Method of improving the contact between bipolar plates and membrane electrode assembly of a flat panel fuel cell
A flat panel DMFC (direct methanol fuel cell) includes a first electrode plate, a set of membrane assemblies, at least a bonding sheet, a second electrode, and fuel container base. Because of the gap between the first/second electrode plates and the membrane assembly when they are laminated, the present invention provides a method to improve the contact between the first/second electrode plates and the membrane assembly.
This is a divisional application of U.S. patent application Ser. No. 10/908,830 filed on May 27, 2005, and the contents of which are included herein by reference.
BACKGROUND OF THE INVENTION1. Field of the Invention
The present invention relates to a flat panel fuel cell, and more particularly, to a method of improving the contact between bipolar plates and membrane electrode assembly of a flat panel fuel cell.
2. Description of the Prior Art
A fuel cell is an electrochemical cell in which a free energy change resulting from a fuel oxidation reaction is converted into electrical energy. Fuel cells utilizing methanol as fuel are typically called Direct Methanol Fuel Cells (DMFCs), which generate electricity by combining gaseous or aqueous methanol with air. DMFC technology has become widely accepted as a viable fuel cell technology that offers itself to many application fields such as electronic apparatuses, vehicles, military equipment, the aerospace industry, and so on.
DMFCs, like ordinary batteries, provide DC electricity from two electrochemical reactions. These reactions occur at electrodes (or poles) to which reactants are continuously fed. The negative electrode (anode) is maintained by supplying methanol, whereas the positive electrode (cathode) is maintained by the supply of air. When providing current, methanol is electrochemically oxidized at the anode electrocatalyst to produce electrons, which travel through the external circuit to the cathode electrocatalyst where they are consumed together with oxygen in a reduction reaction. The circuit is maintained within the cell by the conduction of protons in the electrolyte. One molecule of methanol (CH3OH) and one molecule of water (H2O) together store six atoms of hydrogen. When fed as a mixture into a DMFC, they react to generate one molecule of CO2, 6 protons (H+), and 6 electrons to generate a flow of electric current. The protons and electrons generated by methanol and water react with oxygen to generate water.
In terms of the amount of electricity generated, a DMFC can generate 300-500 milliwatts per centimeter squared. In general, conventional DMFCs are comprised of numerous basic cells and each cell only carries a limited amount of working voltage. Consequently, the cells need to be stacked together in order to achieve a required level of operational voltage.
SUMMARY OF THE INVENTIONIt is therefore an objective of the present invention to provide a method of improving the contact between bipolar plates and the membrane electrode assembly of a flat panel fuel cell for solving the above-mentioned problems.
According to the preferred embodiment of the present invention, a method of improving the contact between bipolar plates and membrane electrode assembly of a flat panel fuel cell comprises the following steps: providing a first bipolar plate, a membrane electrode assembly, a second bipolar plate, and at least one bonding sheet; the MEA being disposed on the first bipolar plate, an opening being included in the bonding sheet for containing the MEA, and the second bipolar plate being disposed on the MEA; the first bipolar plate including a first MEA surface contacting the MEA and a fuel surface contacting the fuel, and the second bipolar plate including a second MEA surface contacting the MEA and an air surface contacting the air; a first metal layer being disposed on the metal surface, a second metal layer being disposed on the first MEA surface, a third metal layer being disposed on the second MEA surface, and a fourth metal layer being disposed on the air surface; the thickness of the second metal layer being greater than the thickness of the first metal layer and the thickness of the third metal layer being greater than the thickness of the fourth metal layer; and laminating the first bipolar plate, the MEA, the second bipolar plate, and the bonding sheet together for forming a bipolar/MEA assembly.
According to the second embodiment of the present invention, a method for improving the contact between bipolar plates and membrane electrode assembly (MEA) of a flat panel fuel cell comprises the following steps: providing a bipolar plate and a membrane electrode assembly (MEA), in which the bipolar plate includes at least one electrode region and the MEA is disposed on the electrode region of the bipolar plate; providing a plurality of conductive bumps on the electrode region; and contacting the membrane electrode assembly with the plurality of conductive bumps.
