METHOD FOR PRODUCING OPTICAL FIBER PREFORM

Abstract

A method for producing an optical fiber preform according to the present invention includes an etching step of heating a silica-based glass tube using a heat source continuously traversed in the longitudinal direction of the glass tube to etch the inner surface portion of the glass tube containing impurities while an etching gas is allowed to flow into the glass tube. The glass tube has a maximum alkali metal concentration of 500 to 20,000 atomic ppm, a maximum chlorine concentration of 0 to 1000 atomic ppm, and a maximum fluorine concentration of 0 to 10,000 atomic ppm. In the etching step, the maximum temperature of the outer surface of the glass tube is in the range of 1900° C. to 2250° C., and the heating time is set to a time equal to or less than a time (min) given by ( 7 - alkai   metal   concentration   ppm 5000 ) .

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a method for producing an optical fiber preform.

2. Description of the Related Art

Japanese Unexamined Patent Application Publication (Translation of PCT Application) Nos. 2007-504080 and 2009-541796 and U.S. Patent Application Publication No. 2005/0144986 describe optical fibers composed of silica-based glass, each of the optical fibers including an alkali metal-doped core region. The doping of a core part of an optical fiber preform with the alkali metal in a concentration of several hundreds to several millions of atomic parts per million reduces the viscosity of the core part during the drawing of the optical fiber preform. This allows the relaxation of the network structure of the silica glass to proceed, thereby reducing the Rayleigh scattering loss of an optical fiber produced by drawing the preform.

As a method for doping a silica glass with an alkali metal, a diffusion method is known. In the diffusion method, a glass pipe composed of the silica-based glass is heated to 1500° C. to 2000° C. with an external heat source or a plasma is generated in the glass pipe while the vapor of an alkali metal or alkali metal salt (e.g., KBr or KI), which serves as a raw material, is fed into the glass pipe together with oxygen. Thereby, the inner surface of the glass pipe is doped with the alkali metal element by diffusion.

After the glass pipe is doped with the alkali metal element, the diameter of the resulting glass pipe is reduced. After the reduction in diameter, the inner surface of the glass pipe is etched to remove transition metals, such as Ni and Fe, which are contaminants incorporated during the doping of the glass pipe with the alkali metal element. After the etching, the glass pipe is collapsed to form an alkali metal-doped core rod. A cladding part is formed on the outside of the alkali metal-doped core rod to produce an optical fiber preform. The optical fiber preform is drawn to produce an optical fiber.

For an alkali metal-containing silica glass, the glass transition temperature is as low as 1000° C. to 1400° C., and the rate of crystallization is high. Thus, in the production of an optical fiber preform, in the steps of heating and cooling an alkali metal doped-glass, the glass is likely to crystallize, disadvantageously reducing the yield of a satisfactory optical fiber preform. In the case where a high-purity silica glass article is formed by a vapor-phase method, in a step of drying a silica glass soot article with chlorine gas, the silica glass article is contaminated with chlorine. The reaction of chlorine and an alkali metal in the silica glass forms an alkali chloride. The alkali chloride is not included in the network of the silica glass. Thus, the alkali chloride causes voids or serves as crystallization nuclei in the production process of an optical fiber preform.

The presence of voids and crystallization nuclei in an optical fiber preform (in particular, a core part) causes an increase in the attenuation of an optical fiber produced by drawing the optical fiber preform. In particular, in an etching step of etching the inner surface of the silica glass tube, the silica glass tube is heated with a high concentration of an alkali oxide exposed at the inner surface of the silica glass tube, so that voids and crystals are likely to be formed. An optical fiber produced by drawing such an optical fiber preform including a core part having voids and crystals has high attenuation.

SUMMARY OF THE INVENTION

Accordingly, it is an object of the present invention to provide a method for producing an optical fiber preform suitably used for the production of an optical fiber having low attenuation.

