coating layer. The coated porous membrane is dried to form a modifier layer disposed on the surface of the porous membrane.

Abstract: This disclosure is related to a method for making a phosphorated polymer for electrochemical reversible lithium storage. A mixture including organic polymer and phosphorus is first heated and then cooled down to room temperature. The mixture is immersed in an alkaline solution after cooling own to room temperature. The pH of the mixture is adjusted to be neutral after immersing in the alkaline solution. The alkaline solution is removed.

Abstract: A method for making a phosphorated polymer is also provided. An organic polymer and phosphorus are mixed to obtain a mixture. A weight ratio of the organic polymer to the phosphorus ranges from about 1:10 to about 4:1. The mixture is dried in an inert atmosphere or vacuum. The mixture is heated in an inert atmosphere or vacuum so that the phosphorus sublimes and reacts with the organic polymer to form a preform. The preform is cooled down to room temperature and immersed in an alkaline solution. The pH of the preform is adjusted to be neutral. The preform is dried.

Abstract: A phosphorated composite capable of electrochemical reversible lithium storage includes a conductive matrix and red phosphorus. The conductive matrix includes a material being selected from the group consisting of conductive polymer and conductive carbonaceous material. A weight percentage of the conductive matrix in the phosphorated composite ranges from about 10% to about 85%. A weight percentage of the red phosphorus in the phosphorated composite ranges from about 15% to about 90%. An anode using the phosphorated composite is also provided.

Abstract: A method for making a modified current collector of a lithium ion battery is provided. In the method, the modifier and a metal plate are provided. The modifier is a mixture of a phosphorus source having a phosphate radical, a trivalent aluminum source, and a metallic oxide provided in a liquid phase solvent. The modifier is coated on a surface of the metal plate to form a coating layer. The coated metal plate is heat treated to transform the coating layer into a protective film formed on the surface of the metal plate.

Abstract: A method for making a phosphorated composite is provided. First, a mixture is obtained by mixing a source material with red phosphorus. The weight ratio of the source material to the red phosphorus ranges from about 1:10 to about 5:1. Second, the mixture is dried in an inert atmosphere or vacuum. Third, the mixture is heated in a reacting room filled with an inert atmosphere so that the red phosphorus sublimes. Finally, the reacting room is cooled down.

Abstract: The present disclosure relates to a method for making an electrode material of lithium-ion batteries. In the method, a carbon source compound is dissolved into a solvent to form a liquid phase solution. A number of titanium dioxide particles are provided and are dispersed into the liquid phase solution. The carbon source compound is pyrolyzed, thereby forming a number of carbon coating titanium dioxide particles. A lithium source solution is provided. The lithium source solution and the carbon coating titanium dioxide particles are mixed, according to a molar ratio in a range from about 4:5 to about 9:10, of lithium element to titanium element, thereby forming a sol. The sol is spray dried to form a number of precursor particles. The precursor particles are heated to form a lithium titanate composite electrode material.

Abstract: The present disclosure relates to a sulfurized polyacrylonitrile and a lithium-ion battery cathode active material. The sulfurized polyacrylonitrile includes a structural unit. A general molecular formula of the structural unit is C3HNSn, in which n is a positive integer. The lithium-ion battery cathode active material includes sulfurized polyacrylonitrile and a sulfurized polyacrylonitrile with inserted ions.

Abstract: An electrode slurry which includes an active component, a conductive agent, a binder, an organic solvent, and octylphenolpoly(ethyleneglycolether)x, wherein x=9˜10. The active component, conductive agent, binder, organic solvent, and octylphenolpoly(ethyleneglycolether)x are mixed together. An electrode of lithium battery includes a current collector, and a layer of electrode material applied on a surface of the current collector, wherein a material of the layer of electrode material comprises an active component, a conductive agent, a binder, and octylphenolpoly(ethyleneglycolether)x, wherein x=9˜10.

Abstract: The present disclosure relates to a piezoelectric sensor. The piezoelectric sensor includes a polymer layer, a first metal layer, and a second metal layer. The polymer layer includes pyrolytic polyacrylonitrile. The first metal layer is located on a surface of the polymer layer. The first metal layer includes a first work function. The second metal layer is located on another surface of the polymer layer and includes a second work function different from the first work function. The present disclosure also relates to a method for making the piezoelectric sensor.

Abstract: The present disclosure relates to a method for making a conjugated polymer. In the method, polyacrylonitrile, a solvent, and a catalyst are provided. The polyacrylonitrile is dissolved in the solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed into the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a conjugated polymer solution with the conjugated polymer dissolved therein.

Abstract: A phosphorated polymer includes a conductive polymer main-chain and a side-chain connected to the conductive polymer main-chain. The side-chain includes an electrochemically active phosphorated group Pm. A method for making the phosphorated polymer and a lithium-ion battery using the phosphorated polymer is also provided.

Abstract: A lithium-ion battery includes an anode, a cathode, and an electrolyte. The anode includes a phosphorated composite including a conductive matrix and a red phosphorus. The conductive matrix includes a material being selected from the group consisting of conductive polymer and conductive carbonaceous material. A weight percentage of the conductive matrix in the phosphorated composite ranges from about 10% to about 85%. A weight percentage of the red phosphorus in the phosphorated composite ranges from about 15% to about 90%.

Abstract: In a method for making sulfurized polyacrylonitrile, polyacrylonitrile, a first solvent, a catalyst, and sulfur or sodium thiosulfate are provided. The polyacrylonitrile is dissolved in the first solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed in the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a first conjugated polymer solution with a conjugated polymer. The sulfur or sodium thiosulfate is uniformly mixed with the conjugated polymer to form a mixture. The mixture is heated to form sulfurized polyacrylonitrile.

Abstract: A modifier of a lithium ion battery includes a clear solution fabricated from a phosphorous source having a phosphate radical, a trivalent aluminum source, and a metallic oxide provided in a liquid phase solvent. A molar ratio of the trivalent aluminum source, the metallic oxide, and the phosphorous source is set by (MolAl+MolMetal):Molp=about 1:2.5 to about 1:4. MolAl is the amount of substance of an aluminum element in the trivalent aluminum source, MolMetal is the amount of substance of a metallic element in the metallic oxide, and Molp is the amount of substance of a phosphorous element in the phosphorous source.

Abstract: An electrode composite material includes an individual electrode active material particle and a protective film coated on a surface of the particle. A composition of the protective film is AlxMyPO4, AlxMy(PO3)3, or a combination thereof. M represents at least one of Cr, Zn, Mg, Zr, Mo, V, Nb, or Ta. A valence of M is represented by k, in which 0<x<1, 0<y<1, and 3x+ky=3. In addition, a molar ratio of an aluminum element, an M element, and a phosphorous element in AlxMyPO4 or AlxMy(PO3)3 is set by (MolAl+MolMetal):Molp equal to about 1:2.5 to about 1:4, MolAl is the amount of substance of the aluminum element, MolMetal is the amount of substance of the M element, and Molp is the amount of substance of the phosphorous element. A lithium ion battery includes the electrode composite material.