Abstract: A plant diagnostic system and method for plant process control and analysis comprising one or more sensors configured to collect and report compositional operation information of the equipment in the plant or refinery in real-time. At least one of the one or more sensors may be selected from a group of GC, GCxGC, micro GC, micro GCxGC, or combinations thereof. The diagnostic system may comprise a detection platform, an analysis platform, a visualization platform, and/or an alert platform.

Abstract: A hydroprocessing catalyst with improved performance has been produced that involves an intimately mixed unsupported metal oxide with a zeolite or other acid function. The intimate mixing allows an intimate interaction between the unsupported metal oxide and the acid function. The hydroprocessing catalyst may be used alone or may be incorporated with a portion of a conventional hydrocracking catalyst.

Abstract: A hydroprocessing catalyst with improved performance has been produced that involves an intimately mixed unsupported metal oxide with a zeolite or other acid function. The intimate mixing allows an intimate interaction between the unsupported metal oxide and the acid function. The hydroprocessing catalyst may be used alone or may be incorporated with a portion of a conventional hydrocracking catalyst.

Abstract: A plant diagnostic system and method for plant process control and analysis comprising one or more sensors configured to collect and report compositional operation information of the equipment in the plant or refinery in real-time. At least one of the one or more sensors may be selected from a group of GC, GCxGC, micro GC, micro GCxGC, or combinations thereof The diagnostic system may comprise a detection platform, an analysis platform, a visualization platform, and/or an alert platform.

Abstract: A unique crystalline mixed transition metal tungstate material has been developed material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Abstract: A unique crystalline transition metal molybdotungstate material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Abstract: A new crystalline aluminosilicate zeolite comprising a new framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions. The calcined zeolite is used in hydrocarbon conversion reactions.

Abstract: A new crystalline aluminosilicate zeolite comprising a novel framework has been synthesized that has been designated UZM-55. This zeolite is represented by a three-dimensional framework of at least SiO2 tetrahedral units and an empirical composition in the as-synthesized and anhydrous basis expressed by an empirical formula of: Mmn+RrAlxEySiOz where M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, R is a structure directing agent or agents such as 1,6-bis(N-methylpiperidinium)hexane, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions including methanol to hydrocarbons (MTH).

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-77 has been synthesized. These metallophosphates are represented by the empirical formula HxMm2+EPxSiyOz where M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-77 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for adsorption applications.

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-78 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-78 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

Abstract: A new crystalline aluminosilicate zeolite comprising a new framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions. The calcined zeolite is used in hydrocarbon conversion reactions.

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-91 has been synthesized. These metallophosphates are represented by the empirical formula Cc+Aa+Mm2+EPxSiyOz where M is a divalent framework metal such as magnesium or zinc, C is a cyclic organoammonium cation, A is an acyclic organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-91 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

Abstract: A unique crystalline transition metal molybdotungstate material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Abstract: A unique crystalline mixed transition metal tungstate material has been developed material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-92 has been synthesized. These metallophosphates are represented by the empirical formula Cc+Aa+Mm2+EPxSiyOz where M is a divalent framework metal such as magnesium, C is a cyclic organoammonium cation, A is an acyclic organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-92 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

Abstract: A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions.

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-78 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-78 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

Abstract: A new family of crystalline microporous metallophosphates designated AlPO-77 has been synthesized. These metallophosphates are represented by the empirical formula HxMm2+EPxSiyOz where M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-77 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for adsorption applications.

Abstract: A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions.

Abstract: A new crystalline aluminosilicate zeolite comprising a novel framework has been synthesized that has been designated UZM-55. This zeolite is represented by a three-dimensional framework of at least SiO2 tetrahedral units and an empirical composition in the as-synthesized and anhydrous basis expressed by an empirical formula of: Mmn+RrAlxEySiOz where M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, R is a structure directing agent or agents such as 1,6-bis(N-methylpiperidinium)hexane, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions including methanol to hydrocarbons (MTH).