Battery module with stack restraining member
A displacement adjustment member provided in a battery module disclosed herein has at least a first elastic body and a second elastic body capable of undergoing elastic deformation in the stacking direction of unit cells. The first elastic body is made of an elastic body in which an elastic deformation extent, with respect to a predetermined load, is relatively larger than that of the second elastic body.
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The present application claims priority to Japanese Patent Application No. 2018-007550 filed on Jan. 19, 2018, the entire contents whereof are incorporated into the present specification by reference.
BACKGROUND OF THE INVENTION 1. Field of the InventionThe present invention relates to a battery module (also referred to as battery pack and assembled battery). More particularly, the present invention relates to a battery module in which a plurality of unit cells is held in a restrained state.
2. Description of the Related ArtBattery modules provided with a plurality of unit cells in the form of secondary batteries such as lithium ion secondary batteries or nickel-hydride batteries have gained in importance as power sources for mounting in vehicles that are driven by electricity, and as power sources installed in electric appliances such as personal computers and portable terminals. In particular, battery modules that utilize unit cells in the form of lithium ion secondary batteries that are lightweight and boast high energy density are preferred as high-output power sources for vehicle drive in electric vehicles (EV), plug-in hybrid vehicles (PHV) and hybrid vehicles (HV), and the demand for such batteries is expected to further grow in the future.
In a typical configuration, such battery modules are provided with a stack (battery stack) resulting from stacking a plurality of unit cells of identical shape in a predetermined direction, the stack being restrained in a state of having a predetermined load applied thereto by a restraining member that restrains, in the stacking direction, the plurality of unit cells that make up the stack. For instance JP 2009-238606 A, which discloses a battery module of this type, describes a battery module provided with a pressure holding means for holding, within a predetermined range, the pressure that is applied to the stack in the stacking direction.
SUMMARYSecondary batteries (unit cells) such as lithium ion secondary batteries that are charged and discharged at comparatively high C rates tend to exhibit comparatively large volume expansion/shrinkage when charged or discharged. In particular, so-called laminate-type batteries of flat shape in which an exterior body of the battery is made of a laminate film tend to exhibit significant volume expansion/shrinkage when charged or discharged. Volume differences between unit cells may also occur, on account of dimensional error, during production of the batteries. In other words, an error may arise in that the stacking-direction thickness of the plurality of unit cells when arrayed in the stacking direction does not match a design value. For this reason the restraining member provided in the battery module exhibits preferably a comparatively large dimensional displacement, so as to allow offsetting such volume expansion/shrinkage or thickness error. On the other hand, however, excessive expansion/shrinkage (variation) of the volume of the unit cells is undesirable in that it may result in alteration of the active material built into the battery (for instance in micronization of active material particles). From that point of view it is deemed that the dimensional displacement of the restraining member provided in the battery module is preferably comparatively small.
Therefore, the present invention was arrived at in order to resolve the above conflicting goals pertaining to restraining of a stack (group of stacked unit cells) of a battery module. It is an object of the present invention to provide a battery module provided with a restraining structure which, through setting of different degrees of dimensional displacement in the stacking direction, allows realizing displacement such that the above conflicting goals are attained.
In order to achieve the above goals, the battery module disclosed herein is provided with a stack in which a plurality of unit cells is stacked; a restraining member that restrains the stack by applying a load in the direction of the stacking; and a displacement adjustment member restrained in the stacking direction, together with the stack, by the restraining member, and being disposed at least at one site among a gap between any two unit cells in the stack, and a first end and a second end of the stack in the stacking direction.
In the battery module disclosed herein, the displacement adjustment member is provided with at least a first elastic body and a second elastic body capable of undergoing elastic deformation in the stacking direction. The first elastic body is made of an elastic body in which an elastic deformation extent, with respect to a predetermined load, is relatively larger than that of the second elastic body. The second elastic body is made of an elastic body in which the elastic deformation extent is relatively small.
In the battery module disclosed herein, when a reference length X0 is defined as a length of the stack in the stacking direction in a state in which the stack is restrained by the restraining member at a predetermined load in the stacking direction, a restraining load on the stack in the stacking direction is controlled through elastic deformation of the first elastic body when the stack expands from the reference length X0 up to a first length X1; and the restraining load on the stack in the stacking direction is controlled through elastic deformation of the second elastic body when the stack further expands from X1 up to a second length X2.