According to a first aspect of the present invention, a method for producing an optical fiber preform that includes a core part and a cladding part, the optical fiber preform being composed of a silica-based glass, includes an etching step of heating a silica-based glass tube having the inner surface doped with an alkali metal element using a heat source continuously traversed in the longitudinal direction of the glass tube to etch the inner surface portion by 5% or more of the thickness of a region where the alkali metal element is diffused while an etching gas is allowed to flow into the glass tube, and after the etching step, a collapse step of collapsing the glass tube by heating the glass tube with a heat source continuously traversed in the longitudinal direction of the glass tube to form a first glass rod to be formed into a core part or part of a core part of an optical fiber, in which the glass tube has a maximum alkali metal concentration of 500 to 20,000 atomic ppm, a maximum chlorine concentration of 0 to 1000 atomic ppm, and a maximum fluorine concentration of 0 to 10,000 atomic ppm, and in which in the etching step, the maximum temperature of the outer surface of the glass tube is in the range of 1900° C. to 2250° C., and the heating time is set to a time equal to or less than a time (min) given by

$\left(7-\frac{\mathrm{alkai}\mathrm{metal}\mathrm{concentration}\mathrm{ppm}}{5000}\right).$

According to a second aspect of the present invention, a method for producing an optical fiber preform that includes a core part and a cladding part, the optical fiber preform being composed of a silica-based glass, includes an etching step of heating a silica-based glass tube having the inner surface doped with an alkali metal element using a heat source continuously traversed in the longitudinal direction of the glass tube to etch the inner surface portion by 5% or more of the thickness of a region where the alkali metal element is diffused while an etching gas is allowed to flow into the glass tube, and after the etching step, a collapse step of collapsing the glass tube by heating the glass tube with a heat source continuously traversed in the longitudinal direction of the glass tube to form a first glass rod to be formed into a core part or part of a core part of an optical fiber, in which the glass tube has a maximum alkali metal concentration of 500 to 20,000 atomic ppm, a maximum chlorine concentration of 0 to 1000 atomic ppm, and a maximum fluorine concentration of 0 to 10,000 atomic ppm, and in which in the etching step, the maximum temperature of the outer surface of the glass tube is in the range of 1900° C. to 2250° C., and the traverse speed of the heat source is in the range of 50 mm/min to 100 mm/min.

In the method for producing an optical fiber preform according to any one of the aspects of the present invention, in the etching step, the inner surface portion of the glass tube is preferably etched by 5% to 25% of the thickness of the region where the alkali metal element is diffused. In the method for producing an optical fiber preform according to any one of the aspects of the present invention, in the etching step, a pressure inside the glass tube is preferably 0.1 to 1 kPa higher than a pressure outside the glass tube. In the method for producing an optical fiber preform according to any one of the aspects of the present invention, the maximum value of the relative refractive index difference of the first glass rod is preferably in the range of −0.1% to +0.1%, and the method may further include a cladding part formation step of forming an optical cladding part or part of an optical cladding part around the perimeter of the first glass rod, in which the minimum value of the relative refractive index difference of the optical cladding part is preferably in the range of −0.2% to −0.5%. In this specification, the term “relative refractive index difference” indicates a value with respect to the refractive index of pure silica glass, unless otherwise specified, i.e.,

$\frac{{\Delta }_{\mathrm{object}}-{\Delta }_{\mathrm{pure}\mathrm{silica}}}{{\Delta }_{\mathrm{pure}\mathrm{silica}}}.$

Preferably, the method for producing an optical fiber preform according to any one of the aspects of the present invention further includes a core part diameter extension step of arranging a silica glass having a chlorine concentration of 1000 atomic ppm to 15,000 atomic ppm around the perimeter of the first glass rod formed in the collapse step to form a second glass rod to be formed into a core part or part of a core part of an optical fiber. In this case, the maximum value of the relative refractive index difference of the second glass rod is preferably in the range of −0.1% to +0.1%, and the method may further include a cladding part formation step of forming an optical cladding part or part of an optical cladding part around the perimeter of the second glass rod, in which the minimum value of the relative refractive index difference of the optical cladding part is preferably in the range of −0.2% to −0.5%.

According to the present invention, it is possible to produce an optical fiber preform suitably used for the production of an optical fiber having low attenuation.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a flowchart of a method for producing an optical fiber preform according to an embodiment of the present invention.