These and other objectives of the present invention will no doubt become obvious to those of ordinary skill in the art after reading the following detailed description of the preferred embodiment that is illustrated in the various figures and drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
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In addition, the first substrate 522 and the second substrate 552 can be comprised of glass fiber reinforced polymeric materials, such as FR-1, FR-2, FR-3, FR-4, FR-5, CEM-1, or CEM-3 ANSI grade and the MEA can be Nafion membrane electrode assembly from DuPont Corp., or any other solid state membrane electrode assembly with similar functions, whereas the bonding sheet can be made of prepreg B-stage resin commonly utilized in PCB fabrication.
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In contrast to the conventional method, the disclosed method for improving the contact between bipolar plates and membrane electrode assembly of a flat panel fuel cell provides numerous advantages. By utilizing upper and lower metal layers having different thickness and the conductive bumps on the surface of the electrode region of the MEA, the present invention is able to effectively reduce the contact inability problem between the bipolar plates and the MEA, which is caused by the uneven thickness and decrease in thickness of the MEA after lamination. Moreover, an increase in electric power can also be achieved by applying an appropriate amount of pressure to the MEA.
Those skilled in the art will readily observe that numerous modifications and alterations of the device and method may be made while retaining the teachings of the invention. Accordingly, the above disclosure should be construed as limited only by the metes and bounds of the appended claims.
Claims
1. A method for improving the contact between bipolar plates and membrane electrode assembly (MEA) of a flat panel fuel cell, comprising:
- providing a first bipolar plate, a membrane electrode assembly, a second bipolar plate, and at least one bonding sheet; the MEA being disposed on the first bipolar plate, an opening being included in the bonding sheet for containing the MEA, and the second bipolar plate being disposed on the MEA; the first bipolar plate including a first MEA surface contacting the MEA and a fuel surface contacting the fuel, and the second bipolar plate including a second MEA surface contacting the MEA and an air surface contacting the air; a first metal layer being disposed on the fuel surface, a second metal layer being disposed on the first MEA surface, a third metal layer being disposed on the second MEA surface, and a fourth metal layer being disposed on the air surface; the thickness of the second metal layer being greater than the thickness of the first metal layer and the thickness of the third metal layer being greater than the thickness of the fourth metal layer; and
- laminating the first bipolar plate, the MEA, the second bipolar plate, and the bonding sheet together for forming a bipolar/MEA assembly.
2. The method of claim 1 wherein the flat panel fuel cell is a direct methanol fuel cell (DMFC).
3. The method of claim 1 wherein the membrane electrode assembly is a solid state membrane electrode assembly.
4. The method of claim 1, wherein the bonding sheet is a prepreg commonly utilized in the B-stage of a printed circuit board (PCB) fabrication.
5. The method of claim 1 wherein the first bipolar plate comprises a first substrate, and a first metal layer and a second metal layer formed thereon.
6. The method of claim 5 wherein the first substrate is comprised of glass fiber reinforced polymeric materials.
7. The method of claim 5 wherein the first substrate is comprised of glass fiber reinforced polymeric materials derived from ANSI-grade FR-1, FR-2, FR-3, FR-4, FR-5, CEM-1, or CEM-3.
8. The method of claim 1 wherein the second bipolar plate comprises a second substrate, and a third metal layer and a fourth metal layer formed thereon.
9. The method of claim 8 wherein the second substrate is comprised of glass fiber reinforced polymeric materials.
10. The method of claim 8 wherein the second substrate is comprised of glass fiber reinforced polymeric materials derived from ANSI-grade FR-1, FR-2, FR-3, FR-4, FR-5, CEM-1, or CEM-3.
Type: Application
Filed: Jun 13, 2007
Publication Date: Oct 4, 2007
Inventors: Yung-Yi LIU (Taipei Hsien), James SHANG (Taoyuan)
Application Number: 11/762,074
International Classification: B32B 37/00 (20060101);