Patents by Inventor William P. Hettinger

William P. Hettinger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4425259
    Abstract: A process is disclosed for the conversion of high boiling oil feeds having a significant level of Conradson carbon components and metals to form lighter oil products by contacting the feed under catalytic conversion conditions with a catalyst containing one of a select group of metal additives to catalyze the endothermic removal of carbon with CO.sub.2. Conversion conditions are such that hydrocarbonaceous material and metals are deposited to deactivate the catalyst in the conversion zone. Deactivated catalyst is partially regenerated in the presence of carbon dioxide containing gas before or after oxygen regeneration at a temperature below 1600.degree. F. to provide a regenerated catalyst which is recycled to the conversion zone for further contact with fresh feed. The metal additive is present on the catalyst in an amount sufficient to catalyze the endothermic removal of carbonaceous material in the presence of a carbon dioxide rich gas at regeneration temperature below 1500.degree. F.
    Type: Grant
    Filed: August 5, 1981
    Date of Patent: January 10, 1984
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., Stephen M. Kovach, James F. Hoffman
  • Patent number: 4424116
    Abstract: A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650.degree. F.+ material which is characterized by a carbon residue on pyrolysis of at least about 1 and a Nickel Equivalents of heavy metals content of at least about 4 parts per million. This process comprises flowing the carbo-metallic oil together with particulate cracking catalyst through a progressive flow type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a predetermined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900.degree. to about 1400.degree. F., and under a pressure of about 10 to about 50 pounds per square inch absolute sufficient for causing a conversion per pass in the range of about 40% to 90% while producing coke in amounts in the range of about 6 to about 14% by weight based on fresh feed, and laying down coke on the catalyst in amounts in the range of about 0.
    Type: Grant
    Filed: March 25, 1982
    Date of Patent: January 3, 1984
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4414098
    Abstract: A process is disclosed for upgrading a hydrocarbon oil feed having a significant content of metals, especially vanadium, to provide a higher grade of oil products by contacting the feed under sorbing conditions in an upgrading zone with a high surface area, high pore volume sorbent material containing an added alkaline metal to neutralize acidic cracking sites. Upgrading conditions are such that coke and metals are deposited on the sorbent in the upgrading zone. Coked sorbent is regenerated by contact with an oxygen containing gas under regeneration conditions to remove the coke, and regenerated sorbent is recycled to the upgrading zone for contact with fresh feed. The added alkaline metal is present on the sorbent in an amount sufficient to neutralize substantially all of the acidic cracking sites and provide a sorbent material having a MAT relative activity in the range of about 0 to about 1 percent.
    Type: Grant
    Filed: July 30, 1981
    Date of Patent: November 8, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: Oliver J. Zandona, William P. Hettinger, Jr.
  • Patent number: 4412914
    Abstract: A process is disclosed for decarbonization-demetallization of a poor quality residual oil feed boiling above about 650.degree. F. and comprising substantial Conradson carbon components to provide a higher grade of oil feed by contacting the poor quality oil feed with sorbent particle material containing one or more metal additives selected to catalyze the endothermic removal of coke with CO.sub.2. Sorbent decarbonization conditions are selected so that substantial quantities of carbonaceous material and metals are deposited on the sorbent in the decarbonizing zone. Sorbent material with metals and hydrocarbonaceous deposits is regenerated in the presence of an oxygen and carbon dioxide containing gas streams in separate sorbent regeneration zones at a temperature sufficiently elevated to remove residual coke to a desired low level. Regenerated sorbent particle material at an elevated temperature below about 1500.degree. F.
    Type: Grant
    Filed: August 10, 1981
    Date of Patent: November 1, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., James F. Hoffman, Stephen M. Kovach
  • Patent number: 4407714
    Abstract: A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650.degree. F..sup.+ material, at least a portion of said 650.degree. F..sup.+ material containing components which will not boil before about 1025.degree. F., said 650.degree. F..sup.+ material further being characterized by a carbon residue on pyrolysis of at least about 1 and a Nickel Equivalents of heavy metals content of at least about 4 parts per million. This process comprises providing a cracking catalyst having an average pore volume of at least about 0.2 cc per gram and an average particle diameter in the range of about 20 microns to about 150 microns, flowing the carbo-metallic oil together with the cranking catalyst through a progressive flow type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a predetermined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900.degree. to about 1400.