FIGS. 2A to 2D are conceptual drawings illustrating alkali metal addition step S1 in the flowchart in FIG. 1.

FIG. 3 is a graph illustrating the presence or absence of the occurrence of crystallization as a function of the maximum temperature in a heated portion in an etching step and the potassium concentration.

FIG. 4 is a conceptual drawing illustrating the presence or absence of the occurrence of crystallization as a function of the heating time in the etching step and the potassium concentration.

FIG. 5 is a graph illustrating the presence or absence of the occurrence of crystallization as a function of the traverse speed in the etching step and the potassium concentration.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Embodiments of the present invention will be described below with reference to the attached drawings. The embodiments are provided solely for purposes of illustration and are not intended to be limitative. In the drawings, the same elements are designated using the same reference numerals, and descriptions are not redundantly repeated. The ratios of dimensions in the drawings are not always accurate.

FIG. 1 illustrates a flowchart of a method for producing an optical fiber preform according to an embodiment of the present invention. The method for producing an optical fiber preform according to this embodiment includes alkali metal addition step S1, diameter reduction step S2, etching step S3, collapse step S4, elongation step S5, first perimeter grinding step S6, core part diameter extension step S7, second perimeter grinding step S8, cladding part formation step S9, and jacket formation step S10. These steps are sequentially performed to produce an optical fiber preform including a core part and a cladding part and being composed of a silica-based glass.

FIGS. 2A to 2D illustrate alkali metal addition step S1 in the flowchart in FIG. 1. In alkali metal addition step S1, the inner surface of a glass tube 10 composed of a silica-based glass (hereinafter, referred to as a “silica glass tube 10”) is doped with an alkali metal. As the alkali metal added, potassium is preferably used. Sodium, rubidium, and cesium may also be used. The silica glass tube 10 has a maximum chlorine concentration of 0 to 1000 atomic ppm and a maximum fluorine concentration of 0 to 10,000 atomic ppm. The concentrations of contaminants other than chlorine and fluorine, for example, transition metals and OH groups, are sufficiently low and are preferably, for example, 10 mol ppb or less. For example, the concentration of chlorine is 200 atomic ppm. The maximum concentration of fluorine is 4000 atomic ppm. The outside diameter is 25 mm. The inside diameter is 10 mm.

As illustrated in FIG. 2A, a supporting pipe 20 to be connected to an end of the silica glass tube 10 has a source-material supply portion with a reduced inside diameter. A KBr source 30 is placed in the source-material supply portion. As illustrated in FIG. 2B, the silica glass tube 10 is connected to the supporting pipe 20. The resulting article is mounted on a lathe.

Dry N₂ gas fed from a gas supply unit (not illustrated) is allowed to flow from the supporting pipe 20 to the silica glass tube 10 to dry the KBr source 30 placed in the source-material supply portion while the source-material supply portion of the supporting pipe 20 is heated to 600° C. for 30 minutes with an electric furnace 40. Then, as illustrated in FIG. 2C, SF₆ gas is allowed to flow from the supporting pipe 20 to the silica glass tube 10 to etch a predetermined thickness of the inner surface of the silica glass tube 10, thereby removing impurities attached to the inner surface of the silica glass tube 10.

As illustrated in FIG. 2D, O₂ gas fed from a gas supply unit (not illustrated) is allowed to flow from the supporting pipe 20 to the silica glass tube 10 while the source-material supply portion of the supporting pipe 20 is heated to 780° C. with the electric furnace 40, so that KBr vapor generated from the KBr source 30 placed in the source-material supply portion is allowed to flow into the silica glass tube 10 together with the O₂ gas. The silica glass tube 10 is heated from the outside thereof with a heat source, such as an oxyhydrogen burner 50, in such a manner that the maximum outer surface temperature is in the range of 2000° C. to 2250° C. Consequently, the silica glass tube 10 is doped with potassium flowing therethrough by diffusion. After the alkali metal addition step S1, the silica glass tube 10 has a maximum potassium concentration of 500 to 20,000 atomic ppm.