In a battery module having such a configuration, the displacement adjustment member is provided with the first elastic body and the second elastic body having mutually different elastic deformation extents, in other words having mutually different moduli of elasticity. As a result, when the thickness of several unit cells that make up the stack expands during use of the battery module (i.e. upon expansion of the stack containing the unit cells), the extent of expansion the stack, such as immediately after start of expansion, is relatively small, and the restraining load in the stacking direction is controlled through elastic deformation of the first elastic body exhibiting a relatively large elastic deformation extent (i.e. having a relatively small elastic modulus) with respect to a predetermined load, until the length in the stacking direction reaches X1 (mm) which is relatively close to the reference length X0. The thickness displacement amount of the stack (in other words the individual unit cells) in the stacking direction accompanying expansion of the stack can be made as a result comparatively large. The region from X0 up to X1 will be referred to hereafter as high displacement region.
Upon further expansion of the thickness of several unit cells that make up the stack, specifically, the restraining load in the stacking direction is controlled through elastic deformation of the second elastic body exhibiting a relatively small elastic deformation extent (i.e. having a relatively large elastic modulus) with respect to a predetermined load, until the length in the stacking direction reaches a predetermined X2 (mm) beyond the above X1 (mm). Accordingly, the thickness displacement amount of the stack (in other words, of the individual unit cells) accompanying expansion of the stack can be kept comparatively small at this stage. The region from X1 up to X2 will be hereafter referred to as low displacement region.
The battery module disclosed herein can thus address both a situation in which a comparatively large dimensional displacement is required so as to allow offsetting the volume expansion of the stack and/or thickness error, and a situation in which there is required a small comparative dimensional displacement to suppress excessive volume expansion of the stack, so as to preclude alteration of the active materials inside the unit cells (for instance micronization of active material particles).
In a preferred implementation of the battery module disclosed herein, the first elastic body is made of a spring, and the second elastic body is made of a metal, an alloy, a rubber or a synthetic resin. A battery module having such a configuration allows easily bringing about an elastic deformation extent (elastic modulus) between the first elastic body and the second elastic body, so as to attain the above goal.
In a particularly preferred implementation of the battery module disclosed herein, the displacement adjustment member is provided with a plate adjacent to the first elastic body and the second elastic body, the first elastic body deforms elastically through abutting of the first elastic body against the plate when the length of the stack in the stacking direction is from X0 to X1, and the second elastic body deforms elastically through abutting of the second elastic body against the plate when the length of the stack in the stacking direction is from X1 to X2. In a battery module having such a configuration, the main agent of elastic deformation switches over from the first elastic body to the second elastic body at X1; as a result, the length of the stack in the stacking direction can reliably include the high displacement region from the reference length X0 up to a predetermined X1 (mm), and the low displacement region from X1 up to a predetermined X2 (mm).
In another preferred implementation of the battery module disclosed herein, the displacement adjustment member is further provided with a third elastic body. The third elastic body is made of an elastic body exhibiting an elastic deformation extent, with respect to a predetermined load, that is relatively smaller than those of both the first and second elastic bodies. Herein, the restraining load on the stack in the stacking direction is controlled through elastic deformation of the third elastic body from X2 when the stack further expands from X2 up to a third length X3. In a battery module having such a configuration an ultra-low displacement region can thus be further provided, in addition to the high displacement region and the low displacement region, and hence the restraining load can be controlled yet more precisely.
Embodiments of the present invention will be explained below with reference to accompanying drawings. In the drawings explained below, members and portions eliciting identical effects are denoted by identical reference symbols, and a recurrent explanation thereof may be omitted or simplified. The dimensional relationships (length, width, thickness and so forth) in the figures do not reflect actual dimensional relationships. Any features other than the matter specifically set forth in the present specification and that may be necessary for carrying out the present invention can be regarded as instances of design matter, for a person skilled in the art, based on known techniques in the relevant technical field.
As depicted in
The material that constitutes the exterior body 12 is not particularly limited, and for instance may be the same as materials used in typical unit cells. For instance there can be preferably used a metal-made (for example aluminum-made) exterior body 12, from the viewpoint of achieving high physical strength and heat dissipation properties in the unit cells 10. Alternatively, the exterior body 12 may be made of a laminate film, in terms of stackability and reduction of the weight of the module as a whole. Preferred examples of such an instance include a laminate film having a three-layer structure in which a metal layer is disposed between two synthetic resin layers. On the top face of the exterior body 12 there are provided a positive electrode terminal 14 and a negative electrode terminal 16 electrically connected to the positive electrode and the negative electrode, respectively, of the electrode body in the interior.
