Spin transfer MRAM device with reduced coefficient of MTJ resistance variation
We describe the manufacturing process for and structure of a CPP MTJ MRAM unit cell that utilizes transfer of spin angular momentum as a mechanism for changing the magnetic moment direction of a free layer. The cell is formed of a vertically or horizontally series connected sequence of N sub-cells, each sub-cell being an MTJ element. A statistical population of such multiple sub-cell unit cells has a variation of resistance that is less by a factor of N−1/2 than that of a population of single sub-cells. As a result, such unit cells have an improved read margin while not requiring an increase in the critical switching current.
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1. Field of the Invention
This invention relates generally to a current perpendicular to plane random access memory (CPP-MRAM) cell formed as a magnetic tunneling junction (MTJ) and using a spin transfer effect with enhanced spin torque.
2. Description of the Related Art
The conventional magnetic tunneling junction (MTJ) device is a form of ultra-high magnetoresistive device in which the relative orientation of the magnetic moments of parallel, vertically separated, upper and lower magnetized layers controls the flow of spin-polarized electrons tunneling through a very thin dielectric layer (the tunneling barrier layer) formed between those layers. When injected electrons pass through the upper layer they are spin polarized by interaction with the magnetic moment of that layer. The majority of the electrons emerge polarized in the direction of the magnetic moment of the upper layer, the minority being polarized opposite to that direction. The probability of such a polarized electron then tunneling through the intervening tunneling barrier layer into the lower layer then depends on the availability of states within the lower layer that the tunneling electron can occupy. This number, in turn, depends on the magnetization direction of the lower electrode. The tunneling probability is thereby spin dependent and the magnitude of the current (tunneling probability times number of electrons impinging on the barrier layer) depends upon the relative orientation of the magnetizations of magnetic layers above and below the barrier layer. The MTJ device can therefore be viewed as a kind of multi-state resistor, since different relative orientations (e.g. parallel and antiparallel) of the magnetic moments will change the magnitude of a current passing through the device. In a common type of device configuration (spin filter), one of the magnetic layers has its magnetic moment fixed in direction (pinned) by exchange coupling to an antiferromagnetic layer, while the other magnetic layer has its magnetic moment free to move (the free layer). The magnetic moment of the free layer is then made to switch its direction from being parallel to that of the pinned layer, whereupon the tunneling current is large, to being antiparallel to the pinned layer, whereupon the tunneling current is small. Thus, the device is effectively a two-state resistor. The switching of the free layer moment direction (writing) is accomplished by external magnetic fields that are the result of currents passing through conducting lines adjacent to the cell.
The use of magnetic fields externally generated by current carrying lines (as in
For this reason, a new type of magnetic device, called a spin transfer device and described by Slonczewski, (U.S. Pat. No. 5,695,164) and by Redon et al. (U.S. Pat. No. 6,532,164) has been developed and seems to eliminate some of the problems associated with the excessive power consumption necessitated by external switching fields. The spin transfer device shares some of the operational features of the conventional MTJ cell described above, except that the switching of the free layer magnetic moment is produced by the spin polarized current itself. In this device, unpolarized conduction electrons passing through a first magnetic layer having its magnetic moment oriented in a given direction (such as the pinned layer) are preferentially polarized by their passage through that layer by a quantum mechanical exchange interaction with the polarized bound electrons in the layer. Such a polarization can occur to conduction electrons that reflect from the surface of the magnetized layer as well as to those that pass through it. When such a stream of polarized conduction electrons subsequently pass through a second magnetic layer whose polarization direction is not fixed in space (such as the free layer), the polarized conduction electrons exert a torque on the bound electrons in the magnetic layers which, if sufficient, can reverse the polarization of the bound electrons and, thereby, reverse the magnetic moment of the magnetic layer. The use of a spin-polarized current internal to the cell to cause the magnetic moment reversal requires much smaller currents than those required to produce an external magnetic field from adjacent current carrying lines to produce the moment switching. Recent experimental data (W. H. Rippard et al., Phys. Rev. Lett., 92, (2004) ) confirm magnetic moment transfer as a source of magnetic excitation and, subsequently, magnetic moment switching. These experiments confirm earlier theoretical predictions (J. C. Slonczewski, J. Magn. Mater. 159 (1996) L I, and J. Z. Sun, Phys. Rev. B., Vol. 62 (2000) 570). These latter papers show that the net torque, Γ, on the magnetization of a free magnetic layer produced by spin-transfer.from a spin-polarized DC current is proportional to:
Γ=s nmx(nsx nm), (1)
Where s is the spin-angular momentum deposition rate, ns is a unit vector whose direction is that of the initial spin direction of the current and nm is a unit vector whose direction is that of the free layer magnetization and x symbolizes a vector cross product. According equation (1), the torque is maximum when ns is orthogonal to nm.