In diameter reduction step S2, after the supply of KBr vapor by heating the source-material supply portion, heating is continued with the oxyhydrogen burner 50 to reduce the diameter of the glass tube until the inside diameter of the glass tube reaches about 3 mm.

In etching step S3, the glass tube is heated to the maximum temperature of 1900° C. to 2250° C. with the oxyhydrogen burner continuously traversed at a speed of 50 mm/min to 100 mm/min while SF₆ and O₂ are allowed to flow into the glass tube having a reduced inside diameter at a flow rate of 100 sccm (100 cc/min in terms of standard conditions) and 100 sccm, respectively. Preferably, SF₆ is used as an etching gas. Other examples of the etching gas that may be used include CF₄, NF₃, and C₂F₆. Thereby, the inner surface of the glass tube is etched by a thickness of about 400 to about 800 μm to remove a layer containing impurities, such as transition metals and OH groups, incorporated during the step of diffusing potassium, the layer having a high impurity concentration (e.g., 10 mol ppb or more).

The etching step is performed under the conditions, thus inhibiting the occurrence of the crystallization during the etching step. A maximum alkali metal concentration of 500 atomic ppm or more results in a reduction in the viscosity of the core, thereby reducing the scattering loss. A maximum alkali metal concentration of 20,000 atomic ppm or more results in a very high crystallization rate, thus causing difficulty in inhibiting the occurrence of the crystallization during the etching step.

A high chlorine concentration in the silica glass leads to the formation of KCl in the silica glass. KCl serves as a nucleus to cause the crystallization of the silica glass to proceed. Thus, the maximum chlorine concentration is preferably 1000 atomic ppm or less. A high fluorine concentration leads to the scattering loss due to fluorine and leads to a reduction in the refractive index of the core, causing difficulty in forming a waveguide structure. Thus, the maximum fluorine concentration is preferably in the range of 0 to 10,000 atomic ppm.

With respect to the heat source, an oxyhydrogen burner may be used. Dry heat sources, such as electric furnaces and thermal plasmas, are preferably used. The heating temperature is preferably 1900° C. or higher to inhibit the formation of crystals. However, it is difficult to increase the glass temperature to 2250° C. or higher. At a potassium concentration of 500 ppm to 20,000 ppm, the heating time (time obtained by dividing the length of a portion heated to 800° C. or higher with a stopped burner by the traverse speed of the burner) is set to a time shorter than a time (min) given by

$\left(7-\frac{\mathrm{alkai}\mathrm{metal}\mathrm{concentration}\mathrm{ppm}}{5000}\right).$

thereby inhibiting the crystallization. At a potassium concentration of 25,000 ppm, the rate of crystallization is high. The crystallization occurs even at a short heating time of 1.5 minutes. Even if the heating time is set to less than 1.5 minutes, it is difficult to inhibit the crystallization because the temperature of the glass tube does not reach 1900° C. or higher. A traverse speed of the heat source of 50 mm/min or more also results in the inhibition of the crystallization. If the traverse speed is very high, the glass tube is not sufficiently heated, thus failing to be etched. Consequently, the traverse speed is preferably 100 mm/min or less.

In etching step S3, the inner surface of the glass tube is preferably etched by 5% to 25% of the thickness of a region where the alkali metal element is diffused. Transition metals (e.g., Fe, Ni, and Co) contained in the source material or the carrier gas are diffused into the glass simultaneously with the diffusion of the alkali metal. The diffusion velocities of transition metals are lower than those of alkali metals. Thus, removal of 5% or more of the thickness of the alkali metal-doped region by etching permits an increase in attenuation due to impurities to be reduced to 0.001 dB/km or less at a wavelength of 1.55 with potassium remaining. In the case where a thickness to be removed by the etching is as large as 25% or more, the alkali metal addition step is uneconomical, thus increasing the production cost of an optical fiber.

In etching step S3, the pressure inside the glass tube is preferably set to a pressure 0.1 to 1 kPa higher than the pressure outside the glass tube. In this case, the glass tube can be etched at a high temperature without being collapsed.

