Method of manufacturing stretchable sheet
To acquire a stretchable sheet having air permeability due to the presence of through-holes, with no hole formed through outer layers. There are provided: interposing a resilient film (30) that stretches and contracts, in a stretched state between a first sheet layer (21) having no elasticity and a second sheet layer (22) having no elasticity; and joining the first sheet layer (21) and the second sheet layer (22) together with a number of joints directly or through the resilient film 30 by melting the resilient film (30) with ultrasonic fusion energy applied by a thermal fusion device from the outside of the first sheet layer (21) and the outside of the second sheet layer (22) to a number of joint regions with intervals, during the interposing. A through-hole (31) is formed through at least a boundary portion in a direction of the stretching between the resilient film (30) and each of joints (40), with the first sheet layer (21) and the second sheet layer (22) retained, no hole being formed over the entirety of each of the joint regions.
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The present invention relates to a method of manufacturing a stretchable sheet including a resilient film interposed between a first sheet layer and a second sheet layer.
BACKGROUND ARTElasticity is typically added to proper positions, such as legs and a waist, in an absorbent article, for example, a disposable diaper in order to improve a fit to the surface of a body. Conventionally, a technique of securing an elongated resilient and elastic member, such as a rubber thread, that has stretched in a longitudinal direction, has been widely adopted as an exemplary technique of adding elasticity. In a case where elasticity is added with a degree of width, a mode of securing rubber threads arranged with intervals in a width direction, has been adopted.
Meanwhile, a stretchable sheet having a nonwoven fabric/elastomeric film/nonwoven fabric structure, has been proposed in consideration of performing pressing to an elongated face to add elasticity in addition to texture, instead of the plurality of rubber threads arranged in parallel (e.g., Patent Literature 1).
Patent Literature discloses a porous mode in which a hole that penetrates through the entirety of a first outer layer, a second outer layer, and a resilient film, is formed, in addition to a nonporous mode in which no hole is formed through the entirety of the first outer layer, the second outer layer, and the elastic film.
However, in the porous mode in Patent Literature 1, the resilient film (an elastomer) that is continuous and stretches and contracts in an MD direction is supplied between the first outer layer and the second outer layer, the elastic film having a melting point higher than those of the outer layers or no melting point, and then the first outer layer and the second outer layer are directly joined together by welding at a predetermined position. After that, tensile force acts in a CD direction to form a through-hole penetrating through the entirety of the first outer layer, the resilient film, and the second outer layer, at a joined site.
In a case where the stretchable sheet in the nonporous mode is used, for example, as a sheet included in the back surface of a disposable diaper, there is a problem that stuffiness occurs due to no air permeability.
Meanwhile, the porous mode has air permeability, but it is assumed that there is a possibility of breaking in a case where excessive stretching and contracting stress acts on the stretchable sheet.
CITATION LIST Patent Literature
- Patent Literature 1: JP 4562391 B2
A main object of the present invention is to acquire a stretchable sheet having air permeability due to the presence of through-holes, the stretchable sheet including no hole formed through outer layers.
Solution to ProblemThe present invention that has solved the problem, as follows:
(Primary Mode)
A method of manufacturing an stretchable sheet that stretches and contracts, according to the present invention, includes: interposing a resilient film that stretches and contracts, in a stretched state between a first sheet layer having no elasticity and a second sheet layer having no elasticity; and joining the first sheet layer and the second sheet layer together with a number of joints directly or through the resilient film by melting the resilient film with ultrasonic fusion energy applied by a thermal fusion device from an outside of the first sheet layer and an outside of the second sheet layer to a number of joint regions with intervals, in a state where the resilient film has been interposed in the stretched state between the first sheet layer and the second sheet layer, during the interposing. A through-hole is formed through at least a boundary portion in a direction of the stretching between the resilient film and each of the joints, with the first sheet layer and the second sheet layer retained, no hole being formed over the entirety of each of the joint regions, during the joining.
The stretchable sheet according to the present invention, includes no hole formed through the first sheet layer and the second sheet layer. Regarding this point, the stretchable sheet is different from a stretchable sheet illustrated in FIG. 5 or 7 in JP 4562391 B2.
Meanwhile, providing the resilient film in the stretched state in a machine direction to a position at which the joining is performed, can form a through-hole through at least a boundary portion in the machine direction between the resilient film and each of the joints.
