Abstract: A nanocage-confined catalyst has the formula: NC-m[M(Salen1)X]-n[M?(Salen2)]. NC is a material having a nanocage structure, and M(Salen1)X and M? (Salen2) are active centers, respectively; each occurrence of M is independently selected from the group consisting of Co ion, Fe ion, Ga ion, Al ion, Cr ion, and a mixture thereof. Each occurrence of M? is independently selected from Cu ion, Ni ion and a mixture thereof, m is 0 to 100; n is 0 to 100, with the proviso that at least one of m and n is not 0; each occurrence of Salen1 and Salen2 is independently a derivative of Shiff bases; X is an axial anion selected from the group consisting of substituted or unsubstituted acetate, substituted or unsubstituted benzene sulfonate, substituted or unsubstituted benzoate, F—, Cl—, Br—, I—, SbF6-, PF6-, BF4-, and a mixture thereof.

Abstract: A hydrogenation-acid catalysis bifunctional catalyst, based on the mass of the catalyst, contains 80-99.8% of a silica-alumina molecular sieve component, 0.2-2% of a metal component with hydrogenation activity supported on the molecular sieve, and 0-20% of a hydrocarbyl modifying component. The hydrogenation active metal is selected from ruthenium, platinum, palladium, copper, nickel, or a combination thereof. The hydrocarbyl modifying component is a C1-20 hydrocarbyl. The catalyst has dual functions of hydrogenation and acid catalysis, and is suitable for benzene hydroalkylation reaction and alkane hydroisomerization reaction. It can be used in the benzene hydroalkylation to produce cyclohexylbenzene with high benzene conversion rate, high product selectivity, and less by-product cyclohexane.

Abstract: A SCM-34 molecular sieve, preparation method therefor and use thereof are provided. The SCM-34 molecular sieve contains aluminum, phosphorus, oxygen and optionally silicon. In the XRD diffraction data of the molecular sieve, a 2? degree of the strongest peak within the range of 5-50° is 7.59±0.2. The SCM-34 molecular sieve has a new skeleton structure and can be used to prepare a metal-containing AFI type molecular sieve or an SAPO-17 molecular sieve.

Abstract: A SCM-38 molecular sieve and preparation process and use thereof are provided. The SCM-38 molecular sieve is a phosphorus-aluminium or silicon-phosphorus-aluminium molecular sieve, which has the following diffraction peak feature in its XRD spectrum: X-ray diffraction peaks appear at 2? of 7.20±0.1, 10.81±0.1, 11.60±0.1, 14.32±0.1, 21.39±0.1, 21.83±0.1, 27.31±0.1, 28.72±0.1. The most intense peak appears at 2? of 7.20±0.1.

Abstract: A silicon-aluminum zeolite SCM-36, a manufacturing method therefor and an application thereof are provided. The zeolite has a silicon/aluminum ratio n?5, and has a distinctive XRD diffraction spectrum. The SCM-36 zeolite can be used as an adsorbent, a catalyst, or a catalyst carrier.

Abstract: A separator for a lithium-sulfur battery, a method for preparing the same and a lithium-sulfur battery containing the same are provided. The separator includes a polymeric substrate film and a composite layer on one surface of the polymeric substrate film. The composite layer has a SCM molecular sieve and a conductive carbon material. The SCM molecular sieve is selected from SCM-14 and SCM-15. The SCM molecular sieve further contains cobalt. The separator in accordance can effectively suppress the shuttle of polysulfides in lithium-sulfur batteries, and thereby reduce side reactions within the batteries, lower the self-discharge rate of lithium-sulfur batteries, and improve the cycling performances, rate performances, and storage life of the batteries.

Abstract: A biphasic solvent system for converting biomass to prepare 2,5-hexanedione and a one-pot process for catalytically converting biomass to prepare 2,5-hexanedione with said biphasic solvent system are provided. The process includes the steps of contacting and reacting a biomass raw material with a hydrogenation catalyst using hydrogen gas as a hydrogen source in a heterogeneous system formed from an organic solvent, an inorganic salt and water to obtain 2,5-hexanedione. The hydrogenation catalyst includes a hydrogenation active component and a support. The support is selected from one or more of hydrophobic active carbon and graphene. The process can achieve efficient conversion of biomass without the participation of acid catalysts, and have a very high selectivity for the product 2,5-hexanedione.

Abstract: A method for preparing paraxylene by biomass conversion includes the following steps: (1) contacting a biomass starting material with a hydrogenation catalyst for reaction in a multiphase system formed by an organic solvent, an inorganic salt and water, in the presence of hydrogen as a hydrogen source, and separating the resulting product to obtain an organic phase comprising 2,5-hexanedione; and (2) contacting the organic phase comprising 2,5-hexanedione obtained in the step (1) and ethylene with a molecular sieve catalyst for reaction to obtain paraxylene. The molecular sieve catalyst is at least one selected from the group consisting of aluminophosphate molecular sieves and SCM-14 molecular sieves.

Abstract: A discrete element method contact model building method includes: selecting a filling body in a disaster-causing structure to obtain a change rule of cumulative loss of the filling body; performing test simulation, and determining a relation function of each group of corresponding mesoscopic mechanical parameters in each time period and mesoscopic parameters of a DEM contact model representing a change rule of macroscopical parameters of the filling body; embedding each mesoscopic parameter relation function into an existing particle contact model, performing test simulation, and updating a fracture failure criterion of the contact model according to a corresponding relation of macro-mesoscopic strength during model failure; and based on a seepage failure indoor test, building a seepage failure discrete element calculation model, and simulating the seepage failure process of a rock and soil mass by using the obtained particle contact model and the fracture criterion of the particle contact model.

