Patents by Inventor William E. Garwood

William E. Garwood has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4717465
    Abstract: A novel process is disclosed for the production of high boiling jet fuels which comprises contacting a chargestock with an end boiling point of about 750.degree. F. with ZSM-22 under carefully controlled conditions of temperature and pressure and blending the 330.degree. F. plus fraction with a conventional jet fuel in order to obtain a product having acceptable jet fuel properties and having a high boiling range.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: January 5, 1988
    Assignee: Mobil Oil Corporation
    Inventors: Nai Y. Chen, William E. Garwood
  • Patent number: 4684756
    Abstract: The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel.
    Type: Grant
    Filed: May 1, 1986
    Date of Patent: August 4, 1987
    Assignee: Mobil Oil Corporation
    Inventors: W. Rodman Derr, Jr., William E. Garwood, James C. Kuo, Tiberiu M. Leib, Donald M. Nace, Samuel A. Tabak
  • Patent number: 4665253
    Abstract: Feedstock comprising aromatic compounds is converted by isomerization, alkylation, disproportionation or transalkylation to product comprising aromatic compounds which differs from the feedstock over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
    Type: Grant
    Filed: October 29, 1985
    Date of Patent: May 12, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Pochen Chu, William E. Garwood
  • Patent number: 4665265
    Abstract: Feedstock comprising C.sub.2.sup.+ olefins, C.sub.2 -C.sub.7 paraffins or a mixture thereof is converted to product comprising C.sub.5.sup.+ hydrocarbon compounds over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
    Type: Grant
    Filed: October 29, 1985
    Date of Patent: May 12, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Pochen Chu, William E. Garwood
  • Patent number: 4665269
    Abstract: Feedstock comprising oxygenates is converted to product comprising hydrocarbons over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
    Type: Grant
    Filed: October 29, 1985
    Date of Patent: May 12, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Pochen Chu, William E. Garwood
  • Patent number: 4618737
    Abstract: High viscosity lubricants are formed by oligomerizing olefins in two stages. The first stage converts a lower olefin feed to distillate range hydrocarbons in the presence of an aluminosilicate zeolite such as ZSM-5. The distillate effluent from the first stage is further polymerized to lubricant range hydrocarbons at elevated temperatures in the presence of a ditertiary alkylperoxide catalyst.
    Type: Grant
    Filed: December 13, 1985
    Date of Patent: October 21, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Arthur W. Chester, William E. Garwood, Samuel A. Tabak
  • Patent number: 4605488
    Abstract: Relatively heavy and relatively light lube chargestocks are dewaxed in two parallel, separate reactors. The reactor used for dewaxing the relatively light chargestock contains a crystallize zeolite having pore openings defined by: (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P.sub.o of 0.1 and at a temperature of 50.degree. C. for n-hexane and 80.degree. C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane (3MP) in preference to the doubly branched 2,3-dimethylbutane (DMB) at 1000.degree. F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methyl-pentane/2,3-dimethylbutane, with the ratio of rate constants k.sub.3MP /k.sub.DMB determined at a temperature of 1000.degree. F. being in excess of about 2, e.g., natural and synthetic ferrierite, ZSM-22, ZSM-23, ZSM-35 and mixtures thereof.
    Type: Grant
    Filed: May 13, 1985
    Date of Patent: August 12, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Arthur W. Chester, William E. Garwood, James C. Vartuli
  • Patent number: 4574043
    Abstract: The invention relates to a process for catalytically hydrodewaxing hydrocarbon feedstocks over zeolite ZSM-22 to produce high yields of low pour, high viscosity index hydrocracked lubricating oil stock.
    Type: Grant
    Filed: November 19, 1984
    Date of Patent: March 4, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Arthur W. Chester, William E. Garwood, James C. Vartuli
  • Patent number: 4564440
    Abstract: Partial desulfurization in the range of about 30-90% during hydrotreating of a dewaxed lube oil basestock provides an increase in viscosity index of up to five numbers with less than about 5 wt. % yield loss, a consequence of the desulfurized compounds staying in the lube boiling range.
    Type: Grant
    Filed: July 11, 1983
    Date of Patent: January 14, 1986
    Assignee: Mobil Oil Corporation
    Inventors: William E. Garwood, William C. Starr, John W. Walker
  • Patent number: 4563435
    Abstract: High silica-containing zeolites having substantially no acid activity are enhanced by reacting the same with a solid binder such as alumina in the presence of water. Hydrocarbon conversion utilizing said enhanced zeolites is also disclosed.
    Type: Grant
    Filed: June 13, 1984
    Date of Patent: January 7, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Pochen Chu, William E. Garwood
  • Patent number: 4549396
    Abstract: Utilizing air, rather than oxygen, to convert coal to synthesis gas containing very high proportions of inert nitrogen; subjecting this entire gas, possibly with intermediate cleanup, e.g., sulfur removal, to conversion over a special metal-zeolite catalyst to produce a product comprising C.sub.5 to C.sub.11 normally liquid hydrocarbons, a gas containing C.sub.1 to C.sub.4 hydrocarbons, carbon dioxide and large proportions of nitrogen, and an aqueous product comprising water; utilizing the gas product to run electric power generation equipment, such as a direct fired turbine, at base load levels; storing and accumulating the liquid product; and intermittently using the liquid product for electric power generation to meet higher than base loads, including peak load situations.
