Abstract: A bio-electrode, excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried, includes an electro-conductive base material and a living body contact layer formed on the electro-conductive base material. The living body contact layer is a cured material of a bio-electrode composition including (A) an ionic material and (C) a metal powder, wherein the component (A) is a polymer compound containing a repeating unit-a having a structure selected from an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide.

Abstract: The present invention provides a bio-electrode composition including a silsesquioxane bonded to a sulfonic acid salt shown by the following general formula (1): wherein R1 represents an alkylene group having 1 to 20 carbon atoms or an arylene group having 6 to 10 carbon atoms, optionally containing an ether group or an ester group, and the alkylene group may also contain an aromatic group; Rf1 and Rf2 represent H, F, O, or a CF3 group and can form a carbonyl group with a carbon atom bonded therewith; Rf3 and Rf4 represent H, F, or a CF3 group and one or more fluorine atoms are contained in Rf1 to Rf4; M is selected from Na, K, and Ag. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity.

Abstract: The present invention provides a bio-electrode composition including: (A) an ionic material; and (B) a resin other than the component (A); wherein the component (A) contains both of a repeating unit-a having a structure of any of silver salts of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide; and a repeating unit-b having silicon. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light in weight, manufacturable at low cost, and free from large lowering of the electric conductivity even when it is wetted with water or dried. The present invention also provides a bio-electrode in which the living body contact layer is formed from the bio-electrode composition, and a method for manufacturing the bio-electrode.

Abstract: Provided is a silicone adhesive composition having (A) a condensation product of a linear or branched diorganopolysiloxane having a silicon atom-bonded hydroxy group and/or a silicon atom-bonded alkoxy group having 1 to 10 carbon atoms at a terminal and having no alkenyl group, a linear or branched diorganopolysiloxane having at least two alkenyl groups, and an organopolysiloxane comprising an R13SiO0.5 unit and an SiO2 unit and having a silicon atom-bonded hydroxy group and/or a silicon atom-bonded alkoxy group having 1 to 6 carbon atoms, (B) an organohydrogenpolysiloxane having at least three SiH groups and an average polymerization degree of 80 or less in an amount of 0.1 to 5 parts by mass, relative to 100 parts by mass of component (A), and (C) a platinum group metal catalyst in a catalytic amount.

Abstract: An adhesive silicone composition having (A) a linear or branched organopolysiloxane having at least two alkenyl groups in a molecule (B) an organopolysiloxane comprising R23SiO1/2 units and SiO4/2 units, wherein R2 is, independently of each other, a substituted or unsubstituted, monovalent hydrocarbon group having 1 to 10 carbon atoms, (C) an organohydrogenpolysiloxane having at least three hydrogen atoms each bonded to a silicon atom in a molecule and having no aryl group, and (E) an organohydrogenpolysiloxane having at least three hydrogen atoms each bonded to a silicon atom in a molecule and having an aryl group-containing organic group.

Abstract: The present invention provides a bio-electrode composition including a silicone bonded to a sulfonamide salt, wherein the sulfonamide salt is shown by the following general formula (1): wherein R1 represents a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms optionally having an aromatic group, an ether group, or an ester group, or an arylene group having 6 to 10 carbon atoms; Rf represents a linear, branched, or cyclic alkyl group having 1 to 4 carbon atoms and containing at least one fluorine atom; M+ is an ion selected from a lithium ion, a sodium ion, a potassium ion, and a silver ion. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

Abstract: The present invention provides a bio-electrode composition including a silicone bonded to a sulfonimide salt, wherein the sulfonimide salt is shown by the following general formula (1): wherein R1 represents a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms optionally having an aromatic group, an ether group, or an ester group, or an arylene group having 6 to 10 carbon atoms; Rf represents a linear, branched, or cyclic alkyl group having 1 to 4 carbon atoms and containing at least one fluorine atom; M+ is an ion selected from a lithium ion, a sodium ion, a potassium ion, and a silver ion. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

