LAMINATED SOLAR CELL INTERCONNECTION SYSTEM
Thin film photovoltaic cells and strings of cells may be electrically joined in series. More specifically, electrical contacts between photovoltaic cells may be formed by positioning the cells between a pair of interconnection substrates, each of which includes a conductive grid. By positioning the cells appropriately between the substrates, an electrical connection is formed between one polarity of a given cell and the opposite polarity of an adjacent cell.
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This application claims priority from U.S. Provisional Patent Applications Ser. No. 61/284,958, filed Dec. 28, 2009, Ser. No. 61/284,956 filed Dec. 28, 2009 and Ser. No. 61/284,924 filed Dec. 28, 2009 all of which are incorporated herein by reference. Also incorporated by reference in their entireties are the following patents and patent applications: U.S. Pat. No. 7,194,197, U.S. Pat. No. 6,690,041, Ser. No. 12/364,440 filed Feb. 2, 2009 and Ser. No. 12/587,111 filed Sep. 30, 2009.
BACKGROUNDThe field of photovoltaics generally relates to multi-layer materials that convert sunlight directly into DC electrical power. The basic mechanism for this conversion is the photovoltaic effect, first observed by Antoine-Cesar Becquerel in 1839, and first correctly described by Einstein in a seminal 1905 scientific paper for which he was awarded a Nobel Prize for physics. In the United States, photovoltaic (PV) devices are popularly known as solar cells or PV cells. Solar cells are typically configured as a cooperating sandwich of p-type and n-type semiconductors, in which the n-type semiconductor material (on one “side” of the sandwich) exhibits an excess of electrons, and the p-type semiconductor material (on the other “side” of the sandwich) exhibits an excess of holes, each of which signifies the absence of an electron. Near the p-n junction between the two materials, valence electrons from the n-type layer move into neighboring holes in the p-type layer, creating a small electrical imbalance inside the solar cell. This results in an electric field in the vicinity of the metallurgical junction that forms the electronic p-n junction.
When an incident photon excites an electron in the cell into the conduction band, the excited electron becomes unbound from the atoms of the semiconductor, creating a free electron/hole pair. Because, as described above, the p-n junction creates an electric field in the vicinity of the junction, electron/hole pairs created in this manner near the junction tend to separate and move away from junction, with the electron moving toward the electrode on the n-type side, and the hole moving toward the electrode on the p-type side of the junction. This creates an overall charge imbalance in the cell, so that if an external conductive path is provided between the two sides of the cell, electrons will move from the n-type side back to the p-type side along the external path, creating an electric current. In practice, electrons may be collected from at or near the surface of the n-type side by a conducting grid that covers a portion of the surface, while still allowing sufficient access into the cell by incident photons.
Such a photovoltaic structure, when appropriately located electrical contacts are included and the cell (or a series of cells) is incorporated into a closed electrical circuit, forms a working PV device. As a standalone device, a single conventional solar cell is not sufficient to power most applications. As a result, solar cells are commonly arranged into PV modules, or “strings,” by connecting the front of one cell to the back of another, thereby adding the voltages of the individual cells together in electrical series. Typically, a significant number of cells are connected in series to achieve a usable voltage. The resulting DC current then may be fed through an inverter, where it is transformed into AC current at an appropriate frequency, which is chosen to match the frequency of AC current supplied by a conventional power grid. In the United States, this frequency is 60 Hertz (Hz), and most other countries provide AC power at either 50 Hz or 60 Hz.
One particular type of solar cell that has been developed for commercial use is a “thin-film” PV cell. In comparison to other types of PV cells, such as crystalline silicon PV cells, thin-film PV cells require less light-absorbing semiconductor material to create a working cell, and thus can reduce processing costs. Thin-film based PV cells also offer reduced cost by employing previously developed deposition techniques for the electrode layers, where similar materials are widely used in the thin-film industries for protective, decorative, and functional coatings. Common examples of low cost commercial thin-film products include water impermeable coatings on polymer-based food packaging, decorative coatings on architectural glass, low emissivity thermal control coatings on residential and commercial glass, and scratch and anti-reflective coatings on eyewear. Adopting or modifying techniques that have been developed in these other fields has allowed a reduction in development costs for PV cell thin-film deposition techniques.
