Friction welding

A method of bonding two materials by friction welding method. A first material may be made from a titanium aluminide intermetallic alloy and a second material may be made from a titanium alloy. The first material may be heated to a temperature between about 300° C. and about 800° C. The second material may be rotated relative to the first material. The first material and the second material may be pressed against each other while one of the first material, and the second material is rotated. The rotation of one of the first material and the second material may be stopped, and the first material and the second material may be pressed against each other after the rotation of one of the first material and the second material is stopped.

Skip to: Description  ·  Claims  · Patent History  ·  Patent History
Description
U.S. GOVERNMENT RIGHTS

This invention was made with government support under the terms of Contract No. DE-AC05-00OR22725 awarded by the Department of Energy. The government may have certain rights in this invention.

TECHNICAL FIELD

The present disclosure relates generally to a method of bonding different materials, and more particularly, to a method of bonding different materials by friction welding.

BACKGROUND

Titanium aluminide intermetallic alloys possess a favorable combination of low density and high temperature capabilities, and thus have emerged as potential high temperature materials to replace super-alloys in many applications, e.g. turbines and valves. The use of titanium aluminide intermetallic alloys, however, depends on the resolution of a critical issue, namely, integrating a titanium aluminide intermetallic alloy component successfully to its application system by bonding titanium aluminide intermetallic alloy to itself or a different material. Bonding titanium aluminide intermetallic alloys is challenging mainly because of three reasons: high local thermal stress involved with bonding process, formation of brittle intermetallic phases at the bonding interface, and inherent low room temperature ductility of titanium aluminide intermetallic alloys. Because of these reasons, the titanium aluminide intermetallic alloy components and the bonding interface are prone to crack during or after the bonding process and usually associated with inferior joint properties. In some applications, because of specific geometry or large component size of the titanium aluminide intermetallic alloy components, the local thermal stresses can become extremely high and therefore render the bonding process even more challenging. For example, in turbine rotor applications, the bonding interface is fairly close to turbine backface, and the geometry of the turbine hub changes rapidly. This rapid changing in geometry, in addition to the large thermal mass of turbine wheel, may cause a steep temperature gradient, and therefore, may cause large thermal stress which may exceed the strength of the titanium aluminide intermetallic alloy in the vicinity of the bonding interface. In valve applications, the geometry change may be relative gradual as compared to turbine. However, in large size valves (for example, more than four inches (10.16 cm) in valve head diameter), the temperature change across the joining interface of the valve during bonding process may cause additional thermal stresses.

One method of bonding titanium aluminide intermetallic alloy components and titanium (Ti) alloy is described in Japanese Patent Publication No. 1990/02160188 (the '188 publication) to Misao et al. The '188 publication describes a specific set of parameters for joining titanium aluminide intermetallic alloy and Ti alloy by friction welding. The friction welding method with specific set of parameters can help to reduce the formation of intermetallic phases at the joining interface. The method may not be capable of providing acceptable joint properties for joining components with relatively large size, e.g., large size valves, or joining components with special geometry shapes, e.g., turbine wheels, which may experience large thermal and stress changes during bonding process.

Another method of joining titanium aluminide intermetallic alloy and Ti alloy is described in U.S. Patent Publication No. 2003/0015570 (now U.S. Pat. No. 6,691,910) (the '910 patent) to Hirose et al. The '910 patent describes a method of joining a valve stem made of Ti alloy with a valve head made of titanium aluminide intermetallic alloy to form a poppet valve by friction welding. This '910 patent discloses a method of reducing the plastic deformation (burrs) of Ti alloy. The '910 patent uses an induction unit for in-situ heating the titanium aluminide intermetallic alloy component to 900-1100° C. during the welding process to reduce the burrs of Ti alloy. When the titanium aluminide intermetallic alloy component is heated beyond 900° C., the strength of titanium aluminide intermetallic alloy may decrease significantly, and therefore, may cause damage to the titanium aluminide intermetallic alloy component. Heating titanium aluminide component, which may increase the burrs from the titanium aluminide generated from the friction welding process, however, may not reduce the burrs from titanium alloy. Moreover, to avoid oxidation, thermal stress and other possible detrimental effects to the titanium aluminide intermetallic alloy component, heating the titanium aluminide intermetallic alloy component to 900-1100° C. has to be performed in a complicated manner, which may increase the cost. Furthermore, the induction heating method in '910 patent might not be applicable in some applications, e.g. turbine wheels, due to the turbine wheels' special geometry.