Abstract: The present invention provides a bio-electrode composition including a silsesquioxane bonded to a sulfonimide salt, wherein the sulfonimide salt is shown by the following general formula (1): wherein R1 represents a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms that may have an aromatic group, an ether group, or an ester group, or an arylene group having 6 to 10 carbon atoms; Rf represents a linear, branched, or cyclic alkyl group having 1 to 4 carbon atoms containing at least one fluorine atom; M+ is an ion selected from a lithium ion, a sodium ion, a potassium ion, and a silver ion. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

Abstract: The present invention provides a bio-electrode composition including a silsesquioxane bonded to an N-carbonyl sulfonamide salt, wherein the N-carbonyl sulfonamide salt is shown by the following general formula (1): wherein R1 represents a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms that may have an aromatic group, an ether group, or an ester group, or an arylene group having 6 to 10 carbon atoms; Rf represents a linear, branched, or cyclic alkyl group having 1 to 4 carbon atoms containing at least one fluorine atom; M+ is an ion selected from a lithium ion, a sodium ion, a potassium ion, and a silver ion. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

Abstract: A bio-electrode composition contains (A) an ionic polymer material, (B) an addition reaction-curable silicone having at least a hydrosilyl group, (C) a platinum-group catalyst, and a solvent. The bio-electrode composition has a water content of 0.2 mass % or less. The solvent includes one or more of an ether solvent, an ester solvent, and a ketone solvent each of which does not contain a hydroxy group, a carboxyl group, a nitrogen atom, or a thiol group. Thus, present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity and biocompatibility, light-weight, and manufacturable at low cost, and which does not leave residue on skin after attachment to and peeling from the skin; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.

Abstract: A bio-electrode composition contains: (A) a polymer compound containing a repeating unit-a having a structure selected from the group consisting of salts of ammonium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide; and (B) a silicone compound having a polyglycerin structure. This bio-electrode composition is able to form a living body contact layer for a bio-electrode which enable quick signal collection after attachment to skin.

Abstract: The present invention provides a silicone release agent composition comprising the components (A), (B), (C) and (D): 50 to 99.9 parts by mass of (A) linear or branched organopolysiloxane represented by the general formula (1) and having at least two alkenyl group-containing organic groups and at least one aryl group-containing organic group in one molecule and having no fluorine-containing organic group, wherein a percentage of the number of the alkenyl group-containing organic group is 0.005 to 5% and a percentage of the number of the aryl group-containing organic groups is 0.1 to 40%, each based on the total number of groups each bonded to a silicon atom; 50 to 0.

Abstract: The present invention provides a bio-electrode composition including a silicone bonded to a fluorosulfonic acid salt, wherein the fluorosulfonic acid salt is shown by the following general formula (1): wherein R1 represents an alkylene groups with 1 to 20 carbon atoms or an arylene groups with 6 to 10 carbon atoms; Rf1 and Rf2 each represent a hydrogen atom, a fluorine atom, an oxygen atom, or a trifluoromethyl group; Rf3 and Rf4 each represent a hydrogen atom, a fluorine atom, or a trifluoromethyl group, provided that one or more fluorine atoms are contained in Rf1 to Rf4; M is selected from sodium, potassium, and silver. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

Abstract: A bio-electrode, excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried, includes an electro-conductive base material and a living body contact layer formed on the electro-conductive base material. The living body contact layer is a cured material of a bio-electrode composition including (A) an ionic material and (C) a metal powder, wherein the component (A) is a polymer compound containing a repeating unit-a having a structure selected from an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide.

Abstract: Provided is a method for easily producing a silicone adhesive that has a reduced amount of remaining silanol groups, contains no aromatic hydrocarbon solvent, and is capable of preventing an impact(s) on the human body as well as skin irritancy as caused by remaining and volatilizing substances. The method includes: a first step of mixing, under the presence of a basic catalyst, (A) a polydiorganosiloxane, (B) an organopolysiloxane whose molar ratio of R13SiO0.5 unit/SiO2 unit is 0.5 to 1.5, and (C) an aliphatic hydrocarbon solvent; and a second step of treating a product obtained in the first step with an organic disilazane compound and/or a silane compound, for the purpose of lowering an amount of silanol groups contained in a solid product obtained after the treatment to a range of 0.002 to 0.03 mol/100 g of the solid product obtained after the treatment.