Furthermore, thin-film cells have exhibited efficiencies approaching 20%, which rivals or exceeds the efficiencies of the most efficient crystalline cells. In particular, the semiconductor material copper indium gallium diselenide (CIGS) is stable, has low toxicity, and is truly a thin film, requiring a thickness of less than two microns in a working PV cell. As a result, to date CIGS appears to have demonstrated the greatest potential for high performance, low cost thin-film PV products, and thus for penetrating bulk power generation markets. Other semiconductor variants for thin-film PV technology include copper indium diselenide, copper indium disulfide, copper indium aluminum diselenide, and cadmium telluride.
Some thin-film PV materials may be deposited either on rigid glass substrates, or on flexible substrates. Glass substrates are relatively inexpensive, generally have a coefficient of thermal expansion that is a relatively close match with the CIGS or other absorber layers, and allow for the use of vacuum deposition systems. However, when comparing technology options applicable during the deposition process, rigid substrates suffer from various shortcomings during processing, such as a need for substantial floor space for processing equipment and material storage, expensive and specialized equipment for heating glass uniformly to elevated temperatures at or near the glass annealing temperature, a high potential for substrate fracture with resultant yield loss, and higher heat capacity with resultant higher electricity cost for heating the glass. Furthermore, rigid substrates require increased shipping costs due to the weight and fragile nature of the glass. As a result, the use of glass substrates for the deposition of thin films may not be the best choice for low-cost, large-volume, high-yield, commercial manufacturing of multi-layer functional thin-film materials such as photovoltaics.
In contrast, roll-to-roll processing of thin flexible substrates allows for the use of compact, less expensive vacuum systems, and of non-specialized equipment that already has been developed for other thin film industries. PV cells based on thin flexible substrate materials also exhibit a relatively high tolerance to rapid heating and cooling and to large thermal gradients (resulting in a low likelihood of fracture or failure during processing), require comparatively low shipping costs, and exhibit a greater ease of installation than cells based on rigid substrates. Additional details relating to the composition and manufacture of thin film PV cells of a type suitable for use with the presently disclosed methods and apparatus may be found, for example, in U.S. Pat. Nos. 6,310,281, 6,372,538, and 7,194,197, all to Wendt et al. These patents are hereby incorporated into the present disclosure by reference for all purposes.
As noted previously, a significant number of PV cells often are connected in series to achieve a usable voltage, and thus a desired power output. Such a configuration is often called a “string” of PV cells. Due to the different properties of crystalline substrates and flexible thin film substrates, the electrical series connection between cells may be constructed differently for a thin film cell than for a crystalline cell, and forming reliable series connections between thin film cells poses several challenges. For example, soldering (the traditional technique used to connect crystalline solar cells) directly on thin film cells exposes the PV coatings of the cells to damaging temperatures, and the organic-based silver inks typically used to form a collection grid on thin film cells may not allow strong adherence by ordinary solder materials in any case. Thus, PV cells often are joined with wires or conductive tabs attached to the cells with an electrically conductive adhesive (ECA), rather than by soldering.
However, even when wires or tabs are used to form inter-cell connections, the extremely thin coatings and potential flaking along cut PV cell edges introduces opportunities for shorting (power loss) wherever a wire or tab crosses over a cell edge. Furthermore, the conductive substrate on which the PV coatings are deposited, which typically is a metal foil, may be easily deformed by thermo-mechanical stress from attached wires and tabs. This stress can be transferred to weakly-adhering interfaces, which can result in delamination of the cells. In addition, adhesion between the ECA and the cell back side, or between the ECA and the conductive grid on the front side, can be weak, and mechanical stress may cause separation of the wires or tabs at these locations. Also, corrosion can occur between the molybdenum or other coating on the back side of a cell and the ECA that joins the tab to the solar cell there. This corrosion may result in a high-resistance contact or adhesion failure, leading to power losses.
Advanced methods of joining thin film PV cells with conductive tabs or ribbons may largely overcome the problems of electrical shorting and delamination, but may require undesirably high production costs to do so. Furthermore, all such methods—no matter how robust—require that at least some portion of the PV string be covered by a conductive tab, which blocks solar radiation from striking that portion of the string and thus reduces the efficiency of the system. As a result, there is a need for improved methods of interconnecting PV cells into strings, and for improved strings of interconnected cells. Specifically, there is a need for strings and methods of their formation that reduce interconnection costs and reduce the fraction of each PV cell that is covered by the interconnection mechanism, while maintaining or improving the ability of the cell to withstand stress.