Nevertheless, although the methods of the '188 publication and '910 patent may be used to join the Ti alloy with the titanium aluminide intermetallic alloy, they may have been only successful on components with relatively small scale and relatively simple geometry shape, e.g., small size valves having gradual geometry contour changes.

The disclosed system is directed to overcoming one or more of the problems set forth above.

SUMMARY OF THE INVENTION

In one aspect, the present disclosure is directed to a method of bonding two materials. A first material may be made from a titanium aluminide intermetallic alloy and a second material may be made from a titanium alloy. The first material may be heated to a temperature between about 300° C. and about 800° C. The second material may be rotated relative to the first material. The first material and the second material may be pressed against each other while one of the first material and the second material is rotated. The rotation of one of the first material and the second material may be stopped, and the first material and the second material may be pressed against each other after the rotation of one of the first material and the second material is stopped.

In another aspect, the present disclosure is directed to a method of producing a turbine rotor assembly. A turbine rotor wheel made from a titanium aluminide intermetallic compound is heated to a predetermined temperature. A turbine rotor shaft is rotated relative to the turbine rotor wheel. The turbine rotor shaft is pressed against the turbine rotor wheel while the turbine rotor shaft is rotated. The rotation of the turbine rotor shaft may be stopped and the turbine rotor shaft is pressed against the turbine rotor wheel after the rotation of the turbine rotor shaft is stopped.

In yet another aspect, the present disclosure is directed to an assembly made by a friction welding process. The assembly includes a first material and a second material. At least one of the first material and the second material may include a cavity at an end of at least one of the first material and the second material to be coupled to the other material. The cavity may be at least partially filled with at least one of the first material and the second material as a result of the friction welding process.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a partial section view of an exemplary disclosed turbine rotor assembly according to one embodiment of the invention;

FIG. 2 is a partial section view of an exemplary disclosed turbine rotor assembly according to another embodiment of the invention;

FIG. 3 is a partial section view of the exemplary disclosed turbine rotor assembly of FIG. 1 after friction welding;

FIG. 4 is a partial section view of the exemplary disclosed turbine rotor assembly of FIG. 2 after friction welding; and

FIG. 5 is a flow chart illustrating an exemplary disclosed method according to one embodiment of the invention.

DETAILED DESCRIPTION

FIG. 1 illustrates a first exemplary turbine rotor assembly 10. The turbine rotor assembly 10 may be used in a turbocharger in an internal combustion engine to increase engine power and efficiency. The internal combustion engine may be any type of engine, for example, a diesel engine, a gasoline engine or a gaseous-fuel-driven engine. The internal combustion engine may be associated with a fixed or mobile machine. Such machines may include, for example, an earth moving machine such as an excavator, a dozer, a loader, a backhoe loader, a motor grader, a dump truck, any other earth moving machines or a ship.

As shown in FIG. 1, the turbine rotor assembly 10 may include a rotor shaft 12 extending along a central axis A between a first end 16 and a second end 18, and a turbine rotor wheel 20 joined to the second end 18 of the rotor shaft 12. FIG. 1 shows a longitudinal partial cross-sectional view of the rotor shaft 12 and the turbine rotor wheel 20 prior to the two members being joined together to form the turbine rotor assembly 10. The turbine rotor wheel 20 may include a hub portion 22 extending along a central axis B and a plurality of vanes 24 extending radially and outwardly from the hub portion 22. The second end 18 of the rotor shaft 12 may include an end surface 26. The hub portion 22 may include an end surface 28.

