SUNSCREEN COMPOSITIONS FOR APPLICATION TO PLANTS

Abstract

A sunscreen composition to be used on plants comprises titanium dioxide (TiO2), zinc oxide (ZnO), and a surfactant, wetting agent, dispersant (SWD), the TiO2 and ZnO combined are in a proportion of greater than 30% by weight. The composition forms a suspension concentrate that when diluted in water provides a solution that enables uniform coverage of an area using conventional spraying equipment.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS

The present application claims the benefit of and is a continuation of co-pending U.S. patent application Ser. No. 14/054,030 filed on Oct. 15, 2013, which claims the benefit of and is a continuation of U.S. patent application Ser. No. 12/869,514, filed Aug. 26, 2010, which issued as U.S. Pat. No. 8,557,293 on Oct. 15, 2013, the subject matter of thereof incorporated by reference herein in their entireties for all purposes.

FIELD OF THE INVENTION

The present invention relates to sunscreen compositions. More particularly, the present invention relates to sunscreen compositions applicable to plants such as turfgrass.

BACKGROUND OF THE INVENTION

Plants are living organisms, many of which rely on the sun to survive. Green plants capture the energy of the sun and convert the sunlight into energy to sustain the plant through the process of photosynthesis. Plants have many uses including food, medicines and other non-food products, as well as aesthetic uses such as lawns, turf, gardens and the like. Plant species are cultivated to provide shade, modify temperatures, reduce wind and noise, provide privacy and prevent soil erosion. Lawn grasses, shade trees, ornamental trees, shrubs, vines, herbs, perennials and bedding plants are frequently used to beautify outdoor gardens. Sports such as football, soccer, baseball and golf are performed on grass surfaces.

The effects of harmful radiation from the sun are well known. Exposure to ultra-violet (UV) radiation can damage the skin and deteriorate certain materials through extended exposure to sunlight containing the UV spectrum. In the case of skin, the protective layer of skin may burn or blister, causing painful and possibly irreversible damage. In extreme cases of prolonged exposure, permanent damage such as skin cancer may develop. Sunscreens have been developed to help mitigate the damages from UV radiation. Sunscreens may take the form of lotions, gels, oils among other formulae that may be applied to the skin and reflect or absorb light in the UV spectrum, thus preventing the UV radiation from penetrating the skin. Plants and other forms of life are also susceptible to the harmful effects of the sun. In particular, plants are adversely affected by the UV radiation emitted by the sun, as well as the heat generated from the sun's radiation.

The ultra-violet spectrum (wavelength of 100-400 nanometers (nm)) is comprised of UV-C (100-280 nm), UV-B (280-313 nm) and UV-A (315-400 nm) radiation. UV-B radiation in particular may have significant photo-biological effects, causing modifications to the biological and biochemical environment of the plant. Radiation may affect a plant by direct destruction of the DNA at a molecular level, disruption of cell membranes or other cell structures, and may inhibit various physiological functions, for example, photosynthesis, nutrient assimilation and chlorophyll and protein synthesis which may result in reduced growth and development of the plant.

An example where the damage of UV radiation to plants is acutely evident is with regard to cultivated turfgrass. Cultivated turfgrass may be used in locations such as golf courses, ball fields, parks and botanical gardens. Over the area of the typical golf course, for example, different grass heights are maintained for different types of play and leisure activities. In some areas, for example, putting greens, it is desirable to have a ball move rapidly across the surface during play. To achieve this, turfgrass on greens may be maintained at blade lengths of ⅛ inch (in.) or less. With such small blade lengths, the effects of heat and radiation are magnified and require measures be taken to prevent damage or possibly death of the turfgrass.

Golf courses and other institutional users of turfgrass must supply water to the affected turfgrass in an amount sufficient to provide adequate cooling. This however, requires significant manpower and water resources. In many areas, water resources are strictly monitored and rationed due to water shortages. This results in high costs for labor and irrigation and contributes to shortages of valuable water resources. It would be beneficial to have a composition to provide UV protection from the sun and that can be spread uniformly and over a wide area of the terrain.

