Contact for memory cell
A contact for memory cells and integrated circuits having a conductive layer supported by the sidewall of a dielectric mesa, memory cells incorporating such a contact, and methods of forming such structures.
The invention relates to semiconductor devices. In particular, the invention relates to contacts for memory devices.
BACKGROUND OF THE INVENTIONNon-volatile memories are a desirable evolution in integrated circuit design due to their ability to maintain data absent a power supply. Phase-change materials, as well as other resistance variable materials, have been investigated for use in non-volatile memory cells. Phase-change memory cells include phase-change materials, such as chalcogenide alloys, which are capable of stably transitioning between amorphous and crystalline phases. Each phase exhibits a particular resistance state and the resistance states distinguish the logic values of the memory cell. For example, a memory element in an amorphous state exhibits a relatively high resistance and a memory element in a crystalline state exhibits a relatively low resistance, each of which can be sensed as stored data.
A typical phase-change memory cell has a layer of phase-change material between first and second electrodes. As an example, the phase-change material can be a chalcogenide alloy, such as Ge2Sb2Te5 or AgInSbTe. When used in a memory device, a portion of the phase-change material is set to a particular resistance state according to the amount of current applied via the electrodes. To obtain an amorphous state, a relatively high write current pulse (a reset pulse) is applied through the phase-change cell to melt a portion of the material for a first period of time. The current is removed and the cell cools rapidly to a temperature below its crystallization temperature, which results in a portion of the material having an amorphous phase. To obtain a crystalline state, a lower current write pulse (a set pulse) is applied to the phase-change cell for a second period of time (typically longer in duration than the first period of time) to heat the material to a temperature below its melting point, but above its crystallization temperature. This causes the amorphous portion of the material to re-crystallize to a crystalline phase that is maintained once the current is removed and the cell is cooled.
The typically large programming current of phase-change memory devices is a limiting factor in reducing the memory cell size. The programmable volume of phase-change memory cell and programming current requirement are dependent on the area of the bottom electrode in contact with the memory element of the cell. To reduce such current, it is desirable to reduce the effective bottom electrode area in contact with the cell.
One issue effecting resistance-based memory, such as phase change memory, functionality is the non-uniformity of bottom electrode area. Non-uniformity in bottom electrode size across a memory array leads to non-uniformity of programming current requirement for different memory cells of the array, which makes it difficult to design a circuit that can accommodate the variation between bits. Undesired variation in bottom electrode size causes set and reset resistance distribution overlap, which, in the worst case, makes establishing a sensing scheme for all bits of an array impossible. Reduction in bottom electrode size should be combined with electrode size uniformity to achieve an ideal contact for a resistance memory device.
One technique used to reduce bottom electrode size has been to employ anisotropically etched spacers in a via to make contacts smaller than the photolithographic limit. This technique gives rise to large variations in contact size since variations in chemical mechanical polishing (CMP) and via edge rounding cause the contacts to have different heights and cross-sections and thus different contact areas with respect to an overlying memory element.
Another technique used to reduce bottom electrode size has been to use ring shaped contacts.
As shown in the side-by-side comparisons of the contact 20 of
There have been attempts to resolve the problems of the prior art relating to the rounded edge of via and CMP height variations. For example, a two-step CMP process, as shown in
The above proposed process does potentially resolve CMP height variation and via edge rounding issues. However, due to via 14a slope variation, the contacts 20a formed simultaneously by such a technique will still tend to vary in size and shape, as shown by the comparison between the contact 20a shown in
It is desirable to mitigate processing variability and provide more consistently shaped contacts for electrodes.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention relates to electrodes for memory cells. The electrodes are formed, in part, by chemical mechanical polishing techniques and also, in part, by selective etching techniques to provide support mesas for ring shaped conductive layers. The electrodes formed in accordance with the invention have more consistently sized surface areas across an array of memory cells. Using dielectric mesas as a support structure for the electrodes allows surface area variation due to CMP height and via size and curvature to be mitigated. These and other features of the invention will be better understood from the following detailed description, which is provided in connection with the accompanying drawings.
Although this invention will be described in terms of certain exemplary embodiments, other embodiments will be apparent to those of ordinary skill in the art, which also are within the scope of this invention. Accordingly, the scope of the invention is defined only by reference to the appended claims.
