Abstract: A method of preparing a carboxylic acid-modified nitrile-based copolymer latex is provided. The method of preparing a carboxylic acid-modified nitrile-based copolymer later includes emulsion-polymerizing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile-based monomer, and an ethylenically unsaturated acid monomer in the presence of a cross-linking agent including glyoxal.

Abstract: Disclosed is a latex composition for dip molding including a carboxylic acid-modified nitrile-based copolymer latex satisfying General Formula 1, wherein the carboxylic acid-modified nitrile-based copolymer includes: 15 wt % to 30 wt % of the ethylenic unsaturated nitrile-based monomer-derived unit and 2.5 wt % to 4.5 wt % of the ethylenic unsaturated acid monomer-derived unit, and a molded article: 1.0 mm2/s?CV0?3.0 mm2/s.

Abstract: A latex composition for dip forming, and more particularly, to a latex composition for dip forming includes carboxylic acid-modified nitrile-based copolymer latex; and a phenolic emulsifier, wherein the phenolic emulsifier is included in an amount of 0.08 parts by weight to 6 parts by weight (based on a solid content) based on 100 parts by weight of the carboxylic acid-modified nitrile-based copolymer latex. A method for preparing the latex composition and a formed article produced using the latex composition are also provided.

Abstract: A latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex having pKa of 9.5 to 10.2 and satisfying General Formulas 1 and 2. 0.85?P?1.0, P=CVD/CV0??[General Formula 1] 5?M?20, M=m1×m2??[General Formula 2] wherein CV0 represents a capillary viscosity which is measured in a swollen in a methyl ethyl ketone solvent, CVD represents a capillary viscosity in a deswollen state, m1 represents an insolubility of a dried film in the methyl ethyl ketone solvent, and m2 represents a swelling index of the dried film in the methyl ethyl ketone solvent, wherein a carboxylic acid-modified nitrile-based copolymer of carboxylic acid-modified nitrile-based copolymer latex includes: a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit.

Abstract: Provided are a carboxylic acid-modified nitrile-based copolymer latex composition, a preparation method thereof, a latex composition for dip-molding including the same, and an article molded by the same, the carboxylic acid-modified nitrile-based copolymer latex composition including: a carboxylic acid-modified nitrile-based copolymer, wherein the carboxylic acid-modified nitrile-based copolymer includes a 2-hydroxyethyl methacrylate monomer-derived repeating unit in an amount of more than 0.1 wt % to less than 12 wt %, and a coagulum in the carboxylic acid-modified nitrile-based copolymer latex composition has an amount of less than 1 wt %.

Abstract: A latex composition for dip molding having an excellent flow mark property and syneresis property and being capable of providing a molded article having excellent tensile properties and texture is provided. A method of preparing the latex composition, and a dip-molded article produced using the latex composition are also provided.

Abstract: Disclosed is a dip-formed article comprising a layer derived from a latex composition for dip-forming, wherein the latex composition for dip-forming contains a carboxylic acid-modified nitrile-based copolymer latex, the carboxylic acid-modified nitrile-based copolymer latex contains a carboxylic acid-modified nitrile-based copolymer, and the dip-formed article has an elongation of more than 650% and satisfies the following Expressions 1 and 2, [Expression 1] k1?+k2?+k3??9.3 N/mm??(1) [Expression 2] 0.55?k1?/(k1?+k2?+k3?)??(2) wherein k1? is a value obtained by dividing an equilibrium coefficient k1 by a thickness of a test piece, and k2? and k3? are values obtained by dividing viscous coefficients k2 and k3 by the thickness of the test piece, respectively.

Abstract: Provided is a dip-molded article, and more particularly, provided are a dip-molded article including: a layer derived from a latex composition for dip-molding; and a layer derived from a polymer including a repeating unit derived from a diacetylene-based compound, a latex composition for dip-molding, and a preparation method thereof.

Abstract: Provided is a latex composition for dip molding. The latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex and a hydrophobically modified alkali-soluble emulsion thickener, wherein the hydrophobically modified alkali-soluble emulsion thickener includes a copolymer including an associative portion and a non-associative portion, and the associative portion includes a monomer-derived repeating unit substituted by one or more first hydrophobic groups selected from the group consisting of alkyl, alkenyl, perfluoroalkyl, and carbosilyl having 8 to 15 carbon atoms, and aryl, arylalkyl, arylalkenyl, alicyclic alkyl, and polycyclic alkyl having 6 to 15 carbon atoms. A method of preparing the latex composition for dip molding, and a molded article manufactured therefrom are also provided.

