Abstract: The present invention is a pressure sensitive adhesive including a polyurethane polymer comprising a reaction product of an isocyanate, a (meth) acrylate-containing alcohol having at least one (meth)acrylate group and at least one alcohol group, and a polyol component having a defined solubility parameter of less than about 10; an oligomer comprising a multifunctional (meth)acrylate; and a photoinitiator. A peel adhesion of the pressure sensitive adhesive to glass decreases at least about 20% after being exposed to light radiation.

Abstract: Various embodiments disclosed relate to a surfacing film. The surfacing film includes a base layer. The base layer includes a thermoplastic polyurethane film comprising a reaction product of a reaction mixture of a diisocyanate, a polyester polyol having a melting temperature of at least about 30° C.; and a diol chain extender. There are many reasons to use the surfacing film including easier and more cost effective manufacturing of the surfacing film by directly extruding the base layer by mixing the reaction mixture in an extruder. Another reason to use the surfacing film is that the film has improved resistance to discoloration. Another reason to use the film is that the film shows good toughness.

Abstract: Described herein is a pressure sensitive adhesive comprising a polyurethane polymer derived from a polyester polyol and a polyisocyanate component, wherein the polyester polyol, which is derived from a first reaction product of (a) a Component A, wherein the Component A is a phthalic acid, a phthalic anhydride or mixtures thereof, (b) a Component B, wherein the Component B is a dimer fatty acid, a dimer fatty acid diol or mixtures thereof, and (c) a Component C, wherein the Component C is an aliphatic diol, an aromatic diol, or mixtures thereof, wherein Component C comprises 2 to 10 carbon atoms and optionally catenated heteroatoms selected from O, S, and N. Also disclosed herein are polyurethane polymers and pressure sensitive adhesives made from the polyurethane polymers or the polyester polyols.

Abstract: Described herein is a multilayered article (10) and methods of making and using such articles. The multilayered article (10) comprises: ?(a) a microsphere layer (11) comprising a plurality of microspheres disposed in a monolayer; ?(b) a bead bonding layer (12) comprising a first major surface and a second opposing major surface and the plurality of microspheres is partially embedded in the first major surface of the bead bonding layer, and comprises a thermoset polyurethane having a glass transition temperature of at least 35° C.; ?(c) a primer layer (14) disposed on the second major surface of the bead bonding layer wherein the primer layer comprises a copolymer of polyurea and polyurethane and wherein the primer layer is covalently attached to the bead bonding layer via urea linkages; and ?(d) an elastomeric layer (16) disposed on the primer layer opposite the bead bonding layer, wherein the elastomeric layer comprises a polyurethane thermoplastic elastomer.

Abstract: Provided is a surfacing film that includes a plurality of layers. The layers include a first clear coat layer made from a crosslinked polyurethane that is a reaction product of a reactive mixture including an isocyanate and a polyol containing a styrene repeat unit and a hydroxyl-containing (meth)acrylate repeat unit. The surfacing film further includes a bulk layer made from a thermoplastic polyurethane and an adhesive layer. Optionally, the surfacing film includes second clear coat layer, which can be made from a polyurethane that is at least partially crosslinked. The resulting surfacing film can display high stain resistance, high peel strength, superior scratch resistance and self-healing properties.

Abstract: An organic light emitting diode (OLED) display includes a pixelated OLED display panel and a color-correction component disposed on the pixelated OLED display panel. The pixelated OLED display panel has a ratio of blue-to-red color mixing weights at 30 degrees of ?030, and a ratio of blue-to-red color mixing weights at 45 degrees of ?045, where ?045??030?1.05 and 1.5??045?1.1. The color-correction component is configured such that a ratio of blue-to-red color mixing weights at 45 degrees of the display is ?45 and a ratio of blue-to-red color mixing weights at 30 degrees of the display is ?30, where ?045?0.1??45?2.1??045 and ?030?0.05??30?2.05??030. Methods of making OLED displays are described.

Abstract: The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article.

Abstract: A multilayer film is described comprising a first film layer comprising an organic polymeric material, wherein the first film layer has an elongation of at least 250%; and a second film layer comprising a crosslinked polyurethane wherein the polyurethane comprises polymerized units of a polyamide. In some embodiments, the organic polymeric material of the first film layer comprises polyurethane. Also described is a method of protecting a surface of a motor vehicle and a method of making a multilayer protective film.

Abstract: An OLED display including a display panel and a color-correction component is described. A plurality of comparative display panels otherwise equivalent to the display panel but having one or more different optical thicknesses of OLED layers have a maximum white-point color shift from 0 to 45 degrees of WPCSC45 and a white-point axial efficiency of WPAEC. The plurality of comparative display panels defines a performance curve along a boundary of performance points. The OLED display and the display panel have respective maximum white-point color shifts from 0 to 45 degrees of WPCS45 and WPCS045 and respective white-point axial efficiencies of WPAE and WPAE0. WPCS045 and WPAE0 defines a performance point of the display panel to the right of the performance curve and WPCS45 and WPAE defines a performance point of the OLED display above or to the left of the performance curve. Methods of making the OLED display are described.