SUMMARYA photovoltaic module includes multiple photovoltaic cells connected in series between protective outer layers. A first conductive grid is attached to a first substantially transparent substrate. A second conductive grid is attached to a second substrate. A plurality of thin film photovoltaic cells are disposed between the first and second substrates with a photoactive side of each cell facing the first substrate. The first and second conductive grids are configured to interconnect the negative side of one cell to the positive side of an adjacent cell in a flexible laminated package formed by the first and second substrates. Methods of producing photovoltaic modules are also provided including preparation of first and second flexible substrates, by applying conductive grid patterns over an adhesive layer on each substrate. Photovoltaic cells are then placed on the grid on the first substrate. Next the second substrate is laminated with the first substrate, sandwiching the cells between, and establishing electrical interconnection between the cells by connecting the grid of the first substrate with the grid on the second substrate. Numerous related intermediate articles of manufacture and sub-methods and processes are also disclosed.
Substrate 102 may be a transparent polymer that allows solar radiation to pass through the substrate to a significant degree, and that is conducive to a roll-to-roll manufacturing process. For example, suitable substrates may be constructed from polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyetheretherketone (PEEK), polyimide, or ethylene tetrafluoroethylene (ETFE), among others. Alternative transparent materials, such as glass substrates, also may be used.
Adhesive layer 104 may be applied to substrate 102 as a thin, substantially transparent coating configured to have relatively strong adhesion to the substrate and also to the other components of the module. Suitable adhesives may include, for example, ethylene vinyl acetate (EVA), polyolefins, ionomers, polyvinyl butyral (PVB), and various urethanes, among others.
Conductive grid 106 is applied to the adhesive-coated substrate by any suitable method, such as printing, and typically will be constructed primarily from a conductive metal such as silver or copper. Grid 106 need not be continuous throughout the surface of substrate 102. A lack of continuity may result in improved bonding and electrical contact during subsequent assembly steps, as described below.
Dielectric strip 108 is preferably substantially transparent to increase the amount of the surface area of the cell which is exposed to the sun through upper module portion 100, and is applied in a configuration, for example as depicted in
Substrate 152 of lower module portion 150 may be similar or identical in its characteristics to substrate 102 of upper module portion 100, and this similarity may help to minimize stresses (such as thermal stress) on the assembled module. Alternatively, or in addition to including a polymer layer, substrate 152 may incorporate a vapor barrier. For reasons that will become apparent below, the bottom interconnection substrate need not be transparent. Accordingly, substrate 152 may be constructed partially or entirely from a non-transparent material such as a polyvinyl fluoride (PVF), polycarbonate, printed circuit board, aluminum foil, or some other metallic foil. In some cases, substrate 152 may include both a metallic foil and a polymer, combined to form a multi-layer laminated structure.
Adhesive layer 154 may be formed from the same adhesive as adhesive layer 104, or layer 154 may be formed from an alternative non-transparent (or less transparent) adhesive with other beneficial properties such as increased vapor resistance relative to the adhesive used in layer 104. Conductive grid 156 will typically be similar to grid 106, except grid 156 also includes conductive bus bars 158. As will be described below, bus bars 158 form electrical connections between adjacent photovoltaic cells in an assembled module.
Each of cells 120 is attached to the upper module portion 100 with its photoactive side (anode or “sunny side”) facing conductive grid 106, and is held in place by adhesive layer 104 to minimize movement between cell 120 and substrate 102 during subsequent processing steps and in the final product configuration. In some cases, heat may be applied to further bond each cell 120 to adhesive layer 104. In addition, as
At step 302, a conductive collection grid is applied to a first substrate coated with an adhesive on one side. The collection grid is applied on the same side as the adhesive. The conductive grid need not be continuous across the entire substrate. A lack of continuity of the grid may result in improved bonding and electrical contact during a subsequent lamination step. At step 304, a transparent dielectric strip is applied to the first substrate at selective locations as shown, for example, at 108 in
At step 306, a second conductive collection grid is applied to a second substrate coated with an adhesive on one side. As in the case of step 302, the collection grid of step 306 is applied on the same side as the adhesive, and need not be continuous across the entire substrate. The grid applied in this step includes relatively thicker bus bars as depicted, for example, at 158 in
At step 308, photovoltaic cells are placed along the adhesive-coated side of the first substrate, with the photoactive or “sunny” side of each cell facing the conductive collection grid. The cells are positioned so that the long edge of each cell is overlapped by the dielectric that was applied in step 304, to help prevent the cells from short circuiting. Pressure and/or heat may be applied to help form a secure bond between the cells and the substrate.