Abstract: The present invention provides a bio-electrode composition including (A) an ionic material and (C) a metal powder, wherein the component (A) is a polymer compound containing a repeating unit-a having a structure selected from the group consisting of an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

Abstract: This silicone adhesive agent composition contains (A) an alkenyl group-containing diorganopolysiloxane, (B) a resin having an R13SiO1/2 unit (each occurrence of R1 represents a monovalent hydrocarbon group which does not have an aliphatic unsaturated bond. The same applies to R1 described below.) and a SiO4/2 unit, (C) an alkenyl group-containing diorganopolysiloxane, (D) (D-1) a resinous copolymer having an R43SiO1/2 unit (each occurrence of R4 represents a monovalent hydrocarbon group which does not have an aliphatic unsaturated bond, or an alkenyl group, and at least one of all occurrences of R4 is an alkenyl group) and a SiO4/2 unit and/or (D-2) a resinous copolymer having an R13SiO1/2 unit, an R1R5SiO2/2 unit (R5 represents an alkenyl group.), and a SiO4/2 unit, (E) an organohydrogen polysiloxane, and (G) a platinum-based catalyst (platinum group metal-based catalyst).

Abstract: An addition-curable silicone adhesive composition for skin application, containing: (X) a mixture or condensation reaction product of a component (A) and a component (B); (C) an organohydrogenpolysiloxane containing three or more SiH groups per molecule; and (D) a platinum group metal-based catalyst. (A) is a diorganopolysiloxane with a mass ratio of (A1)/(A2) being 90/10 to 15/85. (A1) is a diorganopolysiloxane which has two or more alkenyl groups per molecule, and the alkenyl group-content is at least 0.0005 mol/100 g and less than 0.15 mol/100 g. (A2) is a diorganopolysiloxane having a SiOH group at a terminal and no alkenyl group. (B) is an organopolysiloxane with a molar ratio of R13SiO0.5 unit/SiO2 unit being 0.5 to 1.5. This addition reaction-curable silicone adhesive composition for skin application results in an adhesive layer which has suitable adhesive strength and excellent re-attachability, reworkability, and durability.

Abstract: The present invention provides a bio-electrode that is excellent in conductivity and biocompatibility, is light-weight, can be manufactured at low cost, and can control significant reduction in conductivity even though the bio-electrode is soaked in water or dried. The present invention is accomplished by providing a conductive substrate and a living body contact layer formed on the conductive substrate, where the living body contact layer is a cured product of a bio-electrode composition including an (A) ionic material and a (B) resin other than the component (A), in which the component (A) has both a repeating unit “a” of a lithium salt, a sodium salt, a potassium salt, or an ammonium salt of sulfonamide including a partial structure represented by the following general formula (1) and a repeating unit “b” having a silicon atom, —R1—C(?O)—N?—SO2—Rf1M+(1).

Abstract: Provided is a silicone adhesive composition having (A) a condensation product of a linear or branched diorganopolysiloxane having a silicon atom-bonded hydroxy group and/or a silicon atom-bonded alkoxy group having 1 to 10 carbon atoms at a terminal and having no alkenyl group, a linear or branched diorganopolysiloxane having at least two alkenyl groups, and an organopolysiloxane comprising an R13SiO0.5 unit and an SiO2 unit and having a silicon atom-bonded hydroxy group and/or a silicon atom-bonded alkoxy group having 1 to 6 carbon atoms, (B) an organohydrogenpolysiloxane having at least three SiH groups and an average polymerization degree of 80 or less in an amount of 0.1 to 5 parts by mass, relative to 100 parts by mass of component (A), and (C) a platinum group metal catalyst in a catalytic amount.