Abstract: In a capacitor having a high dielectric constant, the capacitor includes a cylindrical lower electrode, a dielectric layer and an upper electrode. A metal oxide layer is formed on inner, top and outer surfaces of the lower electrode as the dielectric layer. A first sub-electrode is formed on a surface of the dielectric layer along the profile of the lower electrode and a second sub-electrode is continuously formed on the first sub-electrode corresponding to the top surface of the lower electrode, so an opening portion of the lower electrode is covered with the second sub-electrode. The first and second sub-electrodes include first and second metal nitride layers in which first and second stresses are applied, respectively. Directions of the first and second stresses are opposite to each other. Accordingly, cracking is minimized in the upper electrode with the high dielectric constant, thereby reducing current leakage.

Abstract: In an embodiment, a method of forming a lower electrode of a capacitor in a semiconductor memory device includes etching a mold oxide layer to have at a cylindrical structure, resulting in an electrode with increased surface area. The cylindrical structure may have more than one radius. This increased surface area results in an increased capacitance. An excessive etch phenomenon, which occurs because a sacrificial oxide layer is etched at a higher rate than the mold oxide layer, is avoided.

Abstract: Methods of forming a storage capacitor include forming an interlayer insulation layer having an opening therethrough on a semiconductor substrate, forming a contact plug in the opening, forming a molding oxide layer on the interlayer insulation layer and the contact plug, selectively removing portions of the molding oxide layer to form a recess above the contact plug, forming a titanium layer on a bottom surface and side surfaces of the recess, forming a titanium nitride layer on the titanium layer, and forming a titanium oxide nitride layer on the titanium nitride layer. A storage capacitor includes a semiconductor substrate, an interlayer insulation layer having a contact plug therein on the substrate, and a storage electrode on the contact plug including a titanium silicide layer, a titanium nitride layer on the titanium silicide layer, and a titanium oxide nitride layer on the titanium nitride layer.

Abstract: A capacitor and method of manufacturing the same include an insulating interlayer, a lower electrode, a protection structure, a dielectric layer and an upper electrode. The insulating interlayer may include a conductive pattern formed on a substrate. The lower electrode may be electrically connected to the conductive pattern. The protection structure may be formed on an outer sidewall of the cylindrical lower electrode and on the insulating interlayer.

Abstract: A method of fabricating a storage capacitor includes depositing a first titanium nitride layer on a dielectric layer using a chemical vapor deposition technique or an atomic layer deposition technique performed at a first temperature with reactant gases of titanium chloride (TiCl4) gas and ammonia (NH3) gas at a predetermined flow ratio and depositing a second titanium nitride layer on the first titanium nitride layer using a chemical vapor deposition process performed at a second temperature that is greater than the first temperature with reactant gases of titanium chloride (TiCl4) gas and ammonia (NH3) gas.

Abstract: In a method for forming an interlayer dielectric film, an insulating film is deposited on a semiconductor substrate that has a metal wiring pattern. The insulating film is polished by CMP until exposing an upper portion of the wiring pattern. A spin on glass composition, which includes polysilazane, is coated over the polished insulating material and exposed portions of the wiring pattern to form a film. The film is then pre-baked in a temperature range of 50 to 350° C., and then hard-baked in a temperature range of 300 to 500° C. After the hard-baking, the film is then heat-treated in an oxidation atmosphere. With the hard-baking, gasses of the coating of film may be removed so that the amount of gas generated during a subsequent anneal or heat-treating process may be reduced. Accordingly, particle contaminants may be reduced by such process in addition to providing a means for reduced risk of crack formation.

Abstract: In a method for forming an interlayer dielectric film, an insulating film is deposited on a semiconductor substrate that has a metal wiring pattern. The insulating film is polished by CMP until exposing an upper portion of the wiring pattern. A spin on glass composition, which includes polysilazane, is coated over the polished insulating material and exposed portions of the wiring pattern to form a film. The film is then pre-baked in a temperature range of 50 to 350° C., and then hard-baked in a temperature range of 300 to 500° C. After the hard-baking, the film is then heat-treated in an oxidation atmosphere. With the hard-baking, gasses of the coating of film may be removed so that the amount of gas generated during a subsequent anneal or heat-treating process may be reduced. Accordingly, particle contaminants may be reduced by such process in addition to providing a means for reduced risk of crack formation.