At step 310, conductive ribbons are positioned to make electrical contact with particular cells, to form strings of a desired length (i.e., a desired number of interconnected cells). One of the ribbons is placed to make electrical contact with a cell through the conductive grid of the first substrate, and the other ribbon is placed so that it will make electrical contact with another cell through the conductive grid of the second substrate after the second substrate is attached to the first substrate in a subsequent step. Thus, the potential difference between the two ribbons will be equal to the voltage generated by the string of photovoltaic cells bounded by the cells to which the ribbons are attached.
At step 312, the second substrate is aligned with and then attached to the first substrate, with the conductive grid of the second substrate facing the back side (the side opposite from the “sunny” side) of the photovoltaic cells. More specifically, the second substrate is aligned with the first substrate so that the free ends of the conductive grid on the first substrate overlap the thick bus bars of the conductive grid on the second substrate. At step 314, the entire interconnected structure may be laminated to fix the components in place and protect them from the elements.
The method described above and shown in
The method described above and shown in
In the embodiment described above, the grid patterns are substantially identical on the front and back sheets, which provides symmetry and simplicity in the manufacturing process. However, it should be appreciated that distinguishable grid patterns on the front and back sheets may be advantageous. For example, the front grid pattern should be optimal for permitting sun to reach the photovoltaic cell and for collecting and transmitting current from the top side of the cell. On the other side there is no need to permit light to reach the backside of the cell. Therefore, the back grid pattern may use thicker more expansive conductive lines to cut down on resistance. The conductive arms may still be identical on the two substrates for overlapping and interconnecting adjacent cells.
The various structural members disclosed herein may be constructed from any suitable material, or combination of materials, such as metal, plastic, nylon, rubber, or any other materials with appropriate conductivity characteristics, and sufficient structural strength to withstand the loads incurred during typical use. Materials may be selected based on their conductivity, durability, flexibility, weight, and/or aesthetic qualities.
It is believed that the following claims particularly point out certain combinations and subcombinations that are directed to one of the disclosed inventions and are novel and non-obvious. Inventions embodied in other combinations and subcombinations of features, functions, elements and/or properties may be claimed through amendment of the present claims or presentation of new claims in this or a related application. Such amended or new claims, whether they are directed to a different invention or directed to the same invention, whether different, broader, narrower or equal in scope to the original claims, are also regarded as included within the subject matter of the inventions of the present disclosure.
Claims
1. A photovoltaic module comprising
- a first flexible dielectric sheet having an inner side, and a first conductive grid on the inner side,
- a second flexible dielectric sheet having an inner side and a second conductive grid on the inner side of the second flexible dielectric sheet,
- an adhesive layer between the first and second flexible dielectric sheets, and
- a series of thin film flexible photovoltaic cells sandwiched between the first and second dielectric sheets, wherein the first and second conductive grids overlap near an edge of one of the cells providing electrical interconnection between a top side of one cell and a bottom side of an adjacent cell.
2. The photovoltaic module of claim 1, wherein each sheet has an adhesive layer between the inner side and the conductive grid.
3. The photovoltaic module of claim 1, wherein the conductive grids overlap in a gap between adjacent cells.
4. The photovoltaic module of claim 1, wherein first and second sheets are laminated into a flexible flat package having a side edge, the conductive grids overlapping near the side edge of the package.
5. The photovoltaic module of claim 1, wherein the second dielectric sheet has an outer side provided with a mechanism for attaching the module to a surface of a building.
6. The photovoltaic module of claim 5, wherein the mechanism includes an adhesive.
7. The photovoltaic module of claim 1, wherein each of the first and second sheets is made of one or more of the following materials: polyethylene terephthalate, polyethylene naphthalate, polyetheretherketone, polyimide, and ethylene tetrafluoroethylene.
8. An interconnected photovoltaic module, comprising:
- a first conductive grid attached to a first substantially transparent substrate;
- a second conductive grid attached to a second substrate; and
- a plurality of thin film photovoltaic cells disposed between the first and second substrates with a photoactive side of each cell facing the first substrate;
- wherein the first and second conductive grids are configured to make electrical contact with each other in regions between adjacent photovoltaic cells and thereby to connect the adjacent photovoltaic cells in electrical series.
9. The photovoltaic module of claim 8, further comprising a first substantially transparent layer of adhesive applied to the first substrate, and a second layer of adhesive applied to the second substrate.