Abstract: The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article.

Abstract: The present invention is an adhesive delivery system including a conformable film having top and bottom faces, an adhesive releasably coated on at least a portion of the top face of the conformable film, and a light release liner adhered to the adhesive side opposite the conformable film.

Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer.

Abstract: A surfacing film is provided that includes a plurality of layers in the following order: an outer layer comprised of a reaction product of a two-part curable fluoropolyurethane composition including a polyisocyanate and at least one polyhydroxy-functional fluoropolymer, optionally a primer layer comprising a polyurethane; and a base layer. Advantageously, the surfacing films can display superior gloss, mechanical durability, chemical/stain resistance, easy cleaning performance, and weather aging stability compared with conventional surfacing films.

Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. The present disclosure further provides an article and methods thereof.

Abstract: Disclosed herein are hard coat compositions and composite films including a thermoplastic polyurethane. A hard coat composition includes a thermoplastic polyurethane having a hard segment content of 80 percent by weight or greater. The thermoplastic polyurethane is a reaction product of a) a diisocyanate; b) a polyol optionally comprising a cyclic structure; and c) a chain extender. At least one of the polyol or the chain extender comprises at least one side chain and at least one of the diisocyanate or the chain extender comprises a cyclic structure. A composite film includes 1) a hard coat layer having opposing first and second major surfaces; and 2) a second layer disposed on at least a portion of the hard coat layer. These materials can serve decorative and/or protective functions while displaying both good elongation at moderate temperatures and high hardness.

Abstract: Described herein is a multilayered article and methods of making and using such articles. The multilayered article comprises: · (a) a microsphere layer comprising a plurality of microspheres (11) disposed in a monolayer; · (b) a bead bonding layer (12) comprising a first major surface and a second opposing major surface wherein the plurality of microspheres is at least partially embedded in the first major surface of the bead bonding layer, and wherein the bead bonding layer comprises a thermoset polyurethane, and wherein the thermoset polyurethane is derived from one or more liquid polyols; and · (c) an elastomeric layer (14) disposed on the second opposing major surface of the bead bonding layer.

Abstract: There is provided a pressure sensitive adhesive composition comprising a polyurethane polymer that comprises the reaction product of a polyisocyanate component and a polyol component. The polyol component has a hydrophilic-lipophilic balance (HLB) less than 10. The polyurethane further comprises 0.5 to 10 wt.-% of hydrophilic polymerized units having an HLB greater than 12, such as a reaction product of a polyethylene glycol polymer. In another embodiment, the polyurethane further comprises pendent ethylenically unsaturated groups. Also described are articles such as laminating tapes and protective films as well as methods of bonding substrates with the pressure sensitive adhesive and laminating tape.

Abstract: Polymeric films, which may be adhesive films, and display devices including such polymeric films, wherein a polymeric film includes: a first polymeric layer having two major surfaces, wherein the first polymeric layer includes a first polymeric matrix and particles. The first polymeric layer includes: a first a polyolefin-based low WVTR adhesive polymeric matrix having a refractive index n1; and particles having a refractive index n2 uniformly dispersed within the first polymeric matrix; wherein the particles are present in an amount of less than 30 vol-%, based on the volume of the first polymeric layer, and have a particle size range of 400 nanometers (nm) to 3000 nm; and wherein n1 is different than n2.

Abstract: Polymeric films, which may be adhesive films, and display devices including such polymeric films, wherein a polymeric film includes: a first polymeric layer having two major surfaces, wherein the first polymeric layer includes a first polymeric matrix and particles. The first polymeric layer includes: a first polymeric matrix having a refractive index n1; and particles having a refractive index n2 uniformly dispersed within the first polymeric matrix; wherein the particles are present in an amount of less than 30 vol-%, based on the volume of the first polymeric layer, and have a particle size range of 400 nanometers (nm) to 3000 nm; and wherein n1 is different than n2.

Abstract: Polymerizable compositions suitable for use for 3D printed (e.g. orthodontic) articles, especially orthodontic alignment trays, are described. The polymerizable composition comprises a) 30-70 parts by weight of (meth)acrylate monomer(s); and b) urethane (meth)acrylate polymer; wherein the reaction product comprises at least 1 wt. % polymerized units of a multifunctional compound comprising pendent cyclic moieties. The orthodontic article comprises the reaction product of a polymerizable composition as described herein. The urethane (meth)acrylate polymer typically comprises polymerized units of a multifunctional compound comprising pendent cyclic moieties and/or at least one (meth)acrylate monomer comprises polymerized units of a multifunctional compound comprising pendent cyclic moieties. Also described are methods of making an article, non-transitory machine-readable medium comprising data representing a three-dimensional model of an article, and systems.