HETEROLEPTIC OSMIUM COMPLEX AND METHOD OF MAKING THE SAME

Info

Publication number: 20150028290
Type: Application
Filed: Jul 25, 2013
Publication Date: Jan 29, 2015
Applicant: UNIVERSAL DISPLAY CORPORATION (EWING, NJ)
Inventors: Chuanjun Xia (Lawrenceville, NJ), Jui-Yi Tsai (Newtown, PA), Beatriz Eguillor Armendáriz (Zaragoza), Miguel A. Esteruelas Rodrigo (Zaragoza), Roberto Gómez Alabau (Zaragoza), Montserrat Oliván Esco (Zaragoza), Enrique Oñate Rodriguez (Zaragoza)
Application Number: 13/950,591

Abstract

A method of making an osmium(II) complex having Formula I, L1-Os-L2, wherein L1 and L2 are independently a biscarbene tridentate ligand, wherein L1 and L2 can be same or different is disclosed. The method includes (a) reacting a precursor of ligand L1 with an osmium precursor to form an intermediate product, wherein the osmium precursor having the formula OsHx(PR3)y, wherein x is an integer from 2 to 6 and y is an integer from 2 to 5, and R is selected from the group consisting of aryl, alkyl and cycloalkyl; and (b) reacting a precursor of ligand L2 with said intermediate product.

Description

Description

PARTIES TO A JOINT RESEARCH AGREEMENT

The claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: Regents of the University of Michigan, Princeton University, University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement.

FIELD OF THE INVENTION

The present invention relates to compounds for use as emitters and devices, such as organic light emitting diodes, including the same. More particularly, the compounds disclosed herein are novel heteroleptic bistridentate osmium carbene complexes and a novel synthetic method to make both homoleptic and heteroleptic bistridentate osmium carbene complexes.

BACKGROUND

Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.

OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.

One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Color may be measured using CIE coordinates, which are well known to the art.

One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)₃, which has the following structure:

In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.

As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.

As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.

As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.

More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.

SUMMARY OF THE INVENTION

According to an aspect of the present disclosure, a method of making an osmium(II) complex having Formula I

L¹-Os-L₂, wherein L¹and L²are independently a biscarbene tridentate ligand, wherein L¹and L²can be same or different is disclosed. The method comprises: (a) reacting a precursor of ligand L¹with an osmium precursor to form an intermediate product, wherein the osmium precursor having the formula OsH_x(PR₃)_y, wherein x is an integer from 2 to 6 and y is an integer from 2 to 5, and R is selected from the group consisting of aryl, alkyl and cycloalkyl; and (b) reacting a precursor of ligand L²with said intermediate product.

In one embodiment of the method, L¹and L²are monoanionic ligands. In some embodiments, L¹and L²are independently selected from ligands having Formula II:

wherein Y¹, Y²and Y³comprise C or N; wherein R³and R⁴may represent mono-, or di-substitutions, or no substitution; wherein R⁵may represent mono-, di-, or tri-substitutions, or no substitution; wherein R¹, R², R³, R⁴and R⁵are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any two adjacent substituents of R¹, R², R³, R⁴and R⁵are optionally joined to form a ring; and wherein the dash lines show the connection points to osmium.

According to an embodiment, a compound having the structure according to Formula I as defined herein is disclosed.

According to another aspect of the present disclosure, a first device comprising a first organic light emitting device is disclosed. The first organic light emitting device comprises an anode; a cathode; and an organic layer, disposed between the anode and the cathode. The organic layer can comprise a compound having the structure according Formula I

The novel compounds, heteroleptic bistridentate osmium carbene complexes, and a novel synthetic method to make both homoleptic and heteroleptic bistridentate osmium carbene complexes disclosed herein are useful as emitters in organic light emitting devices. The inventors have discovered that the incorporation of these ligands can narrow the emission spectrum and improve device efficiency.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.

FIG. 3 shows molecular diagram of complex monohydride with X-ray diffraction analysis characterization.

FIG. 4 shows molecular diagram of Complex A with X-ray diffraction analysis characterization.

DETAILED DESCRIPTION

Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.

The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.

More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), which are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.

FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.

More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.

Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.

Devices fabricated in accordance with embodiments of the invention may be incorporated into a wide variety of consumer products, including flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads up displays, fully transparent displays, flexible displays, laser printers, telephones, cell phones, personal digital assistants (PDAs), laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.

The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.

The terms halo, halogen, alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group, aryl, aromatic group, and heteroaryl are known to the art, and are defined in U.S. Pat. No. 7,279,704 at cols. 31-32, which are incorporated herein by reference.

As used herein, “substituted” indicates that a substituent other than H is bonded to the relevant carbon. Thus, where R²is monosubstituted, then one R²must be other than H. Similarly, where R³is disubstituted, then two of R³must be other than H. Similarly, where R²is unsubstituted R²is hydrogen for all available positions.

In the present disclosure, novel heteroleptic bistridentate Os(II) complexes and a novel method for synthesizing both homoleptic and heteroleptic bistridentate Os(II) complexes is provided. Heteroleptic osmium complexes provide great freedom of tuning emission color, electrochemical energy levels, and improving evaporation properties.

Osmium (II) complexes have been investigated for OLED applications. The octahedral ligand arrangement of the Os(II) complexes resembles that of Ir(III) complexes. Os(II) complexes generally exhibit low oxidation potential, i.e. shallow HOMO energy level than Ir(III) complexes. The inventors have discovered that bistridentate Os(II) carbene complexes offer performance advantages for OLED applications. Without being bound to a theory, the inventors believe that the rigid nature of the tridentate ligands are providing narrow emission line widths and short excited state lifetimes, which can result in better color purity and longer device lifetime, making them suitable for display applications.

US2005260449 and WO2009046266 disclosed bistridentate Os(II) complexes. Examples of homoleptic Os(II) complexes were provided. The two tridentate ligands binding to Os(II) metal are identical. It may be beneficial to incorporate two different ligands to Os(II) metal to form a heterlopetic complex. For example, the thermal properties, electrochemical properties, and photophysical properties can be tuned by selecting two proper ligands. It offers more flexibility for materials design than two identical ligands.

The synthesis of homoleptic complexes, however, has been challenging; let alone the heteroleptic complexes. The synthesis method used in WO2009046266 generated very low yield, typically 2-5%. In a later application, US2012215000, the yield was significantly improved to over 30% using a new osmium precursor. In theory, both of these methods should work for synthesis of heteroleptic bistridentate Os(II) complexes by introducing two different ligands at the complexation stage and isolating the desired heteroleptic complex from the reaction mixture. The synthesis will be extremely inefficient and impractical.

The inventors have developed a new stepwise complexation method. This method is suitable for making both homoleptic and heteroleptic bistridentate Os(II) complexes. As shown in the scheme below, an osmium precursor was first reacted with a bistridentate ligand to generate an intermediate that has one tridentate ligand coordinated to the metal. The intermediate was then treated with another tridentate ligand to generate the final complex. Depending on the structure of the second ligand, homoleptic or heteroleptic complexes can be synthesized. In addition, the yield was improved. One example of the inventive synthetic method is shown below:

In describing the novel synthesis method of the inventors, all reactions were carried out with rigorous exclusion of air using Schlenk-tube techniques. Solvents, except DMF and acetonitrile that were dried and distilled under argon, were obtained oxygen- and water-free from an MBraun solvent purification apparatus. ¹H, ³¹P{¹H}, ¹⁹F and ¹³C{¹H} NMR spectra were recorded on Bruker 300 ARX, Bruker Avance 300 MHz, and Bruker Avance 400 MHz instruments. Chemical shifts (expressed in parts per million) are referenced to residual solvent peaks (¹H, ¹³C {¹H}) or external 85% H₃PO₄(³¹P {¹H}), or external CFCl₃(¹⁹F). Coupling constants J and N are given in hertz. Attenuated total reflection infrared spectra (ATR-IR) of solid samples were run on a Perkin-Elmer Spectrum 100 FT-IR spectrometer. C, H, and N analyses were carried out in a Perkin-Elmer 2400 CHNS/O analyzer. High-resolution electrospray mass spectra were acquired using a MicroTOF-Q hybrid quadrupole time-of-flight spectrometer (Bruker Daltonics, Bremen, Germany). OsH₆(PⁱPr₃)₂was prepared by the method published in Aracama, M.; Esteruelas, M. A.; Lahoz, F. J.; López, J. A.; Meyer, U.; Oro, L. A.; Werner, H. Inorg. Chem. 1991, 30, 288.

Preparation of Dihydride-BF4

A solution of OsH₆(PⁱPr₃)₂(261 mg, 0.505 mmol) in dimethylformamide (DMF) (5 mL) was treated with 1,3-bis[(1-methyl)benzylimidazolium-3-yl]benzene diiodide (300 mg, 0.505 mmol). The resulting mixture was refluxed for 20 min, getting a very dark solution. After cooling at room temperature the solvent was removed in vacuo, affording a dark residue. The residue was dissolved in acetonitrile (10 mL) and AgBF₄(98.3 mg, 0.505 mmol) was added. After stirring protected from the light for 30 min the resulting suspension was filtered through Celite to remove the silver salts. The solution thus obtained was evaporated to ca. 0.5 mL and diethyl ether (10 mL) was added to afford a beige solid, that was washed with further portions of diethyl ether (2×2 mL) and dried in vacuo. Yield: 240 mg (50%). Analytical Calculation for C₄₀H₆₁BF₄N₄OsP₂: C, 51.28; H, 6.56; N, 5.98. Found: C, 51.55; H, 6.70; N, 5.62. HRMS (electrospray, m/z): calcd for C₄₀H₆₁N₄OsP₂[M]⁺: 851.3983; found: 851.4036. IR (cm⁻¹): v(Os—H) 2104 (w), v(BF₄) 1080-1000 (vs). ¹H NMR (300 MHz, CD₃CN, 298K): δ 8.31 (m, 2H, CH bzm), 7.98 (d, J_H-H=7.9, 2H, CH Ph), 7.70 (m, 2H, CH bzm), 7.57 (t, J_H-H=7.9, 1H, CH Ph), 7.54-7.50 (m, 4H, CH bzm), 4.32 (s, 6H, CH₃), 1.54 (m, 6H, PCH(CH₃)₂), 0.67 (dvt, J_HH=6.2, N=13.2, 36H, PCH(CH₃)₂), −6.25 (t, J_H-P=13.6, 2H, Os—H). ¹³C {¹H} NMR (75.42 MHz, CD₃CN, 293K): δ 189.4 (t, J_C-P=7.5, NCN), 161.3 (Os—C), 146.9 (s, CPh), 137.3 (s, CBzm), 132.8 (s, C Bzm), 124.9 (s, CH Bzm), 124.5 (s, CH Bzm), 124.2 (s, CH Ph), 112.8 (s, CH Bzm), 111.9 (s, CH Bzm), 109.2 (s, CH Ph), 38.9 (s, CH₃), 29.3 (t, N=27, PCH(CH₃)₂), 18.5 (s, PCH(CH₃)₂). ³¹P{¹H} NMR (121.4 MHz, CD₃CN, 293K): δ 4.5 (s).

Preparation of Complex Monohydride, Shown Below:

This monohydride compound can be prepared by using two different methods. Method (A): A solution of OsH₆(PⁱPr₃)₂(261 mg, 0.505 mmol) in DMF (5 mL) was treated with 1,3-bis[(1-methyl)benzylimidazolium-3-yl]benzene diiodide (300 mg, 0.505 mmol). The resulting mixture was refluxed for 20 min, getting a very dark solution. After cooling at room temperature the solvent was removed in vacuo, affording a dark residue. The dark residue was dissolved in 10 mL of tetrahydrofuran (THF) and K^tBuO (142 mg, 1.263 mmol) was added to the solution. After stirring at room temperature for 10 min the resulting suspension was filtered through Celite to remove the potassium salts. The solution thus obtained was evaporated to dryness to afford a yellow residue. Addition of pentane afforded a yellow solid, which was washed with pentane (1×2 mL) and dried in vacuo to obtain a yellow solid. Yield: 378 mg (88%). Method (B): A solution of dihydride-BF4 (200 mg, 0.213 mmol) in THF (5 mL) was treated with K^tBuO (28.6 mg, 0.255 mmol). After stirring at room temperature for 10 min the resulting suspension was filtered through Celite to remove the potassium salts. The solution thus obtained was evaporated to dryness to afford a yellow residue. Addition of pentane afforded a yellow solid, which was washed with pentane (1×2 mL) and dried in vacuo obtain a yellow solid. Yield: 163 mg (90%). Anal. Calcd. for C₄₀H₆₀N₄OsP₂: C, 56.58; H, 7.12; N, 6.60. Found: C, 56.00; H, 6.69; N, 6.76. HRMS (electrospray, m/z): calcd. For [M+H]⁺851.3983; found: 851.3979. IR (cm⁻¹): v(Os—H) 1889 (w). ¹H NMR (300 MHz, C₆D₆, 298K): δ 8.17 (d, J_H-H=7.7, 2H, CH Ph), 8.06 (d, J_H-H=7.7, 2H, CH bzm), 7.60 (t, J_H-H=7.7, 1H, CH Ph), 7.20 (td, J_H-H=7.9, J_H-H=1.0, 2H, CH bzm), 7.14-7.03 (m, 4H CH bzm), 3.92 (s, 6H, CH₃), 1.55 (m, 6H, PCH(CH₃)₂), 0.67 (dvt, J_H-H=6.9, N=12.3, 36H, PCH(CH₃)₂), −9.55 (t, J_H-P=33.6, 1H, Os—H). ¹³C {¹H} NMR (75.42 MHz, C₆D₆, 293K): δ 197.6 (t, J_C-P=9.2, Os—NCN), 173.2 (t, J_C-P=2.9, Os—C), 148.4 (s, CPh), 137.3 (s, C Bzm), 134.4 (s, CBzm), 121.5 (s, CH Bzm), 121.2 (s, CH Bzm), 117.9 (s, CH Ph), 109.6 (s, CH Bzm), 108.5 (s, CH Bzm), 105.8 (s, CH Ph), 37.9 (s, CH₃), 31.0 (t, N=24.2, PCH(CH₃)₂), 19.7 (s, PCH(CH₃)₂). ³¹P {¹H} NMR (121.4 MHz, C₆D₆, 293K): δ 20.6 (s, doublet under off resonance conditions). FIG. 3 shows the molecular structure of complex monohydride with the X-ray diffraction analysis characterization. Selected bond lengths (A) and angles)(°) were: Os—P(1)=2.3512(18), Os—P(2)=2.3529(17), Os—C(1)=2.052(6), Os—C(9)=2.036(3), Os—C(15)=2.035(6); P(1)-Os—P(2)=152.86(6), C(1)-Os—C(9)=75.5(2), C(9)-Os—C(15)=75.4(2), C(1)-Os(C15)=150.9(2).

Preparation of Complex Monohydride-CF3:

Method (A): A solution of dihydride-CF3-BF4 (200 mg, 0.2 mmol) in THF (5 mL) was treated with K^tBuO (26.8 mg, 0.24 mmol). After stirring at room temperature for 10 min the resulting suspension was filtered through Celite to remove the potassium salts. The solution thus obtained was evaporated to dryness to afford a yellow residue. Addition of pentane afforded a yellow solid, which was washed with pentane (1×2 mL) and dried in vacuo obtain a yellow solid. Yield: 240 mg (50%). Anal. Calcd. for C₄H₅₉F₃N₄OsP₂: C, 53.69; H, 6.48; N, 6.11. Found: C, 53.20; H, 6.33; N, 6.18. IR (cm⁻¹): v(Os—H) 1842 (w). ¹H NMR (300 MHz, C₆D₆, 298K): δ 8.53 (s, 2H, CH Ph-CF₃), 8.18 (m, 2H, CH bzm), 7.15-6.98 (m, 6H, CH bzm), 3.86 (s, 6H, CH₃), 1.49 (m, 6H, PCH(CH₃)₂), 0.60 (dvt, J_H.H=6.6, N=12.9, 36H, PCH(CH₃)₂), −9.29 (t, J_H-P=34.0, 1H, Os—H). ¹³C {¹H} NMR (75.42 MHz, C₆D₆, 293K): δ 197.4 (t, J_C-P=9.0, Os—NCN), 173.2 (t, J_C-P=3.6, Os—C), 148.0 (s, CPh), 137.2 (s, CBzm), 133.9 (s, CBzm), 128.2 (q, J_C-F=270.0, CF₃), 122.0 (s, CH Bzm), 121.7 (s, CH Bzm), 118.9 (q, J_C-F=30.8, C—CF₃), 109.8 (s, CH Bzm), 108.7 (s, CH Bzm), 102.0 (q, J_C-F=4.0 CH Ph), 37.9 (s, CH₃), 30.9 (t, N=24.8, PCH(CH₃)₂), 19.5 (s, PCH(CH₃)₂). ³¹P {¹H} NMR (121.4 MHz, C₆D₆, 293K): δ 21.4 (s, doublet under off resonance conditions). ¹⁹F NMR 282 MHz, C₆D₆, 293K): 6-60.10 (CF₃). Method (B): A solution of OsH₆(PⁱPr₃)₂(235 mg, 0.455 mmol) in DMF (5 mL) was treated with 1,3-bis[(1-methyl)benzylimidazolium-3-yl]-5-trifluoromethyl-benzene diiodide (300 mg, 0.455 mmol). The resulting mixture was refluxed for 20 min, getting a very dark solution. After cooling at room temperature the solvent was removed in vacuo, affording a dark residue. The addition of 4 mL of toluene caused the precipitation of a brown solid that was washed with further portions of diethyl ether (2×4 mL). The brown solid was dissolved in THF (10 mL) and K^tBuO (102 mg, 0.906 mmol) was added. After stirring for 20 min the resulting suspension was filtered through Celite to remove the iodide salts. The solution thus obtained was evaporated to dryness and pentane (4 mL) was added to afford an orange solid that was washed with further portions of pentane (1×3 mL) and dried in vacuo. This orange solid was suspended in diethyl ether (10 mL) and treated with HBF₄:Et₂O (93 μL, 0.680 mmol) getting a white suspension. This solid was decanted, washed with further portions of diethyl ether (2×4 mL) and dried in vacuo. Yield: 405 mg (89%) Anal. Calcd. for C₄₁H₆₀BF₇N₄OsP₂: C, 49.00; H, 6.02; N, 5.58. Found: C, 49.21; H, 5.79; N, 5.69. HRMS (electrospray, m/z): calcd for [M]⁺: 919.3857; found: 919.4035. IR (cm⁻¹): v(Os—H) 2097 (w), v(BF₄) 1080-1000 (vs). ¹H NMR (300 MHz, CD₃CN, 298K): δ 9.60 (m, 2H, CH bzm), 9.41 (s, 2H, CH Ph), 8.96 (m, 2H, CH bzm), 8.80 (m, 4H, CH bzm), 5.57 (s, 6H, CH₃), 2.80 (m, 6H, CH_P), 1.91 (dvt, 36H, J_HH=7.1, N=13.5, CH_3-P), −4.70 (t, 2H, J_H-P=13.5, H_hyd); ¹³C {¹H}NMR (75.42 MHz, CD₃CN, 293K): δ 189.6 (t, J_C-P=7.5, NCN), 169.6 (t, J_C-P=5.7, Os—C), 146.7 (s, C Ph), 137.4 (s, C Bzm), 132.6 (s, C Bzm), 126.7 (q, J_C-F=270, CF₃), 126.3 (q, J_C-F=28.6, CCF₃), 125.4 (s, CH Bzm), 125.1 (s, CH Bzm), 113.2 (s, CH Bzm), 112.3 (s, CH Bzm), 105.6 (q, J_C-F=3.9, CH Ph), 39.1 (s, CH₃), 29.5 (t, N=13.5, PCH(CH₃)₂), 19.6 (s, PCH(CH₃)₂). ³¹P {¹H} NMR (121.4 MHz, CD₃CN, 293K): δ 5.2 (s). ¹⁹F {¹H} NMR (282 MHz, CD₃CN, 293K): δ−60.21 (s, CF₃); −151.7 (broad signal, BF₄)