10. The photovoltaic module of claim 8, further comprising dielectric strips disposed between the first and second substrates and configured to prevent electrical short circuits between opposite polarities of each cell.
11. The photovoltaic module of claim 10, wherein the dielectric strips are constructed from a substantially transparent dielectric material.
12. The photovoltaic module of claim 8, wherein the second substrate includes a vapor barrier.
13. The photovoltaic module of claim 8, further comprising a protective lamination layer enclosing the first and second substrates and the photovoltaic cells.
14. A photovoltaic module comprising
- a first flexible dielectric substrate having a long axis and a width axis, and a series of conductive grid patterns arranged in series along the long axis of the substrate, each grid pattern having a central region including multiple parallel strips of conductive material, and at least one projecting arm region of conductive material connected to the central region,
- first and second thin film flexible photovoltaic cells positioned on the first flexible substrate each cell being substantially registered on the central region of one of the grid patterns, each cell having an upper anode surface and a lower cathode surface, and
- a second flexible dielectric substrate having a long axis and a width axis, and a series of conductive grid patterns arranged in series along the long axis of the substrate, each grid pattern having a central region including multiple parallel strips of conductive material, and at least one projecting arm region of conductive material connected to the central region, wherein the first and second substrates are laminated together on opposite sides of the photovoltaic cells, with corresponding arm regions from the two substrates overlapping and projecting in opposite directions to establish in series electrical interconnection between the first and second photovoltaic cells.
15. The photovoltaic module of claim 14, wherein each grid pattern has at least two projecting arm regions on opposite sides of the respective central region of the grid pattern.
16. The photovoltaic module of claim 14, wherein each photovoltaic cell has a pair of side edges parallel to the long axis of the substrates, further comprising dielectric strips overlapping the edges of the photovoltaic cells.
17. The photovoltaic module of claim 14, wherein each substrate had a layer of adhesive for bonding the substrates together.
18. The photovoltaic module of claim 14, wherein at least one of the substrates has a layer of adhesive for bonding the substrates together.
19. The photovoltaic module of claim 14, wherein arm regions have holes for increasing surface area bonding of the two substrates together.
20. The photovoltaic module of claim 14, wherein the first and second substrates are identical except one is inverted relative to the other in the final sandwich configuration.
21. The photovoltaic module of claim 14, further comprising positive and negative terminals at opposite ends of the module.
22. The photovoltaic module of claim 14, wherein each photovoltaic cell includes a CIGS layer.
23. A photovoltaic module comprising
- a first flexible dielectric sheet having a top side adhesive layer, and a first conductive grid on the top side adhesive layer,
- a second flexible dielectric sheet having a bottom side adhesive layer, and a second conductive grid on the bottom side adhesive layer, and
- a series of thin film flexible photovoltaic cells sandwiched between the first and second dielectric sheets, wherein the first and second conductive grids overlap near an edge of one of the cells providing electrical interconnection between a top side of one cell and a bottom side of an adjacent cell.
24. The photovoltaic module of claim 23, wherein the top and bottom side adhesive layers are heat activated.
25. The photovoltaic module of claim 24, wherein the adhesive layers comprise ionomer.
26. The photovoltaic module of claim 23, wherein the adhesive layers include one or more of the following: ethylene vinyl acetate, polyolefins, ionomers, polyvinyl butyral, and urethane.
27. The photovoltaic module of claim 23, wherein the conductive grids overlap near a gap between two adjacent cells.
28. The photovoltaic module of claim 23, wherein the conductive grids overlap near side edges of the first and second dielectric sheets.
29. The photovoltaic module of claim 23, wherein the first dielectric sheet is substantially transparent.
30. The photovoltaic module of claim 23, wherein each conductive grid is discontinuous.
31. The photovoltaic module of claim 23, wherein the conductive grids are identical, with one grid being inverted relative to the other.
32. The photovoltaic module of claim 23, further comprising
- a dielectric strip on said edge of one of the cells.
Type: Application
Filed: Dec 28, 2010
Publication Date: Jan 5, 2012
Applicant: GLOBAL SOLAR ENERGY, INC. (Tucson, AZ)
Inventors: Scott Wiedeman (Tucson, AZ), Jeffrey S. Britt (Tucson, AZ)
Application Number: 12/980,151
International Classification: H01L 31/048 (20060101); H01L 31/0264 (20060101); H01L 31/05 (20060101);