Method For Producing A Sintered Body
This invention relates to a method for forming a three dimensional sintered body comprising the steps of a) providing a basic mould having a configuration adapted to the sintered body that is to be produced, b) treating the surface of the basic mould to facilitate application of a first surface layer of the sintered body, c) applying powder particles onto the basic mould, to form said first surface layer, d) applying at least one more layer on top of said first surface layer, e) heat treating the basic mould and the particles to form a sintered body, wherein step b) is performed by providing an adhering layer to the basic mould arranged to adhere the particles of at least a portion of the surface layer.
The present invention relates to a method for forming a three dimensional sintered body comprising the steps of:
a) providing a basic mould having a configuration adapted to the sintering body that is to be produced,
b) treating the surface of the basic mould to facilitate application of a first surface layer of the sintered body,
c) applying powder particles onto the basic mould, to form said first surface layer,
d) applying at least one more layer on top of said first surface layer,
e) heat treating the basic mould and the particles to form a sintered body.
Production of three dimensional sintered bodies is traditionally a complex and costly process, e.g. porous bodies. Porous bodies are used for many different technical applications in filtration of gases and liquids, fluidising processes, separation and catalysing. One important application is in filtration of pulps. The shape of the porous body or mould is in the latter case quite complicated. However, the shape of filters for gases and liquids is commonly quite simple due to the inherent manufacturing problems in producing porous bodies having a more complex configuration. Furthermore the production series may be of relative small size, why a low production cost of the mould is an advantage, as also fast and cost effective way of manufacturing it. Another aspect is the internal structure of such products, e.g. drainage properties.
There are some key properties of a filter that have large importance on the requested functionality at the filtering operation. Two of these properties, i.e. high yield at the filtering operation and low pressure drop over the filter, are very often contradictory. High yield of the substance to be taken away by the filtering operation e.g. fibres in a pulp is achieved by using a filter with a fine porous structure. A fine porous structure means in this case that the channels formed by the pores are small in size. However, the pressure drop over the filter increases with decreasing size of the pore channels. On the other hand as mentioned above, a fine structure is often desired to obtain high yield and some times also to facilitate providing a body having a smooth surface structure.
It is well known that a fine pore structure can be achieved by manufacturing the porous body from fine particles or fibres and obviously a coarse pore structure by using coarse particles or fibres in the manufacturing process of the filter.
One rather recent method for producing three-dimensional objects, e.g. to provide filters with a graduated structure, is the WPS-process (Wet Powder Spraying Process). In this process a mixture containing sinter able powder is sprayed on to a supporting body, where after the binding agent of the mixture is decomposed in a first step and the actual sintering is performed in a second step. In US 2004/0050773 there is presented such a process intended for the production of at least two layers of different pore size.
From US 2002/0195188 there is known a similar but somewhat modified process wherein the mixture contains pore forming material containing particles with predetermined size or size distribution. Further, there is also known a process wherein centrifugal forces are used to obtain a graduated structure of a three-dimensional sintered body. As is evident, all of these processes need sophisticated arrangements/apparatuses to achieve a desired result, which leads to a relatively high cost of the final product.
From EP0559490 and EP0559491 there is known a further process for producing a three dimensional body, e.g. a pulp moulding die, preferably comprising glass beads to form a porous structure is presented, which also mentions that sintered particles can be used. The production technology described therein is however complicated.
SUMMARY OF THE INVENTIONIt is an object of the invention to provide a method for forming a three dimensional sintered body comprising the steps of:
a) providing a basic mould having a configuration adapted to the sintering body that is to be produced,
b) treating the surface of the basic mould to facilitate application of a first surface layer of the sintered body,
c) applying powder particles onto the basic mould, to form said first surface layer,
d) applying at least one more layer on top of said first surface layer,
e) heat treating the basic mould and the particles to form a sintered body wherein step b) is performed by providing an adhering layer to the basic mould arranged to adhere the particles of the surface layer.
Thanks to the invention there is provided a method that substantially improves the efficiency for producing a three-dimensional sintered body. Further the present invention provides for the manufacture of a filter having a thin surface layer with fine pore structure and an inner core with coarse pore structure. Hereby is a filter obtained with efficient filtering capability and excellent drainage properties, primarily low pressure-drop during the filtering operations.
According to further aspects of the invention:
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- said adhering layer, is applied as a liquid, which preferably is applied to the basic mould by means of spraying, which provides for a surprisingly efficient process of performing a method according to the invention.
- said liquid substantially comprises water, which preferably is applied to the basic mould by means of spraying, which provides for an especially cost-effective and environmental friendly manner of performing a method according to the invention, and which not least advantageous provides a method where the binder may easily be removed (evaporation) without leaving any rest products.