The reason why the through-holes are formed, will be described in detail later.
The thermal fusion device includes an anvil roll and an ultrasonic horn. The anvil roll includes a number of protruding portions formed with intervals in a roll length direction and in an outer circumferential direction on an outer surface. A group of the protruding portions and the ultrasonic horn can perform the joining.
Instead of the ultrasonic thermal fusion device, a different thermal fusion unit may be provided.
The resilient film is inserted into a nip roll stage including the anvil roll and a nip roll facing the anvil roll so as to be supplied around the anvil roll through a nip, and the anvil roll and the ultrasonic horn can join the first sheet layer, the resilient film, and the second sheet layer together, the ultrasonic horn being arranged to face the anvil roll at a position downstream from a position of the nip.
Accelerating the anvil roll to be faster than the nip roll in peripheral speed, can stretch the resilience film.
In stretching the resilient film, nip roll stages including a pair of nips arranged in a front-back direction are provided, the nips facing each other. Due to the interaction of the front and back nip roll stages, the front nip roll stage is accelerated to be faster than the rear nip roll stage in peripheral speed. Thus, the resilient film in the stretched state can be supplied to the interposing.
An exemplary arrangement of the joints has a staggered pattern
The following exemplary joining modes may be provided for the joints in an elastic portion according to the present invention.
- (1) A mode in which the first sheet layer and the second sheet layer partially melt to join the resilient film together, namely, the first sheet layer and the second sheet layer are joined together through the resilient film.
- (2) A mode in which the resilient film melts so as to make a transition into the first sheet layer and the second sheet layer so that the first sheet layer and the second sheet layer are directly joined together without the resilient film.
- (3) A mode in which both surface regions of the resilient film melt to make a transition into the first sheet layer and the second sheet layer, but the resilient film partially remains so that the first sheet layer and the second sheet layer are jointed together through the remaining resilient film, the mode being intermediate between the mode (1) and the mode (2).
Particularly, a difference occurs in resilient film strength between the joints and non-joints in the mode (2) and the mode (3) among the modes. Therefore, breaking occurs at the boundary portion between each joint and each non-joint when stretching is performed mechanically or manually in the stretching and contracting direction: after a product is made with the stretchable sheet contracted by temporarily releasing the stretched state in which the stretchable sheet has stretched; or after a product is made with the stretchable sheet contracted by temporarily releasing the stretched state after the stretchable sheet that has stretched is joined to a different member.
As a result, the through-holes are formed.
The formation of the through-holes has the advantage of securing air permeability. The through-holes are not necessarily required to be formed to all the joints, and thus forming the through-holes to some joints also indicates air permeability. In a case where the resilient film can stretch and contract only in the machine direction, the through-holes each have a shape stretched from the edge of the joint in the machine direction. In a case where the resilient film can stretch and contract in both the machine direction (MD) and a direction orthogonal to the machine direction (e.g., a CD direction), the through-holes each have a shape stretched from the edge of the joint in both directions and, in some cases, may have an annular shape around the joint.
As previously described, the resilient film according to the present invention, includes an elastomer in general so as to be able to stretch and contract in the machine direction (MD) and in the orthogonal direction (CD).
The joints having no directivity, such as a circle, are provided or the joints each having a length in the orthogonal direction (the width direction: CD) longer than a length in the machine direction (MD), are provided.
In order to perform the method according to the present invention, the melting point of the resilient film is preferably approximately 80 to 145° C., the melting points of the first sheet layer and the second sheet layer are preferably approximately 85 to 190° C., particularly preferably approximately 130 to 190° C., and the difference between the melting points of the first sheet layer and the second sheet layer and the melting point of the resilient film being lower is preferably approximately 50 to 80° C.
As a preferred specific example, the melting point of the resilient film is 95 to 125° C., the melting point of the first sheet layer is more than 125° C. to 160° C., more preferably 130 to 160° C., and the melting point of the second sheet layer is more than 125° C. to 160° C., more preferably 130 to 160° C.
As a preferred example of the points, the area of each of the joints in the elastic region is 0.14 to 3.5 mm2. The area of the opening of each of the through-holes in a natural length state, is 1 to 1.5 times the area of each of the joints. The area rate of the joints in the elastic region is 1.8 to 22.5%.