Preparation of Complex A:

Monohydride (250 mg, 0.294 mmol) and 1,3-bis[(1-methyl)benzylimidazolium-3-yl]benzene ditetrafluoroborate (181 mg, 0.353 mmol) were dissolved in 5 mL of DMF and triethyl amine (0.6 mL, 4.4 mmol) was added to the solution. The resulting mixture was refluxed for 1.5 h and then it was cooled to room temperature. The solvent was evaporated under vacuum to afford a brown residue. Addition of acetonitrile afforded a bright yellow solid that was washed with acetonitrile (1×2 mL) and dried in vacuo. Yield: 153 mg (60%). HRMS (electrospray, m/z): calcd for C₄₄H₃₄N₈Os [M]⁺: 867.2562; found: 867.2597. ¹H NMR (300 MHz, C₆D₆, 293K): δ 8.29 (d, J_H-H=7.7, 4H, CH Ph), 8.18 (d, J_H-H=7.9, 4H, CH bzm), 7.81 (t, J_H-H=7.7, 2H, CH Ph), 7.08 (td, J_H-H=7.9, J_H-H=1.0, 4H, CH bzm), 6.80 (td, J_H-H=7.9, J_H-H=1.0, 4H, CH bzm), 6.18 (d, J_H-H=7.9, 4H, CH bzm), 2.25 (s, 12H, CH₃). ¹³C {¹H} NMR (75.42 MHz, C₆D₆, 293K): δ 192.6 (s, Os—NCN), 171.1 (s, Os—C), 146.8 (s, CPh), 137.2 (s, CBzm), 133.4 (s, CBzm), 121.43 (s, CH Bzm), 121.03 (s, CH Bzm), 117.8 (s, CH Ph), 109.9 (s, CH Bzm), 109.0 (s, CH Bzm), 106.4 (s, CH Ph), 32.7 (s, CH₃). FIG. 4 shows molecular diagram of Complex A with X-ray diffraction analysis characterization. The structure has two chemically equivalent but crystallographically independent molecules in the asymmetric unit. Selected bond lengths (A) and angles (°): Os(1)-C(10)=2.048(7), 2.057 (7), Os(1)-C(32)=2.045(7), 2.049 (8), Os(1)-C(15)=2.026(8), 2.032 (8), Os(1)-C(1)=2.042(8), 2.037 (7), Os(1)-C(23)=2.049(7), 2.037 (8), Os(1)-C(37)=2.043(7), 2.051(8); C(15)-Os(1)-C(1)=149.6(3), 149.9 (3), C(23)-Os(1)-C(37)=150.0(3), 150.6 (3), C(10)-Os(1)-C(32)=177.8(3), 178.6 (3).

Preparation of Complex A-CF₃:

Monohydride (250 mg, 0.294 mmol) and 1,3-bis[(1-methyl)benzylimidazolium-3-yl]-5-trifluoromethyl-benzene ditetrafluoroborate (170 mg, 0.294 mmol) were dissolved in 5 mL of DMF and triethyl amine (0.6 mL, 4.4 mmol) was added to the solution. The resulting mixture was refluxed for 1.5 h and then it was cooled to room temperature. The solvent was evaporated under vacuum to afford a brown residue. Addition of acetonitrile afforded a bright yellow solid that was washed with acetonitrile (1×2 mL) and dried in vacuo. Yield: 147 mg (53%). HRMS (electrospray, m/z): calcd for C₄₅H₃₃F₃N₈Os [M]⁺: 934.2392; found: 934.2398. ¹H NMR (300 MHz, C₆D₆, 293K): δ 8.75 (s, 2H, CH Ph-CF₃), 8.24 (d, J_H-H=7.8, 2H, CH Ph), 8.16 (d, J_H-H=7.8, 2H, CH bzm), 8.14 (d, J_H-H=7.8, 2H, CH bzm), 7.78 (t, J_H-H=7.8, 1H, CH Ph), 7.08 (t, J_H-H=7.8, 2H, CH bzm), 6.99 (t, J_H-H=7.8, 2H, CH bzm), 6.81 (t, J_H-H=7.9, 2H, CH bzm), 6.78 (t, J_H-H=7.9, 2H, CH bzm), 6.21 (d, J_H-H=7.8, 2H, CH bzm), 6.14 (d, J_H-H=7.8, 2H, CH bzm), 2.22 (s, 6H, CH₃), 2.11 (s, 6H, CH₃). ¹³C {¹H} NMR (100.63 MHz, C₆D₆, 293K): δ 192.4 (s, Os—NCN), 192.1 (s, Os—NCN), 179.0 (s, Os—C), 170.1 (s, Os—C), 146.7 (s, CPh), 146.5 (s, CPh), 137.2 (s, CBzm), 137.1 (s, CBzm), 133.4 (s, CBzm), 133.2 (s, CBzm), 128.4 (q, J_C-F=270.4 Hz, CF₃) 122.0 (s, CH Bzm), 121.8 (s, CH Bzm), 121.7 (s, CH Bzm), 121.4 (s, CH Bzm), 119.0 (q, J_C-F=30.7 Hz, CCF₃) 118.5 (s, CH Ph), 110.14 (s, CH Bzm), 110.08 (s, CH Bzm), 109.30 (s, CH Bzm), 109.28 (s, CH Bzm), 107.0 (s, CH Ph), 103.1 (q, J_C-F=3.8 Hz, CHPh), 32.8 (s, CH₃), 32.7 (s, CH₃). ¹⁹F NMR (282 MHz, C₆D₆, 293K): δ −57.1 (CF₃).

According to an aspect of the present disclosure, a method of making an osmium(II) complex having Formula I

L¹-Os-L², wherein L¹and L²are independently a biscarbene tridentate ligand, wherein L¹and L²can be same or different is disclosed. The method comprises: (a) reacting a precursor of ligand L¹with an osmium precursor to form an intermediate product, wherein the osmium precursor having the formula OsH_x(PR₃)_y, wherein x is an integer from 2 to 6 and y is an integer from 2 to 5, and R is selected from the group consisting of aryl, alkyl and cycloalkyl; and (b) reacting a precursor of ligand L²with said intermediate product.

In one embodiment of the method, L¹and L²are monoanionic ligands. In some embodiments, L¹and L²are independently selected from ligands having Formula II:

wherein Y¹, Y²and Y³comprise C or N; wherein R³and R⁴may represent mono-, or di-substitutions, or no substitution; wherein R⁵may represent mono-, di-, or tri-substitutions, or no substitution; wherein R¹, R², R³, R⁴and R⁵are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any two adjacent substituents of R¹, R², R³, R⁴and R⁵are optionally joined to form a ring; and wherein the dash lines show the connection points to osmium.

In one embodiment of the method, Y¹, Y²and Y³comprise C. In one embodiment, Y¹and Y³comprise C, and Y²is N. In one embodiment, Y¹and Y³are N, and Y²comprise C. In one embodiment, R¹and R²are independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and partially or fully deuterated variants thereof. In one embodiment, R¹and R²are independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, partially or fully deuterated variants thereof, and combinations thereof.

In one embodiment of the method, the osmium precursor having the formula OsH₆(PR₃)₂. In another embodiment, R in the osmium precursor having the formula OsH₆(PR₃)_yis selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, cyclohexyl, phenyl, 2,6-dimethylphenyl, and 2-methylphenyl. In other embodiment, R is 1-methylethyl.

In another embodiment, the ligands having Formula II are selected from the group consisting of:

According to an embodiment, a compound having a structure according to Formula I, L¹-Os-L²is provided, wherein L¹and L²are different; wherein L¹and L²are independently selected from ligands having Formula II,

In Formula II, Y¹, Y²and Y³comprise C or N; wherein R³and R⁴may represent mono-, or di-substitutions, or no substitution; wherein R⁵may represent mono-, di-, or tri-substitutions, or no substitution; wherein R¹and R²are independently selected from the group consisting of alkyl and cycloalkyl; wherein R³, Wand R⁵are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, aralkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combinations thereof; wherein any two adjacent substituents of R¹, R², R³, R⁴and R⁵are optionally joined to condense into a fused ring; and wherein the dash lines show the connection points to osmium.

In an embodiment of the compound, Y¹, Y²and Y³comprise C. In one embodiment of the compound, Y¹and Y³comprise C, and Y²is N. In some embodiments, Y¹and Y³are N, and Y²comprise C. In one embodiment, R¹and R²are independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and partially or fully deuterated variants thereof. In one embodiment, R¹and R²are independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, partially or fully deuterated variants thereof, and combinations thereof.

In some embodiments of the compound, L¹and L²are independently selected from ligands having Formula III:

wherein X¹, X², X³, X⁴, X⁵, X⁶, X⁷and X⁸comprise C or N. In one embodiment, X¹, X², X³, X⁴, X⁵, X⁶, X⁷and X⁸comprise C.

In some embodiments, the ligands having Formula II are selected from the group consisting of: L¹⁰¹to L¹⁵⁹defined herein.

In some embodiments, the compound having a structure according to Formula I, L¹-Os-L²is selected from the group consisting of Compounds 1 to 1159 defined in Table 1 below:

TABLE 1 Compound Number L¹ L² 1. L¹⁰¹ L¹⁰² 2. L¹⁰¹ L¹⁰³ 3. L¹⁰¹ L¹⁰⁴ 4. L¹⁰¹ L¹⁰⁵ 5. L¹⁰¹ L¹⁰⁶ 6. L¹⁰¹ L¹⁰⁷ 7. L¹⁰¹ L¹⁰⁸ 8. L¹⁰¹ L¹⁰⁹ 9. L¹⁰¹ L¹¹⁰ 10. L¹⁰¹ L¹¹¹ 11. L¹⁰¹ L¹¹² 12. L¹⁰¹ L¹¹³ 13. L¹⁰¹ L¹¹⁴ 14. L¹⁰¹ L¹¹⁵ 15. L¹⁰¹ L¹¹⁶ 16. L¹⁰¹ L¹¹⁷ 17. L¹⁰¹ L¹¹⁸ 18. L¹⁰¹ L¹¹⁹ 19. L¹⁰¹ L¹²⁰ 20. L¹⁰¹ L¹²¹ 21. L¹⁰¹ L¹²² 22. L¹⁰¹ L¹²³ 23. L¹⁰¹ L¹²⁴ 24. L¹⁰¹ L¹²⁵ 25. L¹⁰¹ L¹²⁶ 26. L¹⁰¹ L¹²⁷ 27. L¹⁰¹ L¹²⁸ 28. L¹⁰¹ L¹²⁹ 29. L¹⁰¹ L¹³⁰ 30. L¹⁰¹ L¹³¹ 31. L¹⁰¹ L¹³² 32. L¹⁰¹ L¹³³ 33. L¹⁰¹ L¹³⁴ 34. L¹⁰¹ L¹³⁵ 35. L¹⁰¹ L¹³⁶ 36. L¹⁰¹ L¹³⁷ 37. L¹⁰¹ L¹³⁸ 38. L¹⁰¹ L¹³⁹ 39. L¹⁰¹ L¹⁴⁰ 40. L¹⁰¹ L¹⁴¹ 41. L¹⁰¹ L¹⁴² 42. L¹⁰¹ L¹⁴³ 43. L¹⁰¹ L¹⁴⁴ 44. L¹⁰¹ L¹⁴⁵ 45. L¹⁰¹ L¹⁴⁶ 46. L¹⁰¹ L¹⁴⁷ 47. L¹⁰¹ L¹⁴⁸ 48. L¹⁰¹ L¹⁴⁹ 49. L¹⁰¹ L¹⁵⁰ 50. L¹⁰¹ L¹⁵¹ 51. L¹⁰¹ L¹⁵² 52. L¹⁰¹ L¹⁵³ 53. L¹⁰¹ L¹⁵⁴ 54. L¹⁰¹ L¹⁵⁵ 55. L¹⁰¹ L¹⁵⁶ 56. L¹⁰¹ L¹⁵⁷ 57. L¹⁰¹ L¹⁵⁸ 58. L¹⁰¹ L¹⁵⁹ 59. L¹⁰² L¹⁰³ 60. L¹⁰² L¹⁰⁴ 61. L¹⁰² L¹⁰⁵ 62. L¹⁰² L¹⁰⁶ 63. L¹⁰² L¹⁰⁷ 64. L¹⁰² L¹⁰⁸ 65. L¹⁰² L¹⁰⁹ 66. L¹⁰² L¹¹⁰ 67. L¹⁰² L¹¹¹ 68. L¹⁰² L¹¹² 69. L¹⁰² L¹¹³ 70. L¹⁰² L¹¹⁴ 71. L¹⁰² L¹¹⁵ 72. L¹⁰² L¹¹⁶ 73. L¹⁰² L¹¹⁷ 74. L¹⁰² L¹¹⁸ 75. L¹⁰² L¹¹⁹ 76. L¹⁰² L¹²⁰ 77. L¹⁰² L¹²¹ 78. L¹⁰² L¹²² 79. L¹⁰² L¹²³ 80. L¹⁰² L¹²⁴ 81. L¹⁰² L¹²⁵ 82. L¹⁰² L¹²⁶ 83. L¹⁰² L¹²⁷ 84. L¹⁰² L¹²⁸ 85. L¹⁰² L¹²⁹ 86. L¹⁰² L¹³⁰ 87. L¹⁰² L¹³¹ 88. L¹⁰² L¹³² 89. L¹⁰² L¹³³ 90. L¹⁰² L¹³⁴ 91. L¹⁰² L¹³⁵ 92. L¹⁰² L¹³⁶ 93. L¹⁰² L¹³⁷ 94. L¹⁰² L¹³⁸ 95. L¹⁰² L¹³⁹ 96. L¹⁰² L¹⁴⁰ 97. L¹⁰² L¹⁴¹ 98. L¹⁰² L¹⁴² 99. L¹⁰² L¹⁴³ 100. L¹⁰² L¹⁴⁴ 101. L¹⁰² L¹⁴⁵ 102. L¹⁰² L¹⁴⁶ 103. L¹⁰² L¹⁴⁷ 104. L¹⁰² L¹⁴⁸ 105. L¹⁰² L¹⁴⁹ 106. L¹⁰² L¹⁵⁰ 107. L¹⁰² L¹⁵¹ 108. L¹⁰² L¹⁵² 109. L¹⁰² L¹⁵³ 110. L¹⁰² L¹⁵⁴ 111. L¹⁰² L¹⁵⁵ 112. L¹⁰² L¹⁵⁶ 113. L¹⁰² L¹⁵⁷ 114. L¹⁰² L¹⁵⁸ 115. L¹⁰² L¹⁵⁹ 116. L¹⁰³ L¹⁰⁴ 117. L¹⁰³ L¹⁰⁵ 118. L¹⁰³ L¹⁰⁶ 119. L¹⁰³ L¹⁰⁷ 120. L¹⁰³ L¹⁰⁸ 121. L¹⁰³ L¹⁰⁹ 122. L¹⁰³ L¹¹⁰ 123. L¹⁰³ L¹¹¹ 124. L¹⁰³ L¹¹² 125. L¹⁰³ L¹¹³ 126. L¹⁰³ L¹¹⁴ 127. L¹⁰³ L¹¹⁵ 128. L¹⁰³ L¹¹⁶ 129. L¹⁰³ L¹¹⁷ 130. L¹⁰³ L¹¹⁸ 131. L¹⁰³ L¹¹⁹ 132. L¹⁰³ L¹²⁰ 133. L¹⁰³ L¹²¹ 134. L¹⁰³ L¹²² 135. L¹⁰³ L¹²³ 136. L¹⁰³ L¹²⁴ 137. L¹⁰³ L¹²⁵ 138. L¹⁰³ L¹²⁶ 139. L¹⁰³ L¹²⁷ 140. L¹⁰³ L¹²⁸ 141. L¹⁰³ L¹²⁹ 142. L¹⁰³ L¹³⁰ 143. L¹⁰³ L¹³¹ 144. L¹⁰³ L¹³² 145. L¹⁰³ L¹³³ 146. L¹⁰³ L¹³⁴ 147. L¹⁰³ L¹³⁵ 148. L¹⁰³ L¹³⁶ 149. L¹⁰³ L¹³⁷ 150. L¹⁰³ L¹³⁸ 151. L¹⁰³ L¹³⁹ 152. L¹⁰³ L¹⁴⁰ 153. L¹⁰³ L¹⁴¹ 154. L¹⁰³ L¹⁴² 155. L¹⁰³ L¹⁴³ 156. L¹⁰³ L¹⁴⁴ 157. L¹⁰³ L¹⁴⁵ 158. L¹⁰³ L¹⁴⁶ 159. L¹⁰³ L¹⁴⁷ 160. L¹⁰³ L¹⁴⁸ 161. L¹⁰³ L¹⁴⁹ 162. L¹⁰³ L¹⁵⁰ 163. L¹⁰³ L¹⁵¹ 164. L¹⁰³ L¹⁵² 165. L¹⁰³ L¹⁵³ 166. L¹⁰³ L¹⁵⁴ 167. L¹⁰³ L¹⁵⁵ 168. L¹⁰³ L¹⁵⁶ 169. L¹⁰³ L¹⁵⁷ 170. L¹⁰³ L¹⁵⁸ 171. L¹⁰³ L¹⁵⁹ 172. L¹⁰⁴ L¹⁰⁵ 173. L¹⁰⁴ L¹⁰⁶ 174. L¹⁰⁴ L¹⁰⁷ 175. L¹⁰⁴ L¹⁰⁸ 176. L¹⁰⁴ L¹⁰⁹ 177. L¹⁰⁴ L¹¹⁰ 178. L¹⁰⁴ L¹¹¹ 179. L¹⁰⁴ L¹¹² 180. L¹⁰⁴ L¹¹³ 181. L¹⁰⁴ L¹¹⁴ 182. L¹⁰⁴ L¹¹⁵ 183. L¹⁰⁴ L¹¹⁶ 184. L¹⁰⁴ L¹¹⁷ 185. L¹⁰⁴ L¹¹⁸ 186. L¹⁰⁴ L¹¹⁹ 187. L¹⁰⁴ L¹²⁰ 188. L¹⁰⁴ L¹²¹ 189. L¹⁰⁴ L¹²² 190. L¹⁰⁴ L¹²³ 191. L¹⁰⁴ L¹²⁴ 192. L¹⁰⁴ L¹²⁵ 193. L¹⁰⁴ L¹²⁶ 194. L¹⁰⁴ L¹²⁷ 195. L¹⁰⁴ L¹²⁸ 196. L¹⁰⁴ L¹²⁹ 197. L¹⁰⁴ L¹³⁰ 198. L¹⁰⁴ L¹³¹ 199. L¹⁰⁴ L¹³² 200. L¹⁰⁴ L¹³³ 201. L¹⁰⁴ L¹³⁴ 202. L¹⁰⁴ L¹³⁵ 203. L¹⁰⁴ L¹³⁶ 204. L¹⁰⁴ L¹³⁷ 205. L¹⁰⁴ L¹³⁸ 206. L¹⁰⁴ L¹³⁹ 207. L¹⁰⁴ L¹⁴⁰ 208. L¹⁰⁴ L¹⁴¹ 209. L¹⁰⁴ L¹⁴² 210. L¹⁰⁴ L¹⁴³ 211. L¹⁰⁴ L¹⁴⁴ 212. L¹⁰⁴ L¹⁴⁵ 213. L¹⁰⁴ L¹⁴⁶ 214. L¹⁰⁴ L¹⁴⁷ 215. L¹⁰⁴ L¹⁴⁸ 216. L¹⁰⁴ L¹⁴⁹ 217. L¹⁰⁴ L¹⁵⁰ 218. L¹⁰⁴ L¹⁵¹ 219. L¹⁰⁴ L¹⁵² 220. L¹⁰⁴ L¹⁵³ 221. L¹⁰⁴ L¹⁵⁴ 222. L¹⁰⁴ L¹⁵⁵ 223. L¹⁰⁴ L¹⁵⁶ 224. L¹⁰⁴ L¹⁵⁷ 225. L¹⁰⁴ L¹⁵⁸ 226. L¹⁰⁴ L¹⁵⁹ 227. L¹⁰⁵ L¹⁰⁶ 228. L¹⁰⁵ L¹⁰⁷ 229. L¹⁰⁵ L¹⁰⁸ 230. L¹⁰⁵ L¹⁰⁹ 231. L¹⁰⁵ L¹¹⁰ 232. L¹⁰⁵ L¹¹¹ 233. L¹⁰⁵ L¹¹² 234. L¹⁰⁵ L¹¹³ 235. L¹⁰⁵ L¹¹⁴ 236. L¹⁰⁵ L¹¹⁵ 237. L¹⁰⁵ L¹¹⁶ 238. L¹⁰⁵ L¹¹⁷ 239. L¹⁰⁵ L¹¹⁸ 240. L¹⁰⁵ L¹¹⁹ 241. L¹⁰⁵ L¹²⁰ 242. L¹⁰⁵ L¹²¹ 243. L¹⁰⁵ L¹²² 244. L¹⁰⁵ L¹²³ 245. L¹⁰⁵ L¹²⁴ 246. L¹⁰⁵ L¹²⁵ 247. L¹⁰⁵ L¹²⁶ 248. L¹⁰⁵ L¹²⁷ 249. L¹⁰⁵ L¹²⁸ 250. L¹⁰⁵ L¹²⁹ 251. L¹⁰⁵ L¹³⁰ 252. L¹⁰⁵ L¹³¹ 253. L¹⁰⁵ L¹³² 254. L¹⁰⁵ L¹³³ 255. L¹⁰⁵ L¹³⁴ 256. L¹⁰⁵ L¹³⁵ 257. L¹⁰⁵ L¹³⁶ 258. L¹⁰⁵ L¹³⁷ 259. L¹⁰⁵ L¹³⁸ 260. L¹⁰⁵ L¹³⁹ 261. L¹⁰⁵ L¹⁴⁰ 262. L¹⁰⁵ L¹⁴¹ 263. L¹⁰⁵ L¹⁴² 264. L¹⁰⁵ L¹⁴³ 265. L¹⁰⁵ L¹⁴⁴ 266. L¹⁰⁵ L¹⁴⁵ 267. L¹⁰⁵ L¹⁴⁶ 268. L¹⁰⁵ L¹⁴⁷ 269. L¹⁰⁵ L¹⁴⁸ 270. L¹⁰⁵ L¹⁴⁹ 271. L¹⁰⁵ L¹⁵⁰ 272. L¹⁰⁵ L¹⁵¹ 273. L¹⁰⁵ L¹⁵² 274. L¹⁰⁵ L¹⁵³ 275. L¹⁰⁵ L¹⁵⁴ 276. L¹⁰⁵ L¹⁵⁵ 277. L¹⁰⁵ L¹⁵⁶ 278. L¹⁰⁵ L¹⁵⁷ 279. L¹⁰⁵ L¹⁵⁸ 280. L¹⁰⁵ L¹⁵⁹ 281. L¹⁰⁶ L¹⁰⁷ 282. L¹⁰⁶ L¹⁰⁸ 283. L¹⁰⁶ L¹⁰⁹ 284. L¹⁰⁶ L¹¹⁰ 285. L¹⁰⁶ L¹¹¹ 286. L¹⁰⁶ L¹¹² 287. L¹⁰⁶ L¹¹³ 288. L¹⁰⁶ L¹¹⁴ 289. L¹⁰⁶ L¹¹⁵ 290. L¹⁰⁶ L¹¹⁶ 291. L¹⁰⁶ L¹¹⁷ 292. L¹⁰⁶ L¹¹⁸ 293. L¹⁰⁶ L¹¹⁹ 294. L¹⁰⁶ L¹²⁰ 295. L¹⁰⁶ L¹²¹ 296. L¹⁰⁶ L¹²² 297. L¹⁰⁶ L¹²³ 298. L¹⁰⁶ L¹²⁴ 299. L¹⁰⁶ L¹²⁵ 300. L¹⁰⁶ L¹²⁶ 301. L¹⁰⁶ L¹²⁷ 302. L¹⁰⁶ L¹²⁸ 303. L¹⁰⁶ L¹²⁹ 304. L¹⁰⁶ L¹³⁰ 305. L¹⁰⁶ L¹³¹ 306. L¹⁰⁶ L¹³² 307. L¹⁰⁶ L¹³³ 308. L¹⁰⁶ L¹³⁴ 309. L¹⁰⁶ L¹³⁵ 310. L¹⁰⁶ L¹³⁶ 311. L¹⁰⁶ L¹³⁷ 312. L¹⁰⁶ L¹³⁸ 313. L¹⁰⁶ L¹³⁹ 314. L¹⁰⁶ L¹⁴⁰ 315. L¹⁰⁶ L¹⁴¹ 316. L¹⁰⁶ L¹⁴² 317. L¹⁰⁶ L¹⁴³ 318. L¹⁰⁶ L¹⁴⁴ 319. L¹⁰⁶ L¹⁴⁵ 320. L¹⁰⁶ L¹⁴⁶ 321. L¹⁰⁶ L¹⁴⁷ 322. L¹⁰⁶ L¹⁴⁸ 323. L¹⁰⁶ L¹⁴⁹ 324. L¹⁰⁶ L¹⁵⁰ 325. L¹⁰⁶ L¹⁵¹ 326. L¹⁰⁶ L¹⁵² 327. L¹⁰⁶ L¹⁵³ 328. L¹⁰⁶ L¹⁵⁴ 329. L¹⁰⁶ L¹⁵⁵ 330. L¹⁰⁶ L¹⁵⁶ 331. L¹⁰⁶ L¹⁵⁷ 332. L¹⁰⁶ L¹⁵⁸ 333. L¹⁰⁶ L¹⁵⁹ 334. L¹⁰⁷ L¹⁰⁸ 335. L¹⁰⁷ L¹⁰⁹ 336. L¹⁰⁷ L¹¹⁰ 337. L¹⁰⁷ L¹¹¹ 338. L¹⁰⁷ L¹¹² 339. L¹⁰⁷ L¹¹³ 340. L¹⁰⁷ L¹¹⁴ 341. L¹⁰⁷ L¹¹⁵ 342. L¹⁰⁷ L¹¹⁶ 343. L¹⁰⁷ L¹¹⁷ 344. L¹⁰⁷ L¹¹⁸ 345. L¹⁰⁷ L¹¹⁹ 346. L¹⁰⁷ L¹²⁰ 347. L¹⁰⁷ L¹²¹ 348. L¹⁰⁷ L¹²² 349. L¹⁰⁷ L¹²³ 350. L¹⁰⁷ L¹²⁴ 351. L¹⁰⁷ L¹²⁵ 352. L¹⁰⁷ L¹²⁶ 353. L¹⁰⁷ L¹²⁷ 354. L¹⁰⁷ L¹²⁸ 355. L¹⁰⁷ L¹²⁹ 356. L¹⁰⁷ L¹³⁰ 357. L¹⁰⁷ L¹³¹ 358. L¹⁰⁷ L¹³² 359. L¹⁰⁷ L¹³³ 360. L¹⁰⁷ L¹³⁴ 361. L¹⁰⁷ L¹³⁵ 362. L¹⁰⁷ L¹³⁶ 363. L¹⁰⁷ L¹³⁷ 364. L¹⁰⁷ L¹³⁸ 365. L¹⁰⁷ L¹³⁹ 366. L¹⁰⁷ L¹⁴⁰ 367. L¹⁰⁷ L¹⁴¹ 368. L¹⁰⁷ L¹⁴² 369. L¹⁰⁷ L¹⁴³ 370. L¹⁰⁷ L¹⁴⁴ 371. L¹⁰⁷ L¹⁴⁵ 372. L¹⁰⁷ L¹⁴⁶ 373. L¹⁰⁷ L¹⁴⁷ 374. L¹⁰⁷ L¹⁴⁸ 375. L¹⁰⁷ L¹⁴⁹ 376. L¹⁰⁷ L¹⁵⁰ 377. L¹⁰⁷ L¹⁵¹ 378. L¹⁰⁷ L¹⁵² 379. L¹⁰⁷ L¹⁵³ 380. L¹⁰⁷ L¹⁵⁴ 381. L¹⁰⁷ L¹⁵⁵ 382. L¹⁰⁷ L¹⁵⁶ 383. L¹⁰⁷ L¹⁵⁷ 384. L¹⁰⁷ L¹⁵⁸ 385. L¹⁰⁷ L¹⁵⁹ 386. L¹⁰⁸ L¹⁰⁹ 387. L¹⁰⁸ L¹¹⁰ 388. L¹⁰⁸ L¹¹¹ 389. L¹⁰⁸ L¹¹² 390. L¹⁰⁸ L¹¹³ 391. L¹⁰⁸ L¹¹⁴ 392. L¹⁰⁸ L¹¹⁵ 393. L¹⁰⁸ L¹¹⁶ 394. L¹⁰⁸ L¹¹⁷ 395. L¹⁰⁸ L¹¹⁸ 396. L¹⁰⁸ L¹¹⁹ 397. L¹⁰⁸ L¹²⁰ 398. L¹⁰⁸ L¹²¹ 399. L¹⁰⁸ L¹²² 400. L¹⁰⁸ L¹²³ 401. L¹⁰⁸ L¹²⁴ 402. L¹⁰⁸ L¹²⁵ 403. L¹⁰⁸ L¹²⁶ 404. L¹⁰⁸ L¹²⁷ 405. L¹⁰⁸ L¹²⁸ 406. L¹⁰⁸ L¹²⁹ 407. L¹⁰⁸ L¹³⁰ 408. L¹⁰⁸ L¹³¹ 409. L¹⁰⁸ L¹³² 410. L¹⁰⁸ L¹³³ 411. L¹⁰⁸ L¹³⁴ 412. L¹⁰⁸ L¹³⁵ 413. L¹⁰⁸ L¹³⁶ 414. L¹⁰⁸ L¹³⁷ 415. L¹⁰⁸ L¹³⁸ 416. L¹⁰⁸ L¹³⁹ 417. L¹⁰⁸ L¹⁴⁰ 418. L¹⁰⁸ L¹⁴¹ 419. L¹⁰⁸ L¹⁴² 420. L¹⁰⁸ L¹⁴³ 421. L¹⁰⁸ L¹⁴⁴ 422. L¹⁰⁸ L¹⁴⁵ 423. L¹⁰⁸ L¹⁴⁶ 424. L¹⁰⁸ L¹⁴⁷ 425. L¹⁰⁸ L¹⁴⁸ 426. L¹⁰⁸ L¹⁴⁹ 427. L¹⁰⁸ L¹⁵⁰ 428. L¹⁰⁸ L¹⁵¹ 429. L¹⁰⁸ L¹⁵² 430. L¹⁰⁸ L¹⁵³ 431. L¹⁰⁸ L¹⁵⁴ 432. L¹⁰⁸ L¹⁵⁵ 433. L¹⁰⁸ L¹⁵⁶ 434. L¹⁰⁸ L¹⁵⁷ 435. L¹⁰⁸ L¹⁵⁸ 436. L¹⁰⁸ L¹⁵⁹ 437. L¹⁰⁹ L¹¹⁰ 438. L¹⁰⁹ L¹¹¹ 439. L¹⁰⁹ L¹¹² 440. L¹⁰⁹ L¹¹³ 441. L¹⁰⁹ L¹¹⁴ 442. L¹⁰⁹ L¹¹⁵ 443. L¹⁰⁹ L¹¹⁶ 444. L¹⁰⁹ L¹¹⁷ 445. L¹⁰⁹ L¹¹⁸ 446. L¹⁰⁹ L¹¹⁹ 447. L¹⁰⁹ L¹²⁰ 448. L¹⁰⁹ L¹²¹ 449. L¹⁰⁹ L¹²² 450. L¹⁰⁹ L¹²³ 451. L¹⁰⁹ L¹²⁴ 452. L¹⁰⁹ L¹²⁵ 453. L¹⁰⁹ L¹²⁶ 454. L¹⁰⁹ L¹²⁷ 455. L¹⁰⁹ L¹²⁸ 456. L¹⁰⁹ L¹²⁹ 457. L¹⁰⁹ L¹³⁰ 458. L¹⁰⁹ L¹³¹ 459. L¹⁰⁹ L¹³² 460. L¹⁰⁹ L¹³³ 461. L¹⁰⁹ L¹³⁴ 462. L¹⁰⁹ L¹³⁵ 463. L¹⁰⁹ L¹³⁶ 464. L¹⁰⁹ L¹³⁷ 465. L¹⁰⁹ L¹³⁸ 466. L¹⁰⁹ L¹³⁹ 467. L¹⁰⁹ L¹⁴⁰ 468. L¹⁰⁹ L¹⁴¹ 469. L¹⁰⁹ L¹⁴² 470. L¹⁰⁹ L¹⁴³ 471. L¹⁰⁹ L¹⁴⁴ 472. L¹⁰⁹ L¹⁴⁵ 473. L¹⁰⁹ L¹⁴⁶ 474. L¹⁰⁹ L¹⁴⁷ 475. L¹⁰⁹ L¹⁴⁸ 476. L¹⁰⁹ L¹⁴⁹ 477. L¹⁰⁹ L¹⁵⁰ 478. L¹⁰⁹ L¹⁵¹ 479. L¹⁰⁹ L¹⁵² 480. L¹⁰⁹ L¹⁵³ 481. L¹⁰⁹ L¹⁵⁴ 482. L¹⁰⁹ L¹⁵⁵ 483. L¹⁰⁹ L¹⁵⁶ 484. L¹⁰⁹ L¹⁵⁷ 485. L¹⁰⁹ L¹⁵⁸ 486. L¹⁰⁹ L¹⁵⁹ 487. L¹¹⁰ L¹¹¹ 488. L¹¹⁰ L¹¹² 489. L¹¹⁰ L¹¹³ 490. L¹¹⁰ L¹¹⁴ 491. L¹¹⁰ L¹¹⁵ 492. L¹¹⁰ L¹¹⁶ 493. L¹¹⁰ L¹¹⁷ 494. L¹¹⁰ L¹¹⁸ 495. L¹¹⁰ L¹¹⁹ 496. L¹¹⁰ L¹²⁰ 497. L¹¹⁰ L¹²¹ 498. L¹¹⁰ L¹²² 499. L¹¹⁰ L¹²³ 500. L¹¹⁰ L¹²⁴ 501. L¹¹⁰ L¹²⁵ 502. L¹¹⁰ L¹²⁶ 503. L¹¹⁰ L¹²⁷ 504. L¹¹⁰ L¹²⁸ 505. L¹¹⁰ L¹²⁹ 506. L¹¹⁰ L¹³⁰ 507. L¹¹⁰ L¹³¹ 508. L¹¹⁰ L¹³² 509. L¹¹⁰ L¹³³ 510. L¹¹⁰ L¹³⁴ 511. L¹¹⁰ L¹³⁵ 512. L¹¹⁰ L¹³⁶ 513. L¹¹⁰ L¹³⁷ 514. L¹¹⁰ L¹³⁸ 515. L¹¹⁰ L¹³⁹ 516. L¹¹⁰ L¹⁴⁰ 517. L¹¹⁰ L¹⁴¹ 518. L¹¹⁰ L¹⁴² 519. L¹¹⁰ L¹⁴³ 520. L¹¹⁰ L¹⁴⁴ 521. L¹¹⁰ L¹⁴⁵ 522. L¹¹⁰ L¹⁴⁶ 523. L¹¹⁰ L¹⁴⁷ 524. L¹¹⁰ L¹⁴⁸ 525. L¹¹⁰ L¹⁴⁹ 526. L¹¹⁰ L¹⁵⁰ 527. L¹¹⁰ L¹⁵¹ 528. L¹¹⁰ L¹⁵² 529. L¹¹⁰ L¹⁵³ 530. L¹¹⁰ L¹⁵⁴ 531. L¹¹⁰ L¹⁵⁵ 532. L¹¹⁰ L¹⁵⁶ 533. L¹¹⁰ L¹⁵⁷ 534. L¹¹⁰ L¹⁵⁸ 535. L¹¹⁰ L¹⁵⁹ 536. L¹¹¹ L¹¹² 537. L¹¹¹ L¹¹³ 538. L¹¹¹ L¹¹⁴ 539. L¹¹¹ L¹¹⁵ 540. L¹¹¹ L¹¹⁶ 541. L¹¹¹ L¹¹⁷ 542. L¹¹¹ L¹¹⁸ 543. L¹¹¹ L¹¹⁹ 544. L¹¹¹ L¹²⁰ 545. L¹¹¹ L¹²¹ 546. L¹¹¹ L¹²² 547. L¹¹¹ L¹²³ 548. L¹¹¹ L¹²⁴ 549. L¹¹¹ L¹²⁵ 550. L¹¹¹ L¹²⁶ 551. L¹¹¹ L¹²⁷ 552. L¹¹¹ L¹²⁸ 553. L¹¹¹ L¹²⁹ 554. L¹¹¹ L¹³⁰ 555. L¹¹¹ L¹³¹ 556. L¹¹¹ L¹³² 557. L¹¹¹ L¹³³ 558. L¹¹¹ L¹³⁴ 559. L¹¹¹ L¹³⁵ 560. L¹¹¹ L¹³⁶ 561. L¹¹¹ L¹³⁷ 562. L¹¹¹ L¹³⁸ 563. L¹¹¹ L¹³⁹ 564. L¹¹¹ L¹⁴⁰ 565. L¹¹¹ L¹⁴¹ 566. L¹¹¹ L¹⁴² 567. L¹¹¹ L¹⁴³ 568. L¹¹¹ L¹⁴⁴ 569. L¹¹¹ L¹⁴⁵ 570. L¹¹¹ L¹⁴⁶ 571. L¹¹¹ L¹⁴⁷ 572. L¹¹¹ L¹⁴⁸ 573. L¹¹¹ L¹⁴⁹ 574. L¹¹¹ L¹⁵⁰ 575. L¹¹¹ L¹⁵¹ 576. L¹¹¹ L¹⁵² 577. L¹¹¹ L¹⁵³ 578. L¹¹¹ L¹⁵⁴ 579. L¹¹¹ L¹⁵⁵ 580. L¹¹¹ L¹⁵⁶ 581. L¹¹¹ L¹⁵⁷ 582. L¹¹¹ L¹⁵⁸ 583. L¹¹¹ L¹⁵⁹ 584. L¹¹² L¹¹³ 585. L¹¹² L¹¹⁴ 586. L¹¹² L¹¹⁵ 587. L¹¹² L¹¹⁶ 588. L¹¹² L¹¹⁷ 589. L¹¹² L¹¹⁸ 590. L¹¹² L¹¹⁹ 591. L¹¹² L¹²⁰ 592. L¹¹² L¹²¹ 593. L¹¹² L¹²² 594. L¹¹² L¹²³ 595. L¹¹² L¹²⁴ 596. L¹¹² L¹²⁵ 597. L¹¹² L¹²⁶ 598. L¹¹² L¹²⁷ 599. L¹¹² L¹²⁸ 600. L¹¹² L¹²⁹ 601. L¹¹² L¹³⁰ 602. L¹¹² L¹³¹ 603. L¹¹² L¹³² 604. L¹¹² L¹³³ 605. L¹¹² L¹³⁴ 606. L¹¹² L¹³⁵ 607. L¹¹² L¹³⁶ 608. L¹¹² L¹³⁷ 609. L¹¹² L¹³⁸ 610. L¹¹² L¹³⁹ 611. L¹¹² L¹⁴⁰ 612. L¹¹² L¹⁴¹ 613. L¹¹² L¹⁴² 614. L¹¹² L¹⁴³ 615. L¹¹² L¹⁴⁴ 616. L¹¹² L¹⁴⁵ 617. L¹¹² L¹⁴⁶ 618. L¹¹² L¹⁴⁷ 619. L¹¹² L¹⁴⁸ 620. L¹¹² L¹⁴⁹ 621. L¹¹² L¹⁵⁰ 622. L¹¹² L¹⁵¹ 623. L¹¹² L¹⁵² 624. L¹¹² L¹⁵³ 625. L¹¹² L¹⁵⁴ 626. L¹¹² L¹⁵⁵ 627. L¹¹² L¹⁵⁶ 628. L¹¹² L¹⁵⁷ 629. L¹¹² L¹⁵⁸ 630. L¹¹² L¹⁵⁹ 631. L¹¹³ L¹¹⁴ 632. L¹¹³ L¹¹⁵ 633. L¹¹³ L¹¹⁶ 634. L¹¹³ L¹¹⁷ 635. L¹¹³ L¹¹⁸ 636. L¹¹³ L¹¹⁹ 637. L¹¹³ L¹²⁰ 638. L¹¹³ L¹²¹ 639. L¹¹³ L¹²² 640. L¹¹³ L¹²³ 641. L¹¹³ L¹²⁴ 642. L¹¹³ L¹²⁵ 643. L¹¹³ L¹²⁶ 644. L¹¹³ L¹²⁷ 645. L¹¹³ L¹²⁸ 646. L¹¹³ L¹²⁹ 647. L¹¹³ L¹³⁰ 648. L¹¹³ L¹³¹ 649. L¹¹³ L¹³² 650. L¹¹³ L¹³³ 651. L¹¹³ L¹³⁴ 652. L¹¹³ L¹³⁵ 653. L¹¹³ L¹³⁶ 654. L¹¹³ L¹³⁷ 655. L¹¹³ L¹³⁸ 656. L¹¹³ L¹³⁹ 657. L¹¹³ L¹⁴⁰ 658. L¹¹³ L¹⁴¹ 659. L¹¹³ L¹⁴² 660. L¹¹³ L¹⁴³ 661. L¹¹³ L¹⁴⁴ 662. L¹¹³ L¹⁴⁵ 663. L¹¹³ L¹⁴⁶ 664. L¹¹³ L¹⁴⁷ 665. L¹¹³ L¹⁴⁸ 666. L¹¹³ L¹⁴⁹ 667. L¹¹³ L¹⁵⁰ 668. L¹¹³ L¹⁵¹ 669. L¹¹³ L¹⁵² 670. L¹¹³ L¹⁵³ 671. L¹¹³ L¹⁵⁴ 672. L¹¹³ L¹⁵⁵ 673. L¹¹³ L¹⁵⁶ 674. L¹¹³ L¹⁵⁷ 675. L¹¹³ L¹⁵⁸ 676. L¹¹³ L¹⁵⁹ 677. L¹¹⁴ L¹¹⁵ 678. L¹¹⁴ L¹¹⁶ 679. L¹¹⁴ L¹¹⁷ 680. L¹¹⁴ L¹¹⁸ 681. L¹¹⁴ L¹¹⁹ 682. L¹¹⁴ L¹²⁰ 683. L¹¹⁴ L¹²¹ 684. L¹¹⁴ L¹²² 685. L¹¹⁴ L¹²³ 686. L¹¹⁴ L¹²⁴ 687. L¹¹⁴ L¹²⁵ 688. L¹¹⁴ L¹²⁶ 689. L¹¹⁴ L¹²⁷ 690. L¹¹⁴ L¹²⁸ 691. L¹¹⁴ L¹²⁹ 692. L¹¹⁴ L¹³⁰ 693. L¹¹⁴ L¹³¹ 694. L¹¹⁴ L¹³² 695. L¹¹⁴ L¹³³ 696. L¹¹⁴ L¹³⁴ 697. L¹¹⁴ L¹³⁵ 698. L¹¹⁴ L¹³⁶ 699. L¹¹⁴ L¹³⁷ 700. L¹¹⁴ L¹³⁸ 701. L¹¹⁴ L¹³⁹ 702. L¹¹⁴ L¹⁴⁰ 703. L¹¹⁴ L¹⁴¹ 704. L¹¹⁴ L¹⁴² 705. L¹¹⁴ L¹⁴³ 706. L¹¹⁴ L¹⁴⁴ 707. L¹¹⁴ L¹⁴⁵ 708. L¹¹⁴ L¹⁴⁶ 709. L¹¹⁴ L¹⁴⁷ 710. L¹¹⁴ L¹⁴⁸ 711. L¹¹⁴ L¹⁴⁹ 712. L¹¹⁴ L¹⁵⁰ 713. L¹¹⁴ L¹⁵¹ 714. L¹¹⁴ L¹⁵² 715. L¹¹⁴ L¹⁵³ 716. L¹¹⁴ L¹⁵⁴ 717. L¹¹⁴ L¹⁵⁵ 718. L¹¹⁴ L¹⁵⁶ 719. L¹¹⁴ L¹⁵⁷ 720. L¹¹⁴ L¹⁵⁸ 721. L¹¹⁴ L¹⁵⁹ 722. L¹¹⁵ L¹¹⁶ 723. L¹¹⁵ L¹¹⁷ 724. L¹¹⁵ L¹¹⁸ 725. L¹¹⁵ L¹¹⁹ 726. L¹¹⁵ L¹²⁰ 727. L¹¹⁵ L¹²¹ 728. L¹¹⁵ L¹²² 729. L¹¹⁵ L¹²³ 730. L¹¹⁵ L¹²⁴ 731. L¹¹⁵ L¹²⁵ 732. L¹¹⁵ L¹²⁶ 733. L¹¹⁵ L¹²⁷ 734. L¹¹⁵ L¹²⁸ 735. L¹¹⁵ L¹²⁹ 736. L¹¹⁵ L¹³⁰ 737. L¹¹⁵ L¹³¹ 738. L¹¹⁵ L¹³² 739. L¹¹⁵ L¹³³ 740. L¹¹⁵ L¹³⁴ 741. L¹¹⁵ L¹³⁵ 742. L¹¹⁵ L¹³⁶ 743. L¹¹⁵ L¹³⁷ 744. L¹¹⁵ L¹³⁸ 745. L¹¹⁵ L¹³⁹ 746. L¹¹⁵ L¹⁴⁰ 747. L¹¹⁵ L¹⁴¹ 748. L¹¹⁵ L¹⁴² 749. L¹¹⁵ L¹⁴³ 750. L¹¹⁵ L¹⁴⁴ 751. L¹¹⁵ L¹⁴⁵ 752. L¹¹⁵ L¹⁴⁶ 753. L¹¹⁵ L¹⁴⁷ 754. L¹¹⁵ L¹⁴⁸ 755. L¹¹⁵ L¹⁴⁹ 756. L¹¹⁵ L¹⁵⁰ 757. L¹¹⁵ L¹⁵¹ 758. L¹¹⁵ L¹⁵² 759. L¹¹⁵ L¹⁵³ 760. L¹¹⁵ L¹⁵⁴ 761. L¹¹⁵ L¹⁵⁵ 762. L¹¹⁵ L¹⁵⁶ 763. L¹¹⁵ L¹⁵⁷ 764. L¹¹⁵ L¹⁵⁸ 765. L¹¹⁵ L¹⁵⁹ 766. L¹¹⁶ L¹¹⁷ 767. L¹¹⁶ L¹¹⁸ 768. L¹¹⁶ L¹¹⁹ 769. L¹¹⁶ L¹²⁰ 770. L¹¹⁶ L¹²¹ 771. L¹¹⁶ L¹²² 772. L¹¹⁶ L¹²³ 773. L¹¹⁶ L¹²⁴ 774. L¹¹⁶ L¹²⁵ 775. L¹¹⁶ L¹²⁶ 776. L¹¹⁶ L¹²⁷ 777. L¹¹⁶ L¹²⁸ 778. L¹¹⁶ L¹²⁹ 779. L¹¹⁶ L¹³⁰ 780. L¹¹⁶ L¹³¹ 781. L¹¹⁶ L¹³² 782. L¹¹⁶ L¹³³ 783. L¹¹⁶ L¹³⁴ 784. L¹¹⁶ L¹³⁵ 785. L¹¹⁶ L¹³⁶ 786. L¹¹⁶ L¹³⁷ 787. L¹¹⁶ L¹³⁸ 788. L¹¹⁶ L¹³⁹ 789. L¹¹⁶ L¹⁴⁰ 790. L¹¹⁶ L¹⁴¹ 791. L¹¹⁶ L¹⁴² 792. L¹¹⁶ L¹⁴³ 793. L¹¹⁶ L¹⁴⁴ 794. L¹¹⁶ L¹⁴⁵ 795. L¹¹⁶ L¹⁴⁶ 796. L¹¹⁶ L¹⁴⁷ 797. L¹¹⁶ L¹⁴⁸ 798. L¹¹⁶ L¹⁴⁹ 799. L¹¹⁶ L¹⁵⁰ 800. L¹¹⁶ L¹⁵¹ 801. L¹¹⁶ L¹⁵² 802. L¹¹⁶ L¹⁵³ 803. L¹¹⁶ L¹⁵⁴ 804. L¹¹⁶ L¹⁵⁵ 805. L¹¹⁶ L¹⁵⁶ 806. L¹¹⁶ L¹⁵⁷ 807. L¹¹⁶ L¹⁵⁸ 808. L¹¹⁶ L¹⁵⁹ 809. L¹¹⁷ L¹¹⁸ 810. L¹¹⁷ L¹¹⁹ 811. L¹¹⁷ L¹²⁰ 812. L¹¹⁷ L¹²¹ 813. L¹¹⁷ L¹²² 814. L¹¹⁷ L¹²³ 815. L¹¹⁷ L¹²⁴ 816. L¹¹⁷ L¹²⁵ 817. L¹¹⁷ L¹²⁶ 818. L¹¹⁷ L¹²⁷ 819. L¹¹⁷ L¹²⁸ 820. L¹¹⁷ L¹²⁹ 821. L¹¹⁷ L¹³⁰ 822. L¹¹⁷ L¹³¹ 823. L¹¹⁷ L¹³² 824. L¹¹⁷ L¹³³ 825. L¹¹⁷ L¹³⁴ 826. L¹¹⁷ L¹³⁵ 827. L¹¹⁷ L¹³⁶ 828. L¹¹⁷ L¹³⁷ 829. L¹¹⁷ L¹³⁸ 830. L¹¹⁷ L¹³⁹ 831. L¹¹⁷ L¹⁴⁰ 832. L¹¹⁷ L¹⁴¹ 833. L¹¹⁷ L¹⁴² 834. L¹¹⁷ L¹⁴³ 835. L¹¹⁷ L¹⁴⁴ 836. L¹¹⁷ L¹⁴⁵ 837. L¹¹⁷ L¹⁴⁶ 838. L¹¹⁷ L¹⁴⁷ 839. L¹¹⁷ L¹⁴⁸ 840. L¹¹⁷ L¹⁴⁹ 841. L¹¹⁷ L¹⁵⁰ 842. L¹¹⁷ L¹⁵¹ 843. L¹¹⁷ L¹⁵² 844. L¹¹⁷ L¹⁵³ 845. L¹¹⁷ L¹⁵⁴ 846. L¹¹⁷ L¹⁵⁵ 847. L¹¹⁷ L¹⁵⁶ 848. L¹¹⁷ L¹⁵⁷ 849. L¹¹⁷ L¹⁵⁸ 850. L¹¹⁷ L¹⁵⁹ 851. L¹¹⁸ L¹¹⁹ 852. L¹¹⁸ L¹²⁰ 853. L¹¹⁸ L¹²¹ 854. L¹¹⁸ L¹²² 855. L¹¹⁸ L¹²³ 856. L¹¹⁸ L¹²⁴ 857. L¹¹⁸ L¹²⁵ 858. L¹¹⁸ L¹²⁶ 859. L¹¹⁸ L¹²⁷ 860. L¹¹⁸ L¹²⁸ 861. L¹¹⁸ L¹²⁹ 862. L¹¹⁸ L¹³⁰ 863. L¹¹⁸ L¹³¹ 864. L¹¹⁸ L¹³² 865. L¹¹⁸ L¹³³ 866. L¹¹⁸ L¹³⁴ 867. L¹¹⁸ L¹³⁵ 868. L¹¹⁸ L¹³⁶ 869. L¹¹⁸ L¹³⁷ 870. L¹¹⁸ L¹³⁸ 871. L¹¹⁸ L¹³⁹ 872. L¹¹⁸ L¹⁴⁰ 873. L¹¹⁸ L¹⁴¹ 874. L¹¹⁸ L¹⁴² 875. L¹¹⁸ L¹⁴³ 876. L¹¹⁸ L¹⁴⁴ 877. L¹¹⁸ L¹⁴⁵ 878. L¹¹⁸ L¹⁴⁶ 879. L¹¹⁸ L¹⁴⁷ 880. L¹¹⁸ L¹⁴⁸ 881. L¹¹⁸ L¹⁴⁹ 882. L¹¹⁸ L¹⁵⁰ 883. L¹¹⁸ L¹⁵¹ 884. L¹¹⁸ L¹⁵² 885. L¹¹⁸ L¹⁵³ 886. L¹¹⁸ L¹⁵⁴ 887. L¹¹⁸ L¹⁵⁵ 888. L¹¹⁸ L¹⁵⁶ 889. L¹¹⁸ L¹⁵⁷ 890. L¹¹⁸ L¹⁵⁸ 891. L¹¹⁸ L¹⁵⁹ 892. L¹¹⁹ L¹²⁰ 893. L¹¹⁹ L¹²¹ 894. L¹¹⁹ L¹²² 895. L¹¹⁹ L¹²³ 896. L¹¹⁹ L¹²⁴ 897. L¹¹⁹ L¹²⁵ 898. L¹¹⁹ L¹²⁶ 899. L¹¹⁹ L¹²⁷ 900. L¹¹⁹ L¹²⁸ 901. L¹¹⁹ L¹²⁹ 902. L¹¹⁹ L¹³⁰ 903. L¹¹⁹ L¹³¹ 904. L¹¹⁹ L¹³² 905. L¹¹⁹ L¹³³ 906. L¹¹⁹ L¹³⁴ 907. L¹¹⁹ L¹³⁵ 908. L¹¹⁹ L¹³⁶ 909. L¹¹⁹ L¹³⁷ 910. L¹¹⁹ L¹³⁸ 911. L¹¹⁹ L¹³⁹ 912. L¹¹⁹ L¹⁴⁰ 913. L¹¹⁹ L¹⁴¹ 914. L¹¹⁹ L¹⁴² 915. L¹¹⁹ L¹⁴³ 916. L¹¹⁹ L¹⁴⁴ 917. L¹¹⁹ L¹⁴⁵ 918. L¹¹⁹ L¹⁴⁶ 919. L¹¹⁹ L¹⁴⁷ 920. L¹¹⁹ L¹⁴⁸ 921. L¹¹⁹ L¹⁴⁹ 922. L¹¹⁹ L¹⁵⁰ 923. L¹¹⁹ L¹⁵¹ 924. L¹¹⁹ L¹⁵² 925. L¹¹⁹ L¹⁵³ 926. L¹¹⁹ L¹⁵⁴ 927. L¹¹⁹ L¹⁵⁵ 928. L¹¹⁹ L¹⁵⁶ 929. L¹¹⁹ L¹⁵⁷ 930. L¹¹⁹ L¹⁵⁸ 931. L¹¹⁹ L¹⁵⁹ 932. L¹²⁰ L¹²¹ 933. L¹²⁰ L¹²² 934. L¹²⁰ L¹²³ 935. L¹²⁰ L¹²⁴ 936. L¹²⁰ L¹²⁵ 937. L¹²⁰ L¹²⁶ 938. L¹²⁰ L¹²⁷ 939. L¹²⁰ L¹²⁸ 940. L¹²⁰ L¹²⁹ 941. L¹²⁰ L¹³⁰ 942. L¹²⁰ L¹³¹ 943. L¹²⁰ L¹³² 944. L¹²⁰ L¹³³ 945. L¹²⁰ L¹³⁴ 946. L¹²⁰ L¹³⁵ 947. L¹²⁰ L¹³⁶ 948. L¹²⁰ L¹³⁷ 949. L¹²⁰ L¹³⁸ 950. L¹²⁰ L¹³⁹ 951. L¹²⁰ L¹⁴⁰ 952. L¹²⁰ L¹⁴¹ 953. L¹²⁰ L¹⁴² 954. L¹²⁰ L¹⁴³ 955. L¹²⁰ L¹⁴⁴ 956. L¹²⁰ L¹⁴⁵ 957. L¹²⁰ L¹⁴⁶ 958. L¹²⁰ L¹⁴⁷ 959. L¹²⁰ L¹⁴⁸ 960. L¹²⁰ L¹⁴⁹ 961. L¹²⁰ L¹⁵⁰ 962. L¹²⁰ L¹⁵¹ 963. L¹²⁰ L¹⁵² 964. L¹²⁰ L¹⁵³ 965. L¹²⁰ L¹⁵⁴ 966. L¹²⁰ L¹⁵⁵ 967. L¹²⁰ L¹⁵⁶ 968. L¹²⁰ L¹⁵⁷ 969. L¹²⁰ L¹⁵⁸ 970. L¹²⁰ L¹⁵⁹ 971. L¹²¹ L¹²² 972. L¹²¹ L¹²³ 973. L¹²¹ L¹²⁴ 974. L¹²¹ L¹²⁵ 975. L¹²¹ L¹²⁶ 976. L¹²¹ L¹²⁷ 977. L¹²¹ L¹²⁸ 978. L¹²¹ L¹²⁹ 979. L¹²¹ L¹³⁰ 980. L¹²¹ L¹³¹ 981. L¹²¹ L¹³² 982. L¹²¹ L¹³³ 983. L¹²¹ L¹³⁴ 984. L¹²¹ L¹³⁵ 985. L¹²¹ L¹³⁶ 986. L¹²¹ L¹³⁷ 987. L¹²¹ L¹³⁸ 988. L¹²¹ L¹³⁹ 989. L¹²¹ L¹⁴⁰ 990. L¹²¹ L¹⁴¹ 991. L¹²¹ L¹⁴² 992. L¹²¹ L¹⁴³ 993. L¹²¹ L¹⁴⁴ 994. L¹²¹ L¹⁴⁵ 995. L¹²¹ L¹⁴⁶ 996. L¹²¹ L¹⁴⁷ 997. L¹²¹ L¹⁴⁸ 998. L¹²¹ L¹⁴⁹ 999. L¹²¹ L¹⁵⁰ 1000. L¹²¹ L¹⁵¹ 1001. L¹²¹ L¹⁵² 1002. L¹²¹ L¹⁵³ 1003. L¹²¹ L¹⁵⁴ 1004. L¹²¹ L¹⁵⁵ 1005. L¹²¹ L¹⁵⁶ 1006. L¹²¹ L¹⁵⁷ 1007. L¹²¹ L¹⁵⁸ 1008. L¹²¹ L¹⁵⁹ 1009. L¹²² L¹²³ 1010. L¹²² L¹²⁴ 1011. L¹²² L¹²⁵ 1012. L¹²² L¹²⁶ 1013. L¹²² L¹²⁷ 1014. L¹²² L¹²⁸ 1015. L¹²² L¹²⁹ 1016. L¹²² L¹³⁰ 1017. L¹²² L¹³¹ 1018. L¹²² L¹³² 1019. L¹²² L¹³³ 1020. L¹²² L¹³⁴ 1021. L¹²² L¹³⁵ 1022. L¹²² L¹³⁶ 1023. L¹²² L¹³⁷ 1024. L¹²² L¹³⁸ 1025. L¹²² L¹³⁹ 1026. L¹²² L¹⁴⁰ 1027. L¹²² L¹⁴¹ 1028. L¹²² L¹⁴² 1029. L¹²² L¹⁴³ 1030. L¹²² L¹⁴⁴ 1031. L¹²² L¹⁴⁵ 1032. L¹²² L¹⁴⁶ 1033. L¹²² L¹⁴⁷ 1034. L¹²² L¹⁴⁸ 1035. L¹²² L¹⁴⁹ 1036. L¹²² L¹⁵⁰ 1037. L¹²² L¹⁵¹ 1038. L¹²² L¹⁵² 1039. L¹²² L¹⁵³ 1040. L¹²² L¹⁵⁴ 1041. L¹²² L¹⁵⁵ 1042. L¹²² L¹⁵⁶ 1043. L¹²² L¹⁵⁷ 1044. L¹²² L¹⁵⁸ 1045. L¹²² L¹⁵⁹ 1046. L¹²³ L¹²⁴ 1047. L¹²³ L¹²⁵ 1048. L¹²³ L¹²⁶ 1049. L¹²³ L¹²⁷ 1050. L¹²³ L¹²⁸ 1051. L¹²³ L¹²⁹ 1052. L¹²³ L¹³⁰ 1053. L¹²³ L¹³¹ 1054. L¹²³ L¹³² 1055. L¹²³ L¹³³ 1056. L¹²³ L¹³⁴ 1057. L¹²³ L¹³⁵ 1058. L¹²³ L¹³⁶ 1059. L¹²³ L¹³⁷ 1060. L¹²³ L¹³⁸ 1061. L¹²³ L¹³⁹ 1062. L¹²³ L¹⁴⁰ 1063. L¹²³ L¹⁴¹ 1064. L¹²³ L¹⁴² 1065. L¹²³ L¹⁴³ 1066. L¹²³ L¹⁴⁴ 1067. L¹²³ L¹⁴⁵ 1068. L¹²³ L¹⁴⁶ 1069. L¹²³ L¹⁴⁷ 1070. L¹²³ L¹⁴⁸ 1071. L¹²³ L¹⁴⁹ 1072. L¹²³ L¹⁵⁰ 1073. L¹²³ L¹⁵¹ 1074. L¹²³ L¹⁵² 1075. L¹²³ L¹⁵³ 1076. L¹²³ L¹⁵⁴ 1077. L¹²³ L¹⁵⁵ 1078. L¹²³ L¹⁵⁶ 1079. L¹²³ L¹⁵⁷ 1080. L¹²³ L¹⁵⁸ 1081. L¹²³ L¹⁵⁹ 1082. L¹²⁴ L¹²⁵ 1083. L¹²⁴ L¹²⁶ 1084. L¹²⁴ L¹²⁷ 1085. L¹²⁴ L¹²⁸ 1086. L¹²⁴ L¹²⁹ 1087. L¹²⁴ L¹³⁰ 1088. L¹²⁴ L¹³¹ 1089. L¹²⁴ L¹³² 1090. L¹²⁴ L¹³³ 1091. L¹²⁴ L¹³⁴ 1092. L¹²⁴ L¹³⁵ 1093. L¹²⁴ L¹³⁶ 1094. L¹²⁴ L¹³⁷ 1095. L¹²⁴ L¹³⁸ 1096. L¹²⁴ L¹³⁹ 1097. L¹²⁴ L¹⁴⁰ 1098. L¹²⁴ L¹⁴¹ 1099. L¹²⁴ L¹⁴² 1100. L¹²⁴ L¹⁴³ 1101. L¹²⁴ L¹⁴⁴ 1102. L¹²⁴ L¹⁴⁵ 1103. L¹²⁴ L¹⁴⁶ 1104. L¹²⁴ L¹⁴⁷ 1105. L¹²⁴ L¹⁴⁸ 1106. L¹²⁴ L¹⁴⁹ 1107. L¹²⁴ L¹⁵⁰ 1108. L¹²⁴ L¹⁵¹ 1109. L¹²⁴ L¹⁵² 1110. L¹²⁴ L¹⁵³ 1111. L¹²⁴ L¹⁵⁴ 1112. L¹²⁴ L¹⁵⁵ 1113. L¹²⁴ L¹⁵⁶ 1114. L¹²⁴ L¹⁵⁷ 1115. L¹²⁴ L¹⁵⁸ 1116. L¹²⁴ L¹⁵⁹ 1117. L¹²⁵ L¹²⁶ 1118. L¹²⁵ L¹²⁷ 1119. L¹²⁵ L¹²⁸ 1120. L¹²⁵ L¹²⁹ 1121. L¹²⁵ L¹³⁰ 1122. L¹²⁵ L¹³¹ 1123. L¹²⁵ L¹³² 1124. L¹²⁵ L¹³³ 1125. L¹²⁵ L¹³⁴ 1126. L¹²⁵ L¹³⁵ 1127. L¹²⁵ L¹³⁶ 1128. L¹²⁵ L¹³⁷ 1129. L¹²⁵ L¹³⁸ 1130. L¹²⁵ L¹³⁹ 1131. L¹²⁵ L¹⁴⁰ 1132. L¹²⁵ L¹⁴¹ 1133. L¹²⁵ L¹⁴² 1134. L¹²⁵ L¹⁴³ 1135. L¹²⁵ L¹⁴⁴ 1136. L¹²⁵ L¹⁴⁵ 1137. L¹²⁵ L¹⁴⁶ 1138. L¹²⁵ L¹⁴⁷ 1139. L¹²⁵ L¹⁴⁸ 1140. L¹²⁵ L¹⁴⁹ 1141. L¹²⁵ L¹⁵⁰ 1142. L¹²⁵ L¹⁵¹ 1143. L¹²⁵ L¹⁵² 1144. L¹²⁵ L¹⁵³ 1145. L¹²⁵ L¹⁵⁴ 1146. L¹²⁵ L¹⁵⁵ 1147. L¹²⁵ L¹⁵⁶ 1148. L¹²⁵ L¹⁵⁷ 1149. L¹²⁵ L¹⁵⁸ 1150. L¹²⁵ L¹⁵⁹

