Abstract: Catalyzed soot filters comprising a wall flow monolith having microcracks and pores and a catalyst comprising support particles with particle sizes greater than about the size of the microcracks and less than about the size of the pores are disclosed. Methods of manufacturing catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.

Abstract: Catalyzed soot filters comprising a wall flow monolith having microcracks and pores and a catalyst comprising support particles with particle sizes greater than about the size of the microcracks and less than about the size of the pores are disclosed. Methods of manufacturing catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.

Abstract: An emission treatment system and method for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system includes a catalyzed soot filter comprising a wall flow monolith and a catalyst comprising support particles. The wall flow monolith may be washcoated with a slurry comprising catalytic support particles without applying a passivation layer to the wall flow monolith.

Abstract: Provided is an emissions treatment system for an exhaust stream, having a NOx storage reduction (NSR) catalyst with a NOx sorbent at a concentration of at least 0.1 g/in3 and a platinum group metal component dispersed on a refractory metal oxide support; and, an SCR catalyst disposed downstream of the NSR catalyst. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

Abstract: Provided is an emissions treatment system for an exhaust stream, having a NOx storage reduction (NSR) catalyst with a NOx sorbent at a concentration of at least 0.1 g/in3 and a platinum group metal component dispersed on a refractory metal oxide support; and, an SCR catalyst disposed downstream of the NSR catalyst. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

Abstract: The present invention discloses a novel use of the FGD byproduct from thermal power plants and facilities and the specific method for alkali soil amelioration. In this method, after sampling, amount of Na2CO3, NaHCO3, Mg(HCO3)2,±)Na and ±)Mg can be calculated by analysis. According to the component in FGD byproduct from thermal power plants and facilities, the amount for FGD byproduct from thermal power plants and facilities needed in the alkali soil to be ameliorated can be determined. The FGD byproduct from thermal power plants and facilities are scattered on the surface according to the alkalization degree. After irrigating, the soil is operated just like common land. This invention allows the FGD byproduct from thermal power plants and facilities to be utilized effectively and economically, changing from it from waste to a useful substance. Moreover, it provides a method for alkali soil amelioration, which is fast, efficient, consumes less water, is cost effective, and promising.

Abstract: The present invention is directed to an exhaust gas treatment system and method for removing particulate matter and nitrogen oxides from diesel engine exhaust streams. More specifically, the present invention relates to an emission treatment system that effectively provides simultaneous treatment of the particulate matter, as well as the NOx and other gaseous components of diesel engine exhaust. The emission treatment system uses an integrated soot filter coated with a catalyst washcoat composition comprising sub-micron particles, thereby providing an ultra-thin sub-micron washcoat layer showing improved catalyst performance without causing excessive backpressure.

Abstract: A composition for controlling CO and NOx emissions during FCC processes comprises (i) acidic oxide support, (ii) cerium oxide, (iii) lanthanide oxide other than ceria such as praseodymium oxide (iv), optionally, oxide of a metal from Groups Ib and IIb such as copper, silver and zinc and (v) precious metal such as Pt and Pd.

Abstract: A layered catalyst composite for controlling vehicular exhaust emissions is disclosed. The composite comprises a substrate such as cordierite, at least one bottom layer deposited on the substrate containing a precious metal component such as platinum and at least one NOx storage component present in the amount of about 0.3 to about 1.5 g/in3, and at least one top layer deposited on the bottom layer containing a precious metal component such as platinum and at least one NOx storage component present in the amount of about 0.0 to less than about 0.3 g/in3.

Abstract: Provided is an emissions treatment system for an exhaust stream, having a NOx storage reduction (NSR) catalyst with a NOx sorbent at a concentration of at least 0.1 g/in3 and a platinum group metal component dispersed on a refractory metal oxide support; and, an SCR catalyst disposed downstream of the NSR catalyst. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

Abstract: A layered catalyst composite for controlling vehicular exhaust emissions is disclosed. The composite comprises a substrate such as cordierite, at least one bottom layer deposited on the substrate containing a precious metal component such as platinum and at least one NOx storage component present in the amount of about 0.3 to about 1.5 g/in3, and at least one top layer deposited on the bottom layer containing a precious metal component such as platinum and at least one NOx storage component present in the amount of about 0.0 to less than about 0.3 g/in3.

Abstract: A composition for controlling CO and NOx emissions during FCC processes comprises (i) acidic oxide support, (ii) cerium oxide, (iii) lanthanide oxide other than ceria such as praseodymium oxide (iv), optionally, oxide of a metal from Groups Ib and IIb such as copper, silver and zinc and (v) precious metal such as Pt and Pd.

Abstract: The present invention relates to sulfur tolerant catalyst composites useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved NOx trap catalysts for use in diesel engines as well as lean burn gasoline engines. The sulfur tolerant NOx trap catalyst composites comprise a platinum component, a support, a NOx sorbent component, and a spinel material prepared by calcining an anionic clay material represented by the formula MmNn(OH)(2m+2n)Aa.bH2O, wherein the formula is defined herein. The sulfur tolerant NOx trap catalyst composites are highly effective with a sulfur containing fuel by trapping sulfur oxide contaminants which tend to poison conventional NOx trap catalysts used to abate other pollutants in the stream.