The term “substrate” in the following description refers to any supporting layer suitable for fabricating an integrated circuit, typically semiconductor based, but not necessarily so. A substrate may be silicon-based, may include epitaxial layers of silicon supported by a base semiconductor foundation, can be sapphire-based, silicon-on-insulator (SOI), metal, polymer, or any other materials suitable for supporting an integrated circuit. When reference is made to a substrate or wafer in the following description, previous process steps may have been utilized to form regions or junctions in or over a base semiconductor or foundation.
Although this invention will be described primarily in relation to phase-change memories, the invention is not limited to such uses. The contacts and methods of forming contacts described herein are suitable for use in any integrated circuit and would be advantageous wherever a reduction of size or increased uniformity in electrodes would be desirable, particularly in memory cells. Although the invention is described in relation to a single memory cell and the forming thereof, it can be utilized in an array of such memory cells, which can be formed simultaneously, or in parts of an integrated circuit not used for memory.
The invention will now be explained with reference to the accompanying figures wherein like reference numbers are used consistently for like features throughout the drawings.
The memory cell 122 also includes a bottom electrode layer 114, which is preferably shaped like a ring, but not necessarily so, supported by a dielectric material mesa 112. The mesa 112 structure is preferably substantially circular shaped in top view such that it has a single, continuous sidewall; however, this is not necessarily so and the mesa 112 can be other shapes as well, e.g., rectangular. The bottom electrode layer 114 is preferably titanium nitride (TiN), but can also be other conductive materials that can be selectively removed from horizontally planar surfaces by etching, such as titanium aluminum nitride (TiAlN) or tantalum nitride (TaN), for example. The bottom electrode layer 114 is configured so that it has a surface area 114a in contact with the memory element 118 of the memory cell 122. The surface area 114a of the bottom electrode layer 114 is determined by the thickness of the layer 114, which is preferably about 100 Å, and the interior radius “r” of the electrode ring (
The ring-shaped bottom electrode layer 114 has a surface area 114a consistent with respective surface areas of other bottom electrode layers of a memory array formed during the same processing acts because CMP variations during processing are mitigated and CMP height is controlled, and the overall surface area 114a depends primarily on the thickness of the bottom electrode layer 114, not on any via formation shape (
The memory cell 122 shown in
The memory element 118 and top electrode layer 120 provided over the bottom electrode layer 114 and mesa 112 can be electrically isolated from other memory cells of an array, as well as from other parts of the same integrated circuit, by another dielectric layer 124. This dielectric layer 124 can be any insulating material, such as an oxide, nitride or BPSG, for example.
A sequence of processing steps for forming a ring-shaped electrode 114 and memory cell 122 as shown in
Another dielectric layer 106 is formed over the conductive layer 104 and dielectric layer 102. This dielectric layer 106 can be many materials, as discussed above in relation to
A layer of hard mask material 108 is formed over the dielectric layer 106. If the dielectric layer 106 is silicon nitride, the hard mask layer 108 is preferably silicon oxide so that the dielectric layer 106 can be selectively etched relative to the hard mask 108 and also so the hard mask 108 can be selectively removed by CMP relative to the dielectric layer 106. Silicon oxide and silicon nitride are materials having such characteristics for this selectivity. It is also possible to use these materials in the reverse order, i.e., an oxide for the dielectric layer 106 and a nitride for the hard mask 108. Other such combinations of materials are also possible, so long as the selective etch and selective CMP can be used.
A layer of photoresist 110 is formed over the hard mask layer 108. The photoresist layer 110 is patterned (see solid portion), for example, by known photolithographic techniques, to leave a mask to define the area where a mesa 112 is to be formed (
A layer of conductive material 114 is formed over the mesa 112, conductive layer 104, and dielectric layer 102. This layer 114 will eventually become the bottom electrode layer 114 shown in
Now referring to
In the case of a computer system, the processor system may include peripheral devices such as a hard disk drive 454 and a compact disc (CD) ROM drive 456, which also communicate with CPU 444 over the bus 452. Memory circuit 448 is preferably constructed as an integrated circuit, which includes one or more resistance variable memory devices, e.g., device 122. If desired, the memory circuit 448 may be combined with the processor, for example CPU 444, in a single integrated circuit.