The unit cells 10 may be fuel cells or secondary batteries such as nickel-hydride batteries, but are preferably lithium ion secondary batteries. The lithium ion secondary batteries can be typically a nonaqueous electrolyte lithium ion secondary battery, where the electrolyte of the battery is a nonaqueous electrolyte solution, or an all-solid-state lithium ion secondary battery in which the electrolyte is solid. All-solid-state lithium ion secondary batteries are problematic in that the internal resistance of the battery is comparatively high, since all of the positive electrode, the negative electrode and the electrolyte are solid. In a case where the stack 20 is formed using all-solid-state lithium ion secondary batteries as the unit cells 10, it is important therefore to properly secure a restraining load in the stacking direction. Although depending also on the positive and negative electrode materials that are used, all-solid-state lithium ion secondary batteries tend to exhibit a greater degree of expansion and shrinkage, accompanying charging and discharge, than nonaqueous electrolyte lithium ion secondary batteries. From this viewpoint as well it is important to properly secure a restraining load in the stacking direction. All-solid-state lithium ion secondary batteries are thus suitable as unit cells in which the art disclosed herein is adopted. Materials and members conventionally utilized can be used, without particular limitations, as the materials and members that make up the unit cells in an all-solid-state lithium ion secondary battery, a lithium ion secondary battery of some other form (typically a lithium ion secondary battery provided with an nonaqueous electrolyte solution), or secondary batteries other than lithium ion secondary batteries. The internal configuration itself of the unit cells is not a characterizing feature of the present invention, and accordingly there will follow no further detailed explanation of the unit cells.
The battery module 100 according to the present embodiment can be constructed similarly to conventional battery modules of this type. Specifically, as illustrated in
As a result of this series of processes, the stack 20 can be restrained together with the pair of displacement adjustment members 50 in a state where a predetermined restraining load acts in the stacking direction, in other words, in a state where the length of the stack 20 (i.e. the plurality of unit cells 10) in the stacking direction is a reference length X0 (mm) set beforehand. The magnitude of the restraining load herein may vary depending on the properties of the unit cells 10, and hence is not particularly limited, but typically the stack 20 and the displacement adjustment members 50 are restrained so that the surface pressure on the flat surface 13 of the stacked unit cells 10 is about 104 Pa to 106 Pa. The positive and negative electrodes of the plurality of unit cells 10 that make up the stack 20 are electrically connected in series by respective predetermined connectors (not shown), to thereby construct the target battery module 100.
The configuration and effect of the displacement adjustment members 50 according to the present embodiment will be explained next with reference to accompanying drawings. As illustrated in
In the displacement adjustment members 50 according to the present embodiment, as illustrated in
As illustrated in
In the battery module 100 according to the present embodiment, therefore, the adjustment amount of the restraining load or the elastic deformation extent of the displacement adjustment members 50 can be caused to vary, from the reference length X0 until X1 is reached, and from X1 until X2 is reached, during the process of expansion of the stack 20, such as during charging.
The design in the present embodiment is such that the elastic modulus of the coil springs 52 is relatively small and the elastic modulus of the elastic columnar bodies 54 is relatively large. As a result a suitable high displacement region and low displacement region can be set to be continuous, accompanying the expansion of the stack 20, as illustrated schematically in the graph of
As illustrated in
A preferred embodiment of the displacement adjustment members 50 provided with the first elastic body (coil springs 52) and the second elastic body (elastic columnar bodies 54) having mutually different elastic moduli has been explained above. However, the displacement adjustment members 50 provided in the battery module 100 disclosed herein are not limited to the embodiment above, and it suffices that there be used two types of elastic body having mutually different elastic moduli (elastic deformation extent); and, for instance, the first elastic body may be a an elastic columnar body having a small elastic modulus and being made of a synthetic resin or rubber, while the second elastic body may be a spring having a large elastic modulus.