Abstract: Acetonitrile is produced directly from alkanes or alkenes by ammoxidation over a catalyst which is a silica-alumina exchanged with a metal of Period 4, Groups VIIA and VIII of the Periodic Table. The silica-alumina can be amorphous but is preferably crystalline zeolite. Preferred zeolite include ZSM-5, beta, NU-87 and USY. Cobalt is the favored metal for exchange. Particularly good results are obtained when the zeolite has been modified with a surface coating of silicon oxides prior to the metal exchange or modified with a boron or phosphorous containing compound followed by calcination. Ammoxidation of alkanes produce alkenes as a byproduct which can be recycled to the reaction to increase acetonitrile yield.

Abstract: The invention describes a highly efficient catalytic pollution control process for removing N.sub.2 O from gaseous mixtures. The process utilizes catalysts derived from anionic clay minerals, which after appropriate heat activation, provide superior N.sub.2 O decomposition activity. The catalytic process comprises contacting an N.sub.2 O-containing gaseous mixture with the decomposition catalyst under conditions sufficient to convert the N.sub.2 O into gaseous nitrogen and gaseous oxygen. The process catalysts are derived from anionic clay materials such as the hydrotalcites, sjogrenites and pyroaurites. A small but critical amount of an activator metal is provided to promote the decomposition of N.sub.2 O, particularly in wet gas steams. The activator metal may be an alkali metal such as sodium, potassium or lithium, or an alkaline-earth metal such as magnesium, with sodium giving particularly good results.

Abstract: Nitrogen oxides and carbon monoxide are removed from the exhaust of an internal combustion engine which operates on a methane-containing fuel by reacting the carbon monoxide, nitrogen oxides, and oxygen in the exhaust gas with methane in the presence of a catalyst comprising a crystalline zeolite having a silicon to aluminum ratio of equal to or greater than about 2.5 which is exchanged with a cation selected from the group consisting of cobalt, nickel, iron, chromium, rhodium, gallium, and manganese. Methane for the reaction is provided as a portion of the methane-containing fuel.

Abstract: The invention describes a highly efficient catalytic pollution control process for removing N.sub.2 O from gaseous mixtures. The process utilizes catalysts derived from anionic clay minerals, which after appropriate heat activation, provide superior N.sub.2 O decomposition activity. The catalytic process comprises contacting an N.sub.2 O -containing gaseous mixture with the decomposition catalyst under conditions sufficient to convert the N.sub.2 O into gaseous nitrogen and gaseous oxygen. The process catalysts are derived from anionic clay materials such as the hydrotalcites, sjogrenites and pyroaurites.

Abstract: The invention describes a process for catalytically destroying NOx and carbon monoxide present in oxygen-containing combustion products wherein methane serves as a reductant. The process comprises combusting a fuel source in the presence of oxygen to form combustion products comprising nitrogen oxides, carbon monoxide and oxygen; introducing methane into the combustion products in an amount such that the total amount of methane to nitrogen oxides present, expressed as a ratio, by volume is greater than about 0.1; and reacting the nitrogen oxides, carbon monoxide, methane and oxygen in the presence of an exchanged crystalline zeolite under conditions sufficient to convert the nitrogen oxides and carbon monoxide to gaseous nitrogen, water and carbon oxides. Suitable catalysts include zeolites having a silicon to aluminum ratio of greater than or equal to about 2.

Abstract: The invention describes a highly efficient catalytic pollution control process for removing N.sub.2 O from gaseous mixtures. The catalytic process, which is substantially unaffected by the presence of oxygen, comprises contacting an N.sub.2 O-containing gaseous mixture with a catalyst comprising a crystalline zeolite which, at least in part, is composed of five membered rings having a structure type selected from the group consisting of BETA, MOR, MFI, MEL and FER wherein the crystalline zeolite has been at least partially ion-exchanged with a metal selected from the group consisting of copper, cobalt, rhodium, iridium, ruthenium and palladium under conditions sufficient to convert the N.sub.2 O into gaseous nitrogen and gaseous oxygen.

Abstract: The present invention relates to sulfur tolerant catalyst composites useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved NOx trap catalysts for use in diesel engines as well as lean burn gasoline engines. The sulfur tolerant NOx trap catalyst composites comprise a platinum component, a support, a NOx sorbent component, and a spinel material prepared by calcining as anionic clay material represented by the formula MmNn(OH)(2m+2n)Aa.bH2O, wherein the formula is defined herein. The sulfur tolerant NOx trap catalyst composites are highly effective with a sulfur containing fuel by trapping sulfur oxide contaminants which tend to poison conventional NOx trap catalysts used to abate other pollutants in the stream.