SUMMARY OF THE INVENTION

A composition comprising titanium dioxide (TiO₂), zinc oxide (ZnO), silicon dioxide (SiO₂), a surfactant, wetting, dispersant agent (SWD) and a pigment are suspended in a suspension concentrate for use as sun protection for plants, for example, turfgrass. A dilute solution using the composition is suitable for application using conventional spraying equipment such as a backpack sprayer or a boom sprayer. The TiO₂ and ZnO, in combination form an aggregate composed of varying sized particles resulting in enhanced sun protective properties. The particles are suspended in such a way that they are evenly dispersed throughout the composition and thus provide even coverage when sprayed. The composition protects the plant through its high refractive index and attenuation of ultra violet radiation, resulting in less plant damage from drought, heat stress, and sunburn.

DETAILED DESCRIPTION OF THE EMBODIMENTS

When used in this specification, the term exemplary should be given the meaning of representative or serving as an illustration or specimen. Use of the term exemplary should not be construed to indicate any other status such as preferred, commendable, worthy of imitation, or the like.

By shielding a plant, for example, turfgrass from harmful ultra-violet (UV) radiation, the health and vitality of the plant may be dramatically improved. The rate of photosynthesis in plants is directly affected by temperature. For example, when turfgrass reaches a temperature of about 84° F., the turfgrass plant shuts down, stopping photosynthesis until the temperature again drops into an acceptable range. Water in the soil is used by the plant in an attempt to regulate the leaf temperature. However, in situations where there is inadequate water available to compensate for the high temperature, the plant goes dormant. Dormancy is observable in browning of turfgrass and the cessation of growth. In the context of a household lawn, the turfgrass browns and remains that way until the temperature drops, or sufficient water is applied through watering or rainfall at which time the turfgrass revives itself, becoming green and continuing to grow.

In turfgrass applications such as a golf course, however, dormancy of the turfgrass creates additional problems. First, the aesthetics of brown turfgrass at a finely groomed golf course is unacceptable to most customers utilizing the course. The additional pressure of pedestrian and cart traffic on the turfgrass contributes to further damage, as the turfgrass cannot grow and regenerate itself. Once the turfgrass is damaged by traffic, it may not grow back, causing the permanent damage to be particularly evident. Common types of turfgrass used in golf courses include but are not limited to Kentucky Bluegrass, Bentgrass, Ryegrass, Bermuda grass, Fescue and the like.

By way of non-limiting example, the composition may be used on ryegrass. Ryegrass is a popular choice for turfgrass because of its ability to rapidly produce thick, durable turf. One of the world's most widely used grasses, Ryegrass possesses the ability to germinate in as little as 7 to 10 days. Being a cool season grass, ryegrass is commonly used in Northern regions, or is used to overseed dormant grass during the winter months in hotter regions, such as the Southern United States. Ryegrass produces dark green turf with a strong root system and is resistant to some diseases which frequently affect other grasses like bluegrass. Ryegrass thrives in a variety of soil types and even grows well in clay and compacted areas. When the composition is applied to the turf canopy (the distance between the soil and the tip of the blade of turfgrass) of ryegrass, the UV blocking properties of the composition protect the ryegrass from sun damage and help produce healthy vibrant turfgrass.

Certain compositions have traditionally been used in an attempt to shield plants from the damaging effects of the sun. The main ingredients of these conventional compositions have been calcium carbonate (limestone) or kaolin clay. These products act to create a thick film over the plant or fruit to prevent insect damage (e.g. in the case of kaolin clay) and sun damage. Compositions that use limestone preparations are very high in pH. As a result, such compositions are not suitable for turfgrass where high pH conditions are undesirable, in that among other things, high pH environments facilitate fungal diseases. Additionally, these materials are highly soluble in water, and tend to wash off the plant surface when it rains. Furthermore, the film created by kaolin clay applications is not suitable for turfgrass for aesthetic reasons, as the clay changes the color of the turfgrass to the reddish brown color of the clay.