Here, the “area rate” means the ratio of an object portion per unit area, and the total area of the object portion (e.g., the joints and the openings of the through-holes) in an object region (e.g., the elastic region), divided by the area of the object region, is expressed in percentage. In particular, the “area rate of the joints” means an area rate in a state where the object region has stretched up to an elastic limit. The area of the opening of each of the through-holes means a value in a state where the stretchable structure has had a natural length, and means a minimum value in a case where the area of the opening of each of the through-holes is nonuniform in a thickness direction, such as nonuniformity between the front and back of the resilient film.
The joint area rate in the present specification, can be selected by determining the protruding portions of the anvil roll in size, shape, space interval, arrangement pattern in the roll length direction and the roll circumferential direction, to be described later.
“stretching stress” to be described later means “stress (N/35 mm) in performing stretching up to 50% of the elastic limit” measured in a tensile test having an initial chuck interval (a reference inter-line distance) of 50 mm and a tensile speed of 300 mm/min conforming to JIS K7127: 1999 “Plastics-Determination of tensile properties”. In a case where a test piece having a width of 35 mm may not be cut out, the test piece having a width that can be cut out is prepared and then a value including a measured value converted into the width of 35 mm, is used. In a case where an object region is small and no sufficient test piece may be extracted, as long as comparison in stretching and contracting stress is made, even a small test piece can be at least compared appropriately.
In an embodiment to be described later, in a case where a region includes different pieces of stretching stress, there is the problem of how to extract test pieces for verifying a difference in elastic force. In this case, for comparison in stretching and contracting stress, a test piece is extracted for each site of the stretchable sheet, and then the test pieces can be compared in magnitude with the stress when a length of 100% in a natural state is stretched to a length of 150%, instead of acquiring an absolute value in stretching and contracting stress.
Advantageous Effects of InventionAs described above, according to the present invention, the stretchable sheet has air permeability due to the presence of the through-holes in a case where the first sheet layer and the second sheet layer each include a nonwoven fabric. Furthermore, both outer layers have no hole formed so that there is the advantage that excellent appearance is acquired.
An embodiment of the present invention will be described in detail below with reference to the attached drawings.
A stretchable sheet according to the present invention can be used for an absorbent article, such as a disposable diaper, a sanitary napkin, or an absorbent pad, that absorbs and retains a body fluid.
As illustrated in
Here, the “having no elasticity” of each of the first sheet layer 21 and the second sheet layer 22 does not mean completely no stretch and contraction but substantially no stretch and contraction for comparison in the degree of the elasticity of the resilient film 30.
In the joining, as illustrated in
Note that, exemplary joining modes will be described in detail later.
The resilient film 30 is inserted into a nip roll stage including a nip roll 63 and the anvil roll 60 facing the nip roll 63, the resilient film 30 being supplied around the nip roll 63, so that the resilient film 30 can be supplied around the anvil roll 60 through the nip of the nip roll stage.
At this time, selecting a speed difference for accelerating the peripheral speed of the anvil roll 60 driven to rotate, to be faster than the peripheral speed of the nip roll 63, can set a stretch rate (a length is defined as 100% in a natural state as a reference) in a manufacturing process of the resilient film 30.
As illustrated in
The stretchable sheet is manufactured in a manufacturing line for a product and additionally a web of the stretchable sheet is manufactured. After that, the stretchable sheet cut into a predetermined area, can be applied to a predetermined site of the product.
Typically, a sheet secured with a plurality of rubber threads in parallel is applied to a conventional disposable diaper. However, the conventional disposable diaper is disadvantageous in terms of deterioration in quality due to degradation of a hot-melt adhesive for securing to the rubber threads and the sheet as well as unstable productivity in manufacturing. The stretchable sheet can solve the problems.
Moreover, as apparent from the contracted state in
Meanwhile, the first sheet layer 21 and the second sheet layer 22 are joined together with the resilient film 30 melted in the example. In this case, there may be provided: (1) a mode in which the first sheet layer 21 or the second sheet layer 22 is joined on the surface of the resilient film 30; (2) a mode in which a surface region of the resilient film 30 melts and invades the respective fibers of the first sheet layer 21 and the second sheet layer 22 to perform the joining; and (3) a mode in which substantially the entire resilient film 30 melts and invades the respective fibers of the first sheet layer 21 and the second sheet layer 22 to perform the joining. The layer-to-layer joining mode according to the present invention, is not limited to these modes.