Various embodiments of the invention have been described above. Although this invention has been described with reference to these specific embodiments, the descriptions are intended to be illustrative of the invention and are not intended to be limiting. Various modifications and applications may occur to those skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.
Claims
1. A contact for an integrated circuit, comprising:
- a mesa structure having at least one sidewall surface and an upper planar surface; and
- a conductive layer at least partially surrounding said mesa structure on said at least one sidewall surface and having an upper surface substantially planar with the upper planar surface of said mesa structure.
2. The contact of claim 1, wherein the at least one sidewall surface of said mesa structure is substantially circular and defines a perimeter of said mesa structure.
3. The contact of claim 1, wherein said conductive layer is substantially circular.
4. The contact of claim 1, wherein said conductive layer surrounds said mesa structure along said at least one sidewall surface.
5. The contact of claim 1, wherein said conductive layer is surrounded by a dielectric layer.
6. The contact of claim 1, wherein said mesa structure comprises a nitride.
7. The contact of claim 1, wherein said mesa structure comprises an oxide.
8. The contact of claim 1, wherein said mesa structure comprises a material selected from the group consisting of silicon nitride, tantalum oxide, aluminum oxide, titanium dioxide, magnesium oxide, silicon carbide, zirconia, and strontium titanate.
9. The contact of claim 1, wherein said conductive layer comprises at least one of titanium nitride, titanium aluminum nitride, and tantalum nitride.
10. The contact of claim 1, wherein said contact is an electrode for a memory cell.
11. The contact of claim 10, wherein said memory cell is a phase-change memory cell.
12. A phase-change memory device, comprising:
- a phase-change memory element positioned between a first electrode and a second electrode; and
- said first electrode comprising a conductive layer on a sidewall of a mesa structure, at least partially surrounding said mesa structure, and having a surface in contact with said memory element.
13. The memory device of claim 12, wherein the sidewall of said mesa structure is substantially circular and the conductive layer is also substantially circular.
14. The memory device of claim 12, wherein said conductive layer surrounds said mesa structure along said sidewall.
15. The memory device of claim 14, wherein said conductive layer is surrounded by a dielectric layer.
16. The memory device of claim 12, wherein said mesa structure comprises a nitride.
17. The memory device of claim 12, wherein said mesa structure comprises a material selected from the group consisting of silicon nitride, tantalum oxide, aluminum oxide, titanium dioxide, magnesium oxide, silicon carbide, zirconia, and strontium titanate.
18. The memory device of claim 12, wherein said conductive layer comprises at least one of titanium nitride, titanium aluminum nitride, and tantalum nitride.
19. The memory device of claim 12, wherein said memory element comprises a phase-change material.
20. A processor system, comprising:
- a processor and a memory circuit, wherein said memory circuit comprises a memory device, which comprises:
- a memory element positioned between a first electrode and a second electrode; and
- said first electrode comprising a conductive layer on a sidewall of a mesa structure, at least partially surrounding said mesa structure, and having a surface in contact with said memory element.
21. The processor system of claim 20, wherein the sidewall of said mesa structure is substantially circular and the conductive layer is also substantially circular.
22. The processor system of claim 20, wherein said conductive layer surrounds said mesa structure along said sidewall.
23. The processor system of claim 22, wherein said conductive layer is surrounded by a dielectric layer.
24. The processor system of claim 20, wherein said mesa structure comprises a nitride.
25. The processor system of claim 20, wherein said mesa structure comprises a material selected from the group consisting of silicon nitride, tantalum oxide, aluminum oxide, titanium dioxide, magnesium oxide, silicon carbide, zirconia, and strontium titanate.
26. The processor system of claim 20, wherein said conductive layer comprises at least one of titanium nitride, titanium aluminum nitride, and tantalum nitride.
27. The processor system of claim 20, wherein said memory element comprises a phase-change material.
28. A method of forming a contact for an integrated circuit, comprising:
- forming a mesa structure over a substrate, said mesa structure having at least one sidewall;
- forming a conductive layer over said mesa structure and said substrate; and
- removing said conductive layer from surfaces of said mesa structure and said substrate to leave said conductive layer at least partially surrounding said mesa on said sidewall.