The displacement adjustment members of the first embodiment are the displacement adjustment members 50 that allow realizing two displacement regions i.e. a high displacement region and a low displacement region, but for instance the art disclosed herein allows causing an elastic deformation region to be different over three stages. As another embodiment, displacement adjustment members 150, 250 that allow causing an elastic deformation region to be different over three stages will be explained next with reference to
Each displacement adjustment member 150 in the second embodiment illustrated in
By virtue of the above configuration, in the displacement adjustment members 150 according to the present embodiment the restraining load on the stack in the stacking direction is controlled through elastic deformation of the coil springs 152A having relatively smaller spring constant (elastic modulus), from the point in time at which the length of the stack in the stacking direction becomes the reference length X0 until the length reaches the length X1 at which the elastic columnar bodies 154A abut the base plate 56. Accordingly, there is formed a high displacement region (load-displacement relationship 1 in the figure) of comparatively high expansion rate (elongation rate) of the stack per unit increment of the restraining load (kN).
Next, the restraining load on the stack in the stacking direction is controlled through elastic deformation of the coil springs 152B having relatively large spring constant (elastic modulus), from the point in time at which the length of the stack in the stacking direction becomes X1 until the length is the length X2 at which the elastic columnar bodies 154B abut the end plate 36B. Accordingly, a low displacement region (load-displacement relationship 2 in the figure) is formed at which the expansion rate (elongation rate) of the stack per unit increment of the restraining load (kN) is smaller than that in the high displacement region.
Once the length of the stack in the stacking direction exceeds X2, further, the restraining load on the stack in the stacking direction is controlled through elastic deformation of the elastic columnar bodies 152A, 152B having largest elastic modulus, typically from the point in time at which the restraining load reaches an upper limit or until the length of the stack in the stacking direction reaches an upper-limit length (for convenience X3 (mm) in the present embodiment). In this region there is formed an ultra-low displacement region (load-displacement relationship 3 in the figure) in which the expansion rate (elongation rate) of the stack per unit increment of the region is yet smaller than that in the low displacement region. In the displacement adjustment members 150 according to the present embodiment, as described above, a displacement region can be set to be different over three stages, and as a result a battery module provided with the displacement adjustment members 150 having such a configuration allows controlling the restraining load more precisely.
Each displacement adjustment member 250 in a third embodiment illustrated in
The short elastic columnar bodies 254A in the present embodiment are formed to have a relatively larger elastic modulus than that of the long elastic columnar bodies 254B. That is, the coil springs 252A, 252B, the long elastic columnar bodies 254B and the short elastic columnar bodies 254A are formed in that ascending order of elastic modulus.
By virtue of the above configuration, in the displacement adjustment members 250 according to the present embodiment, the restraining load on the stack in the stacking direction is controlled through elastic deformation of the coil springs 252A, 252B from the point in time at which the length of the stack in the stacking direction becomes the reference length X0 until the length reaches the length X1 at which the long elastic columnar bodies 254B abut the end plate 36B. Accordingly, there is formed a high displacement region (load-displacement relationship 1 in the figure) of comparatively high expansion rate (elongation rate) of the stack per unit increment of the restraining load (kN). Next, the restraining load on the stack in the stacking direction is controlled through elastic deformation of the long elastic columnar bodies 254B having relatively smaller elastic modulus, in addition to through elastic deformation of the coil springs 252A, from the point in time at which the length of the stack in the stacking direction is X1 until the length becomes the length X2 at which the short elastic columnar bodies 254A abut the base plate 56. Accordingly, a low displacement region (load-displacement relationship 2 in the figure) is formed at which the expansion rate (elongation rate) of the stack per unit increment of the restraining load (kN) is smaller than that in the high displacement region.
Once the length of the stack in the stacking direction exceeds X2, the restraining load on the stack in the stacking direction is controlled mainly through elastic deformation of the short elastic columnar bodies 252A having largest elastic modulus, typically from the point in time at which the restraining load reaches an upper limit or until the length of the stack in the stacking direction reaches an upper-limit length (for convenience X3 (mm) in the present embodiment). In this region there is formed an ultra-low displacement region (load-displacement relationship 3 in the figure) in which the expansion rate (elongation rate) of the stack per unit increment of the restraining load on the stack in the stacking direction is yet smaller than that in the low displacement region. As described above, also in the configuration of the displacement adjustment members 250 according to the present embodiment a displacement region can be made different over three stages, similarly to the case the second embodiment, and as a result a battery module provided with the displacement adjustment members 250 having such a configuration allows controlling the restraining load more precisely.