In collapse step S4, the surface of the glass tube is heated to 2000° C. to 2250° C. with a heat source, such as a flame from an oxyhydrogen burner, continuously traversed in the longitudinal direction of the glass tube at a traverse speed of 30 mm/min to 100 mm/min while a pressure inside the glass tube is set to a pressure at least 90 kPa lower than a pressure outside the glass tube, thereby collapsing the glass tube to form a transparent glass rod (first glass rod) composed of a silica-based glass. In collapse step S4, a large difference in pressure between the inside and outside of the glass tube makes it possible to efficiently increase the speed of the traverse, which is preferred.

In elongation step S5, the glass rod formed in the collapse step S4 is elongated while the glass rod is heated with a heat source, such as an oxyhydrogen burner, in such a manner that the outside diameter is 11 mm. In first perimeter grinding step S6, the perimeter of the glass rod is ground in such a manner that the outside diameter is 6 mm. This removes a silica glass layer where OH groups are diffused by heating with the oxyhydrogen burner. This also allows the glass rod to have a substantially perfect circular cross section. The term “substantially perfect circular cross section” indicates that the cross section has a non-circularity of 0.4% or less (the non-circularity indicating a value obtained by dividing a difference in length between the major axis and the minor axis by the length of the major axis when the perimeter of the glass rod is approximated as an ellipse).

It is known that in the case where a glass tube is collapsed at a large different in pressure between the inside and outside of the glass tube, the resulting glass rod has an elliptic cross section. In this case, a region doped with an alkali metal also has an elliptic cross section. After the outside of the glass rod is ground in such a manner that the glass rod has a substantially perfect circular cross section, when an optical fiber preform including the glass rod serving as a core part or serving partially as a core part is produced and drawn by a known method, the polarization mode dispersion of the resulting optical fiber is not degraded. The reason for this is as follows: An alkali metal has a high diffusion coefficient (1×10⁻⁶ cm²/s) at 1500° C. Thus, the alkali metal is diffused in a portion by heating during the drawing, the portion having a volume several to several tens of times that of the region doped with the alkali metal. Consequently, the alkali metal is distributed in a region having a diameter several times the mode field diameter of the optical fiber. Note that before the first perimeter grinding step, the step of elongating the silica glass rod may not be provided.

In core part diameter extension step S7, a silica glass having a chlorine concentration of 1000 atomic ppm to 15,000 atomic ppm is arranged around the glass rod whose perimeter has been ground in first perimeter grinding step S6, thereby forming a glass rod having an extended portion (second glass rod). The silica glass will be formed into a core part or part of a core part of an optical fiber.

In core part diameter extension step S7, the increase in the diameter of the core part provides a large-sized optical fiber preform, thus reducing the production cost of the optical fiber preform and the optical fiber. A central portion derived from the glass rod formed in the collapse step before the diameter extension has a small diameter in a fiber state, so that the proportion of light propagating the central portion is low. This reduces the influence of transition metals and OH groups, which can be incorporated together with the addition of an alkali oxide, on attenuation, thereby reducing the attenuation. The ratio of the perimeter of the glass rod after the diameter extension to the perimeter of the glass rod before the diameter extension is preferably in the range of 2 to 10.

In second perimeter grinding step S8, the perimeter of the glass rod having the extended portion formed in core part diameter extension step S7 is ground in such a manner that the glass rod has a substantially perfect circular cross section. Note that core part diameter extension step S7 and second perimeter grinding step S8 may not be performed.

In cladding part formation step S9, an optical cladding part is formed around the perimeter of the resulting glass rod. The maximum refractive index of the glass rod is higher than the minimum refractive index of the optical cladding part. In particular, preferably, the glass rod to be formed into a core or part of a core of an optical fiber contains the alkali metal, chlorine, and fluorine, the concentration of other contaminants being 10 ppb or less. In this case, the maximum value of the relative refractive index difference of the glass rod is preferably in the range of −0.1% to +0.1%. The optical cladding part is preferably composed of a fluorine-doped silica glass. In the case where the fluorine concentration is as high as 45,000 atomic ppm or more and where the relative refractive index difference is −0.5% or less, the attenuation is increased. Thus, the minimum value of the relative refractive index difference of the optical cladding part is preferably in the range of −0.2% to −0.5%.