- at least a portion of said adhering layer is arranged to melt by means of heat supplied from said powder particles, which provides for a surprisingly efficient process of performing a method according to the invention.
- prior to step b) the basic mould has been treated to obtain a temperature of between 0° C.-−100° C., preferably in the range of −10° C.-−30° C., which is an easy way of providing beneficial conditions for performing a method according to the invention.
- step c) is performed in a room having a temperature above +10° C. and below 60° C., preferably between 15-35° C., and more preferred at room temperature between 18-28° C., which for beneficial conditions for performing a method according to the invention and also for individuals involved in it.
- at least one layer and/or at least one portion comprises particles of different size than the particles in other parts of said body, wherein preferably at least one layer and/or one portion comprises particles of larger size than the particles in said surface layer, which provides for en efficient manner of tailoring different properties of a porous body.
- at least one further layer is applied in the same manner on top of said surface layer, which provides for the advantage that more exact tailoring may be achieved concerning properties of a porous body.
- at least one layer comprises powder particles.
- the basic mould is substantially filled prior to step e), which provides an efficient manner of producing a voluminous body, e.g. needing a flat supporting surface.
- at last one channel is provided in the body by applying a solid device that is removed from the body after step d), which is an efficient manner of producing bodies provided with customised properties concerning drainage, etc.
- step b) is also applied to surfaces of the basic mould adapted for substantially non-permeable areas of the body, which for some products provides a very cost-efficient manner of production.
Further aspects and advantages of the method may be found in the description.
In the following the invention will be described in relation to the appended figures, wherein:
In
In the basic mould 400 there is formed a moulding face 402 that corresponds to the surface layer 130 of the product 100 to be sintered and also non-forming surfaces 406. The moulding face 402 may be produced in many different ways known in the art, e.g. by the use of conventional machining techniques. For some products a very smooth surface is desired and then the finish of the surface of the moulding face 402 should preferably be of high quality.
However, the precision, i.e. exact measurement, must not always be extremely high, since an advantage with the invention is that high quality properties of some products may be achieved even if moderate tolerances are used for the configuration of the basic mould, e.g. filter bodies where e.g. drainage properties may be more or less independent of the surface or pulp moulds where heat pressing may improve the surfaces of the moulded object pulp moulds. For moulded pulp objects the first heat pressing action (when producing a moulded pulp product according to a preferred mode, see
In
In
Thereafter, as shown in
In the next step, as shown in
Thereafter the mould 400 may again be put into the freezer 5 (if necessary to re-cool it) and subsequently taken out thereof to apply a further layer of ice 605, as shown in
In the next step a holding device 700 is applied on top of the fixed layers 120, 130, in order to hold the established layers 120, 130 in place during the final sintering stage. In
In
Thereafter the final step when producing a product 100 according to the invention is achieved by sintering (as known per se) the layers 120, 130, in a sintering furnace (not shown) containing an appropriate atmosphere, e.g. H2, H2+N2 or vacuum. For example, if mainly particles of copper-based alloys are used the sintering temperature may be 800-1000 C, and about 1100-1300 C if stainless steel particles are used, combined with a sintering time of 0.5-2 hours.
During the sintering process, at elevated temperature, the water in the ice layers 604, 605 will melt and evaporate, leaving no rest products and merely creating gases in the form of evaporated steam. Hence the use of water/ice provides a very environmental friendly method and also a method that eliminates possible problems related to rest products (as is known in connection with other methods where different kind of binders are used). As is evident the holding device 700 during this process merely fixes the adhered layers 120, 130 in their intended positions during the sintering process. Hence normally the holding device 701 will not exert any pressure onto the layers 120, 130 during the sintering process. However, it is obvious that in connection with production of some specific filters it may be desire to achieve some degree of compactation prior to or during the sintering process, which accordingly may be achieved when using a solid holding device 701 as shown in
After cooling, the sintered body 100 is taken out of the basic mould 400 and is now in principle ready for use, e.g. as a filter body. As can be seen in
However, as indicated by way of example in
As can be seen from
The base structure 110 of the embodiment shown in
As understood by the above and the following, the invention, e.g. by use of the same basic mould 400 to form the same outer configuration, enables production of porous bodies 100 having tailored properties in relation to different parameters, e.g. drainage by varying size and/or shape of the particles and/or temperature conductivity by varying the material of the particles and/or corrosion resistance by varying the material of the particles.
In
In
In the following it will be described that the invention in an efficient manner also enables manufacture of even more complex filter bodies, by describing a pulp mould produced in accordance with the invention.