An embodiment of the composition provides exceptional sun blocking characteristics when applied to the surfaces of plants, such as turfgrass. In an embodiment, the composition comprises the following: TiO₂, ZnO, SiO₂, a surfactant/wetting/dispersant agent (SWD), and a pigment. Combined with a small amount of water, this produces a suspension concentrate. The suspension concentrate may be diluted in water to be used for example, in a sprayer and applied to an affected area. The proportion of TiO₂ may be a range of about 15%-35% by weight composition with an exemplary proportion of about 27% by weight. The proportion of ZnO may be in a range of 6%-17% by weight composition, in an embodiment about 9% by weight. In an exemplary embodiment, the ratio by weight composition of TiO₂ to ZnO is between about 3:1 to 5:1. The proportion of SWD may be in the range of 15%-35% by weight composition with an exemplary proportion of about 27% by weight. SiO₂ is present in a proportion by weight composition in the range of 5%-25% with an exemplary proportion of about 18% by weight.

Due to the white color of the TiO₂ and the ZnO, a pigment with a proportion composition of about 6% by weight may be added. The amount of pigment may be adapted so as to impart a color in the blue or green hues and produce a desired color of turfgrass upon application. For example, in an exemplary embodiment, the pigment may include a copper compound to impart a blue-green hue. The remainder of the composition is water, for example, in a proportion of about 9.5% by weight.

The properties of the individual components are described herein.

Titanium dioxide (TiO₂) occurs in nature, most commonly in a form known as rutile, a very stable form of TiO₂. Rutile has one of the highest refractive indices of any known material. A high refractive index attenuates UV radiation from the sun, redirecting the radiation as it passes through the TiO₂. TiO₂ has strong UV absorbing capabilities that along with its high refractive index provide very high UV protection. Additionally, TiO₂ is also stable and not subject to discoloration under UV light. Further, TiO₂ is a photo-catalyst under UV light. When exposed to UV light, valence electrons in the TiO₂ are released causing surface oxidation which serves to eliminate potentially harmful organic substances such as bacteria and fungi. The anti-microbial characteristics of TiO₂ as a photo catalyst may protect turfgrass from harmful bacterial or fungal infections in addition to its sun blocking properties.

Zinc oxide (ZnO), like TiO₂ has a high refractive index and also exhibits anti-bacterial properties. ZnO in the presence of water produces Hydrogen Peroxide when exposed to UV light. Both ZnO and TiO₂ are opaque and white in color and often used as white pigments. Therefore, according to an embodiment, the composition includes a pigment to compensate for the opacity of the TiO₂ and the ZnO. The particle size of ZnO affects the wavelength at which absorption characteristics are maximized. Thus, the use of a variety of particle sizes in an aggregate form and the tandem use of TiO₂ and ZnO provide broad protection across the entire UV spectrum.

Silicon dioxide (SiO₂) promotes plant health through the formation of a thick silicated epidermal cell layer that maintains erect leaves and enhances photosynthesis. SiO₂, also known as silica, is the most abundant mineral in the Earth's crust. Silica is absorbed into the plant's epidemic layer and promotes resistance to pests through the formation of a thick cuticle silicon layer. Silica helps reduce water losses to transpiration and thereby increases the plant's ability to regulate its temperature.

As described above, TiO₂ has high opacity and a white color. ZnO is slightly less opaque than TiO₂ but still is characterized by a white color. For this reason, application of TiO₂ and ZnO to plants, for example, turfgrass leaves the plants with a white appearance. A pigment is added to the composition so that application of the composition to the plant, for example, turfgrass provides the plant with a natural color appearance. In one embodiment, the pigment is generally blue with some green pigments and is obtained copper compounds.

In order to get the particles of SiO₂, ZnO, and SiO₂ to remain in suspension, a surfactant, wetting agent and dispersant (SWD) is used. A surfactant or wetting agent is a substance that lowers the surface tension of a liquid and lowers the interfacial tension between two different liquids. A SWD is utilized as part of the composition so the particles of TiO₂, ZnO, and SiO₂ form a suspended solution preventing sedimentation and clumping. A surfactant allows the bonding of a non-aqueous substance like ZnO to be combined in solution thereby facilitating even spreading and stable suspension in solution. A dispersant or dispersing agent is added to a solution to improve the separation of particles and to prevent settling and clumping. By way of a non-limiting example, AU-330L, manufactured by Adjuvants Unlimited of Tulsa, Okla. may be used as a SWD.