In one embodiment, a first device comprising a first organic light emitting device is disclosed. The first organic light emitting device comprises an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the structure according Formula I, L¹-Os-L²; wherein L¹and L²are different; wherein L¹and L²are independently selected from ligands having Formula II:

wherein Y¹, Y²and Y³comprise C or N; wherein R³and R⁴may represent mono-, or di-substitutions, or no substitution; wherein R⁵may represent mono-, di-, or tri-substitutions, or no substitution; wherein R¹and R²are independently selected from the group consisting of alkyl and cycloalkyl; wherein R³, R⁴and R⁵are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, aralkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combinations thereof; wherein any two adjacent substituents of R¹, R², R³, R⁴and R⁵are optionally joined to condense into a fused ring; and wherein the dash lines show the connection points to osmium.

In one embodiment of the first device, Y¹, Y²and Y³comprise C. In one embodiment, Y¹, Y²and Y³are N. In one embodiment, R¹and R²are independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, partially or fully deuterated variants thereof, and combinations thereof.

In some embodiments of the first device, L¹and L²are independently selected from ligands having Formula III:

wherein X¹, X², X³, X⁴, X⁵, X⁶, X⁷and X⁸comprise C or N. In some embodiments, X¹, X², X³, X⁴, X⁵, X⁶, X⁷and X⁸comprise C.

In some embodiments of the first device, the ligands having Formula II are selected from the group consisting of L¹⁰¹to L¹⁵⁹defined herein.

In some embodiments of the first device, the first emitting compound is selected from the group consisting of Compounds 1 to 1159 defined in Table 1.

The first device can be one or more of a consumer product, an organic light-emitting device, and/or a lighting panel.

The organic layer in the organic light emitting device can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.

The organic layer can also include a host. In some embodiments, the host can include a metal complex. In one embodiment, the host can be a metal 8-hydroxyquinolate. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of C_nH_2n+1, OC_nH₂₊₁, OAr₁, N(C_nH₂₊₁)₂, N(Ar₁)(Ar₂), CH═CH—C_nH_2n+1, C≡C—C_nH₂₊₁, Ar₁, Ar₁—Ar₂, C_nH_2n—Ar₁, or no substitution. In the preceding substituents n can range from 1 to 10; and Ar₁and Ar₂can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.

The host can be a compound selected from the group consisting of carbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The “aza” designation in the fragments described above, i.e., aza-dibenzofuran, aza-dibenzonethiophene, etc., means that one or more of the C—H groups in the respective fragment can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein. The host can include a metal complex. The host can be a specific compound selected from the group consisting of:

and combinations thereof.

In yet another aspect of the present disclosure, a formulation comprising the compound having a structure according to Formula I, L¹-Os-L², as defined herein, is disclosed. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, and an electron transport layer material, disclosed herein.

Combination with Other Materials

The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

HIL/HTL:

A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but not limit to: a phthalocyanine or porphryin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO_x; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:

Each of Ar¹to Ar⁹is selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each Ar is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, Ar¹to Ar⁹is independently selected from the group consisting of:

wherein k is an integer from 1 to 20; X¹⁰¹to X¹⁰⁸is C (including CH) or N; Z¹⁰¹is NAr¹, O, or S; Ar¹has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but not limit to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40; (Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹and Y¹⁰²are independently selected from C, N, O, P, and S; L¹⁰¹is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In another aspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc⁺/Fc couple less than about 0.6 V.