In one embodiment, the rotor shaft 12 may be made from a titanium alloy, for example, alpha and near alpha alloys, alpha-beta alloys, or unalloyed titanium. Some examples of the alpha-beta alloys may include Ti-6Al-4V, Ti-6Al-6V-2Sn, and Ti-6Al-2Sn-4Zr-6Mo, etc. The turbine rotor wheel 20 may be made from a titanium aluminide intermetallic alloy. Titanium aluminide intermetallic alloys may include TiAl or Ti3Al intermetallic compound-based alloys, for example, Ti-45Al-2Nb-2Cr, Ti-47Al-2Nb-2Cr, or Ti-48Al-2Nb-0.7Cr-0.3Si, etc. Titanium aluminide intermetallic compound-based alloys may be solid state solutions that may have Nb, Cr, Si or other solute atoms randomly distributed in the solvent, namely, titanium aluminide intermetallic compound, in which Ti and Al atoms may form a long-range ordered crystal structure. The rotor shaft 12 may be made from a titanium (Ti) alloy. Ti alloys may be solid solutions that have Al, V, and other solute atoms randomly distributed in the Ti solvent. The rotor shaft 12 may define a cavity 30 extending along the central axis A at the second end 18. In one embodiment, the cavity 30 may have a circular cross-section. The cavity 30 may employ any other configuration.

As shown in FIG. 3, the hub portion 22 of the turbine rotor wheel 20 may be coaxially aligned with the rotor shaft 12, and the end surface 28 of the hub portion 22 may be bonded to the end surface 26 of the rotor shaft 12 by a rotary friction welding process, which will be described in detail below. During the rotary friction welding process, the end surface 28 and the end surface 26 may plastically deform and some material may flow into the cavity 30.

FIG. 2 shows another embodiment 100 of the turbine rotor assembly. The turbine rotor assembly 100 may include a rotor shaft 42, which may include a first section 44 and a second section 50, and a turbine rotor wheel 60. The first section 44 may be a shaft portion extending along a central axis A′ between a first end 46 and a second end 48. The second section 50 may be an intermediate portion 50 extending along a central axis C′ between a first end 52 and a second end 54. FIG. 2 shows the shaft portion 44, the intermediate portion 50, and the turbine rotor wheel 60 prior to these members being joined together to form the turbine rotor assembly 100. The turbine rotor wheel 60 may include a hub portion 62 extending along a central axis B′ and a plurality of vanes 64 extending radially and outwardly from the hub portion 62.

The hub portion 62, the intermediate portion 50, and the shaft portion 44 may be coaxially aligned. The hub portion 62 of the turbine rotor wheel 60 may be bonded to the second end 54 of the intermediate portion 50, and the first end 52 of the intermediate portion 50 may be coupled to the second end 48 of the shaft portion 44.

In one embodiment, the shaft portion 44 may be made from a metal, for example, steel. The intermediate portion 50 may be made from a titanium alloy, for example, alpha and near alpha alloys, alpha-beta alloys, or unalloyed titanium. Some examples of the alpha-beta alloys may include Ti-6Al-4V, Ti-6Al-6V-2Sn, and Ti-6Al-2Sn-4Zr-6Mo, etc. The turbine rotor wheel 60 may be made from a titanium aluminide intermetallic alloy, for example, Ti-45Al-2Nb-2Cr, Ti-47Al-2Nb-2Cr, or Ti-48Al-2Nb-0.7Cr-0.3Si, etc. The intermediate portion 50 may define a cavity 70 extending along the central axis C′ at the second end 54 of the intermediate portion 50. Similar to, the above-described embodiment shown in FIG. 1, the cavity 70 may employ different configurations.

As shown in FIG. 4, the turbine rotor wheel 60 may be bonded to the second end 54 of the intermediate portion 50 by a friction welding process which will be described in detail below. During the friction welding process, the hub portion 62 and the second end 54 may plastically deform and some material may flow into the cavity 70. The intermediate portion 50 may be coupled to the shaft portion 44 by thread, welding, brazing, or other mechanisms. The welding process of intermediate portion 50 to the shaft portion 44 may include friction welding, laser welding, electron beam welding (EBW) (which is a fusion bonding process that produces a weld by impinging a beam of high energy electrons to heat the welding joint), or other welding methods.

INDUSTRIAL APPLICABILITY

The disclosed friction welding method may be used to bond a material made from a titanium aluminide intermetallic alloy to another material that may be made from a titanium alloy. Particularly, the disclosed friction welding method may be used to bond a TiAl turbine rotor wheel to a turbine rotor shaft to form a turbine rotor assembly used in, for example, a turbocharger. The turbocharger can be used in an engine system to improve transient response and thermal efficiency of the engine.