    Type: Grant
    Filed: January 18, 1982
    Date of Patent: October 29, 1985
    Assignee: Mobil Oil Corporation
    Inventors: William E. Garwood, James C. Kuo, Solomon M. Jacob, John J. Wise
  • Patent number: 4547613
    Abstract: Hydrocarbon streams containing primarily olefins such as ethylene up to and inclusive of C.sub.16 olefins are converted at elevated pressures to high viscosity index lube oil base stock by contacting them with a ZSM-5 type zeolite catalyst which has been conditioned by previous contact with a light olefin preferably of 3-6 carbon atoms per molecule under suitable conditions of temperature and pressure.
    Type: Grant
    Filed: July 10, 1984
    Date of Patent: October 15, 1985
    Assignee: Mobil Oil Corporation
    Inventors: William E. Garwood, Hans J. Schoennagel
  • Patent number: 4524232
    Abstract: A combination process for producing high viscosity index lubes from light olefins is provided wherein light olefins are first passed over a small pore zeolite and the liquid product therefrom is then processed over an intermediate pore zeolite to provide a lubricating oil with a higher viscosity, high Viscosity Index and low pour point in greater yield than obtained with either of the catalysts alone.
    Type: Grant
    Filed: January 4, 1984
    Date of Patent: June 18, 1985
    Assignee: Mobil Oil Corporation
    Inventors: Arthur W. Chester, William E. Garwood, Stanley J. Lucki, Samuel A. Tabak
  • Patent number: 4517399
    Abstract: An improved process for the production of high viscosity lubricating oils obtained by reacting olefins over ZSM-5 type zeolites at elevated temperatures and pressures in order to obtain a liquid product and thereafter recovering a lube oil fraction from said liquid product is disclosed. The improvement resides in the use of large crystal ZSM-5 which has been found to enhance the viscosity index of lubes produced from olefins.
    Type: Grant
    Filed: August 9, 1984
    Date of Patent: May 14, 1985
    Assignee: Mobil Oil Corporation
    Inventors: Arthur W. Chester, William E. Garwood, Albert B. Schwartz
  • Patent number: 4463101
    Abstract: An improved catalyst composition is disclosed for converting synthesis gas to hydrocarbon mixtures. The catalyst comprises an iron-containing, Fischer-Tropsch catalyst and a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+M.sub.2 /.sub.n O):SiO.sub.2 rate of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified X-ray diffraction pattern.
    Type: Grant
    Filed: November 24, 1982
    Date of Patent: July 31, 1984
    Assignee: Mobil Oil Corporation
    Inventors: Francis G. Dwyer, William E. Garwood
  • Patent number: 4441991
    Abstract: Straight-chain hydrocarbons and slightly branched chain hydrocarbons are selectively converted utilizing highly siliceous porous crystalline materials of the zeolite type having SiO.sub.2 /Al.sub.2 O.sub.3 ratio of greater than 200, unique molecular sieving properties and superior resistance to ammonia deactivation. The catalyst preferably contains acidic cations and can also contain a component having a hydrogenation/dehydrogenation function. The process of this invention is particularly useful for the dewaxing of hydrocarbon oils, including removal of high freezing point paraffins from jet fuel to lower freezing point, as well as improving the octane rating of naphtha fractions.
    Type: Grant
    Filed: October 20, 1982
    Date of Patent: April 10, 1984
    Assignee: Mobil Oil Corporation
    Inventors: Francis G. Dwyer, William E. Garwood
  • Patent number: 4414097
    Abstract: This invention relates to an energy-efficient process for dewaxing hydrocrackate and manufacturing a stabilized and dewaxed hydrocracked lubricating oil stock from hydrocarbon feedstock boiling above about 343.degree. C.
    Type: Grant
    Filed: April 19, 1982
    Date of Patent: November 8, 1983
    Assignee: Mobil Oil Corporation
    Inventors: Arthur W. Chester, William E. Garwood
  • Patent number: 4413153
    Abstract: The synthetic fuel slate of products derived from wet natural gas is expanded to include both aromatic gasoline from the methane rich dry gas portion via steam reforming to synthesis gas, the production of methanol from synthesis gas and the conversion of methanol to gasoline over a ZSM-5 type catalyst, plus high quality jet fuel, diesel fuel and lubricating oils from the C.sub.3.sup.+ paraffin rich fraction of wet natural gas via thermal cracking of the paraffin rich fraction to olefins and the conversion of the olefins to gasoline and distillate boiling range hydrocarbons over a ZSM-5 type catalyst. Methane separated from the thermal cracked product can be mixed with the dry gas fraction for synthesis gas production and a portion of the hydrogen from the synthesis gas may be used to hydrogenate the distillate fraction from the catalytic conversion of the thermal cracked product.
    Type: Grant
    Filed: October 22, 1982
    Date of Patent: November 1, 1983
    Assignee: Mobil Oil Corporation
    Inventors: William E. Garwood, Wooyoung Lee
  • Patent number: 4376036
    Abstract: A process for the manufacture of high quality lubricating oils having a high viscosity index and low pour point is disclosed which comprises catalytically dewaxing a lubricating oil stock by contacting the same in the presence of hydrogen over a zeolite such as ZSM-5 which has been silica-modified.
    Type: Grant
    Filed: March 6, 1981
    Date of Patent: March 8, 1983
    Assignee: Mobil Oil Corporation
    Inventors: William E. Garwood, Paul G. Rodewald, Nai Y. Chen
  • Patent number: 4361503
    Abstract: An improved catalyst composition is disclosed for converting synthesis gas to hydrocarbon mixtures. The catalyst comprises an iron-containing, Fischer-Tropsch catalyst and a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+M.sub.2 /.sub.n O):SiO.sub.2 rate of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified x-ray diffraction pattern.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: November 30, 1982
    Assignee: Mobil Oil Corporation
    Inventors: Francis G. Dwyer, William E. Garwood