Patents by Inventor Zhigang Lin
Zhigang Lin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11967678Abstract: Electrolyte-infiltrated composite electrode includes an electrolyte component consisting of a polymer matrix with ceramic nanoparticles embedded in the matrix to form a networking structure of electrolyte. Suitable ceramic nanoparticles have the basic formula Li7La3Zr2O12 (LLZO) and its derivatives such as AlxLi7-xLa3Zr2-y-zTayNbzO12 where x ranges from 0 to 0.85, y ranges from 0 to 0.50 and z ranges from 0 to 0.75, wherein at least one of x, y and z is not equal to 0. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between electrode layer and solid-state electrolyte resulting in higher lithium-ion electrochemical cell's cycling stability and longer battery life. Sold-state electrolytes incorporating the ceramic particles demonstrate improved performance.Type: GrantFiled: January 16, 2023Date of Patent: April 23, 2024Assignee: Solid Energies, Inc.Inventors: Zhigang Lin, Chunhu Tan, Tianyu Meng
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Patent number: 11955595Abstract: A ceramic-polymer film includes a polymer matrix; a plasticizer; a lithium salt; and AlxLi7-xLa3Zr1.75Ta0.25O12 where x ranges from 0.01 to 1 (LLZO), wherein the LLZO are nanoparticles with diameters that range from 20 to 2000 nm and wherein the film has an ionic conductivity of greater than 1×10?3 S/cm at room temperature. The nanocomposite film can be formed on a substrate and the concentration of LLZO nanoparticles decreases in the direction of the substrate to form a concentration gradient over the thickness of the film. The film can be employed as a non-flammable, solid-state electrolyte for lithium electrochemical cells and batteries. The LLZO serves as a barrier to dendrite growth.Type: GrantFiled: April 22, 2019Date of Patent: April 9, 2024Assignee: Bioenno Tech LLCInventors: Zhigang Lin, Chunhu Tan, Chao Yi
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Publication number: 20240113299Abstract: High energy density and long cycle life all solid-state electrolyte lithium-ion batteries use ceramic-polymer composite anodes which include a polymer matrix with ceramic nanoparticles, silicon-based anode active materials, conducting agents, lithium salts and plasticizer distributed in the matrix. The silicon-based anode active material are anode active particles formed by high energy milling a mixture of silicon, graphite, and metallic and/or non-metallic oxides. A polymer coating is applied to the particles. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between the electrode layer and solid-state electrolyte resulting in higher lithium-ion battery cell cycling stability and long battery life.Type: ApplicationFiled: December 6, 2023Publication date: April 4, 2024Inventors: Zhigang Lin, Kevin Zanjani
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Patent number: 11888162Abstract: High energy density and long cycle life all solid-state electrolyte lithium-ion batteries use ceramic-polymer composite anodes which include a polymer matrix with ceramic nanoparticles, silicon-based anode active materials, conducting agents, lithium salts and plasticizer distributed in the matrix. The silicon-based anode active material are anode active particles formed by high energy milling a mixture of silicon, graphite, and metallic and/or non-metallic oxides. A polymer coating is applied to the particles. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between the electrode layer and solid-state electrolyte resulting in higher lithium-ion battery cell cycling stability and long battery life.Type: GrantFiled: May 24, 2021Date of Patent: January 30, 2024Assignee: Solid Energies Inc.Inventors: Zhigang Lin, Kevin Zanjani
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Publication number: 20230395843Abstract: A ceramic-polymer film includes a polymer matrix; a plasticizer; a lithium salt; and AlxLi7-xLa3Zr1.75Ta0.25O12 where x ranges from 0.01 to 1 (LLZO), wherein the LLZO are nanoparticles with diameters that range from 20 to 2000 nm and wherein the film has an ionic conductivity of greater than 1×10?3 S/cm at room temperature. The nanocomposite film can be formed on a substrate and the concentration of LLZO nanoparticles decreases in the direction of the substrate to form a concentration gradient over the thickness of the film. The film can be employed as a non-flammable, solid-state electrolyte for lithium electrochemical cells and batteries. The LLZO serves as a barrier to dendrite growth.Type: ApplicationFiled: July 14, 2023Publication date: December 7, 2023Inventors: Zhigang Lin, Chunhu Tan, Chao Yi