Bonding processes that involves very high temperatures may produce large temperature gradient near the bonding region and may cause high local thermal stresses in the joining region. TiAl intermetallic materials have limited ductility, and therefore, are prone to crack during or after the bonding process. In some applications, e.g. turbine wheel, the high local thermal stress near the joining region could be further enhanced because of specific component geometry or large component size, which poses a great challenge to the joining process. Preheating the TiAl intermetallic material to a predetermined temperature, e.g. 600° C., combined with the specified set of welding conditions as described in this disclosure, can decrease thermal stresses and, therefore, avoid cracking. In addition, the specified set of welding conditions with preheating as disclosed in this disclosure can minimize excessive diffusion/reaction, reduce the formation of brittle intermetallic phases at the interface and therefore, produce superior joining properties. The disclosed friction welding method can be used in turbine applications as well as large valve applications (for example, more than four inches (10.16 cm) in valve head diameter), where high local thermal stresses may be encountered because of special geometry or larger size.

An exemplary welding process for bonding a turbine rotor wheel 20 to a rotor shaft 12 to form a turbine rotor assembly 10 as shown in FIG. 5 is described in detail below. At step 102, a first material made from a titanium aluminide intermetallic alloy and a second material made from a titanium alloy are provided. In an exemplary embodiment, the first material may be the turbine rotor wheel 20 made from the titanium aluminide intermetallic alloy, and the second material may be a section of a turbine rotor shaft 12, for example, an intermediate portion 50. At step 104, the TiAl turbine rotor wheel 20 may be preheated to a predetermined temperature, for example, at least about 300° C. In one embodiment, the TiAl turbine rotor wheel 20 may be preheated to a temperature in a range from about 300° C. to about 800° C. In another embodiment, the TiAl turbine rotor wheel 20 may be preheated to a temperature in a range from about 400° C. to about 650° C. Then, the TiAl turbine rotor wheel 20 and the rotor shaft 12 may be bonded by a rotary friction welding process.

The rotary friction welding may include two stages, a friction stage at steps 106, 108, and 110 and a forging stage at step 112. In the friction stage at the step 106, the rotor shaft 12 may be held by a chuck in a rotating machine, and the turbine rotor wheel 20 may be held by a chuck in a machine that may hold the turbine rotor wheel 20 in a stationary manner and that may linearly move the turbine rotor wheel 20 along the central axis. The hub portion 22 of the turbine rotor wheel 20 and the rotor shaft 12 may be coaxially aligned, with the hub portion 22 facing the second end 18 of the rotor shaft 12. While the rotor shaft 12 held by the rotating chuck is rotated at a high speed, the turbine rotor wheel 20 held by the chuck may be moved toward the rotor shaft 12, and the hub portion 22 of the turbine rotor wheel 20 may be pressed onto the second end 18 of the rotor shaft 12 at a predetermined friction pressure for a predetermined time duration at the step 108. The time duration may also be expressed in burn-off distance which may vary with the alloy used.

In one embodiment, in the friction stage, the rotor shaft 12 may be rotated at a predetermined rotational speed, for example, 800 revolutions per minute (rpm). The rotational speed may also correspond to a linear speed between about 0.3 m/s and about 5 m/s at the outer circumference of the hub portion 22. The turbine rotor wheel 20 and the rotor shaft 12 may be pressed against each other at a predetermined pressure, for example, about 10 megapascal (MPa) to 200 MPa for a predetermined time, for example, about 5 to 60 seconds. In another embodiment, the friction stage may include two sub-stages. In the first sub-stage, the turbine rotor wheel 20 and the rotor shaft 12 may be pressed against each other by a first predetermined pressure, for example, about 20 MPa to 60 MPa for about 5 to 30 seconds. In the second sub-stage, the turbine rotor wheel 20 and the rotor shaft 12 may pressed against each other by a second predetermined pressure of about 50 MPa to 200 MPa for about 0.5 to 5 seconds. The pressure and time may be different according to the size, weight and shape of the turbine rotor wheel 20 and the preheat temperature of the turbine rotor wheel 20 before the rotary friction welding process. The rotating chuck may be then rapidly braked to stop the rotation of the rotor shaft 12 at step 110.

The forging stage may start after the rotation of the rotor shaft 12 is stopped. In the forging stage at the step 112, the two end surfaces 26 and 28 may be pressed against each other firmly by a predetermined forge pressure, for example, at least about 200 MPa, for a predetermined time duration depends on component size, for example, about 5 to 60 seconds.