The formation of the optical cladding part provides an optical fiber preform through which a low loss optical fiber can be made. The relative refractive index difference between the maximum value in the core part and the minimum value in the optical cladding is preferably in the range of 0.2% to 0.6%. A silica glass to be formed into a physical cladding part may be arranged outside the optical cladding part.

In jacket formation step S10, a jacket part to be formed into a physical cladding part is formed by a known method, for example, the VAD method, the OVD method, or the rod-in-tube method, thereby providing an optical fiber preform. Drawing the optical fiber preform produces an optical fiber.

The optical fiber produced as described above has low attenuation. That is, it is possible to produce an optical fiber preform by the method for producing an optical fiber preform according to an embodiment of the present invention, the optical fiber preform being suitable for the production of an optical fiber having low attenuation.

In a drawing step, the alkali metal is diffused into the optical cladding part, thus reducing the viscosities of the core part and the optical cladding part compared with the jacket part. As a result, compressive strain remains in the core part and the optical cladding part of the resulting optical fiber. If tensile strain remains in the core part of an optical fiber, density fluctuations in the SiO₂ network structure of the glass are increased, thus disadvantageously increasing the attenuation. In the optical fiber according to the present invention, the compressive strain remains in the core part, eliminating an increase in attenuation. It is thus possible to provide the optical fiber having low attenuation.

The fictive temperature of the core part of the optical fiber may be set to 1500° C. or lower. The fictive temperature is determined by Raman spectroscopy and indicates a temperature of a supercooled state which has the same structure as the glass. A lower fictive temperature results in the relaxation of the density fluctuations of the glass, thereby reducing the Rayleigh scattering loss. It is thus possible to provide the optical fiber having low attenuation.

Furthermore, the attenuation of the optical fiber may be set to 0.175 dB/km or less at a wavelength of 1550 nm. The optical fiber having low attenuation is suitable for long distance transmission. The attenuation is preferably 0.170 dB/km or less and more preferably 0.165 dB/km or less at a wavelength of 1550 nm.

FIG. 3 is a graph illustrating the presence or absence of the occurrence of crystallization as a function of the potassium concentration and the maximum temperature in a heated portion when etching is performed at a traverse speed of 100 mm/min. In the etching step, when the maximum temperature of the outer surface of the glass tube is in the range of 1900° C. to 2250° C., the occurrence of the crystallization is inhibited.

FIG. 4 is a conceptual drawing illustrating the presence or absence of the occurrence of crystallization as a function of the heating time in the etching step and the potassium concentration. Symbol “o” denotes uncrystallized and symbol “x” denotes crystallized. The potassium concentrations and the heating times in examples are described in Table. The results demonstrated that at a potassium concentration of 500 ppm to 20,000 ppm, the heating time is set to a time shorter than a time (min) given by

$\left(7-\frac{\mathrm{potassium}\mathrm{concentration}\mathrm{ppm}}{5000}\right),$

thereby inhibiting the crystallization.

