Abstract: Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a polymer material comprising at least one thermoplastic polymer, at least one polymer precursor, or any combination thereof, and a plurality of piezoelectric particles dispersed in at least a portion of the polymer material. The piezoelectric particles may interact non-covalently with at least a portion of the polymer material, be covalently bonded to at least a portion of the polymer material, and/or be reactive with at least a portion of the polymer material. The compositions may be extrudable and formable into a self-standing three-dimensional structure upon being extruded. Additive manufacturing processes may comprise forming a printed part by depositing the compositions layer-by-layer.

Abstract: An electrochemical device is described, including a first electrochemical cell, a second electrochemical cell, connected in series to the first electrochemical cell, and a biodegradable conductive adhesive may include a conductive additive and a copolymer including at least two polycaprolactone chains attached to a polymeric center block, where the polymeric center block may include polyvinyl alcohol, disposed between the first electrochemical cell and the second electrochemical cell. A biodegradable conductive adhesive includes a hydrogel which may include a copolymer having at least two polycaprolactone chains attached to a polymeric center block, where the polymeric center block may include polyvinyl alcohol. Implementations of the biodegradable conductive adhesive may include a conductive additive or a salt. The biodegradable adhesive can include a dried hydrogel, where the hydrogel is biodegradable.

Abstract: Systems and methods for detecting item placement on a surface are provided. The system includes a pressure-sensitive conductive sheet and a resistive grid connected to the pressure-sensitive conductive sheet. The resistive grid includes an electrically non-conductive polymer. The resistive grid includes one or more lines arranged in a pattern. The lines may include parallel lines, parallel and perpendicular lines, concentric circles, arcs of expanding radius, and/or any other suitable types of lines and/or any combination thereof. The resistive grid may include one or more distinct lines and/or shapes positioned at various points along the pressure-sensitive sheet layer.

Abstract: Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a plurality of piezoelectric particles dispersed in at least a portion of a polymer matrix comprising first polymer material and a sacrificial material, the sacrificial material being removable from the polymer matrix to define a plurality of pores in the polymer matrix. The piezoelectric particles may remain substantially non-agglomerated when combined with the polymer matrix. The sacrificial material may comprise a second polymer material. The compositions may define a composite having a form factor such as a composite filament, a composite pellet, a composite powder, or a composite paste. Additive manufacturing processes may comprise forming a printed part by depositing the compositions layer-by-layer and introducing porosity therein.

Abstract: Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using powder particulates comprising a thermoplastic polymer and piezoelectric particles, wherein the piezoelectric particles are located (i) in the thermoplastic polymer at an outer surface of the powder particulates, (ii) within a core of the powder particulates, or (iii) combinations thereof. Additive manufacturing processes, such as powder bed fusion of powder particulates, may be employed to form printed objects in a range of shapes from the powder particulates. Melt emulsification may be used to form the powder particulates.

Abstract: A renewable material-based furandicarboxylic acid (Bio-FDCA) coating material of a polyurethane controlled release fertilizer is prepared by performing cross-linking reaction between at least one polyester polyol and at least one isocyanate, wherein the polyester polyol is made from the Bio-FDCA. Moreover, a method for preparing a polyurethane controlled release fertilizer includes by spraying the coating material on a surface of granular fertilizer, forming a layer of film after cross-linking in situ on the surface of the granular fertilizer, so as to obtain the polyurethane controlled release fertilizer. In the present invention, it is the first time to introduce the furan ring structure into the coating material of the polyurethane controlled release fertilizer, and the Bio-FDCA is taken as the source of the furan ring structure.

Abstract: A method is disclosed. For example, the method includes applying a clear coat layer on a substrate, drying the clear coat layer to form random microstructures in the clear coat layer, dispensing a printing fluid to print a graphical pattern on the clear coat layer, and generating a physical unclonable function (PUF) pattern by drying the printing fluid that fills the random microstructures formed in the clear coat layer.

Abstract: A staged cementing device includes a cylindrical body having an inner chamber. A circulating opening and a liquid inlet recess open to the inner chamber are arranged on a wall of the body. An opening assembly is arranged in the body, which has an opening sleeve and an opening seat located in the opening sleeve. Initially the opening sleeve is connected with the body through a first shear pin and covers the circulating opening, and the opening seat is connected with the opening sleeve through a second shear pin and covers the liquid inlet recess. A packer includes a packing valve body and a packer rubber. The packing valve body includes a flow channel in communication with the liquid inlet recess, and the packer rubber includes a liquid reservoir in communication with the flow channel. The second shear pin is sheared off in response to primary cementing procedure.

Abstract: A composition, a gas diffusion electrode, and a method for fabricating the same is disclosed. In an example, the composition includes carbon supported carboxyl surface functionalized silver nanoparticles. The gas diffusion electrode can be fabricated with the carbon supported carboxyl surface functionalized silver nanoparticles and deployed in a membrane electrode assembly for various applications.