Concrete examples of the present invention have been explained in detail above, but the examples are merely illustrative in nature, and are not meant to limit the scope of the claims in any way. The features set forth in the claims can accommodate various modifications and alterations of the concrete examples illustrated above. For instance, the sites at which the displacement adjustment members are disposed are not limited to the ends of the stack in the stacking direction, and may be gaps between any two unit cells in the stack.
The battery module and the displacement adjustment members as illustrated in the figures have a simple structure for the purpose of explanation of the present invention, but it will be apparent to a person skilled in the art that all manner of variations can be adopted, and various devices can be added, without detriment to the constitution and the effect of the invention. The battery module disclosed herein is suitable for use, as a power source for motor drive, by being installed in a vehicle such as an electric vehicle (EV), a hybrid vehicle (HV) or a plug-in hybrid vehicle (PHV) from which particularly high battery performance is demanded.
Claims
1. A battery module, comprising:
- a stack in which a plurality of unit cells is stacked;
- a restraining member that restrains the stack by applying a load in the direction of the stacking; and
- a displacement adjustment member restrained in the stacking direction, together with the stack, by the restraining member, and being disposed at least at one site among a gap between any two unit cells in the stack, and a first end and a second end of the stack in the stacking direction;
- wherein the displacement adjustment member is provided with at least a first elastic body and a second elastic body capable of undergoing elastic deformation in the stacking direction;
- the first elastic body is made of an elastic body in which an elastic deformation extent, with respect to a predetermined load, is relatively larger than that of the second elastic body, and the second elastic body is made of an elastic body in which the elastic deformation extent is relatively small;
- a restraining load on the stack in the stacking direction is controlled through elastic deformation of the first elastic body when the stack expands from a reference length X0, which is a length of the stack in the stacking direction in a state in which the stack is restrained by the restraining member at a predetermined load in the stacking direction, up to a first length X1, and the restraining load on the stack in the stacking direction is controlled through elastic deformation of the second elastic body when the stack further expands from X1 up to a second length X2.
2. The battery module of claim 1, wherein the first elastic body is made of a spring, and the second elastic body is made of a metal, an alloy, a rubber or a synthetic resin.
3. The battery module of claim 1,
- wherein the displacement adjustment member is provided with a plate adjacent to the first elastic body and the second elastic body; and
- the first elastic body deforms elastically by abutting of the first elastic body against the plate when the length of the stack in the stacking direction is from X0 up to X1, and the second elastic body deforms elastically by abutting of the second elastic body against the plate when the length of the stack in the stacking direction is from X1 up to X2.
4. The battery module of claim 1,
- wherein the displacement adjustment member is further provided with a third elastic body,
- the third elastic body being made of an elastic body exhibiting an elastic deformation extent, with respect to a predetermined load, that is relatively smaller than those of both the first and second elastic bodies; and
- the restraining load on the stack in the stacking direction is controlled through elastic deformation of the third elastic body when the stack further expands from X2 up to a third length X3.
5. The battery module of claim 3,
- wherein the displacement adjustment member is further provided with a third elastic body,
- the third elastic body being made of an elastic body exhibiting an elastic deformation extent, with respect to a predetermined load, that is relatively smaller than those of both the first and second elastic bodies; and
- the restraining load on the stack in the stacking direction is controlled through elastic deformation of the third elastic body when the stack further expands from X2 up to a third length X3.
20170047562 | February 16, 2017 | Ogawa |
2004-349052 | December 2004 | JP |
2009-187778 | August 2009 | JP |
2009-238606 | October 2009 | JP |
2016-004724 | June 2014 | JP |
2016004724 | January 2016 | JP |
20170038300 | April 2017 | KR |
Type: Grant
Filed: Dec 18, 2018
Date of Patent: Mar 2, 2021
Patent Publication Number: 20190229310
Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA (Toyota)
Inventor: Seigo Fujishima (Miyoshi)
Primary Examiner: Gary D Harris
Application Number: 16/223,369
International Classification: H01M 2/10 (20060101); H01M 8/24 (20160101); H01M 8/10 (20160101); H01M 10/04 (20060101); H01M 10/0525 (20100101); H01M 10/48 (20060101);