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Patent number: 11804318Abstract: Producing CoxFe100-x, where x is an integer from 20 to 95, nanoparticles by: (a) providing a first aqueous hydroxide solution; (b) preparing a second aqueous solution containing iron ions and cobalt ions; and (c) depositing measured volumes of the second aqueous solution into the first aqueous solution whereby coprecipitation yields CoFe alloy nanoparticles, wherein step (c) occurs in an essentially oxygen-free environment. The nanoparticles are annealed at ambient temperatures to yield soft nanoparticles with targeted particle size, saturation magnetization and coercivity. The chemical composition, crystal structure and homogeneity are controlled at the atomic level. The CoFe magnetic nanoparticles have Ms of 200-235 emu/g, (Hc) coercivity of 18 to 36 Oe and size range of 5-40 nm.Type: GrantFiled: June 2, 2021Date of Patent: October 31, 2023Assignee: Aegis Technology Inc.Inventors: Qi Chen, Zhigang Lin
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Publication number: 20230291072Abstract: Fabricating a composite solid-state electrolyte (SSE) membrane by infiltrating a porous polymer substrate with a mixture which comprises: (i) polymer precursor, (ii) ceramic nanoparticles with diameters that range from 10 to 2000 nm, (iii) plasticizer and (iv) lithium salt. Curing the mixture yields a solid-state electrolyte which is formed within pores of the substrate. A continuous roll-to-roll system for manufacturing of large-dimension, flexible, ultrathin, high ionic conductivity (SSE) membrane advances a porous polymer substrate through a coating module, multifunctional module for post-treatment curing and calendar unit. The SSE membrane is used in all solid-state lithium-ion electrochemical pouch cells. The SSE membrane exhibits high ionic conductivity over wide temperature range, especially high value in low temperature (?40° C.).Type: ApplicationFiled: May 16, 2023Publication date: September 14, 2023Inventors: Zhigang Lin, Tianyu Meng
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Publication number: 20230155168Abstract: Electrolyte-infiltrated composite electrode includes an electrolyte component consisting of a polymer matrix with ceramic nanoparticles embedded in the matrix to form a networking structure of electrolyte. Suitable ceramic nanoparticles have the basic formula Li7La3Zr2O12 (LLZO) and its derivatives such as AlxLi7-xLa3Zr2-y-zTayNbzO12 where x ranges from 0 to 0.85, y ranges from 0 to 0.50 and z ranges from 0 to 0.75, wherein at least one of x, y and z is not equal to 0. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between electrode layer and solid-state electrolyte resulting in higher lithium-ion electrochemical cell's cycling stability and longer battery life. Sold-state electrolytes incorporating the ceramic particles demonstrate improved performance.Type: ApplicationFiled: January 16, 2023Publication date: May 18, 2023Inventors: Zhigang Lin, Chunhu Tan, Tianyu Meng
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Patent number: 11631890Abstract: In solid-state lithium-ion battery cells, electrolyte-infiltrated composite electrode includes an electrolyte component consisting of polymer matrix with ceramic nanoparticles embedded in the matrix to form networking structure of electrolyte. The networking structure establishes effective lithium-ion transport pathway in the electrode. Electrolyte-infiltrated composite electrode sheets and solid electrolyte membranes can be used in all solid-state lithium electrochemical pouch and coin cells. Solid-state lithium-ion battery is fabricated by: (a) providing an anode layer; (b) providing a cathode layer; (c) positioning a ceramic-polymer composite electrolyte membrane between the anode layer and the cathode layer to form a laminar battery assembly; (d) applying pressure to the laminar battery assembly; and (e) heating the laminar battery assembly.Type: GrantFiled: May 6, 2021Date of Patent: April 18, 2023Assignee: Solid Energies Inc.Inventors: Zhigang Lin, Tianyu Meng
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Patent number: 11588176Abstract: Electrolyte-infiltrated composite electrode includes an electrolyte component consisting of a polymer matrix with ceramic nanoparticles embedded in the matrix to form a networking structure of electrolyte. Suitable ceramic nanoparticles have the basic formula Li7La3Zr2O12 (LLZO) and its derivatives such as AlxLi7-xLa3Zr2-y-zTayNbzO12 where x ranges from 0 to 0.85, y ranges from 0 to 0.50 and z ranges from 0 to 0.75, wherein at least one of x, y and z is not equal to 0. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between electrode layer and solid-state electrolyte resulting in higher lithium-ion electrochemical cell's cycling stability and longer battery life. Sold-state electrolytes incorporating the ceramic particles demonstrate improved performance.Type: GrantFiled: January 4, 2021Date of Patent: February 21, 2023Assignee: Bioenno Tech LLCInventors: Zhigang Lin, Chunhu Tan, Tianyu Meng