A major difference for a product according to
As is evident from
Finally, as is evident from
As is evident for the skilled person in the field, the above examples show that the invention provides for production of a large variety of different three dimensional products in a flexible and cost-efficient manner.
As mentioned above the process steps for forming the first layers 120, 130 may be the same for the production of a filter body 100 (as shown in
The invention is not limited by what is described above but may be varied within the scope of the appended claims. For instance, it is evident that the surface layer 130 applied within the basic mould 400 may also be configured generally along the principles as shown in
Of course the configuration of the product 100 may vary within wide frames depending on desired needs and hence it is evident that the shapes of the shown embodiments are by means of example only. The shape of the particles may also vary within wide frames depending on desired needs, e.g. spherical, irregular and/or elongated. The material of the powder particles may also be chosen within a wide range, for example to be mainly ceramic, intermetallic or metallic, e.g. copper, bronze and other copper based alloys, nickel based alloys (e.g. Inconel 600, Monel 400, Hastelloy X, etc) titanium, stainless steel etc.
Claims
1-13. (canceled)
14. A method for forming a sintered body comprising the steps of:
- applying to a surface of a mould an adhering layer to facilitate application of a first layer of particles, the mould having a configuration adapted to the sintered body that is to be produced;
- applying the first layer of particles onto the adhering layer on the surface of the mould, wherein at least a portion of the adhering layer melts from heat supplied by the particles when they are applied to the mould;
- applying a second layer of particles on top of the first layer of particles; and
- sintering the particles of the first layer and the second layer on the mould to form the sintered body.
15. The method of claim 14, wherein the adhering layer is applied as a liquid and freezes after being applied to the surface of the mould.
16. The method of claim 14, wherein the portion of the adhering layer that melts from heat supplied by the particles freezes again before the sintering step.
17. The method of claim 14, wherein the particles of the first layer are adhered by means of freezing of the adhering layer.
18. The method of claim 14, further comprising the step of treating the mould to obtain a temperature of the mould between 0° C. and −100° C. before applying the adhering layer.
19. The method of claim 14, further comprising the step of treating the mould to obtain a temperature of the mould between −10° C. and −30° C. before applying the adhering layer.
20. The method of claim 14, wherein the step of applying the first layer of particles is performed in a room having a temperature between 10° C. and 60° C.
21. The method of claim 14, further comprising the step of treating the mould to obtain a temperature of the mould between 0° C. and −100° C. after applying the first layer of particles and before applying the second layer of particles.
22. The method of claim 14, further comprising the step of applying a second adhering layer after applying the first layer of particles and before applying the second layer of particles.
23. The method of claim 14, wherein the particles of the first layer have a different size than the particles in the second layer.
24. A sintered body formed by a process comprising the steps of:
- applying to a surface of a mould an adhering layer to facilitate application of a first layer of particles, the mould having a configuration adapted to the sintered body that is to be produced;
- applying the first layer of particles onto the adhering layer on the surface of the mould, wherein at least a portion of the adhering layer melts from heat supplied by the particles when they are applied to the mould;
- applying a second layer of particles on top of the first layer of particles; and
- sintering the particles of the first layer and the second layer on the mould to form the sintered body.
25. The sintered body of claim 24, wherein the adhering layer is applied as a liquid and freezes after being applied to the surface of the mould.
26. The sintered body of claim 24, wherein the portion of the adhering layer that melts from heat supplied by the particles freezes again before the sintering step.
27. The sintered body of claim 24, wherein the particles of the first layer are adhered by means of freezing of the adhering layer.
28. The sintered body of claim 24, wherein the process further comprises the step of treating the mould to obtain a temperature of the mould between 0° C. and −100° C. before applying the adhering layer.
29. The sintered body of claim 24, wherein the process further comprises the step of treating the mould to obtain a temperature of the mould between −10° C. and −30° C. before applying the adhering layer.
30. The sintered body of claim 24, wherein the step of applying the first layer of particles is performed in a room having a temperature between 10° C. and 60° C.
31. The sintered body of claim 24, wherein the process further comprises the step of treating the mould to obtain a temperature of the mould between 0° C. and −100° C. after applying the first layer of particles and before applying the second layer of particles.
32. The sintered body of claim 24, wherein the process further comprises the step of applying a second adhering layer after applying the first layer of particles and before applying the second layer of particles.
33. The sintered body of claim 24, wherein the particles of the first layer have a different size than the particles in the second layer.
Type: Application
Filed: Aug 27, 2010
Publication Date: Dec 23, 2010
Inventors: Björn Nilsson (Kimstad), Lars Graffton (Bettna), Leif BÅSKMAN (Norrkoping)
Application Number: 12/870,575
International Classification: B29C 35/16 (20060101);