Abstract: A printable flexible overcoat ink composition that can be digitally printed is disclosed. For example, the printable flexible overcoat ink composition includes a mixture of a thermoplastic polyurethane (TPU) and a solvent. The mixture is mixed to have a viscosity of 1 centipoise to 2,000 centipoise to allow the mixture to be digitally printed via an inkjet printhead or an aerosol jet printhead.

Abstract: A gas diffusion electrode and a method for fabricating the same is disclosed. The gas diffusion electrode can be deployed in a membrane electrode assembly for various applications. In an example, the method to fabricate the gas diffusion electrode includes preparing an ink comprising carbon supported surface functionalized silver nanoparticles and depositing the ink on an electrically conductive surface.

Abstract: Carbon supported surface functionalized silver nanoparticles and a method for preparing the same are disclosed. For example, a composition includes carbon supported surface functionalized silver nanoparticles, The methods include preparing a liquid-containing composition comprising a plurality of silver nanoparticles and adding a carbon structure with the liquid-containing composition to form the carbon supported silver nanoparticles in-situ or mixing a composition comprising a carbon structure, a plurality of silver nanoparticles, and a liquid to grow silver nanoparticles on the carbon structure in-situ.

Abstract: A composition, a gas diffusion electrode, and a method for fabricating the same is disclosed. In an example, the composition includes carbon supported nitrogen surface functionalized silver nanoparticles. The gas diffusion electrode can be fabricated with the carbon supported nitrogen surface functionalized silver nanoparticles and deployed in a membrane electrode assembly for various applications.

Abstract: Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a polymer matrix comprising a first polymer material and a second polymer material that are immiscible with each other, and a plurality of piezoelectric particles located in at least a portion of the polymer matrix. The piezoelectric particles may remain substantially non-agglomerated when combined with the polymer matrix. The compositions may define an extrudable material that is a composite having a form factor such as a composite filament, a composite pellet, a composite powder, or a composite paste. Additive manufacturing processes using the compositions may comprise forming a printed part by depositing the compositions layer-by-layer.

Abstract: Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a component present therein. Composite filaments suitable for additive manufacturing may comprise a continuous polymer phase of a first thermoplastic polymer and a second thermoplastic polymer that are immiscible with one another, and electrically conductive particles distributed in the continuous polymer phase, such as microparticles, nanoparticles, or any combination thereof. The first thermoplastic polymer is dissolvable or degradable and the second thermoplastic polymer is insoluble or non-degradable under specified conditions. Removal of the first thermoplastic polymer from a printed part may introduce porosity thereto, thereby inducing or enhancing piezoresistivity within the printed part.

Abstract: A print feedstock has a base material and a marker material, the base material and the marker material having different physical properties. A system to validate objects includes at least one printer to print feedstock onto an object, the feedstock comprising a base material and a marker material, the base material and a marker material having different properties, a device to create a unique identifier for the object based upon a pattern of the feedstock, and a store in which the unique identifier can be stored.

Abstract: An electrode and a method for fabricating the same is disclosed. For example, the method to fabricate the electrode includes preparing a deposition composition comprising amine-functionalized silver nanoparticles and a solvent and depositing the deposition composition onto an electrically conductive substrate. The electrode can be deployed in a gas diffusion electrode.

Abstract: A 5A5B6C tricyclic spironolactone derivative is provided with a formula XI: The present invention also relates to its preparation method and its applications in the areas of insecticide, nematicide, fungicide and anti-viral agent. The 5A5B6C tricyclic spironolactone derivatives in the present invention are high-performance, broad-spectrum, low-toxicity and low-ecological risk compounds with a wide range of applications in the areas of agriculture, horticulture, forestry and health.

Abstract: Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions comprising a plurality of piezoelectric particles and a polymer material comprising at least one thermoplastic polymer and at least one thermally curable polymer precursor. At a sufficient temperature, the at least one thermally curable polymer precursor may undergo a reaction, optionally also undergoing a reaction with the piezoelectric particles, and form an at least partially cured printed part. The piezoelectric particles may be mixed with the polymer material and remain substantially non-agglomerated when combined with the polymer material.

Abstract: Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component present therein. Printed parts having piezoelectric properties may be formed using compositions that are extrudable and comprise a plurality of piezoelectric particles and a plurality of carbon nanomaterials dispersed in at least a portion of a polymer material. The piezoelectric particles may remain substantially non-agglomerated when combined with the polymer material. The polymer material may comprise at least one thermoplastic polymer, optionally further containing at least one polymer precursor. The compositions may define an extrudable material that is a composite having a form factor such as a composite filament, a composite pellet, a composite powder, or a composite paste. Additive manufacturing processes using the compositions may comprise forming a printed part by depositing the compositions layer-by-layer.