Abstract: The present embodiments relate to systems and methods for automatic sign in upon account signup. Particularly, the present embodiments can utilize a federated login approach for automatic sign in upon account signup for a cloud infrastructure. Specifically, the signup and sign in service (also known as SOUP) and an identity provider portal can be configured such that the nodes are aware of each other as Security Assertion Markup Language (SAML) partners. After new account registration, the signup service can redirect the user browser to a cloud infrastructure console to start with a federated login flow, where a sign in service can issue a SAML authentication request, and redirects it to signup service. Responsive to validating the browser using a SAML authentication process, the browser can be automatically signed into the new account and allowed access the account relating to the cloud infrastructure service.

Abstract: Related are a high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether and a preparation method. During preparation, an allyl alcohol raw material and a supported catalyst Rb-NHPA are firstly added into a high-pressure reaction kettle, and it is heated after being replaced with a nitrogen gas; then after the internal temperature of the reaction kettle is raised to a reaction temperature, an ethylene oxide (EO) and propylene oxide (PO) mixture is continuously fed for a reaction; and finally, after the internal temperature of the reaction kettle is reduced, an acetic acid is dropwise added into the reaction kettle so that the crude product of the high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether is neutralized to be neutral. The refining process of a polyether is omitted, the process flow is greatly simplified, and the process time is effectively saved. In addition, the supported catalyst Rb-NHP may be recycled.

Abstract: The present invention relates to a method for preparing a polyether amine catalyst, and polyether amine. A polyether amine catalyst is a supported metal catalyst; ?-Al2O3 is used as a carrier; basic cupric carbonate, basic nickel carbonate and basic cobalt carbonate are used as precursors of supported metals; and the polyether amine catalyst is prepared by performing twice adsorption roasting and once reduction by means of an equivalent-volumetric impregnation method. Easier decomposition is achieved by using basic carbonate, and only water and carbon dioxide are generated, such that processes and costs for treating waste gases can be saved. By using the polyether amine catalyst to prepare polyether amine, a conversion rate and primary amine selectivity can be improved, and the color of products can be reduced. Therefore, the obtained polyether amine can have higher activity and wider application.

Abstract: Related are a high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether and a preparation method. During preparation, an allyl alcohol raw material and a supported catalyst Rb-NHPA are firstly added into a high-pressure reaction kettle, and it is heated after being replaced with a nitrogen gas; then after the internal temperature of the reaction kettle is raised to a reaction temperature, an ethylene oxide (EO) and propylene oxide (PO) mixture is continuously fed for a reaction; and finally, after the internal temperature of the reaction kettle is reduced, an acetic acid is dropwise added into the reaction kettle so that the crude product of the high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether is neutralized to be neutral. The refining process of a polyether is omitted, the process flow is greatly simplified, and the process time is effectively saved. In addition, the supported catalyst Rb-NHP may be recycled.

Abstract: In a log management method performed by a server, the server receives a transaction and generates a command log of the transaction. When detecting the transaction is a multi-partition transaction or a non-deterministic transaction, the server generates a data log of the transaction. When the server is faulty, the server recovers data according to the command log or the data log.

Abstract: The present invention relates to a supported catalyst used for synthesizing polyether amine, a preparation method, and an application. The supported catalyst introduces Mo and CeO2 into Ni and Cu active components. By means of the cooperation of Ni, Cu and Mo, CeO2 and Ni form more active sites, such that the supported catalyst can have high reaction activity and selectivity. By using the supported catalyst to synthesize polyether amine, the amination efficiency and selectivity of polyether polyol can be greatly enhanced, thereby preparing the polyether amine with light color and narrow molecular weight distribution. In addition, the cost of the catalyst can be reduced, a process condition is relatively mild, and the disadvantage of low reaction activity of a nickel-based catalyst in synthesizing small molecule polyether amine can be overcome, such that the supported catalyst has a desirable industrial application prospect.

Abstract: Provided are a system and a method for preparing a polyether amine by catalytic amination of a polyether diol. The preparation method includes: filling a catalyst into the fixed bed reactor; pressurizing the internal pressure of the fixed bed reactor to 10˜13 MPa by a hydrogen gas, and raising the temperature of the fixed bed reactor to 150˜185° C.; adjusting the temperature of the multi-stage preheater so that the feeding temperature of a raw material reaches 125˜135° C.; and simultaneously feeding a polyether diol, liquid ammonia and the hydrogen gas into the multi-stage preheater, and after mixing and preheating, introducing into the fixed bed reactor from the feed inlet of the fixed bed reactor for a continuous catalytic amination reaction. The total amine value of the polyether amine finally obtained by the present invention reaches 28˜32 mgKOH/g, the color reaches 10˜20, and it is colorless transparent liquid.

Abstract: The present disclosure discloses a synthesis method of polyether for a low-modulus sealant, belonging to the technical field of organic compound synthesis. In the synthesis method of the present disclosure, a reaction is performed by using a mixture of monohydric alcohol polyoxypropylene ether and polyhydric alcohol polyoxypropylene ether as a starter, using epoxypropane as a chain extender and adding a metal complex catalyst, so as to obtain the polyether for the low-modulus sealant after the reaction is ended. The polyether prepared in the present disclosure can not only well enhance the rigid strength of the sealant but also reduce the elasticity modulus of the sealant, overcoming the problem that the existing polyether silane modified sealant is high in modulus. The synthesis method of the present disclosure is simple in synthesis process, easy to produce and control, short in production period and low in energy consumption.