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Publication number: 20230035720Abstract: Fabricating a composite solid-state electrolyte (SSE) membrane by infiltrating a porous polymer substrate with a mixture which comprises: (i) polymer precursor, (ii) ceramic nanoparticles with diameters that range from 10 to 2000 nm, (iii) plasticizer and (iv) lithium salt. Curing the mixture yields a solid-state electrolyte which is formed within pores of the substrate. A continuous roll-to-roll system for manufacturing of large-dimension, flexible, ultrathin, high ionic conductivity (SSE) membrane advances a porous polymer substrate through a coating module, multifunctional module for post-treatment curing and calendar unit. The SSE membrane is used in all solid-state lithium-ion electrochemical pouch cells. The SSE membrane exhibits high ionic conductivity over wide temperature range, especially high value in low temperature (?40° C.).Type: ApplicationFiled: July 30, 2021Publication date: February 2, 2023Inventors: Zhigang Lin, Tianyu Meng
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Publication number: 20230013068Abstract: High voltage, high-ionic-conductivity, fire resistant solid-state polymer electrolytes include poly(vinylidene fluoride-co-hexafluoropropylene) P(VDF-HFP), sulfolane plasticizer, lithium salt, and ceramic nanoparticles with the basic formula Li7La3Zr2O12 (LLZO) and derivatives thereof. During the curing process, the presence of the LLZO nanoparticles prevent the P(VDF-HFP) from developing into a crystalline phase. In the electrolyte formed, the P(VDF-HFP) is in an amorphous phase with LLZO nanoparticles, lithium salt and sulfolane distributed in the polymer matrix. The solid-state electrolyte with the amorphous polymer phase exhibit higher ionic conductivities than those having a crystalline polymer phase. The LLZO contributes to mechanical properties of the electrolyte and also function as tough ceramic fillers that inhibit lithium dendrite growth during operation of lithium-ion cells and batteries.Type: ApplicationFiled: September 9, 2022Publication date: January 19, 2023Inventor: Zhigang Lin
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Publication number: 20220376255Abstract: High energy density and long cycle life all solid-state electrolyte lithium-ion batteries use ceramic-polymer composite anodes which include a polymer matrix with ceramic nanoparticles, silicon-based anode active materials, conducting agents, lithium salts and plasticizer distributed in the matrix. The silicon-based anode active material are anode active particles formed by high energy milling a mixture of silicon, graphite, and metallic and/or non-metallic oxides. A polymer coating is applied to the particles. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between the electrode layer and solid-state electrolyte resulting in higher lithium-ion battery cell cycling stability and long battery life.Type: ApplicationFiled: May 24, 2021Publication date: November 24, 2022Inventors: Zhigang Lin, Kevin Zanjani
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Publication number: 20220359906Abstract: In solid-state lithium-ion battery cells, electrolyte-infiltrated composite electrode includes an electrolyte component consisting of polymer matrix with ceramic nanoparticles embedded in the matrix to form networking structure of electrolyte. The networking structure establishes effective lithium-ion transport pathway in the electrode. Electrolyte-infiltrated composite electrode sheets and solid electrolyte membranes can be used in all solid-state lithium electrochemical pouch and coin cells. Solid-state lithium-ion battery is fabricated by: (a) providing an anode layer; (b) providing a cathode layer; (c) positioning a ceramic-polymer composite electrolyte membrane between the anode layer and the cathode layer to form a laminar battery assembly; (d) applying pressure to the laminar battery assembly; and (e) heating the laminar battery assembly.Type: ApplicationFiled: May 6, 2021Publication date: November 10, 2022Inventors: Zhigang Lin, Tianyu Meng
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Patent number: 11430711Abstract: A high performance, lead free, Ag paste thermal interface material (TIM) for die attachment and substrate bonding in electronic packaging includes: (i) multiscale silver particles, (ii) metal-coated carbon nanotubes (CNTs), (iii) a polymer, and (iv) a liquid carrier. The multiscale silver particles and metal-coated carbon nanotubes, which function as hybrid filler components, are uniformly dispersed within the TIM composition. The sintered TIM exhibits high density, high mechanical strength, and high thermal conductivity. The components of the liquid carrier including the solvent, binder, surfactants, and thinner are completely evaporated or burned off during sintering. Sintering of the TIM can be conducted at a relatively low temperature, without or with very low (<0.1 MPa) pressure, in open air and without vacuum or inert gas protection. The TIM can be utilized in substrate bonding not only on conventional metal-plated surfaces but also bare Cu substrate surfaces.Type: GrantFiled: November 26, 2019Date of Patent: August 30, 2022Assignee: Aegis Technology Inc.Inventors: Zhigang Lin, Chunhu Tan, Shuyi Chen