Host:

The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. While the Table below categorizes host materials as preferred for devices that emit various colors, any host material may be used with any dopant so long as the triplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have the following general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³and Y¹⁰⁴are independently selected from C, N, O, P, and S; L¹⁰¹is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

Examples of organic compounds used as host are selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each group is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, host compound contains at least one of the following groups in the molecule:

wherein R¹⁰¹to R¹⁰⁷is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20; k′″ is an integer from 0 to 20. X¹⁰¹to X¹⁰⁸is selected from C (including CH) or N. Z¹⁰¹and Z¹⁰²is selected from NR¹⁰¹, O, or S.

HBL:

A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED.

In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of the following groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹is an another ligand, k′ is an integer from 1 to 3.

ETL:

Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.

In one aspect, compound used in ETL contains at least one of the following groups in the molecule:

wherein R¹⁰¹is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar¹to Ar³has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹to X¹⁰⁸is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N,N; L¹⁰¹is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. encompasses undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also encompass undeuterated, partially deuterated, and fully deuterated versions thereof.

In addition to and/or in combination with the materials disclosed herein, many hole injection materials, hole transporting materials, host materials, dopant materials, exiton/hole blocking layer materials, electron transporting and electron injecting materials may be used in an OLED. Non-limiting examples of the materials that may be used in an OLED in combination with materials disclosed herein are listed in Table 2 below. Table 2 lists non-limiting classes of materials, non-limiting examples of compounds for each class, and references that disclose the materials.

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It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.

Claims

1. A method of making an osmium(II) complex having Formula I

L1-Os-L2, wherein L1 and L2 are independently a biscarbene tridentate ligand, wherein L1 and L2 can be same or different, said method comprising:

(a) reacting a precursor of ligand L1 with an osmium precursor to form an intermediate product, wherein the osmium precursor having the formula OsHx(PR3)y, wherein x is an integer from 2 to 6 and y is an integer from 2 to 5, and R is selected from the group consisting of aryl, alkyl and cycloalkyl; and

(b) reacting a precursor of ligand L2 with said intermediate product.

2. The method of claim 1, wherein L1 and L2 are monoanionic ligands.

3. The method of claim 1, wherein L1 and L2 are independently selected from ligands having Formula II:

wherein Y1, Y2 and Y3 comprise C or N;

wherein R3 and R4 may represent mono-, or di-substitutions, or no substitution;

wherein R5 may represent mono-, di-, or tri-substitutions, or no substitution;

wherein R1, R2, R3, R4 and R5 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;

wherein any two adjacent substituents of R1, R2, R3, R4 and R5 are optionally joined to form a ring; and

wherein the dash lines show the connection points to osmium.

4. The method of claim 3, wherein Y1, Y2 and Y3 comprise C.

5. The method of claim 3, wherein Y1 and Y3 comprise C, and Y2 is N.

6. The method of claim 3, wherein Y1 and Y3 are N, and Y2 comprise C.

7. The method of claim 3, wherein R1 and R2 are independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and partially or fully deuterated variants thereof.

8. The method of claim 3, wherein R1 and R2 are independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, partially or fully deuterated variants thereof, and combinations thereof.

9. The method of claim 1, wherein R is selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, cyclohexyl, phenyl, 2,6-dimethylphenyl, and 2-methylphenyl.

10. The method of claim 1, wherein R is 1-methylethyl.

11. The method of claim 3, wherein the ligands having Formula II are selected from the group consisting of:

12. A compound having a structure according to Formula I:

L1-Os-L2

wherein L1 and L2 are different;

wherein L1 and L2 are independently selected from ligands having Formula II:

wherein Y1, Y2 and Y3 comprise C or N;

wherein R3 and R4 may represent mono-, or di-substitutions, or no substitution;

wherein R5 may represent mono-, di-, or tri-substitutions, or no substitution;

wherein R1 and R2 are independently selected from the group consisting of alkyl and cycloalkyl;

wherein R3, R4 and R5 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, aralkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combinations thereof;

wherein any two adjacent substituents of R1, R2, R3, R4 and R5 are optionally joined to condense into a fused ring; and

wherein the dash lines show the connection points to osmium.

13. The compound of claim 12, wherein Y1, Y2 and Y3 comprise C.

14. The compound of claim 12, wherein Y1 and Y3 comprise C, and Y2 is N.

15. The compound of claim 12, wherein Y1 and Y3 are N, and Y2 comprise C.

16. The compound of claim 12, wherein R1 and R2 are independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and partially or fully deuterated variants thereof.

17. The compound of claim 12, wherein R1 and R2 are independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, partially or fully deuterated variants thereof, and combinations thereof.

18. The compound of claim 12, wherein L1 and L2 are independently selected from ligands having Formula III:

wherein X1, X2, X3, X4, X5, X6, X7 and X8 comprise C or N.

19. The compound of claim 18, wherein X1, X2, X3, X4, X5, X6, X7 and X8 comprise C.

20. The compound of claim 12, wherein the ligands having Formula II are selected from the group consisting of:

21. The compound of claim 12, wherein the compound is selected from the group consisting of Compounds 1 to 1150 defined in the table below: Compound Number L1 L2 1. L101 L102 2. L101 L103 3. L101 L104 4. L101 L105 5. L101 L106 6. L101 L107 7. L101 L108 8. L101 L109 9. L101 L110 10. L101 L111 11. L101 L112 12. L101 L113 13. L101 L114 14. L101 L115 15. L101 L116 16. L101 L117 17. L101 L118 18. L101 L119 19. L101 L120 20. L101 L121 21. L101 L122 22. L101 L123 23. L101 L124 24. L101 L125 25. L101 L126 26. L101 L127 27. L101 L128 28. L101 L129 29. L101 L130 30. L101 L131 31. L101 L132 32. L101 L133 33. L101 L134 34. L101 L135 35. L101 L136 36. L101 L137 37. L101 L138 38. L101 L139 39. L101 L140 40. L101 L141 41. L101 L142 42. L101 L143 43. L101 L144 44. L101 L145 45. L101 L146 46. L101 L147 47. L101 L148 48. L101 L149 49. L101 L150 50. L101 L151 51. L101 L152 52. L101 L153 53. L101 L154 54. L101 L155 55. L101 L156 56. L101 L157 57. L101 L158 58. L101 L159 59. L102 L103 60. L102 L104 61. L102 L105 62. L102 L106 63. L102 L107 64. L102 L108 65. L102 L109 66. L102 L110 67. L102 L111 68. L102 L112 69. L102 L113 70. L102 L114 71. L102 L115 72. L102 L116 73. L102 L117 74. L102 L118 75. L102 L119 76. L102 L120 77. L102 L121 78. L102 L122 79. L102 L123 80. L102 L124 81. L102 L125 82. L102 L126 83. L102 L127 84. L102 L128 85. L102 L129 86. L102 L130 87. L102 L131 88. L102 L132 89. L102 L133 90. L102 L134 91. L102 L135 92. L102 L136 93. L102 L137 94. L102 L138 95. L102 L139 96. L102 L140 97. L102 L141 98. L102 L142 99. L102 L143 100. L102 L144 101. L102 L145 102. L102 L146 103. L102 L147 104. L102 L148 105. L102 L149 106. L102 L150 107. L102 L151 108. L102 L152 109. L102 L153 110. L102 L154 111. L102 L155 112. L102 L156 113. L102 L157 114. L102 L158 115. L102 L159 116. L103 L104 117. L103 L105 118. L103 L106 119. L103 L107 120. L103 L108 121. L103 L109 122. L103 L110 123. L103 L111 124. L103 L112 125. L103 L113 126. L103 L114 127. L103 L115 128. L103 L116 129. L103 L117 130. L103 L118 131. L103 L119 132. L103 L120 133. L103 L121 134. L103 L122 135. L103 L123 136. L103 L124 137. L103 L125 138. L103 L126 139. L103 L127 140. L103 L128 141. L103 L129 142. L103 L130 143. L103 L131 144. L103 L132 145. L103 L133 146. L103 L134 147. L103 L135 148. L103 L136 149. L103 L137 150. L103 L138 151. L103 L139 152. L103 L140 153. L103 L141 154. L103 L142 155. L103 L143 156. L103 L144 157. L103 L145 158. L103 L146 159. L103 L147 160. L103 L148 161. L103 L149 162. L103 L150 163. L103 L151 164. L103 L152 165. L103 L153 166. L103 L154 167. L103 L155 168. L103 L156 169. L103 L157 170. L103 L158 171. L103 L159 172. L104 L105 173. L104 L106 174. L104 L107 175. L104 L108 176. L104 L109 177. L104 L110 178. L104 L111 179. L104 L112 180. L104 L113 181. L104 L114 182. L104 L115 183. L104 L116 184. L104 L117 185. L104 L118 186. L104 L119 187. L104 L120 188. L104 L121 189. L104 L122 190. L104 L123 191. L104 L124 192. L104 L125 193. L104 L126 194. L104 L127 195. L104 L128 196. L104 L129 197. L104 L130 198. L104 L131 199. L104 L132 200. L104 L133 201. L104 L134 202. L104 L135 203. L104 L136 204. L104 L137 205. L104 L138 206. L104 L139 207. L104 L140 208. L104 L141 209. L104 L142 210. L104 L143 211. L104 L144 212. L104 L145 213. L104 L146 214. L104 L147 215. L104 L148 216. L104 L149 217. L104 L150 218. L104 L151 219. L104 L152 220. L104 L153 221. L104 L154 222. L104 L155 223. L104 L156 224. L104 L157 225. L104 L158 226. L104 L159 227. L105 L106 228. L105 L107 229. L105 L108 230. L105 L109 231. L105 L110 232. L105 L111 233. L105 L112 234. L105 L113 235. L105 L114 236. L105 L115 237. L105 L116 238. L105 L117 239. L105 L118 240. L105 L119 241. L105 L120 242. L105 L121 243. L105 L122 244. L105 L123 245. L105 L124 246. L105 L125 247. L105 L126 248. L105 L127 249. L105 L128 250. L105 L129 251. L105 L130 252. L105 L131 253. L105 L132 254. L105 L133 255. L105 L134 256. L105 L135 257. L105 L136 258. L105 L137 259. L105 L138 260. L105 L139 261. L105 L140 262. L105 L141 263. L105 L142 264. L105 L143 265. L105 L144 266. L105 L145 267. L105 L146 268. L105 L147 269. L105 L148 270. L105 L149 271. L105 L150 272. L105 L151 273. L105 L152 274. L105 L153 275. L105 L154 276. L105 L155 277. L105 L156 278. L105 L157 279. L105 L158 280. L105 L159 281. L106 L107 282. L106 L108 283. L106 L109 284. L106 L110 285. L106 L111 286. L106 L112 287. L106 L113 288. L106 L114 289. L106 L115 290. L106 L116 291. L106 L117 292. L106 L118 293. L106 L119 294. L106 L120 295. L106 L121 296. L106 L122 297. L106 L123 298. L106 L124 299. L106 L125 300. L106 L126 301. L106 L127 302. L106 L128 303. L106 L129 304. L106 L130 305. L106 L131 306. L106 L132 307. L106 L133 308. L106 L134 309. L106 L135 310. L106 L136 311. L106 L137 312. L106 L138 313. L106 L139 314. L106 L140 315. L106 L141 316. L106 L142 317. L106 L143 318. L106 L144 319. L106 L145 320. L106 L146 321. L106 L147 322. L106 L148 323. L106 L149 324. L106 L150 325. L106 L151 326. L106 L152 327. L106 L153 328. L106 L154 329. L106 L155 330. L106 L156 331. L106 L157 332. L106 L158 333. L106 L159 334. L107 L108 335. L107 L109 336. L107 L110 337. L107 L111 338. L107 L112 339. L107 L113 340. L107 L114 341. L107 L115 342. L107 L116 343. L107 L117 344. L107 L118 345. L107 L119 346. L107 L120 347. L107 L121 348. L107 L122 349. L107 L123 350. L107 L124 351. L107 L125 352. L107 L126 353. L107 L127 354. L107 L128 355. L107 L129 356. L107 L130 357. L107 L131 358. L107 L132 359. L107 L133 360. L107 L134 361. L107 L135 362. L107 L136 363. L107 L137 364. L107 L138 365. L107 L139 366. L107 L140 367. L107 L141 368. L107 L142 369. L107 L143 370. L107 L144 371. L107 L145 372. L107 L146 373. L107 L147 374. L107 L148 375. L107 L149 376. L107 L150 377. L107 L151 378. L107 L152 379. L107 L153 380. L107 L154 381. L107 L155 382. L107 L156 383. L107 L157 384. L107 L158 385. L107 L159 386. L108 L109 387. L108 L110 388. L108 L111 389. L108 L112 390. L108 L113 391. L108 L114 392. L108 L115 393. L108 L116 394. L108 L117 395. L108 L118 396. L108 L119 397. L108 L120 398. L108 L121 399. L108 L122 400. L108 L123 401. L108 L124 402. L108 L125 403. L108 L126 404. L108 L127 405. L108 L128 406. L108 L129 407. L108 L130 408. L108 L131 409. L108 L132 410. L108 L133 411. L108 L134 412. L108 L135 413. L108 L136 414. L108 L137 415. L108 L138 416. L108 L139 417. L108 L140 418. L108 L141 419. L108 L142 420. L108 L143 421. L108 L144 422. L108 L145 423. L108 L146 424. L108 L147 425. L108 L148 426. L108 L149 427. L108 L150 428. L108 L151 429. L108 L152 430. L108 L153 431. L108 L154 432. L108 L155 433. L108 L156 434. L108 L157 435. L108 L158 436. L108 L159 437. L109 L110 438. L109 L111 439. L109 L112 440. L109 L113 441. L109 L114 442. L109 L115 443. L109 L116 444. L109 L117 445. L109 L118 446. L109 L119 447. L109 L120 448. L109 L121 449. L109 L122 450. L109 L123 451. L109 L124 452. L109 L125 453. L109 L126 454. L109 L127 455. L109 L128 456. L109 L129 457. L109 L130 458. L109 L131 459. L109 L132 460. L109 L133 461. L109 L134 462. L109 L135 463. L109 L136 464. L109 L137 465. L109 L138 466. L109 L139 467. L109 L140 468. L109 L141 469. L109 L142 470. L109 L143 471. L109 L144 472. L109 L145 473. L109 L146 474. L109 L147 475. L109 L148 476. L109 L149 477. L109 L150 478. L109 L151 479. L109 L152 480. L109 L153 481. L109 L154 482. L109 L155 483. L109 L156 484. L109 L157 485. L109 L158 486. L109 L159 487. L110 L111 488. L110 L112 489. L110 L113 490. L110 L114 491. L110 L115 492. L110 L116 493. L110 L117 494. L110 L118 495. L110 L119 496. L110 L120 497. L110 L121 498. L110 L122 499. L110 L123 500. L110 L124 501. L110 L125 502. L110 L126 503. L110 L127 504. L110 L128 505. L110 L129 506. L110 L130 507. L110 L131 508. L110 L132 509. L110 L133 510. L110 L134 511. L110 L135 512. L110 L136 513. L110 L137 514. L110 L138 515. L110 L139 516. L110 L140 517. L110 L141 518. L110 L142 519. L110 L143 520. L110 L144 521. L110 L145 522. L110 L146 523. L110 L147 524. L110 L148 525. L110 L149 526. L110 L150 527. L110 L151 528. L110 L152 529. L110 L153 530. L110 L154 531. L110 L155 532. L110 L156 533. L110 L157 534. L110 L158 535. L110 L159 536. L111 L112 537. L111 L113 538. L111 L114 539. L111 L115 540. L111 L116 541. L111 L117 542. L111 L118 543. L111 L119 544. L111 L120 545. L111 L121 546. L111 L122 547. L111 L123 548. L111 L124 549. L111 L125 550. L111 L126 551. L111 L127 552. L111 L128 553. L111 L129 554. L111 L130 555. L111 L131 556. L111 L132 557. L111 L133 558. L111 L134 559. L111 L135 560. L111 L136 561. L111 L137 562. L111 L138 563. L111 L139 564. L111 L140 565. L111 L141 566. L111 L142 567. L111 L143 568. L111 L144 569. L111 L145 570. L111 L146 571. L111 L147 572. L111 L148 573. L111 L149 574. L111 L150 575. L111 L151 576. L111 L152 577. L111 L153 578. L111 L154 579. L111 L155 580. L111 L156 581. L111 L157 582. L111 L158 583. L111 L159 584. L112 L113 585. L112 L114 586. L112 L115 587. L112 L116 588. L112 L117 589. L112 L118 590. L112 L119 591. L112 L120 592. L112 L121 593. L112 L122 594. L112 L123 595. L112 L124 596. L112 L125 597. L112 L126 598. L112 L127 599. L112 L128 600. L112 L129 601. L112 L130 602. L112 L131 603. L112 L132 604. L112 L133 605. L112 L134 606. L112 L135 607. L112 L136 608. L112 L137 609. L112 L138 610. L112 L139 611. L112 L140 612. L112 L141 613. L112 L142 614. L112 L143 615. L112 L144 616. L112 L145 617. L112 L146 618. L112 L147 619. L112 L148 620. L112 L149 621. L112 L150 622. L112 L151 623. L112 L152 624. L112 L153 625. L112 L154 626. L112 L155 627. L112 L156 628. L112 L157 629. L112 L158 630. L112 L159 631. L113 L114 632. L113 L115 633. L113 L116 634. L113 L117 635. L113 L118 636. L113 L119 637. L113 L120 638. L113 L121 639. L113 L122 640. L113 L123 641. L113 L124 642. L113 L125 643. L113 L126 644. L113 L127 645. L113 L128 646. L113 L129 647. L113 L130 648. L113 L131 649. L113 L132 650. L113 L133 651. L113 L134 652. L113 L135 653. L113 L136 654. L113 L137 655. L113 L138 656. L113 L139 657. L113 L140 658. L113 L141 659. L113 L142 660. L113 L143 661. L113 L144 662. L113 L145 663. L113 L146 664. L113 L147 665. L113 L148 666. L113 L149 667. L113 L150 668. L113 L151 669. L113 L152 670. L113 L153 671. L113 L154 672. L113 L155 673. L113 L156 674. L113 L157 675. L113 L158 676. L113 L159 677. L114 L115 678. L114 L116 679. L114 L117 680. L114 L118 681. L114 L119 682. L114 L120 683. L114 L121 684. L114 L122 685. L114 L123 686. L114 L124 687. L114 L125 688. L114 L126 689. L114 L127 690. L114 L128 691. L114 L129 692. L114 L130 693. L114 L131 694. L114 L132 695. L114 L133 696. L114 L134 697. L114 L135 698. L114 L136 699. L114 L137 700. L114 L138 701. L114 L139 702. L114 L140 703. L114 L141 704. L114 L142 705. L114 L143 706. L114 L144 707. L114 L145 708. L114 L146 709. L114 L147 710. L114 L148 711. L114 L149 712. L114 L150 713. L114 L151 714. L114 L152 715. L114 L153 716. L114 L154 717. L114 L155 718. L114 L156 719. L114 L157 720. L114 L158 721. L114 L159 722. L115 L116 723. L115 L117 724. L115 L118 725. L115 L119 726. L115 L120 727. L115 L121 728. L115 L122 729. L115 L123 730. L115 L124 731. L115 L125 732. L115 L126 733. L115 L127 734. L115 L128 735. L115 L129 736. L115 L130 737. L115 L131 738. L115 L132 739. L115 L133 740. L115 L134 741. L115 L135 742. L115 L136 743. L115 L137 744. L115 L138 745. L115 L139 746. L115 L140 747. L115 L141 748. L115 L142 749. L115 L143 750. L115 L144 751. L115 L145 752. L115 L146 753. L115 L147 754. L115 L148 755. L115 L149 756. L115 L150 757. L115 L151 758. L115 L152 759. L115 L153 760. L115 L154 761. L115 L155 762. L115 L156 763. L115 L157 764. L115 L158 765. L115 L159 766. L116 L117 767. L116 L118 768. L116 L119 769. L116 L120 770. L116 L121 771. L116 L122 772. L116 L123 773. L116 L124 774. L116 L125 775. L116 L126 776. L116 L127 777. L116 L128 778. L116 L129 779. L116 L130 780. L116 L131 781. L116 L132 782. L116 L133 783. L116 L134 784. L116 L135 785. L116 L136 786. L116 L137 787. L116 L138 788. L116 L139 789. L116 L140 790. L116 L141 791. L116 L142 792. L116 L143 793. L116 L144 794. L116 L145 795. L116 L146 796. L116 L147 797. L116 L148 798. L116 L149 799. L116 L150 800. L116 L151 801. L116 L152 802. L116 L153 803. L116 L154 804. L116 L155 805. L116 L156 806. L116 L157 807. L116 L158 808. L116 L159 809. L117 L118 810. L117 L119 811. L117 L120 812. L117 L121 813. L117 L122 814. L117 L123 815. L117 L124 816. L117 L125 817. L117 L126 818. L117 L127 819. L117 L128 820. L117 L129 821. L117 L130 822. L117 L131 823. L117 L132 824. L117 L133 825. L117 L134 826. L117 L135 827. L117 L136 828. L117 L137 829. L117 L138 830. L117 L139 831. L117 L140 832. L117 L141 833. L117 L142 834. L117 L143 835. L117 L144 836. L117 L145 837. L117 L146 838. L117 L147 839. L117 L148 840. L117 L149 841. L117 L150 842. L117 L151 843. L117 L152 844. L117 L153 845. L117 L154 846. L117 L155 847. L117 L156 848. L117 L157 849. L117 L158 850. L117 L159 851. L118 L119 852. L118 L120 853. L118 L121 854. L118 L122 855. L118 L123 856. L118 L124 857. L118 L125 858. L118 L126 859. L118 L127 860. L118 L128 861. L118 L129 862. L118 L130 863. L118 L131 864. L118 L132 865. L118 L133 866. L118 L134 867. L118 L135 868. L118 L136 869. L118 L137 870. L118 L138 871. L118 L139 872. L118 L140 873. L118 L141 874. L118 L142 875. L118 L143 876. L118 L144 877. L118 L145 878. L118 L146 879. L118 L147 880. L118 L148 881. L118 L149 882. L118 L150 883. L118 L151 884. L118 L152 885. L118 L153 886. L118 L154 887. L118 L155 888. L118 L156 889. L118 L157 890. L118 L158 891. L118 L159 892. L119 L120 893. L119 L121 894. L119 L122 895. L119 L123 896. L119 L124 897. L119 L125 898. L119 L126 899. L119 L127 900. L119 L128 901. L119 L129 902. L119 L130 903. L119 L131 904. L119 L132 905. L119 L133 906. L119 L134 907. L119 L135 908. L119 L136 909. L119 L137 910. L119 L138 911. L119 L139 912. L119 L140 913. L119 L141 914. L119 L142 915. L119 L143 916. L119 L144 917. L119 L145 918. L119 L146 919. L119 L147 920. L119 L148 921. L119 L149 922. L119 L150 923. L119 L151 924. L119 L152 925. L119 L153 926. L119 L154 927. L119 L155 928. L119 L156 929. L119 L157 930. L119 L158 931. L119 L159 932. L120 L121 933. L120 L122 934. L120 L123 935. L120 L124 936. L120 L125 937. L120 L126 938. L120 L127 939. L120 L128 940. L120 L129 941. L120 L130 942. L120 L131 943. L120 L132 944. L120 L133 945. L120 L134 946. L120 L135 947. L120 L136 948. L120 L137 949. L120 L138 950. L120 L139 951. L120 L140 952. L120 L141 953. L120 L142 954. L120 L143 955. L120 L144 956. L120 L145 957. L120 L146 958. L120 L147 959. L120 L148 960. L120 L149 961. L120 L150 962. L120 L151 963. L120 L152 964. L120 L153 965. L120 L154 966. L120 L155 967. L120 L156 968. L120 L157 969. L120 L158 970. L120 L159 971. L121 L122 972. L121 L123 973. L121 L124 974. L121 L125 975. L121 L126 976. L121 L127 977. L121 L128 978. L121 L129 979. L121 L130 980. L121 L131 981. L121 L132 982. L121 L133 983. L121 L134 984. L121 L135 985. L121 L136 986. L121 L137 987. L121 L138 988. L121 L139 989. L121 L140 990. L121 L141 991. L121 L142 992. L121 L143 993. L121 L144 994. L121 L145 995. L121 L146 996. L121 L147 997. L121 L148 998. L121 L149 999. L121 L150 1000. L121 L151 1001. L121 L152 1002. L121 L153 1003. L121 L154 1004. L121 L155 1005. L121 L156 1006. L121 L157 1007. L121 L158 1008. L121 L159 1009. L122 L123 1010. L122 L124 1011. L122 L125 1012. L122 L126 1013. L122 L127 1014. L122 L128 1015. L122 L129 1016. L122 L130 1017. L122 L131 1018. L122 L132 1019. L122 L133 1020. L122 L134 1021. L122 L135 1022. L122 L136 1023. L122 L137 1024. L122 L138 1025. L122 L139 1026. L122 L140 1027. L122 L141 1028. L122 L142 1029. L122 L143 1030. L122 L144 1031. L122 L145 1032. L122 L146 1033. L122 L147 1034. L122 L148 1035. L122 L149 1036. L122 L150 1037. L122 L151 1038. L122 L152 1039. L122 L153 1040. L122 L154 1041. L122 L155 1042. L122 L156 1043. L122 L157 1044. L122 L158 1045. L122 L159 1046. L123 L124 1047. L123 L125 1048. L123 L126 1049. L123 L127 1050. L123 L128 1051. L123 L129 1052. L123 L130 1053. L123 L131 1054. L123 L132 1055. L123 L133 1056. L123 L134 1057. L123 L135 1058. L123 L136 1059. L123 L137 1060. L123 L138 1061. L123 L139 1062. L123 L140 1063. L123 L141 1064. L123 L142 1065. L123 L143 1066. L123 L144 1067. L123 L145 1068. L123 L146 1069. L123 L147 1070. L123 L148 1071. L123 L149 1072. L123 L150 1073. L123 L151 1074. L123 L152 1075. L123 L153 1076. L123 L154 1077. L123 L155 1078. L123 L156 1079. L123 L157 1080. L123 L158 1081. L123 L159 1082. L124 L125 1083. L124 L126 1084. L124 L127 1085. L124 L128 1086. L124 L129 1087. L124 L130 1088. L124 L131 1089. L124 L132 1090. L124 L133 1091. L124 L134 1092. L124 L135 1093. L124 L136 1094. L124 L137 1095. L124 L138 1096. L124 L139 1097. L124 L140 1098. L124 L141 1099. L124 L142 1100. L124 L143 1101. L124 L144 1102. L124 L145 1103. L124 L146 1104. L124 L147 1105. L124 L148 1106. L124 L149 1107. L124 L150 1108. L124 L151 1109. L124 L152 1110. L124 L153 1111. L124 L154 1112. L124 L155 1113. L124 L156 1114. L124 L157 1115. L124 L158 1116. L124 L159 1117. L125 L126 1118. L125 L127 1119. L125 L128 1120. L125 L129 1121. L125 L130 1122. L125 L131 1123. L125 L132 1124. L125 L133 1125. L125 L134 1126. L125 L135 1127. L125 L136 1128. L125 L137 1129. L125 L138 1130. L125 L139 1131. L125 L140 1132. L125 L141 1133. L125 L142 1134. L125 L143 1135. L125 L144 1136. L125 L145 1137. L125 L146 1138. L125 L147 1139. L125 L148 1140. L125 L149 1141. L125 L150 1142. L125 L151 1143. L125 L152 1144. L125 L153 1145. L125 L154 1146. L125 L155 1147. L125 L156 1148. L125 L157 1149. L125 L158 1150. L125 L159