    Type: Grant
    Filed: May 13, 1981
    Date of Patent: October 4, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: George D. Myers, deceased, William P. Hettinger, Jr., Stephen M. Kovach
  • Patent number: 4406773
    Abstract: A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650.degree. F. plus material which is characterized by a carbon residue on pyrolysis of at least about 1 and a Nickel Equivalent of heavy metals content of at least about 4 parts per million. This process comprises flowing the carbo-metallic oil together with particulate cracking catalyst through a progressive flow-type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a predetermined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900.degree. to about 1400.degree. F., and under a pressure of about 10 to about 50 pounds per square inch absolute sufficient for causing a conversion per pass in the range of about 50% to about 90% while producing coke in amounts in the range of about 6 to about 14% by weight based on fresh feed, and laying down coke on the catalyst in amounts in the range of about 0.
    Type: Grant
    Filed: May 13, 1981
    Date of Patent: September 27, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., Roger M. Benslay
  • Patent number: 4377470
    Abstract: A process is disclosed for catalytic cracking a hydrocarbon oil feed having significant vanadium content to produce lighter products. The catalyst, from the cracking step, coated with coke and vanadium in an oxidation state less than +5, is regenerated in the presence of an oxygen-containing gas at a temperature high enough to burn off a portion of the coke under conditions keeping the vanadium in an oxidation state less than +5.
    Type: Grant
    Filed: April 28, 1981
    Date of Patent: March 22, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., James D. Carruthers, William D. Watkins
  • Patent number: 4374019
    Abstract: A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650.degree. F.+ material which is characterized by containing material which will not boil below about 1025.degree. F., a carbon residue on pyrolysis of at least about 1 and a Nickel equivalents of heavy metals content of at least about 4 parts per million. This process comprises flowing the carbo-metallic oil together with particulate cracking catalyst through a progressive flow type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a predetermined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900.degree. to about 1400.degree. F.
    Type: Grant
    Filed: May 13, 1981
    Date of Patent: February 15, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., Stephen M. Kovach
  • Patent number: 4371519
    Abstract: A process is provided for encasement and infiltration of cellular tissue to reduce the influx of oxygen and liquid thereto and to retain in situ and retard efflux of liquids and medication therefrom by introducing into said tissue a gel substantially insoluble in said tissue and the body fluids associated therewith.
    Type: Grant
    Filed: May 4, 1976
    Date of Patent: February 1, 1983
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4073716
    Abstract: Synthetic natural gas and high octane motor fuel blending stock is produced by catalytically reforming naphtha at low severity to maximize production of aromatics and minimize hydrocracking, and then converting the remaining paraffins to methane in a methanation zone. The effluent from the methanation zone is separated into synthetic natural gas and motor fuel blending stock.
    Type: Grant
    Filed: November 7, 1975
    Date of Patent: February 14, 1978
    Assignee: Engelhard Minerals & Chemicals Corporation
    Inventors: William C. Pfefferle, William P. Hettinger, Jr.
  • Patent number: 3989472
    Abstract: An anti-foaming agent is added to magnesium chloride containing brine prior to spray drying to produce a spray dried product comprising discrete particles of relatively high bulk density.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: November 2, 1976
    Assignee: NL Industries, Inc.
    Inventors: David G. Braithwaite, William P. Hettinger, Jr.
  • Patent number: 3980536
    Abstract: Magnesium metal is produced by electrolysis of a molten magnesium chloride electrolyte containing fluoride ions, the electrolyte being derived from holding pond brines which are partially deboronated, concentrated, gelled and spray dried in the presence of hydrochloric acid gas to form discrete particles of high density anhydrous magnesium chloride feed material for electrolytic cells.
    Type: Grant
    Filed: April 11, 1975
    Date of Patent: September 14, 1976
    Assignee: NL Industries, Inc.
    Inventors: David G. Braithwaite, William P. Hettinger, Jr.
  • Patent number: 3975283
    Abstract: A gelling agent is added to a brine containing magnesium chloride to convert the brine into a gel which is spray dried to produce dried magnesium chloride comprising substantially solid discrete particles of magnesium chloride having bulk densities in the range from about 12 to 45 pounds per cubic foot.
    Type: Grant
    Filed: March 21, 1975
    Date of Patent: August 17, 1976
    Assignee: NL Industries, Inc.
    Inventors: David G. Braithwaite, William P. Hettinger, Jr.
  • Patent number: 3975516
    Abstract: A process is provided for encasement and infiltration of cellular tissue to reduce the influx of oxygen and liquid thereto and to retain in situ and retard efflux of liquids and medication therefrom by introducing into said tissue a gel substantially insoluble in said tissue and the body fluids associated therewith.
    Type: Grant
    Filed: June 5, 1972
    Date of Patent: August 17, 1976
    Inventor: William P. Hettinger, Jr.