Abstract: A carboxylic acid-modified nitrile-based copolymer latex includes a carboxylic acid-modified nitrile-based copolymer including: 65.5 wt % to 82.5 wt % of a conjugated diene-based monomer-derived unit, 15 wt % to 30 wt % of an ethylenic unsaturated nitrile-based monomer-derived unit, and 2.5 wt % to 4.5 wt % of an ethylenic unsaturated acid monomer-derived unit, wherein the carboxylic acid-modified nitrile-based copolymer latex satisfies General Formula 1: 1.0 mm2/s?CV0?3.0 mm2/s??[General Formula 1] wherein CV0 represents a capillary viscosity of the carboxylic acid-modified nitrile-based copolymer latex which is measured in a swollen state in a methyl ethyl ketone solvent.

Abstract: The present technology provides a carboxylic acid-modified nitrile-based copolymer latex including a carboxylic acid-modified nitrile-based copolymer including a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, wherein a pKa is 9.5 to 10.2, and the carboxylic acid-modified nitrile-based copolymer latex satisfies General Formulas 1 and 2.

Abstract: A latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex having pKa of 9.5 to 10.2 and satisfying General Formulas 1 and 2. 0.85?P?1.0, P=CVD/CV0??[General Formula 1] 5?M?20, M=m1×m2??[General Formula 2] wherein CV0 represents a capillary viscosity which is measured in a swollen in a methyl ethyl ketone solvent, CVD represents a capillary viscosity in a deswollen state, m1 represents an insolubility of a dried film in the methyl ethyl ketone solvent, and m2 represents a swelling index of the dried film in the methyl ethyl ketone solvent, wherein a carboxylic acid-modified nitrile-based copolymer of carboxylic acid-modified nitrile-based copolymer latex includes: a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit. A molded article having a layer derived from the latex composition is also provided.

Abstract: Disclosed is a latex composition for dip molding including a carboxylic acid-modified nitrile-based copolymer latex satisfying General Formula 1, wherein the carboxylic acid-modified nitrile-based copolymer includes: 15 wt % to 30 wt % of the ethylenic unsaturated nitrile-based monomer-derived unit and 2.5 wt % to 4.5 wt % of the ethylenic unsaturated acid monomer-derived unit, and a molded article: 1.0 mm2/s?CV0?3.0 mm2/s.

Abstract: The present technology provides a carboxylic acid-modified nitrile-based copolymer latex including a carboxylic acid-modified nitrile-based copolymer including a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, wherein the carboxylic acid-modified nitrile-based copolymer latex satisfies General Formula 1 and General Formula 2.

Abstract: The present technology relates to a latex composition for dip molding comprising a carboxylic acid-modified nitrile-based copolymer latex satisfying General Formulas 1 and 2, wherein the carboxylic acid-modified nitrile-based copolymer includes a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, and a molded article.

Abstract: The present invention relates to a latex composition for dip molding, and such latex composition includes: a carboxylic acid-modified nitrile-based copolymer latex; and a reactive compound having three or more branched chains and a reactive group at a terminal of each of the branched chains, wherein the reactive group is one or more selected from the group consisting of an amine group, a hydroxy group, an epoxy group, a glycidyl group, and an isocyanate group.

Abstract: A method of preparing a carboxylic acid-modified nitrile-based copolymer latex is provided. The method of preparing a carboxylic acid-modified nitrile-based copolymer later includes emulsion-polymerizing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile-based monomer, and an ethylenically unsaturated acid monomer in the presence of a cross-linking agent including glyoxal.

Abstract: A dip-molded article includes an external molded layer and internal molded layer. The external molded layer includes a content of an ethylenically unsaturated nitrile-based monomer-derived repeating unit is 35 wt % to 60 wt %, and the internal molded layer in which a content of an ethylenically unsaturated nitrile-based monomer-derived repeating unit is 10 wt % to 28 wt %.

Abstract: A latex composition for dip molding having an excellent flow mark property and syneresis property and being capable of providing a molded article having excellent tensile properties and texture is provided. A method of preparing the latex composition, and a dip-molded article produced using the latex composition are also provided.

Abstract: A latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex and a cholate-based emulsifier, wherein the cholate-based emulsifier is included in an amount of 0.02 to 3 parts by weight based on a solid content with respect to a solid content of 100 parts by weight of the carboxylic acid-modified nitrile-based copolymer latex. A method of preparing the latex composition for dip molding and a molded article produced using the same are also provided.