Referring to
Referring again to
Conversely, if the current is directed from top to bottom, the free layer magnetization (40) would be switched, by torque transfer of angular momentum, to the same direction as that of the pinned reference layer (30), since the conduction electrons have passed through that layer before entering the free layer. The MTJ element is then in its low resistance state.
Referring again to
The critical current for spin transfer switching, Ic, is is generally a few milliamperes for a 180 nm sub-micron MTJ cell (of cross-sectional area A approximately A=200 nm×400 nm). The corresponding critical current density, Jc, which is Ic/A, is on the order of several 107 Amperes/cm2. This high current density, which is required to induce the spin transfer effect, could destroy the insulating tunneling barrier in the MTJ cell, such as a layer of AlOx, MgO, etc.
During the reading of data, a small current flows across the MTJ cell and its resistance is compared with a pre-written MTJ cell (not shown) called a reference cell, to determine whether the cell being read is in a high or low resistance state. Typically, the reading margin is determined by the ratio between the magneto-resistive ratio, dR/R (the difference between the maximum and minimum resistance of the cell divided by its maximum resistance) and the coefficient of resistance variance, σ/μ, (the ratio between resistance standard deviation σ and resistance mean value μ).
Normally, the write current density required to switch the direction of the free layer magnetization is mainly determined by the free layer magnetic moment, damping ratio and spin-angular momentum deposition rate, which depend on the MTJ film materials and their quality. As the MTJ device is microminiaturized to nanometer scale dimensions, the write current density is unchanged, giving a much smaller write current which is scalable to the shrinking MTJ cell dimensions. Hence, power consumption in the device is reduced.
However, as the MTJ cell dimensions become smaller and smaller, the MTJ resistance variation rapidly increases. For example. using the same MTJ film materials and deposition processes, the coefficient of MTJ resistance variance is found to be inversely proportional to the square root of each MTJ junction area. This makes the reading process very difficult, even impossible, without a great increase in the magneto-resistive ratio dR/R. To address this problem, a spin transfer MRAM structure with a special arrangement of MTJ cells is proposed to reduce the resistance variance.
Various combinations of MTJ cells can be found in the prior art. Huai et al. (U.S. Pat. No. 7,009,877) shows an MTJ element and a spin transfer element arranged vertically. In this invention they use an MTJ and a CPP-GMR immediately connected together to achieve a low write switching current. They also include the combination of two different MTJ cells, one with a smaller dR/R than the other, to achieve a low write switching current.
Hosotani (US Patent Application 2006/0221680) and Ju et al. (US Patent Application 2006/0202244) and Nickel et al (US Patent Application 2005/0195649) all disclose two MTJ elements connected in series and are used to write two bits per cell. In these applications two different MTJ cells are connected together with different anisotropy directions in their layers, obtained either by different shape orientations or different magnetic materials.
Nguyen et al (U.S. Pat. No. 6,992,359) disclose a method for reducing write current density for spin transfer by using a free layer having a high perpendicular magnetic anisotropy. The purpose is to achieve a low write switching current for a spin-transfer MRAM.
None of the above prior art discuss a method for reducing resistance variation, which will help the reading process for a spin-transfer MRAM. To address this problem, we propose a spin-transfer MRAM cell structure with a special arrangement of MTJ elements designed to reduce the resistance covariance. In this arrangement, electric current flows across two or more identical MTJ elements (denoted “sub-cells”) substantially identical in structure to the MTJ element shown in
During the writing process, the required critical current for switching the magnetization direction of an MTJ free layer is the same for all MTJ sub-cells connected in series. Thus, the same size current-supplying local transistor is required as would be needed for writing a single MTJ element. During the reading process, if each individual sub-cell has a mean resistance value Rp and if the resistance values are distributed with a standard deviation σ, the mean value of the total resistance in one MTJ MRAM cell unit containing N sub-cells is the product (N)(Rp), while the standard deviation of total resistance of many such MRAM units is the product o (N)1/2. Therefore, given that the coefficient of resistance of one MTJ sub-cell is σ/Rp, the coefficient of resistance among the MTJ MRAM units is the product (N)−1/2 (σ/Rp). In other words, the coefficient of resistance is reduced by a factor of (N)1/2, yielding a greatly increased reading margin.
SUMMARY OF THE INVENTIONA first object of this invention is to provide an MRAM device configuration that provides a greatly increased read margin while not requiring any increase in critical current or local transistor size.