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Publication number: 20220216505Abstract: Electrolyte-infiltrated composite electrode includes an electrolyte component consisting of a polymer matrix with ceramic nanoparticles embedded in the matrix to form a networking structure of electrolyte. Suitable ceramic nanoparticles have the basic formula Li7La3Zr2O12 (LLZO) and its derivatives such as AlxLi7-xLa3Zr2-y-zTayNbzO12 where x ranges from 0 to 0.85, y ranges from 0 to 0.50 and z ranges from 0 to 0.75, wherein at least one of x, y and z is not equal to 0. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between electrode layer and solid-state electrolyte resulting in higher lithium-ion electrochemical cell's cycling stability and longer battery life. Sold-state electrolytes incorporating the ceramic particles demonstrate improved performance.Type: ApplicationFiled: January 4, 2021Publication date: July 7, 2022Inventors: Zhigang Lin, Chunhu Tan, Tianyu Meng
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Patent number: 11230529Abstract: Provided is a method of preparing 3-fluoroalkyl-1-substituted pyrazol-4-carboxylic acid by air oxidation. The methoduses 3-fluoroalkyl-1-substituted pyrazol-4-formaldehyde as raw material for reaction in a neutral or alkaline condition under the action of a catalyst and with air as an oxidizing agent, to obtain 3-fluoroalkyl-1-substituted pyrazol-4-carboxylic acid. The method employs a mild, safe and clean reaction, and is suitable for industrial mass production.Type: GrantFiled: February 19, 2014Date of Patent: January 25, 2022Assignee: ABA CHEMICALS (NANTONG) LIMITEDInventors: Zhigang Lin, Yueheng Jiang, Tong Cai
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Patent number: 11223088Abstract: Ceramic-polymer film includes a polymer matrix, plasticizers, a lithium salt, and a ceramic nanoparticle, LLZO: AlxLi7-xLa3Zr1.75Ta0.25O12 where x ranges from 0 to 0.85. The nanoparticles have diameters that range from 20 to 2000 nm and the film has an ionic conductivity of greater than 1×10?4 S/cm (?20° C. to 10° C.) and larger than 1×10?3 S/cm (?20° C.). Using a combination of selected plasticizers to tune the ionic transport temperature dependence enables the battery based on the ceramic-polymer film to be operable in a wide temperature window (?40° C. to 90° C.). Large size nanocomposite film (area ?8 cm×6 cm) can be formed on a substrate and the concentration of LLZO nanoparticles decreases in the direction of the substrate to form a concentration gradient over the thickness of the film. This large size film can be employed as a non-flammable, solid-state electrolyte for lithium electrochemical pouch cell and further assembled into battery packs.Type: GrantFiled: October 7, 2019Date of Patent: January 11, 2022Assignee: BIOENNO TECH LLCInventors: Zhigang Lin, Chunhu Tan, Tianyu Meng, Shuyi Chen, Kevin Zanjani
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Publication number: 20210347654Abstract: Producing CoxFe100-x, where x is an integer from 20 to 95, nanoparticles by: (a) providing a first aqueous hydroxide solution; (b) preparing a second aqueous solution containing iron ions and cobalt ions; and (c) depositing measured volumes of the second aqueous solution into the first aqueous solution whereby coprecipitation yields CoFe alloy nanoparticles, wherein step (c) occurs in an essentially oxygen-free environment. The nanoparticles are annealed at ambient temperatures to yield soft nanoparticles with targeted particle size, saturation magnetization and coercivity. The chemical composition, crystal structure and homogeneity are controlled at the atomic level. The CoFe magnetic nanoparticles have Ms of 200-235 emu/g, (Hc) coercivity of 18 to 36 Oe and size range of 5-40 nm.Type: ApplicationFiled: June 2, 2021Publication date: November 11, 2021Inventors: Qi Chen, Zhigang Lin
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Patent number: 11094463Abstract: Spherical ceramic-glass nanocomposite dielectrics made from ceramics and glasses that are separately pre-milled by mechanical ball milling using selected ball-to-powder weight ratios and combined to form a mixture that is ball milled. A stable liquid suspension of the milled mixture including an added dispersant such as polyacrylic acid to improve uniformity is spray dried through a nozzle and recovered product is annealed. The novel dielectrics have a microstructure where ceramic primary particles are uniformly distributed and fully embedded in a glass matrix. The dielectrics have a mean particle size of about 1-20 um and a sphericity of about 0.8 or higher which are suitable for fabricating multilayer ceramic capacitors for high temperature applications. The novel dielectrics afford decreased sintering temperature, enhanced breakdown strength, lower dielectric lose tangent, and lower costs.Type: GrantFiled: February 27, 2019Date of Patent: August 17, 2021Assignee: Aegis Technology Inc.Inventors: Zhigang Lin, Chunhu Tan