TABLE
		Heating	Heating
K concentration	Traverse speed	length	time
(atomic ppm)	(mm/min)	(mm)	(min)	Crystal state
100	20	150	7.5	uncrystallized
100	20	200	10	uncrystallized
100	20	300	15	crystallized
100	30	150	5	uncrystallized
100	30	200	6.7	uncrystallized
100	30	300	10	uncrystallized
100	50	150	3	uncrystallized
100	50	200	4	uncrystallized
100	50	300	6	uncrystallized
100	100	150	1.5	uncrystallized
100	100	200	2	uncrystallized
100	100	300	3	uncrystallized
500	20	150	7.5	crystallized
500	20	200	10	crystallized
500	20	300	15	crystallized
500	30	150	5	uncrystallized
500	30	200	6.7	uncrystallized
500	30	300	10	crystallized
500	50	150	3	uncrystallized
500	50	200	4	uncrystallized
500	50	300	6	uncrystallized
500	100	150	1.5	uncrystallized
500	100	200	2	uncrystallized
500	100	300	3	uncrystallized
1000	20	150	7.5	crystallized
1000	20	200	10	crystallized
1000	20	300	15	crystallized
1000	30	150	5	uncrystallized
1000	30	200	6.7	crystallized
1000	30	300	10	crystallized
1000	50	150	3	uncrystallized
1000	50	200	4	uncrystallized
1000	50	300	6	uncrystallized
1000	100	150	1.5	uncrystallized
1000	100	200	2	uncrystallized
1000	100	300	3	uncrystallized
5000	20	150	7.5	crystallized
5000	20	200	10	crystallized
5000	20	300	15	crystallized
5000	30	150	5	uncrystallized
5000	30	200	6.7	crystallized
5000	30	300	10	crystallized
5000	50	150	3	uncrystallized
5000	50	200	4	uncrystallized
5000	50	300	6	uncrystallized
5000	100	150	1.5	uncrystallized
5000	100	200	2	uncrystallized
5000	100	300	3	uncrystallized
10000	20	150	7.5	crystallized
10000	20	200	10	crystallized
10000	20	300	15	crystallized
10000	30	150	5	crystallized
10000	30	200	6.7	crystallized
10000	30	300	10	crystallized
10000	50	150	3	uncrystallized
10000	50	200	4	uncrystallized
10000	50	300	6	crystallized
10000	100	150	1.5	uncrystallized
10000	100	200	2	uncrystallized
10000	100	300	3	uncrystallized
20000	20	150	7.5	crystallized
20000	20	200	10	crystallized
20000	20	300	15	crystallized
20000	30	150	5	crystallized
20000	30	200	6.7	crystallized
20000	30	300	10	crystallized
20000	50	150	3	uncrystallized
20000	50	200	4	crystallized
20000	50	300	6	crystallized
20000	100	150	1.5	uncrystallized
20000	100	200	2	uncrystallized
20000	100	300	3	uncrystallized
25000	20	150	7.5	crystallized
25000	20	200	10	crystallized
25000	20	300	15	crystallized
25000	30	150	5	crystallized
25000	30	200	6.7	crystallized
25000	30	300	10	crystallized
25000	50	150	3	crystallized
25000	50	200	4	crystallized
25000	50	300	6	crystallized
25000	100	150	1.5	crystallized
25000	100	200	2	crystallized
25000	100	300	3	crystallized

FIG. 5 is a graph illustrating the presence or absence of the occurrence of crystallization as a function of the potassium concentration and the traverse speed when etching is performed at 2250° C. In the etching step, when the traverse speed of the heat source is in the range of 50 mm/min to 100 mm/min, the occurrence of the crystallization is inhibited.

As a comparative example, in the etching step, a glass tube was etched by heating the outer surface with a flame, having a temperature of 1900° C., from an oxyhydrogen burner traversed at a traverse speed of 5 mm/min while SF₆ (100 sccm) and O₂ (100 sccm) were allowed to flow. In this case, the inner surface of the glass tube was whitened. For such a crystallized glass tube, in the subsequent collapse step, the interstitial spaces and so forth of the crystals remain in the form of voids. It is thus difficult to form a void-free glass rod.

Claims

1. A method for producing an optical fiber preform that includes a core part and a cladding part, the optical fiber preform being composed of a silica-based glass, the method comprising: ( 7 - alkai   metal   concentration   ppm 5000 ).

an etching step of heating a silica-based glass tube having the inner surface doped with an alkali metal element using a heat source continuously traversed in the longitudinal direction of the glass tube to etch the inner surface portion by 5% or more of the thickness of a region where the alkali metal element is diffused while an etching gas is allowed to flow into the glass tube; and

after the etching step, a collapse step of collapsing the glass tube by heating the glass tube with a heat source continuously traversed in the longitudinal direction of the glass tube to form a first glass rod to be formed into a core part or part of a core part of an optical fiber,

wherein the glass tube has a maximum alkali metal concentration of 500 to 20,000 atomic ppm, a maximum chlorine concentration of 0 to 1000 atomic ppm, and a maximum fluorine concentration of 0 to 10,000 atomic ppm, and

wherein in the etching step, the maximum temperature of the outer surface of the glass tube is in the range of 1900° C. to 2250° C., and the heating time is set to a time equal to or less than a time (min) given by

2. The method according to claim 1,

wherein in the etching step, the inner surface portion of the glass tube is etched by 5% to 25% of the thickness of the region where the alkali metal element is diffused.