A second object of this invention is to provide a MRAM device configuration that includes a plurality of series-connected MTJ sub-cells in which the coefficient of resistance of the configuration as a whole is reduced as compared with the coefficient of resistance of the individual sub-cells.
These objects are achieved by an MRAM design in which N (where N is equal to or greater than 2) MTJ sub-cells of identical size are connected in series so as to function as a single unit in a spin transfer MRAM structure. Thus, the passage of a critical current simultaneously switches the free layer magnetization of the free layer in each sub-cell. This arrangement requires the same write current or the same local transistor size, yet it gives a greatly increased reading margin as a result of a coefficient of resistance variation that is reduced by a factor of N−1/2. Thus, in a given unit cell of a multi-cell array, each unit cell will comprise two or more identical sub-cells connected in series between a local transistor and a bit line. The sub-cells may be sequentially connected either in a horizontal configuration, in which adjacent series connected cells are at the same vertical level, or a vertical configuration in which sequentially adjacent cells are at different vertical levels. In each configuration, as will be shown in greater detail below, the bottom electrode of the first sub-cell is connected to the local transistor, the top electrode of the last sub-cell is connected to the bit line and any adjacent intermediate sub-cells are connected by electrically contacting a top electrode to a bottom electrode.
The preferred embodiment of the present invention is an MRAM device (a single unit cell or an array of such cells) of the spin-transfer variety, having as the basic components of each unit cell CPP-MTJ elements. These elements are configured as a series-connected sequence of MTJ sub-cells so that the critical switching current is the same as for a single cell yet the variation of resistance is significantly reduced.
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The horizontal extent of the film stack as well as the horizontal extent of the bottom electrode is sufficient to form, by lithographic patterning to a desired horizontal cross-sectional area, a plurality of sub-cells that will be connected to form a sequentially series connected unit MRAM cell.
As indicated by the cell structure in
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It should be understood by those skilled in the art that the steps outlined above in
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As is finally understood by a person skilled in the art, the preferred embodiments of the present invention are illustrative of the present invention rather than limiting of the present invention. Revisions and modifications may be made to methods, materials, structures and dimensions employed in forming and providing a CPP MTJ MRAM cell device using transfer of spin angular momentum formed as a series connected sequence of sub-cells, while still forming and providing such a device and its method of formation in accord with the spirit and scope of the present invention as defined by the appended claims.
Claims
1. A spin transfer MRAM unit cell comprising:
- a local transistor capable of providing a critical switching current to an MTJ cell element;
- a horizontally directed word line contacting said transistor and capable of activating said transistor so that a current is produced;
- a horizontally directed bit line, vertically separated from said word line and directed transversely to said word line;
- a configuration of N vertically adjacent MTJ sub-cells, wherein N is an integer greater than 1, said configuration including a first sub-cell and a last sub-cell and said configuration being electrically connected in linear series, wherein all MTJ sub-cells have the same multi-layer structure with the same geometry and each sub-cell comprises, in a vertically stacked configuration, a bottom electrode, a pinning layer, a synthetic pinned layer, a tunneling barrier layer, a free layer and an upper electrode and wherein
- the bottom electrode of said first sub-cell of said N sub-cells electrically contacts said local transistor, and
- the top electrode of said last sub-cell of said N sub-cells electrically contacts said bit line, and wherein
- said top electrode and said bottom electrode of each pair of vertically adjacent sub-cells are in electrical contact, whereby
- a critical current capable of simultaneously switching the magnetization of said free layer in each sub-cell can pass vertically between said transistor and said bit line.
2. The unit cell of claim 1 wherein the resistance variations of a statistical population of said unit cell is less by a factor of N−1/2 than the resistance variations of a statistical population of a unit cell having equivalent properties and formed of a single sub-cell.
3. A spin transfer MRAM unit cell comprising:
- a local transistor capable of providing a critical switching current to an MTJ cell element;
- a horizontally directed word line contacting said transistor and capable of activating said transistor so that a current is produced;
- a horizontally directed bit line, vertically separated from said word line and directed transversely to said word line;
- a configuration of N horizontally adjacent MTJ sub-cells, wherein N is an integer greater than 1, each sub-cell of said N sub-cells being at a common vertical level and each sub-cell of said N sub-cells including a first sub-cell and a last sub-cell and said N sub-cells being electrically connected in linear series, wherein all MTJ sub-cells have the same multi-layer structure with the same geometry and each sub-cell comprises, in a vertically stacked configuration, a bottom electrode, a pinning layer, a synthetic pinned layer, a tunneling barrier layer, a free layer and an upper electrode and wherein
- the bottom electrode of said first sub-cell of said configuration electrically contacts said local transistor, and
- the top electrode of said last sub-cell of said configuration electrically contacts said bit line, and wherein
- said top electrode and said bottom electrode of each pair of adjacent sub-cells are vertically displaced from each other and horizontally overlap, whereby said electrodes are placed in electrical contact by means of a conducting via formed between them, whereby
- a critical current capable of simultaneously switching the magnetization of said free layer in each sub-cell can pass from said transistor, through each sub-cell to said bit line.