The TiO₂, ZnO, and SiO₂ begin as granules with particle sizes, for example, in the range of about 0.5 to 1 mm. Smaller particles create dust while mixing and tend to reduce the operational lifetime of spraying equipment and risk the health of operators who must handle the materials and may breathe in dust from the dry raw materials. The use of granules reduces the dust created during the mixing process and produces the aggregate of particle sizes that provide the widest range of UV protection. The SWD maintains the aggregate particles in solution which keeps them sufficiently mixed for effective application to the turfgrass. If sedimentation or clumping occurs, the resulting composition does not fit through a nozzle in a sprayer. Therefore, it is important to maintain the particles in a solution. Such clumping, may cause non-uniform flow through the nozzle of a sprayer, resulting in uneven application to the turfgrass. In more severe circumstances, clumping may result in a fouled or clogged nozzle, further reducing the equipment's operational capacity and overall lifetime.

The sunscreen composition described herein is effective at improving the health and vitality of turfgrass exposed to heat stress and overexposure to the sun's UV radiation. Due to its consistency, the composition is dispersed uniformly via conventional spraying equipment and provides even protection over the spraying area and provides the synergistic advantageous properties provided by all the ingredients. When test sprayed on areas of turfgrass during times of extreme heat and sunlight, turfgrass covered with the composition exhibited vibrant healthy grass compared to control areas that were not treated with the composition.

In an embodiment of the sunscreen composition, a suspension concentrate is formed consisting of TiO₂, ZnO, SiO₂, a pigment, water, and a SWD. The TiO₂ is added in a proportion of about 30.12 percent by weight. The ZnO is added in a proportion of about 9.04 percent by weight. SiO₂ is added in a proportion of about 18.07 percent by weight. A pigment is added to adapt the sunscreen composition to the color of the turf to be treated such that the pigment makes up a proportion of the sunscreen composition at about 6.02 percent by weight. A SWD is added to form a proportion of about 27.10 percent by weight. Finally, water is added in a proportion of about 9.65 percent by weight. According to this embodiment, an amount of suspension concentrate sufficient to cover one acre may be prepared by combining 0.80 pounds (lbs) of water, 2.25 lbs of SWD, 2.50 lbs of TiO₂, 0.75 lbs of ZnO, 1.50 pounds of SiO₂ and 0.5 lbs of pigment.

The suspension concentrate is diluted in water to form a sunscreen solution. The sunscreen solution may then be applied to an area containing plants to be protected in a conventional manner such as a sprayer. The sunscreen solution when sprayed provides an even dispersion of particles providing effective protection from heat stress and sunburn.

In accordance with an embodiment of the composition, a sunscreen for application to plants including turfgrass, is formed by combining in dry form, TiO₂ in an amount representing from about 10% to about 45% by weight of the composition. The TiO₂ may be comprised of particles having particle sizes of about 0.5 millimeters (mm) to about 1.0 mm. ZnO is added to the TiO₂ in a dry form such that the ZnO make up about 6% to about 17% of the composition by weight. The ZnO may likewise be comprised of particles with particle sizes of about 0.5 millimeters (mm) to about 1.0 mm. In an exemplary embodiment, the ratio of TiO₂ to ZnO in the composition by weight is about 3:1 to about 5:1. Added to the combined dry TiO₂ and the dry ZnO, SiO₂ is added in a dry form such that the SiO₂ comprises from about 10% to about 30% of the composition by weight. The combined TiO₂, ZnO, and SiO₂ are then mixed with a SWD. The SWD is a liquid, for example, AU-330L, a SWD manufactured by Adjuvants Unlimited of Tulsa Okla. may be used as the SWD according to an embodiment of the composition. The SWD may constitute from about 15% to about 35% of the composition by weight. The dry TiO₂, ZnO and SiO₂ along with the SWD are combined with water at a percentage by weight of about 9% of the composition. The TiO₂, ZnO, SiO₂, SWD and water may further be combined with a pigment adapted to match a natural color of the turfgrass to which it is applied. A pigment added to the composition may make up about 6% of the composition by weight. The combined components are then mixed in accordance with chemical mixing techniques well known in the art. The resultant composition is a suspension concentrate. The suspension concentrate may be mixed with an amount of water to produce a sunscreen solution adapted to provide UV protection from the sun and be spread uniformly and over a wide area of the terrain.