In the friction stage, the friction between the end surfaces 26 and 28 may generate heat, and the end surface 28 of the hub portion 22 of the turbine rotor wheel 20 and the end surface 26 of the second end 18 of the rotor shaft 12 may plastically deform. In both the friction stage and the forge stage, materials from the hub portion 22 and the second end 18 may flow into the cavity 30 and at least partially fill the cavity 30. The cavity 30 may help to reduce the probability of thermal cracking because the temperature gradient in radial direction may be reduced as the center part generally has a low linear speed and therefore may be heated up slower by friction than the outer circumference. The cavity 30 may also increase joint properties because it may reduce the thickness of diffusion/reaction layer, which can minimize the formation of intermetallic phases. The arrangement of the cavity 30 may also reduce burrs generated at the outer circumference of the rotor shaft 12 and the hub portion 22 during the process of welding the second end 18 of the rotor shaft 12 with the hub portion 22 of the turbine rotor wheel 20, and therefore, it may also reduce the mechanical work needed to remove the burrs afterwards.

In one embodiment, the bonded portion of the turbine rotor assembly 10 may be provided with a post-weld heat treatment to release stress generated in the friction welding process in the bonded portion. For example, the bonded portion of the turbine rotor assembly 10 may be heated to a predetermined temperature, for example, about 400° C., to release stress generated during the friction welding process.

The exemplary turbine rotor assembly 100 as shown in FIG. 2 can be formed by a welding process described in detail below. The hub portion 62 of the TiAl turbine rotor wheel 60 may be preheated to a predetermined temperature at the step 104, for example, at least about 300° C. In one embodiment, the TiAl turbine rotor wheel 60 may be preheated to a temperature in a range from about 300° C. to about 800° C. In another embodiment, the TiAl turbine rotor wheel 60 may be preheated to a temperature in a range from about 400° C. to about 650° C. Then, the TiAl turbine rotor wheel 60 and the intermediate portion 50 may be bonded by a rotary friction welding process, which can be similar or identical to the process of bonding the TiAl turbine rotor wheel 20 to the rotor shaft 12 as described above from the step 106 to the step 112. In one embodiment, after the TiAl turbine rotor wheel 60 is bonded to the intermediate portion 50, the first end 52 of the intermediate portion 50 may be then coupled to the second end 48 of the shaft portion 44. In another embodiment, the intermediate portion 50 may be bonded to the shaft portion 44 first, and then the intermediate portion 50 is bonded to the turbine rotor wheel 60. The intermediate portion 50 may be coupled to the shaft portion 44 by thread, welding, brazing, or other mechanisms. The welding process for bonding the intermediate portion 50 to the shaft portion 44 may include friction welding, laser welding, electron beam welding (EBW), or other welding methods.

Several advantages over the prior art may be associated with the method of bonding a first material made from a titanium aluminide intermetallic alloy to a second material made from a titanium alloy by friction welding described in the subject application. It can be used successfully on turbine applications as well as large-scale valve applications. The arrangement may avoid cracking in the joint or in the titanium aluminide intermetallic alloy component caused by excessive local thermal stress. The disclosed method may also provide successful friction welding on applications with special geometry. The method may utilize specified sets of welding conditions as disclosed above designed to work with preheating to minimize the formation of brittle intermetallic phases in order to provide superior joint quality. It may also avoid damaging the titanium aluminide intermetallic alloy component, increase operation robustness and reduce production cost by limiting the preheating temperature to a predetermined temperature range, for example, below about 800° C. Furthermore, the arrangement of the cavity at the end of the rotor shaft or the intermediate portion to be bonded to the turbine rotor wheel may increase joint properties effectively and may reduce the mechanical work needed to remove burrs generated in welding the turbine rotor wheel with the rotor shaft.

It will be apparent to those skilled in the art that various modifications and variations can be made to the friction welding method. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed friction welding method. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.

Claims

1. A method of bonding two materials comprising:

providing a first material made from a titanium aluminide intermetallic alloy and a second material made from a titanium alloy;
heating the first material to a temperature between about 300° C. and about 800° C.;
rotating the second material relative to the first material;
pressing the first material and the second material against each other while rotating one of the first material and the second material;
stopping the rotation of one of the first material and the second material; and
pressing the first material and the second material against each other after stopping the rotation of one of the first material and the second material.