It can be evaluated that the first sheet layer 21 and the second sheet layer 22 are directly, namely, without the resilient film interposed, joined together in the mode (3) among the modes.
In the modes (1) to (3), the melting point of the resilient film 30 is lower than the melting points of the first sheet layer 21 and the second sheet layer 22. However, the melting point of the resilient film 30 may be higher than the melting points of the first sheet layer 21 and the second sheet layer 22. In this case, a surface portion of at least one of the first sheet layer 21 and the second sheet layer 22, on the side of the resilient film 30, becomes active or melts so as to join to the resilient film 30.
Furthermore, the resilient film 30 partially may melt and additionally at least one of the first sheet layer 21 and the second sheet layer 22 may melt to perform the joining.
At least one of the first sheet layer 21 and the second sheet layer 22 may include a nonwoven fabric, and the fabric may have a core-sheath structure. In this case, for example, melting only the sheath component of the fabric melts can contribute to the joining.
In the stretchable sheet according to the present invention, the bond portion 40 are uniform in shape, size, and arrangement. In addition, the ratio of the total area of the bond portion 40 included in a unit area of the region to the unit area, namely, a joint area rate can be selected.
With reference to
The bond portion 40 each exemplarily has a circular shape as illustrated in
For example, in comparison between a case A where the pitch length Pm and the pitch length Pc are long and a case B where the pitch length Pm and the pitch length Pc are short, the case A where the pitch lengths Pm and Pc are long (a case where the joint area rate is low) is larger than the case B where the pitch lengths Pm and Pc are short (a case where the joint area rate is high) in stretch rate. As a result, the following relationship is satisfied in stretching and contracting stress: A>B.
In the mode in
In
According to the present invention, varying roughness and fineness in arrangement pattern or a joint area, can achieve a difference in joint area rate.
In order to understand the achievement,
Physical properties, such as the thickness, material, distortion and stress characteristic, and melting point of the resilient film 30, can be appropriately selected. Selecting a relationship between the resilient film 30, the ultrasonic fusion energy to be applied to the resilient film 30, and the stretch rate of the resilient film 30 in manufacturing the stretchable sheet, can form a through-hole 31 around each of the bond portion 40 as illustrated in
The reason why the through-holes 31 for the ventilation are formed is not necessarily clarified, but the ultrasonic fusion energy melts the resilient film 30 and additionally the protruding portions 60a of the anvil roll 60 presses the bond portion 40 to be a thin layer. It is considered that, at this time, a peripheral portion of each of the bond portion 40 reaches breaking strength with the resilient film 30 becoming thin and then starts breaking due to stretching and contracting stress acting on the resilient film 30 that has stretched, so that the peripheral portion contracts up to a balanced position so as to open.
The bond portion 40 can be made to have an elongated shape in the direction (the cross direction: CD) orthogonal to the stretching direction (the machine direction: MD). In this case, as illustrated in
On the other hand, the through-holes 31 are not necessarily formed to all the bond portion 40. If the through-holes 31 are required to be securely formed or to open large, a technique illustrated in
That is, as illustrated in
Each bond portion 40 and through-hole 31 in shape in a natural length state, can have an arbitrary shape, such as a perfect circular shape, an elliptical shape, a polygonal shape, such as a rectangular shape (a linear shape and a rounded-corner shape included), a star shape, or a cloud shape. Each bond portion 40 is required at least to appropriately be determined in size. However, when the size is too large, influence of the bond portion 40 in hardness on a feel increases. When the size is too small, the joint area decreases and adhesion may not be sufficiently made between the materials. Thus, typically, each bond portion 40 preferably has an area of approximately 0.14 to 3.5 mm2. Since the joints are formed through the through-holes 31, the opening area of each through-hole 31 is required at least to be not less than each bond portion 40, but is preferably approximately 1 to 1.5 times the area of each of the bond portion 40.
The bond portion 40 according to the present invention may make a transition directly from a main elastic portion to a non-elastic region, and additionally a transition elastic portion can be intermediately formed.