3. The method according to claim 1,

wherein in the etching step, a pressure inside the glass tube is 0.1 to 1 kPa higher than a pressure outside the glass tube.

4. The method according to claim 1,

wherein the maximum value of the relative refractive index difference of the first glass rod is in the range of −0.1% to +0.1%, and the method further comprises:

a cladding part formation step of forming an optical cladding part or part of an optical cladding part around the perimeter of the first glass rod,

wherein the minimum value of the relative refractive index difference of the optical cladding part is in the range of −0.2% to −0.5%.

5. The method according to claim 1, further comprising:

a core part diameter extension step of arranging a silica glass having a chlorine concentration of 1000 atomic ppm to 15,000 atomic ppm around the perimeter of the first glass rod formed in the collapse step to form a second glass rod to be formed into a core part or part of a core part of an optical fiber.

6. The method according to claim 5,

wherein the maximum value of the relative refractive index difference of the second glass rod is in the range of −0.1% to +0.1%, and the method further comprises:

a cladding part formation step of forming an optical cladding part or part of an optical cladding part around the perimeter of the second glass rod,

wherein the minimum value of the relative refractive index difference of the optical cladding part is in the range of −0.2% to −0.5%.

7. A method for producing an optical fiber preform that includes a core part and a cladding part, the optical fiber preform being composed of a silica-based glass, the method comprising:

an etching step of heating a silica-based glass tube having the inner surface doped with an alkali metal element using a heat source continuously traversed in the longitudinal direction of the glass tube to etch the inner surface portion by 5% or more of the thickness of a region where the alkali metal element is diffused while an etching gas is allowed to flow into the glass tube; and

after the etching step, a collapse step of collapsing the glass tube by heating the glass tube with a heat source continuously traversed in the longitudinal direction of the glass tube to form a first glass rod to be formed into a core part or part of a core part of an optical fiber,

wherein the glass tube has a maximum alkali metal concentration of 500 to 20,000 atomic ppm, a maximum chlorine concentration of 0 to 1000 atomic ppm, and a maximum fluorine concentration of 0 to 10,000 atomic ppm, and

wherein in the etching step, the maximum temperature of the outer surface of the glass tube is in the range of 1900° C. to 2250° C., and the traverse speed of the heat source is in the range of 50 mm/min to 100 mm/min.

8. The method according to claim 7,

wherein in the etching step, the inner surface portion of the glass tube is etched by 5% to 25% of the thickness of the region where the alkali metal element is diffused.

9. The method according to claim 7,

wherein in the etching step, a pressure inside the glass tube is 0.1 to 1 kPa higher than a pressure outside the glass tube.

10. The method according to claim 7,

wherein the maximum value of the relative refractive index difference of the first glass rod is in the range of −0.1% to +0.1%, and the method further comprises:

a cladding part formation step of forming an optical cladding part or part of an optical cladding part around the perimeter of the first glass rod,

wherein the minimum value of the relative refractive index difference of the optical cladding part is in the range of −0.2% to −0.5%.

11. The method according to claim 7, further comprising:

a core part diameter extension step of arranging a silica glass having a chlorine concentration of 1000 atomic ppm to 15,000 atomic ppm around the perimeter of the first glass rod formed in the collapse step to form a second glass rod to be formed into a core part or part of a core part of an optical fiber.

12. The method according to claim 11,

wherein the maximum value of the relative refractive index difference of the second glass rod is in the range of −0.1% to +0.1%, and the method further comprises:

a cladding part formation step of forming an optical cladding part or part of an optical cladding part around the perimeter of the second glass rod,

wherein the minimum value of the relative refractive index difference of the optical cladding part is in the range of −0.2% to −0.5%.