2. The method of claim 1, wherein the temperature is between about 400° C. and 650° C.

3. The method of claim 1, wherein pressing the first material and the second material against each other while rotating one of the first material and the second material includes pressing the first material and the second material against each other at a pressure of about 10 MPa to 200 MPa for about 5 to 60 seconds.

4. The method of claim 1, wherein pressing the first material and the second material against each other while rotating one of the first material and the second material includes:

pressing the first material and the second material against each other at a first pressure for a first time period; and
pressing the first material and the second material against each other at a second pressure for a second time period, the second pressure being different from the first pressure.

5. The method of claim 4, wherein the first pressure is about 20 MPa to 60 MPa, and the first time period is about 5 to 30 seconds, and the second pressure is about 50 MPa to 200 MPa, and the second time period is about 0.5 to 5 seconds.

6. The method of claim 1, wherein pressing the first material and the second material against each other after stopping the rotation of one of the first material and the second material includes pressing the first material and the second material against each other at a pressure of about 200 MPa or greater for about 5 to 60 seconds after stopping the rotation of one of the first material and the second material.

7. The method of claim 1, wherein providing a second material made from a titanium alloy includes providing a second material having a cavity at an end of the second material.

8. The method of claim 1, wherein providing a first material made from a titanium aluminide intermetallic alloy includes providing a turbine rotor wheel made from the titanium aluminide intermetallic alloy, and wherein providing a second material made from a titanium alloy includes providing a rotor shaft made from the titanium alloy.

9. The method of claim 1, wherein providing a first material made from a titanium aluminide intermetallic alloy includes providing a turbine rotor wheel made from the titanium aluminide intermetallic alloy, and wherein providing a second material made from a titanium alloy includes providing a section of a turbine rotor shaft, and wherein the section is made from the titanium alloy.

10. The method of claim 1, wherein providing a first material made from a titanium aluminide intermetallic alloy includes providing a valve head having a diameter of about four inches (10.16 cm) or greater.

11. A method of producing a turbine rotor assembly comprising:

heating a turbine rotor wheel to a temperature between about 300° C. and about 800° C., wherein the turbine rotor wheel is made from a titanium aluminide intermetallic alloy;
rotating a turbine rotor shaft relative to the turbine rotor wheel;
pressing the turbine rotor shaft against the turbine rotor wheel while rotating the turbine rotor shaft;
stopping the rotation of the turbine rotor shaft; and
pressing the turbine rotor shaft against the turbine rotor wheel after stopping the rotation of the turbine rotor shaft.

12. The method of claim 11, wherein the turbine rotor shaft is made from a titanium alloy.

13. The method of claim 12, wherein the turbine rotor shaft includes a cavity at an end to be bonded to the turbine rotor wheel.

14. The method of claim 11, wherein the turbine rotor shaft includes a section to be bonded to the turbine rotor wheel, the section being made from a titanium alloy.

15. The method of claim 14, wherein the section of the turbine rotor shaft includes a cavity at an end to be bonded to the turbine rotor wheel.

16. The method of claim 11, wherein the temperature is between about 400° C. and 650° C.

17. The method of claim 11, wherein pressing the turbine rotor shaft against the turbine rotor wheel while rotating the turbine rotor shaft includes pressing the turbine rotor shaft and the turbine rotor wheel against each other at a pressure of about 10 MPa to 200 MPa for about 5 to 60 seconds.

18. An assembly made by a friction welding process comprising:

a first material; and
a second material,
wherein at least one of the first material and the second material includes a cavity at an end of the at least one of the first material and the second material to be coupled to the other material, the cavity being at least partially filled with at least one of the first material and the second material as a result of the friction welding process.

19. The assembly of claim 18, wherein the first material includes a turbine rotor wheel made from a titanium aluminide intermetallic alloy.

20. The assembly of claim 18, wherein the second material includes a turbine rotor shaft having at least a section made from a titanium alloy.

Patent History
Publication number: 20080000558
Type: Application
Filed: Jun 30, 2006
Publication Date: Jan 3, 2008
Inventors: Nan Yang (Dunlap, IL), Jesus G. Chapa-Cabrera (Monterrey)
Application Number: 11/479,599
Classifications
Current U.S. Class: With Metal Next To Or Bonded To Metal (148/527)
International Classification: C22F 1/18 (20060101);