Typically, the area of each bond portion 40 and the area rate of the bond portion 40 in each region, are preferably made as follows:
(Non-Elastic Region)
Area of each bond portion 40: 0.14 to 3.5 mm2 (specifically, 0.25 to 1.0 mm2)
Area rate of the bond portion 40: 16 to 45% (specifically, 25 to 45%)
(Main Elastic Portion)
Area of each bond portion 40: 0.14 to 3.5 mm2 (specifically, 0.14 to 1.0 mm2)
Area rate of the bond portion 40: 1.8 to 19.1% (specifically, 1.8 to 10.6%)
(Transition Elastic Portion)
Area of each bond portion 40: 0.14 to 3.5 mm2 (specifically, 0.25 to 1.0 mm2)
Area rate of the bond portion 40: 8 to 22.5% (specifically, 12.5 to 22.5%)
The plane arrangement of the bond portion 40 and the through-holes 31 can be appropriately determined, and preferably has regular repetition. Examples of the regular repetition that can be used, include a rhombic lattice pattern as illustrated in
The resilient film 30 is not particularly limited, and a resin film required at least to have its own elasticity, can be, but not particularly limited, used. A blend including at least one of thermoplastic elastomers, such as a styrene elastomer, an olefin elastomer, a polyester elastomer, polyamide elastomer, and a polyurethane elastomer, processed to have a film shape by extrusion molding, such as a T-die method or an inflation method, can be used. In addition to a nonporous film, a film including a number of holes or slits formed for ventilation, can be used for the resilient film 30. In particular, the resilient film 30 preferably has a tensile strength of 8 to 25 N/35 mm in the stretching and contracting direction, a tensile strength of 5 to 20 N/35 mm in the direction orthogonal to the stretching and contracting direction, a tensile elongation of 450 to 1050% in the stretching and contracting direction, and a tensile elongation of 450 to 1400% in the direction orthogonal to the stretching and contracting direction. Note that, except that a test piece has a rectangular shape measuring 35 mm wide by 80 mm long and a tensile testing machine (e.g., AUTOGRAPHAGS-G100N manufactured by SHIMADZU Corporation) is used, the tensile strength and the tensile elongation (breaking elongation) indicate values measured with an initial chuck interval of 50 mm and a tensile speed of 300 mm/min conforming to JIS K7127: 1999 “Plastics-Determination of tensile properties”. The thickness of the resilient film 30 is not particularly limited, but is preferably approximately 20 to 40 μm. The basis weight of the resilient film 30 is not particularly limited, but is preferably approximately 30 to 45 g/m2, and particularly preferably approximately 30 to 35 g/m2.
Glossary in SpecificationThe terms in the specification below have the following meanings unless otherwise described in the specification.
-
- The “stretch rate” means a value based on the natural length defined as 100%.
- The “basis weight” is measured as follows: A sample or a test piece is preliminarily dried and then is retained into a laboratory or into a device in a reference condition (the temperature and the relative humidity in an experimental area are 20±5° C. and 65% or less, respectively) so as to have a constant weight. The preliminary drying means that the sample or the test piece is made to have the constant weight in an environment in which the relative humidity is not out of 10 to 25% and the temperature does not exceed 50° C. Note that, fibers having an official regain of 0.0% are not required to be preliminarily dried. A sample having dimensions of 200 mm 250 mm (±2 mm) is cut out from the test piece that has had the constant weight, with a cutting template (200 mm×250 mm, ±2 mm). The weight of the sample is measured and then is multiplied by 20 so that the weight per square meter is calculated to be as the basis weight.
- In a case where no environmental conditions have described in experiment and measurement, the experiment and the measurement are performed in the laboratory or in the device in the reference condition (the temperature and the relative humidity in the experimental area are 20±5° C. and 65% or less, respectively).
The present invention can be applied to absorbent articles in general each having a stretchable structure, examples of the absorbent articles including various disposable diapers, such as a tape type disposable diaper and a pad type disposable diaper, and a sanitary napkin, in addition to the underpants-type disposable diaper exemplarily described above.
With joining being performed in a manufacturing line for an absorbent article, the stretchable sheet according to the present invention can be manufactured as a sheet included in the back of the absorbent article.