22. A first device comprising a first organic light emitting device, the first organic light emitting device comprising:

an anode;

a cathode; and

an organic layer, disposed between the anode and the cathode, comprising a compound having the structure according Formula I L1-Os-L2;

wherein L1 and L2 are different;

wherein L1 and L2 are independently selected from ligands having Formula II:

wherein Y1, Y2 and Y3 comprise C or N;

wherein R3 and R4 may represent mono-, or di-substitutions, or no substitution;

wherein R5 may represent mono-, di-, or tri-substitutions, or no substitution;

wherein R1 and R2 are independently selected from the group consisting of alkyl and cycloalkyl;

wherein R3, R4 and R5 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, aralkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combinations thereof;

wherein any two adjacent substituents of R1, R2, R3, R4 and R5 are optionally joined to condense into a fused ring; and

wherein the dash lines show the connection points to osmium.

23. The first device of claim 22, wherein Y1, Y2 and Y3 comprise C.

24. The first device of claim 22, wherein Y1, Y2 and Y3 are N.

25. The first device of claim 22, wherein R1 and R2 are independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, partially or fully deuterated variants thereof, and combinations thereof.

26. The first device of claim 22, wherein L1 and L2 are independently selected from ligands having Formula III:

wherein X1, X2, X3, X4, X5, X6, X7 and X8 comprise C or N.