Abstract: A silicon-and germanium-based molecular sieve has a framework chemical composition as represented by the formula “SiO2.1/nGeO2”. The silicon/germanium molar ratio is 0.1n30. The molecular sieve has a unique X-ray diffraction pattern. It can be used in adsorptive separation, ion exchange, and catalytic conversion of organic compounds.

Abstract: The disclosed process relates to removal of benzene from a reformate stream and in turn providing gasoline and diesel products along with commodity chemicals (such as cyclohexylbenzene). The disclosed process further relates to the upgrading of heart-cut reformate benzene to higher value products.

Abstract: Disclosed is a device for twisting electrostatic spinning superfine fiber. The device comprises an outer sleeve and a middle sleeve, wherein the outer sleeve sleeves the middle sleeve, an annular gap is formed between the outer sleeve and the middle sleeve, a melt inlet communicating with the annular gap is formed in the outer sleeve, a conical hole is formed in the bottom end of the outer sleeve, the top end of the conical hole communicates with the bottom end of the annular gap, and the outer sleeve is wrapped with a heating ring used for heating a melt in the annular gap; a cylindrical metal rod is arranged in the middle sleeve in a penetrating mode, an interval is formed between the metal rod and the middle sleeve, the bottom end of the metal rod is fixedly connected with a circular truncated cone located below the conical hole.

Abstract: An aluminosilicate molecular sieve catalyst, its preparation and application thereof are provided. The catalyst shows a desorption curve having three peaks P1, P2 and P3 in its NH3-TPD pattern. The desorption temperatures corresponding to the summits of the three peaks P1, P2 and P3 are respectively in a range of 180-220° C., 250-290° C. and 370-410° C. The catalyst shows a higher activity, selectivity and stability when used for producing alkylaromatic hydrocarbons by gas-phase alkylation of aromatics with olefins.

Abstract: An aluminophosphate molecular sieve SCM-18 has a schematic chemical composition, expressed on a molar basis, of Al2O3.n P2O5, in which n represents a phosphorus to aluminum molar ratio, and is in a range of about 0.8-1.2. The aluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.

Abstract: A SCM-34 molecular sieve, preparation method therefor and use thereof are provided. The SCM-34 molecular sieve contains aluminum, phosphorus, oxygen and optionally silicon. In the XRD diffraction data of the molecular sieve, a 2? degree of the strongest peak within the range of 5-50° is 7.59±0.2. The SCM-34 molecular sieve has a new skeleton structure and can be used to prepare a metal-containing AFI type molecular sieve or an SAPO-17 molecular sieve.

Abstract: A novel silicoaluminophosphate molecular sieve has a schematic chemical composition, expressed on a molar basis, of mSiO2·Al2O3·nP2O5, in which m represents the molar ratio of SiO2 to Al2O3 and is in a range of about 0.005-0.15, and n represents the molar ratio of P2O5 to Al2O3 and is in a range of about 0.7-1.1. The silicoaluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.

Abstract: Disclosed is a system and a method for electrospinning superfine fiber bundling, belonging to the technical field of artificial fiber manufacturing, and comprises a spinning nozzle and a bundling disk which are coaxially arranged; the spinning nozzle is arranged at an upper part of the bundling disk; the bundling disk is connected with a motor through a coupling; the motor rotates to drive the bundling disk to rotate; a guide groove is also arranged outside the bundling disk; a center of the bundling disk is provided with a shaft; the insulated outer ring, the central conductive ring, the insulated inner ring and the shaft are fixed by bonding or thermal compounding; inner and outer edges of the central conductive ring are smooth circular arc rounded corners; an inner edge of the insulated outer ring and an outer edge of the insulated inner ring are corresponding smooth rounded corners.

Abstract: The invention relates to a molecular sieve composition, a process of preparing same and use thereof in the production of lower olefins. The molecular sieve composition comprises an aluminophosphate molecular sieve and a CO adsorbing component, both of which are present independently of each other. When the molecular sieve composition is used as a catalyst for producing lower olefins using synthesis gas as a raw material, the molecular sieve composition has the advantages of high selectivity to lower olefins and the like.

Abstract: A SCM-33 molecular sieve has a schematic chemical composition as shown in the formula “SiO2·1/x XO1.5·m MO0.5”, wherein X is a framework trivalent element, the Si/X molar ratio x is ?5, M is a framework equilibrium cation, and the M/Si molar ratio is 0 <m?1. The molecular sieve is a novel molecular sieve with RTE topology and the molecular sieve requires short preparation time, involves a low synthesis cost and can be used as adsorbent or catalyst.

Abstract: Disclosed is a system and a method for electrospinning superfine fiber bundling, belonging to the technical field of artificial fiber manufacturing, and comprises a spinning nozzle and a bundling disk which are coaxially arranged; the spinning nozzle is arranged at an upper part of the bundling disk; the bundling disk is connected with a motor through a coupling; the motor rotates to drive the bundling disk to rotate; a guide groove is also arranged outside the bundling disk; a center of the bundling disk is provided with a shaft; the insulated outer ring, the central conductive ring, the insulated inner ring and the shaft are fixed by bonding or thermal compounding; inner and outer edges of the central conductive ring are smooth circular arc rounded corners; an inner edge of the insulated outer ring and an outer edge of the insulated inner ring are corresponding smooth rounded corners.