REFERENCE SINGS LIST
- A to D regions
- 21 first sheet layer
- 22 second sheet layer
- 30 resilient film
- 31 through-hole
- 40 bond portion
- 60 anvil roll
- 61 ultrasonic horn
Claims
1. A method of manufacturing a stretchable sheet that stretches and contracts, the method comprising:
- interposing a resilient film that stretches and contracts, in a stretched state between a first sheet layer having no elasticity and a second sheet layer having no elasticity; and
- joining the first sheet layer and the second sheet layer together at a number of joints directly or through the resilient film by melting the resilient film with thermal fusion energy applied by a thermal fusion device from an outside of the first sheet layer and an outside of the second sheet layer with intervals, in a state where the resilient film has been interposed in the stretched state between the first sheet layer and the second sheet layer, during the interposing,
- wherein the thermal fusion device includes an anvil roll and an ultrasonic horn,
- the anvil roll includes a number of protruding portions forming on an outer circumferential surface of the anvil roll with intervals in a rolling direction,
- the number of the protruding portions and the ultrasonic horn perform the joining,
- the anvil roll faces a nip roll,
- the resilient film and the second sheet layer are inserted into a nip roll stage including the nip roll and the anvil roll facing the nip roll, the resilient film is supplied around the nip roll, the resilient film and the second sheet layer are supplied around the anvil roll through nips of the nip roll stage,
- the anvil roll and the ultrasonic horn join the first sheet layer, the resilient film, and the second sheet layer together, the ultrasonic horn is arranged to face the anvil roll, and
- a through-hole is formed at least at a boundary portion in a direction of the stretching between the resilient film and each of the joints, with the first sheet layer and the second sheet layer retained, no hole is formed over entirety of each of joint regions during the joining.
2. A method of manufacturing a stretchable sheet that stretches and contracts, the method comprising:
- interposing a resilient film that stretches and contracts, in a stretched state between a first sheet layer having no elasticity and a second sheet layer having no elasticity, the first sheet layer being supplied in a machine direction, the second sheet layer being supplied in the machine direction, the resilient film being supplied in the machine direction; and
- joining the first sheet layer and the second sheet layer together at a number of joints directly or through the resilient film by melting the resilient film with thermal fusion energy applied by a thermal fusion device from an outside of the first sheet layer and an outside of the second sheet layer with intervals, in a state where the resilient film has been interposed in the stretched state between the first sheet layer and the second sheet layer, during the interposing,
- wherein the thermal fusion device includes an anvil roll and an ultrasonic horn,
- the anvil roll includes a number of protruding portions formed with intervals in a roll length direction and in an outer circumferential direction on an outer surface,
- the number of the protruding portions and the ultrasonic horn perform the joining,
- the anvil roll faces a nip roll,
- the resilient film and the second sheet layer are inserted into a nip roll stage including the nip roll and the anvil roll facing the nip roll, the resilient film is supplied around the nip roll, the resilient film and the second sheet layer are supplied around the anvil roll through nips of the nip roll stage,
- the anvil roll and the ultrasonic horn join the first sheet layer, the resilient film, and the second sheet layer together, the ultrasonic horn is arranged to face the anvil roll, and
- a through-hole is formed at least at a boundary portion in the machine direction between the resilient film and each of the joints, with the first sheet layer and the second sheet layer retained, no hole is formed over entirety of each of joint regions during the joining.
3. The method of manufacturing the stretchable sheet according to claim 1, wherein the anvil roll is accelerated to be faster than the nip roll in peripheral speed to stretch the resilient film.
4. The method of manufacturing the stretchable sheet according to claim 1, wherein a driving roll and a guide roller which nip the resilient film are provided,
- the resilient film is configured to pass between the driving roll and the guide roller, then pass between the nip roll and the anvil roll, and
- the anvil roll is accelerated to be faster than the nip roll in peripheral speed to stretch the resilient film with the speed difference.
5. The method of manufacturing the stretchable sheet according to claim 1, wherein the resilient film including the joints is inserted between a pair of rolls each including elongated protrusions or projections, and then,
- the projections on one of the rolls are thrust between the adjacent projections on the other roll so that the through-holes are formed.
6. The method of manufacturing the stretchable sheet according to claim 1, wherein the stretchable sheet includes a transition elastic portion from a main elastic portion to a non-elastic region.
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Type: Grant
Filed: Jan 29, 2016
Date of Patent: Dec 31, 2019
Patent Publication Number: 20180014979
Assignee: DAIO PAPER CORPORATION (Ehime)
Inventor: Masaya Fujita (Tochigi)
Primary Examiner: James D Sells
Application Number: 15/546,175
International Classification: B32B 37/00 (20060101); A61F 13/15 (20060101); A61F 13/49 (20060101); A61F 13/496 (20060101); B29C 65/00 (20060101); B32B 37/14 (20060101);