4. The unit cell of claim 1 wherein the resistance variations of a statistical population of said unit cell is less by a factor of N−1/2 than the resistance variations of a statistical population of a unit cell having equivalent properties and formed of a single sub-cell.
5. A method of forming a spin transfer MRAM unit cell comprising:
- providing a substrate;
- forming a vertically, electrically series connected sequence of MTJ sub-cells, said formation comprising: forming a first bottom electrode layer on said substrate; forming a first MTJ stack film on said first bottom electrode layer; patterning said first bottom electrode layer to form a first bottom electrode; patterning said first MTJ stack film to form a first MTJ sub-cell of desired cross-sectional shape; forming a first blanket refill layer of dielectric material over and around said MTJ sub-cell; planarizing said first blanket refill layer to expose an upper surface of said first MTJ sub-cell and to create a first coplanar surface of said first dielectric refill layer and said first MTJ sub-cell upper surface; forming a first top electrode layer on said first coplanar surface; forming a second MTJ stack layer on said first top electrode layer; patterning said first top electrode layer to firm a first top electrode; patterning said second MTJ stack layer to create a second MTJ sub-cell of desired cross-sectional shape; forming a second blanket dielectric refill layer over and around said second MTJ sub-cell; planarizing said second blanket refill layer to expose an upper surface of said second MTJ sub-cell and to create a second coplanar surface of said first dielectric refill layer and said second MTJ sub-cell upper surface; forming a second top electrode layer on said second coplanar surface; patterning said second top electrode layer to form a second top electrode; forming a third blanket dielectric refill layer over and around said second top electrode; planarizing said third blanket refill layer to expose an upper surface of said second top electrode and to create a third coplanar surface of said third dielectric refill layer and said second top electrode upper surface.
6. The method of claim 5 further comprising the formation of a bit line on said third coplanar surface, said bit line electrically contacting said second top electrode upper surface and the unit cell therefore comprising two sub-cells.
7. The method of claim 5 further comprising the formation of a conducting via through said substrate, wherein said conducting via electrically connects said first bottom electrode to a local transistor
8. The method of claim 5 further comprising the formation of an additional N-2 vertically electrically series connected sequence MTJ sub-cells, wherein the third MTJ sub-cell is formed on said second top electrode upper surface, thereby forming a unit cell comprising N vertically electrically series connected sub-cells.
9. A method of forming a spin transfer MRAM unit cell comprising:
- providing a substrate;
- forming a horizontally, electrically series connected sequence of MTJ sub-cells, said formation comprising: forming a bottom electrode layer on said substrate; forming an MTJ stack film on said bottom electrode layer; patterning said first bottom electrode layer and said MTJ stack film to form a horizontal sequence of N MTJ sub-cells, wherein N is an integer greater than 1, wherein there is a first and a last sub-cell and wherein each sub-cell is formed on a bottom electrode; forming a blanket refill layer of dielectric material over and around said N MTJ sub-cells; planarizing said blanket refill layer to expose an upper surface of each of said N MTJ sub-cell and to create a first coplanar surface of said blanket refill layer and said N MTJ sub-cell upper surfaces; forming conducting vias through said blanket refill layer to contact bottom electrodes of each sub-cell; forming a top electrode layer on said coplanar surface, said top electrode layer electrically contacting each of said vias and each of said top surfaces of said N MTJ sub-cells; patterning said top electrode layer so that N-I electrical connections are formed between the top of an MTJ sub-cell and the top of a via that contacts the bottom electrode of an immediately adjacent sub-cell; forming a planarized second blanket dielectric layer over said N sub-cells; forming a final via to contact the top electrode of the Nth sub-cell and to pass vertically through said planarized blanket dielectric layer; forming a bit line on said planarized blanket dielectric layer, wherein said bit line electrically contacts said final via and, thereby, makes electrical contact with said top electrode of said Nth sub-cell.
10. The method of claim 9 further comprising the formation of a conducting via through said substrate, wherein said conducting via electrically connects the bottom electrode of the said first MTJ sub-cell to a local transistor
Type: Application
Filed: Jul 27, 2007
Publication Date: Jan 29, 2009
Applicant:
Inventor: Yimin Guo (San Jose, CA)
Application Number: 11/881,627
International Classification: G11B 5/33 (20060101);