Abstract: The disclosure provides a preparation process of an allyl alcohol polyether with a low potassium and sodium content, comprising the following steps: reacting allyl alcohol with a mixture of epoxypropane and oxacyclopropane to prepare an allyl alcohol oligomer crude product with a molecular weight of 150-1500; reducing the total content of potassium and sodium ions in the allyl alcohol oligomer crude product prepared in step S1 to 2 ppm or less through a cation exchange resin; and reacting the allyl alcohol oligomer product treated in step S2 with the mixture of epoxypropane and oxacyclopropane to prepare allyl alcohol high-molecular-weight polyether with a molecular weight of 2000-5000. According to the present disclosure, the total content of potassium and sodium ions in the product is reduced to 2 ppm or less, and the product has a good double bond protection rate.

Abstract: The present invention relates to a synthesis method and synthesis reactor of high-selectivity 2-methylallyl chloride by taking isobutylene and chlorine gas as raw materials and performing a gas-phase chlorination reaction in a microchannel reactor with a cooling surface. The isobutylene and the chlorine gas are reacted in a T-shaped microchannel reactor, and the mixing speed is extremely fast. Meanwhile, the huge heat exchange area per unit volume can ensure that the reaction proceeds stably at a substantially constant temperature and has good controllability. Therefore, side reactions caused by excessive local temperature can be effectively suppressed, the reaction selectivity is high, and no coking phenomenon occurs.

Abstract: The present invention relates to a synthesis method and synthesis reactor of high-selectivity 2-methylallyl chloride by taking isobutylene and chlorine gas as raw materials and performing a gas-phase chlorination reaction in a microchannel reactor with a cooling surface. The isobutylene and the chlorine gas are reacted in a T-shaped microchannel reactor, and the mixing speed is extremely fast. Meanwhile, the huge heat exchange area per unit volume can ensure that the reaction proceeds stably at a substantially constant temperature and has good controllability. Therefore, side reactions caused by excessive local temperature can be effectively suppressed, the reaction selectivity is high, and no coking phenomenon occurs.

Abstract: In a log management method performed by a server, the server receives a transaction and generates a command log of the transaction. When detecting the transaction is a multi-partition transaction or a non-deterministic transaction, the server generates a data log of the transaction. When the server is faulty, the server recovers data according to the command log or the data log.

Abstract: An approach is provided that assists visually impaired users. The approach analyzes a document that is being utilized by the visually impaired user. The analysis derives a sensitivity of the document. A vocal characteristic corresponding to the derived sensitivity is retrieved. Text from the document is audibly read to the visually impaired user with a text to speech process that utilizes the retrieved vocal characteristic. The retrieved vocal characteristic conveys the derived sensitivity of the document to the visually impaired user.

Abstract: An approach is provided that assists visually impaired users. The approach analyzes a document that is being utilized by the visually impaired user. The analysis derives a sensitivity of the document. A vocal characteristic corresponding to the derived sensitivity is retrieved. Text from the document is audibly read to the visually impaired user with a text to speech process that utilizes the retrieved vocal characteristic. The retrieved vocal characteristic conveys the derived sensitivity of the document to the visually impaired user.

Abstract: An approach is provided that assists visually impaired users. The approach analyzes a document that is being utilized by the visually impaired user. The analysis derives a sensitivity of the document. A vocal characteristic corresponding to the derived sensitivity is retrieved. Text from the document is audibly read to the visually impaired user with a text to speech process that utilizes the retrieved vocal characteristic. The retrieved vocal characteristic conveys the derived sensitivity of the document to the visually impaired user.

Abstract: An approach is provided that assists visually impaired users. The approach analyzes a document that is being utilized by the visually impaired user. The analysis derives a sensitivity of the document. A vocal characteristic corresponding to the derived sensitivity is retrieved. Text from the document is audibly read to the visually impaired user with a text to speech process that utilizes the retrieved vocal characteristic. The retrieved vocal characteristic conveys the derived sensitivity of the document to the visually impaired user.

Abstract: A method, system and computer program product for providing contextual relevance of an unposted message to an activity stream after a period of time elapses. A comparison is made between the current state of the activity stream at a second point in time with respect to the state of the activity stream at a first point in time, which includes an unposted message. The relevance of the unposted message with respect to a current topic of interest in the activity stream at the second point in time is quantified. If the contextual relevance of the unposted message with respect to the current topic of interest in the activity stream at the second point in time is less than a threshold, then the user is presented with an indication of the contextual relevance of the unposted message to the activity stream.

Abstract: A method, system and computer program product for providing contextual relevance of an unposted message to an activity stream after a period of time elapses. A comparison is made between the current state of the activity stream at a second point in time with respect to the state of the activity stream at a first point in time, which includes an unposted message. The relevance of the unposted message with respect to a current topic of interest in the activity stream at the second point in time is quantified. If the contextual relevance of the unposted message with respect to the current topic of interest in the activity stream at the second point in time is less than a threshold, then the user is presented with an indication of the contextual relevance of the unposted message to the activity stream.

Abstract: A method, system and computer program product for providing contextual relevance of an unposted message to an activity stream after a period of time elapses. A comparison is made between the current state of the activity stream at a second point in time with respect to the state of the activity stream at a first point in time, which includes an unposted message. The relevance of the unposted message with respect to a current topic of interest in the activity stream at the second point in time is quantified. If the contextual relevance of the unposted message with respect to the current topic of interest in the activity stream at the second point in time is less than a threshold, then the user is presented with an indication of the contextual relevance of the unposted message to the activity stream.

Abstract: A method, system and computer program product for providing contextual relevance of an unposted message to an activity stream after a period of time elapses. A comparison is made between the current state of the activity stream at a second point in time with respect to the state of the activity stream at a first point in time, which includes an unposted message. The relevance of the unposted message with respect to a current topic of interest in the activity stream at the second point in time is quantified. If the contextual relevance of the unposted message with respect to the current topic of interest in the activity stream at the second point in time is less than a threshold, then the user is presented with an indication of the contextual relevance of the unposted message to the activity stream.