29. The method of claim 28, further comprising forming a dielectric layer over said mesa structure and said conductive layer and planarizing said dielectric layer using said mesa structure as a stop.
30. The method of claim 28, further comprising utilizing a hard mask and an etching step to form said mesa structure.
31. The method of claim 30, wherein said hard mask and said mesa structure are selectively etchable and planarized by chemical mechanical polishing with respect to each other.
32. The method of claim 31, wherein one of said hard mask and said mesa structure comprises an oxide and the other comprises a nitride.
33. The method of claim 28, wherein said conductive layer is removed using a dry etch.
34. The method of claim 28, wherein after said removing of said conductive layer, the remaining conductive layer surrounds said mesa structure at a sidewall thereof.
35. The method of claim 28, wherein said mesa structure is formed to be substantially circular in shape.
36. The method of claim 28, further comprising forming a memory cell over said contact.
37. The method of claim 36, further comprising forming a phase-change memory element over said contact and an electrode layer over said phase-change memory element.
38. The method of claim 28, wherein said mesa structure comprises a material selected from the group consisting of silicon nitride, tantalum oxide, aluminum oxide, titanium dioxide, magnesium oxide, silicon carbide, zirconia, and strontium titanate.
39. The method of claim 28, wherein said conductive layer comprises at least one of titanium nitride, titanium aluminum nitride, and tantalum nitride.
40. A method of forming a memory cell, comprising:
- providing a substrate;
- providing an electrically conductive region supported by said substrate;
- forming a first dielectric layer over said substrate and said electrically conductive region;
- forming a hard mask layer over said first dielectric layer;
- removing a portion of said first dielectric layer and said hard mask layer to form a mesa structure of said first dielectric layer over said electrically conductive region, wherein said hard mask layer remains over said mesa structure and said mesa structure has at least one sidewall;
- forming a conductive layer over said sidewall of said mesa structure and at least a portion of said electrically conductive region;
- forming a second dielectric layer over said mesa structure, said conductive layer, and said electrically conductive region;
- planarizing said second dielectric layer to expose said conductive layer and remove said hard mask layer, using said mesa structure as a stop; and
- forming a memory element layer over said conductive layer and said mesa structure.
41. The method of claim 40, wherein said electrically conductive region is an active area of said substrate.
42. The method of claim 40, wherein said electrically conductive region is an interconnect line.
43. The method of claim 40, wherein said electrically conductive region is a contact plug.
44. The method of claim 40, wherein said first dielectric layer comprises a nitride.
45. The method of claim 40, wherein said first dielectric layer comprises an oxide.
46. The method of claim 40, wherein said first dielectric layer comprises a material selected from the group consisting of silicon nitride, tantalum oxide, aluminum oxide, titanium dioxide, magnesium oxide, silicon carbide, zirconia, and strontium titanate.
47. The method of claim 40, wherein said hard mask layer is an oxide.
48. The method of claim 40, wherein said hard mask is a nitride.
49. The method of claim 40, wherein said first dielectric layer and said hard mask layer comprise materials that are selectively etchable and planarized by chemical mechanical polishing with respect to each other.
50. The method of claim 40, wherein said conductive layer is removed from surfaces, other than the sidewall of said mesa structure, by a dry etch.
51. The method of claim 40, wherein said conductive layer comprises at least one of titanium nitride, titanium aluminum nitride, and tantalum nitride.
52. The method of claim 40, wherein said hard mask is removed after forming said conductive layer by chemical mechanical polishing.
53. The method of claim 40, wherein said second dielectric layer comprises an oxide.
54. The method of claim 40, wherein said planaraizing of said second dielectric layer comprises a stop on nitride chemical mechanical polishing step.
55. The method of claim 40, wherein said memory element layer comprises a phase-change material.
56. The method of claim 40, further comprising forming an electrode layer over said memory element layer.
57. The method of claim 40, further comprising forming a plurality of second memory cells during the same sequence of acts as used to form said memory cell.
58. The method of claim 40, wherein said plurality of second memory cells have respective second conductive layers of substantially the same shape and size as the conductive layer of said memory cell.
Type: Application
Filed: Apr 4, 2006
Publication Date: Oct 4, 2007
Inventor: Jun Liu (Boise, ID)
Application Number: 11/396,622
International Classification: H01L 21/20 (20060101);