27. The first device of claim 26, wherein X1, X2, X3, X4, X5, X6, X7 and X8 comprise C.

28. The first device of claim 22, wherein the ligands having Formula II are selected from the group consisting of:

29. The first device of claim 22, wherein the first emitting compound is selected from the group consisting of Compounds 1 to 1150 defined in the table below: Compound Number L1 L2 1. L101 L102 2. L101 L103 3. L101 L104 4. L101 L105 5. L101 L106 6. L101 L107 7. L101 L108 8. L101 L109 9. L101 L110 10. L101 L111 11. L101 L112 12. L101 L113 13. L101 L114 14. L101 L115 15. L101 L116 16. L101 L117 17. L101 L118 18. L101 L119 19. L101 L120 20. L101 L121 21. L101 L122 22. L101 L123 23. L101 L124 24. L101 L125 25. L101 L126 26. L101 L127 27. L101 L128 28. L101 L129 29. L101 L130 30. L101 L131 31. L101 L132 32. L101 L133 33. L101 L134 34. L101 L135 35. L101 L136 36. L101 L137 37. L101 L138 38. L101 L139 39. L101 L140 40. L101 L141 41. L101 L142 42. L101 L143 43. L101 L144 44. L101 L145 45. L101 L146 46. L101 L147 47. L101 L148 48. L101 L149 49. L101 L150 50. L101 L151 51. L101 L152 52. L101 L153 53. L101 L154 54. L101 L155 55. L101 L156 56. L101 L157 57. L101 L158 58. L101 L159 59. L102 L103 60. L102 L104 61. L102 L105 62. L102 L106 63. L102 L107 64. L102 L108 65. L102 L109 66. L102 L110 67. L102 L111 68. L102 L112 69. L102 L113 70. L102 L114 71. L102 L115 72. L102 L116 73. L102 L117 74. L102 L118 75. L102 L119 76. L102 L120 77. L102 L121 78. L102 L122 79. L102 L123 80. L102 L124 81. L102 L125 82. L102 L126 83. L102 L127 84. L102 L128 85. L102 L129 86. L102 L130 87. L102 L131 88. L102 L132 89. L102 L133 90. L102 L134 91. L102 L135 92. L102 L136 93. L102 L137 94. L102 L138 95. L102 L139 96. L102 L140 97. L102 L141 98. L102 L142 99. L102 L143 100. L102 L144 101. L102 L145 102. L102 L146 103. L102 L147 104. L102 L148 105. L102 L149 106. L102 L150 107. L102 L151 108. L102 L152 109. L102 L153 110. L102 L154 111. L102 L155 112. L102 L156 113. L102 L157 114. L102 L158 115. L102 L159 116. L103 L104 117. L103 L105 118. L103 L106 119. L103 L107 120. L103 L108 121. L103 L109 122. L103 L110 123. L103 L111 124. L103 L112 125. L103 L113 126. L103 L114 127. L103 L115 128. L103 L116 129. L103 L117 130. L103 L118 131. L103 L119 132. L103 L120 133. L103 L121 134. L103 L122 135. L103 L123 136. L103 L124 137. L103 L125 138. L103 L126 139. L103 L127 140. L103 L128 141. L103 L129 142. L103 L130 143. L103 L131 144. L103 L132 145. L103 L133 146. L103 L134 147. L103 L135 148. L103 L136 149. L103 L137 150. L103 L138 151. L103 L139 152. L103 L140 153. L103 L141 154. L103 L142 155. L103 L143 156. L103 L144 157. L103 L145 158. L103 L146 159. L103 L147 160. L103 L148 161. L103 L149 162. L103 L150 163. L103 L151 164. L103 L152 165. L103 L153 166. L103 L154 167. L103 L155 168. L103 L156 169. L103 L157 170. L103 L158 171. L103 L159 172. L104 L105 173. L104 L106 174. L104 L107 175. L104 L108 176. L104 L109 177. L104 L110 178. L104 L111 179. L104 L112 180. L104 L113 181. L104 L114 182. L104 L115 183. L104 L116 184. L104 L117 185. L104 L118 186. L104 L119 187. L104 L120 188. L104 L121 189. L104 L122 190. L104 L123 191. L104 L124 192. L104 L125 193. L104 L126 194. L104 L127 195. L104 L128 196. L104 L129 197. L104 L130 198. L104 L131 199. L104 L132 200. L104 L133 201. L104 L134 202. L104 L135 203. L104 L136 204. L104 L137 205. L104 L138 206. L104 L139 207. L104 L140 208. L104 L141 209. L104 L142 210. L104 L143 211. L104 L144 212. L104 L145 213. L104 L146 214. L104 L147 215. L104 L148 216. L104 L149 217. L104 L150 218. L104 L151 219. L104 L152 220. L104 L153 221. L104 L154 222. L104 L155 223. L104 L156 224. L104 L157 225. L104 L158 226. L104 L159 227. L105 L106 228. L105 L107 229. L105 L108 230. L105 L109 231. L105 L110 232. L105 L111 233. L105 L112 234. L105 L113 235. L105 L114 236. L105 L115 237. L105 L116 238. L105 L117 239. L105 L118 240. L105 L119 241. L105 L120 242. L105 L121 243. L105 L122 244. L105 L123 245. L105 L124 246. L105 L125 247. L105 L126 248. L105 L127 249. L105 L128 250. L105 L129 251. L105 L130 252. L105 L131 253. L105 L132 254. L105 L133 255. L105 L134 256. L105 L135 257. L105 L136 258. L105 L137 259. L105 L138 260. L105 L139 261. L105 L140 262. L105 L141 263. L105 L142 264. L105 L143 265. L105 L144 266. L105 L145 267. L105 L146 268. L105 L147 269. L105 L148 270. L105 L149 271. L105 L150 272. L105 L151 273. L105 L152 274. L105 L153 275. L105 L154 276. L105 L155 277. L105 L156 278. L105 L157 279. L105 L158 280. L105 L159 281. L106 L107 282. L106 L108 283. L106 L109 284. L106 L110 285. L106 L111 286. L106 L112 287. L106 L113 288. L106 L114 289. L106 L115 290. L106 L116 291. L106 L117 292. L106 L118 293. L106 L119 294. L106 L120 295. L106 L121 296. L106 L122 297. L106 L123 298. L106 L124 299. L106 L125 300. L106 L126 301. L106 L127 302. L106 L128 303. L106 L129 304. L106 L130 305. L106 L131 306. L106 L132 307. L106 L133 308. L106 L134 309. L106 L135 310. L106 L136 311. L106 L137 312. L106 L138 313. L106 L139 314. L106 L140 315. L106 L141 316. L106 L142 317. L106 L143 318. L106 L144 319. L106 L145 320. L106 L146 321. L106 L147 322. L106 L148 323. L106 L149 324. L106 L150 325. L106 L151 326. L106 L152 327. L106 L153 328. L106 L154 329. L106 L155 330. L106 L156 331. L106 L157 332. L106 L158 333. L106 L159 334. L107 L108 335. L107 L109 336. L107 L110 337. L107 L111 338. L107 L112 339. L107 L113 340. L107 L114 341. L107 L115 342. L107 L116 343. L107 L117 344. L107 L118 345. L107 L119 346. L107 L120 347. L107 L121 348. L107 L122 349. L107 L123 350. L107 L124 351. L107 L125 352. L107 L126 353. L107 L127 354. L107 L128 355. L107 L129 356. L107 L130 357. L107 L131 358. L107 L132 359. L107 L133 360. L107 L134 361. L107 L135 362. L107 L136 363. L107 L137 364. L107 L138 365. L107 L139 366. L107 L140 367. L107 L141 368. L107 L142 369. L107 L143 370. L107 L144 371. L107 L145 372. L107 L146 373. L107 L147 374. L107 L148 375. L107 L149 376. L107 L150 377. L107 L151 378. L107 L152 379. L107 L153 380. L107 L154 381. L107 L155 382. L107 L156 383. L107 L157 384. L107 L158 385. L107 L159 386. L108 L109 387. L108 L110 388. L108 L111 389. L108 L112 390. L108 L113 391. L108 L114 392. L108 L115 393. L108 L116 394. L108 L117 395. L108 L118 396. L108 L119 397. L108 L120 398. L108 L121 399. L108 L122 400. L108 L123 401. L108 L124 402. L108 L125 403. L108 L126 404. L108 L127 405. L108 L128 406. L108 L129 407. L108 L130 408. L108 L131 409. L108 L132 410. L108 L133 411. L108 L134 412. L108 L135 413. L108 L136 414. L108 L137 415. L108 L138 416. L108 L139 417. L108 L140 418. L108 L141 419. L108 L142 420. L108 L143 421. L108 L144 422. L108 L145 423. L108 L146 424. L108 L147 425. L108 L148 426. L108 L149 427. L108 L150 428. L108 L151 429. L108 L152 430. L108 L153 431. L108 L154 432. L108 L155 433. L108 L156 434. L108 L157 435. L108 L158 436. L108 L159 437. L109 L110 438. L109 L111 439. L109 L112 440. L109 L113 441. L109 L114 442. L109 L115 443. L109 L116 444. L109 L117 445. L109 L118 446. L109 L119 447. L109 L120 448. L109 L121 449. L109 L122 450. L109 L123 451. L109 L124 452. L109 L125 453. L109 L126 454. L109 L127 455. L109 L128 456. L109 L129 457. L109 L130 458. L109 L131 459. L109 L132 460. L109 L133 461. L109 L134 462. L109 L135 463. L109 L136 464. L109 L137 465. L109 L138 466. L109 L139 467. L109 L140 468. L109 L141 469. L109 L142 470. L109 L143 471. L109 L144 472. L109 L145 473. L109 L146 474. L109 L147 475. L109 L148 476. L109 L149 477. L109 L150 478. L109 L151 479. L109 L152 480. L109 L153 481. L109 L154 482. L109 L155 483. L109 L156 484. L109 L157 485. L109 L158 486. L109 L159 487. L110 L111 488. L110 L112 489. L110 L113 490. L110 L114 491. L110 L115 492. L110 L116 493. L110 L117 494. L110 L118 495. L110 L119 496. L110 L120 497. L110 L121 498. L110 L122 499. L110 L123 500. L110 L124 501. L110 L125 502. L110 L126 503. L110 L127 504. L110 L128 505. L110 L129 506. L110 L130 507. L110 L131 508. L110 L132 509. L110 L133 510. L110 L134 511. L110 L135 512. L110 L136 513. L110 L137 514. L110 L138 515. L110 L139 516. L110 L140 517. L110 L141 518. L110 L142 519. L110 L143 520. L110 L144 521. L110 L145 522. L110 L146 523. L110 L147 524. L110 L148 525. L110 L149 526. L110 L150 527. L110 L151 528. L110 L152 529. L110 L153 530. L110 L154 531. L110 L155 532. L110 L156 533. L110 L157 534. L110 L158 535. L110 L159 536. L111 L112 537. L111 L113 538. L111 L114 539. L111 L115 540. L111 L116 541. L111 L117 542. L111 L118 543. L111 L119 544. L111 L120 545. L111 L121 546. L111 L122 547. L111 L123 548. L111 L124 549. L111 L125 550. L111 L126 551. L111 L127 552. L111 L128 553. L111 L129 554. L111 L130 555. L111 L131 556. L111 L132 557. L111 L133 558. L111 L134 559. L111 L135 560. L111 L136 561. L111 L137 562. L111 L138 563. L111 L139 564. L111 L140 565. L111 L141 566. L111 L142 567. L111 L143 568. L111 L144 569. L111 L145 570. L111 L146 571. L111 L147 572. L111 L148 573. L111 L149 574. L111 L150 575. L111 L151 576. L111 L152 577. L111 L153 578. L111 L154 579. L111 L155 580. L111 L156 581. L111 L157 582. L111 L158 583. L111 L159 584. L112 L113 585. L112 L114 586. L112 L115 587. L112 L116 588. L112 L117 589. L112 L118 590. L112 L119 591. L112 L120 592. L112 L121 593. L112 L122 594. L112 L123 595. L112 L124 596. L112 L125 597. L112 L126 598. L112 L127 599. L112 L128 600. L112 L129 601. L112 L130 602. L112 L131 603. L112 L132 604. L112 L133 605. L112 L134 606. L112 L135 607. L112 L136 608. L112 L137 609. L112 L138 610. L112 L139 611. L112 L140 612. L112 L141 613. L112 L142 614. L112 L143 615. L112 L144 616. L112 L145 617. L112 L146 618. L112 L147 619. L112 L148 620. L112 L149 621. L112 L150 622. L112 L151 623. L112 L152 624. L112 L153 625. L112 L154 626. L112 L155 627. L112 L156 628. L112 L157 629. L112 L158 630. L112 L159 631. L113 L114 632. L113 L115 633. L113 L116 634. L113 L117 635. L113 L118 636. L113 L119 637. L113 L120 638. L113 L121 639. L113 L122 640. L113 L123 641. L113 L124 642. L113 L125 643. L113 L126 644. L113 L127 645. L113 L128 646. L113 L129 647. L113 L130 648. L113 L131 649. L113 L132 650. L113 L133 651. L113 L134 652. L113 L135 653. L113 L136 654. L113 L137 655. L113 L138 656. L113 L139 657. L113 L140 658. L113 L141 659. L113 L142 660. L113 L143 661. L113 L144 662. L113 L145 663. L113 L146 664. L113 L147 665. L113 L148 666. L113 L149 667. L113 L150 668. L113 L151 669. L113 L152 670. L113 L153 671. L113 L154 672. L113 L155 673. L113 L156 674. L113 L157 675. L113 L158 676. L113 L159 677. L114 L115 678. L114 L116 679. L114 L117 680. L114 L118 681. L114 L119 682. L114 L120 683. L114 L121 684. L114 L122 685. L114 L123 686. L114 L124 687. L114 L125 688. L114 L126 689. L114 L127 690. L114 L128 691. L114 L129 692. L114 L130 693. L114 L131 694. L114 L132 695. L114 L133 696. L114 L134 697. L114 L135 698. L114 L136 699. L114 L137 700. L114 L138 701. L114 L139 702. L114 L140 703. L114 L141 704. L114 L142 705. L114 L143 706. L114 L144 707. L114 L145 708. L114 L146 709. L114 L147 710. L114 L148 711. L114 L149 712. L114 L150 713. L114 L151 714. L114 L152 715. L114 L153 716. L114 L154 717. L114 L155 718. L114 L156 719. L114 L157 720. L114 L158 721. L114 L159 722. L115 L116 723. L115 L117 724. L115 L118 725. L115 L119 726. L115 L120 727. L115 L121 728. L115 L122 729. L115 L123 730. L115 L124 731. L115 L125 732. L115 L126 733. L115 L127 734. L115 L128 735. L115 L129 736. L115 L130 737. L115 L131 738. L115 L132 739. L115 L133 740. L115 L134 741. L115 L135 742. L115 L136 743. L115 L137 744. L115 L138 745. L115 L139 746. L115 L140 747. L115 L141 748. L115 L142 749. L115 L143 750. L115 L144 751. L115 L145 752. L115 L146 753. L115 L147 754. L115 L148 755. L115 L149 756. L115 L150 757. L115 L151 758. L115 L152 759. L115 L153 760. L115 L154 761. L115 L155 762. L115 L156 763. L115 L157 764. L115 L158 765. L115 L159 766. L116 L117 767. L116 L118 768. L116 L119 769. L116 L120 770. L116 L121 771. L116 L122 772. L116 L123 773. L116 L124 774. L116 L125 775. L116 L126 776. L116 L127 777. L116 L128 778. L116 L129 779. L116 L130 780. L116 L131 781. L116 L132 782. L116 L133 783. L116 L134 784. L116 L135 785. L116 L136 786. L116 L137 787. L116 L138 788. L116 L139 789. L116 L140 790. L116 L141 791. L116 L142 792. L116 L143 793. L116 L144 794. L116 L145 795. L116 L146 796. L116 L147 797. L116 L148 798. L116 L149 799. L116 L150 800. L116 L151 801. L116 L152 802. L116 L153 803. L116 L154 804. L116 L155 805. L116 L156 806. L116 L157 807. L116 L158 808. L116 L159 809. L117 L118 810. L117 L119 811. L117 L120 812. L117 L121 813. L117 L122 814. L117 L123 815. L117 L124 816. L117 L125 817. L117 L126 818. L117 L127 819. L117 L128 820. L117 L129 821. L117 L130 822. L117 L131 823. L117 L132 824. L117 L133 825. L117 L134 826. L117 L135 827. L117 L136 828. L117 L137 829. L117 L138 830. L117 L139 831. L117 L140 832. L117 L141 833. L117 L142 834. L117 L143 835. L117 L144 836. L117 L145 837. L117 L146 838. L117 L147 839. L117 L148 840. L117 L149 841. L117 L150 842. L117 L151 843. L117 L152 844. L117 L153 845. L117 L154 846. L117 L155 847. L117 L156 848. L117 L157 849. L117 L158 850. L117 L159 851. L118 L119 852. L118 L120 853. L118 L121 854. L118 L122 855. L118 L123 856. L118 L124 857. L118 L125 858. L118 L126 859. L118 L127 860. L118 L128 861. L118 L129 862. L118 L130 863. L118 L131 864. L118 L132 865. L118 L133 866. L118 L134 867. L118 L135 868. L118 L136 869. L118 L137 870. L118 L138 871. L118 L139 872. L118 L140 873. L118 L141 874. L118 L142 875. L118 L143 876. L118 L144 877. L118 L145 878. L118 L146 879. L118 L147 880. L118 L148 881. L118 L149 882. L118 L150 883. L118 L151 884. L118 L152 885. L118 L153 886. L118 L154 887. L118 L155 888. L118 L156 889. L118 L157 890. L118 L158 891. L118 L159 892. L119 L120 893. L119 L121 894. L119 L122 895. L119 L123 896. L119 L124 897. L119 L125 898. L119 L126 899. L119 L127 900. L119 L128 901. L119 L129 902. L119 L130 903. L119 L131 904. L119 L132 905. L119 L133 906. L119 L134 907. L119 L135 908. L119 L136 909. L119 L137 910. L119 L138 911. L119 L139 912. L119 L140 913. L119 L141 914. L119 L142 915. L119 L143 916. L119 L144 917. L119 L145 918. L119 L146 919. L119 L147 920. L119 L148 921. L119 L149 922. L119 L150 923. L119 L151 924. L119 L152 925. L119 L153 926. L119 L154 927. L119 L155 928. L119 L156 929. L119 L157 930. L119 L158 931. L119 L159 932. L120 L121 933. L120 L122 934. L120 L123 935. L120 L124 936. L120 L125 937. L120 L126 938. L120 L127 939. L120 L128 940. L120 L129 941. L120 L130 942. L120 L131 943. L120 L132 944. L120 L133 945. L120 L134 946. L120 L135 947. L120 L136 948. L120 L137 949. L120 L138 950. L120 L139 951. L120 L140 952. L120 L141 953. L120 L142 954. L120 L143 955. L120 L144 956. L120 L145 957. L120 L146 958. L120 L147 959. L120 L148 960. L120 L149 961. L120 L150 962. L120 L151 963. L120 L152 964. L120 L153 965. L120 L154 966. L120 L155 967. L120 L156 968. L120 L157 969. L120 L158 970. L120 L159 971. L121 L122 972. L121 L123 973. L121 L124 974. L121 L125 975. L121 L126 976. L121 L127 977. L121 L128 978. L121 L129 979. L121 L130 980. L121 L131 981. L121 L132 982. L121 L133 983. L121 L134 984. L121 L135 985. L121 L136 986. L121 L137 987. L121 L138 988. L121 L139 989. L121 L140 990. L121 L141 991. L121 L142 992. L121 L143 993. L121 L144 994. L121 L145 995. L121 L146 996. L121 L147 997. L121 L148 998. L121 L149 999. L121 L150 1000. L121 L151 1001. L121 L152 1002. L121 L153 1003. L121 L154 1004. L121 L155 1005. L121 L156 1006. L121 L157 1007. L121 L158 1008. L121 L159 1009. L122 L123 1010. L122 L124 1011. L122 L125 1012. L122 L126 1013. L122 L127 1014. L122 L128 1015. L122 L129 1016. L122 L130 1017. L122 L131 1018. L122 L132 1019. L122 L133 1020. L122 L134 1021. L122 L135 1022. L122 L136 1023. L122 L137 1024. L122 L138 1025. L122 L139 1026. L122 L140 1027. L122 L141 1028. L122 L142 1029. L122 L143 1030. L122 L144 1031. L122 L145 1032. L122 L146 1033. L122 L147 1034. L122 L148 1035. L122 L149 1036. L122 L150 1037. L122 L151 1038. L122 L152 1039. L122 L153 1040. L122 L154 1041. L122 L155 1042. L122 L156 1043. L122 L157 1044. L122 L158 1045. L122 L159 1046. L123 L124 1047. L123 L125 1048. L123 L126 1049. L123 L127 1050. L123 L128 1051. L123 L129 1052. L123 L130 1053. L123 L131 1054. L123 L132 1055. L123 L133 1056. L123 L134 1057. L123 L135 1058. L123 L136 1059. L123 L137 1060. L123 L138 1061. L123 L139 1062. L123 L140 1063. L123 L141 1064. L123 L142 1065. L123 L143 1066. L123 L144 1067. L123 L145 1068. L123 L146 1069. L123 L147 1070. L123 L148 1071. L123 L149 1072. L123 L150 1073. L123 L151 1074. L123 L152 1075. L123 L153 1076. L123 L154 1077. L123 L155 1078. L123 L156 1079. L123 L157 1080. L123 L158 1081. L123 L159 1082. L124 L125 1083. L124 L126 1084. L124 L127 1085. L124 L128 1086. L124 L129 1087. L124 L130 1088. L124 L131 1089. L124 L132 1090. L124 L133 1091. L124 L134 1092. L124 L135 1093. L124 L136 1094. L124 L137 1095. L124 L138 1096. L124 L139 1097. L124 L140 1098. L124 L141 1099. L124 L142 1100. L124 L143 1101. L124 L144 1102. L124 L145 1103. L124 L146 1104. L124 L147 1105. L124 L148 1106. L124 L149 1107. L124 L150 1108. L124 L151 1109. L124 L152 1110. L124 L153 1111. L124 L154 1112. L124 L154 1113. L124 L156 1114. L124 L157 1115. L124 L158 1116. L124 L159 1117. L125 L126 1118. L125 L127 1119. L125 L128 1120. L125 L129 1121. L125 L130 1122. L125 L131 1123. L125 L132 1124. L125 L133 1125. L125 L134 1126. L125 L135 1127. L125 L136 1128. L125 L137 1129. L125 L138 1130. L125 L139 1131. L125 L140 1132. L125 L141 1133. L125 L142 1134. L125 L143 1135. L125 L144 1136. L125 L145 1137. L125 L146 1138. L125 L147 1139. L125 L148 1140. L125 L149 1141. L125 L150 1142. L125 L151 1143. L125 L152 1144. L125 L153 1145. L125 L154 1146. L125 L155 1147. L125 L156 1148. L125 L157 1149. L125 L158 1150. L125 L159

30. The first device of claim 22, wherein the first device is a consumer product.

31. The first device of claim 22, wherein the first device is an organic light emitting device.

32. The first device of claim 22, wherein the first device comprises a light panel.

33. The first device of claim 22, wherein the organic layer is an emissive layer and the compound is an emissive dopant.

34. The first device of claim 22, wherein the organic layer is an emissive layer and the compound is a non-emissive dopant.

35. The first device of claim 22, wherein the organic layer further comprises a host material.

36. The first device of claim 35, wherein the host material comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan;

wherein any substituent in the host material is an unfused substituent independently selected from the group consisting of CnH2n+1, OCnH2n+1, OAr1, N(CnH2n+1)2, N(Ar1)(Ar2), CH═CH—CnH2n+1, C≡CCnH2n+1, Ar1, Ar1—Ar2, CnH2n—Ar1, or no substitution;

wherein n is from 1 to 10; and

wherein Ar1 and Ar2 are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.

37. The first device of claim 35, wherein the host material comprises at least one chemical group selected from the group consisting of carbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

38. The first device of claim 35, wherein the host material is selected from the group consisting of: and combinations thereof.

39. The first device of claim 35, wherein the host material comprises a metal complex.