The sunscreen solution may then be applied to a plant, such as turfgrass by methods commonly employed in the art, such as conventional high-volume hydraulic sprayer, low volume sprayers, ultra-low volume sprays, pressurized liquid injection and like. The relative amounts applied to turfgrass such as ryegrass, is about 1.7 ounces (oz.) to about 3.4 oz. per 1,000 sq. ft.. In an embodiment, the first application of the composition may be performed prior to the onset of heat or sun stress or when the temperature exceeds 80° F. The composition may be applied every 7 to 21 days depending on the rate used, existing weather conditions and the growth rate of the turfgrass. A lower application interval may be used when conditions of low humidity and intense sun are forecasted. It is desirable to provide continuous and uniform to improve the health of treated turfgrass. Tests performed on areas treated with the composition of this embodiment show increased growth rate and vitality of the treated turfgrass. Other benefits are documented based on the use of an embodiment of the composition. In a test on mature creeping bentgrass with a fairway height stand, compositions containing Titanium, Zinc and an embodiment of the composition were applied to test plots of bentgrass along with test plots treated with the commercial fungicide DACONIL brand of chlorothalomil and compared to an untreated control to observe the effect of the treatments on Dollar Spot, a fungal disease that affects many varieties of turfgrasses infected by the fungus Sclerotinia homeocarpa. Test plots were rated as to Dollar Spot severity, turfgrass color and overall turfgrass quality. The test was conducted at a time when dollar spot pressure was severe and the level of turfgrass quality was low due to Dollar Spot blighting. Dollar Spot severity was reduced in all treatments compared with the untreated control. The commercial fungicide resulted in the highest turfgrass quality rating followed by an embodiment of the composition which performed better than either the Ti or Zn alone. Testing thus shows that in addition to the sun screening characteristics of the composition, the additional benefit of fungal disease control is provided by the composition.

In testing, an embodiment of the composition consisting of TiO₂ in a proportion of about 30.12 percent by weight, ZnO in a proportion of about 9.04 percent by weight, SiO₂ in a proportion of about 18.07 percent by weight, a pigment in a proportion of about 6.02 percent by weight, a SWD in a proportion of about 27.10 percent by weight, and water in a proportion of about 9.65 was applied to five 5 cm×5 cm poly methyl methacrylate (PMMA) plates. An additional 5 cm×5 cm PMMA plate was left untreated. Each plate was placed over an integrating sphere aperture of a double monochromator spectroradiometer and irradiated with a solar simulator. The spectral irradiance at wavelengths from 250-800 nm was measured at 1 nm intervals for each plate treated with the composition as well as the untreated plate. A transmission, T_λ of the composition at each wavelength was computed as the ratio of spectral irradiance transmitted by each substrate, with and without the embodiment of the composition. An average value of 1-T_λ for each test treatment was computed as the percentage screened. Based on the test, the composition screened 76% of the solar energy in the ultraviolet spectrum relative to the untreated plate. Furthermore, the composition screened 82% of visible solar energy and 14% of near infrared solar energy.

The above provides a detailed description of a sunscreen composition according to various embodiments of the described composition. This description is provided by way of example only and is not intended to be limiting in any way. The scope of the present invention is limited only by the accompanying set of claims.

Claims

1. A sunscreen composition to be used on plants comprising:

titanium dioxide (TiO2);

zinc oxide (ZnO); and

a surfactant, wetting agent, dispersant (SWD);

wherein the composition is effective in protecting plants from ultraviolet radiation damage, said TiO2 and ZnO in combination comprising greater than about 30% by weight.

2. The sunscreen composition of claim 1, wherein the ratio of TiO2 to ZnO is from about 3:1 to about 5:1 by weight.

3. The sunscreen composition of claim 1, further comprising a pigment.

4. The sunscreen composition of claim 3, wherein the pigment is adapted to match a natural color of the plants.

5. The sunscreen composition of claim 3, wherein said pigment is a copper compound.

6. The sunscreen composition of claim 1, comprising from about 25% to about 45% TiO2 by weight.

7. The sunscreen composition of claim 1, comprising from about 6% to about 17% ZnO by weight.

8. The sunscreen composition of claim 1, comprising from about 15% to about 35% SWD by weight.

9. The sunscreen composition of claim 1, further comprising water.

10. The sunscreen composition of claim 3, the pigment comprising about 6% by weight.

11. The sunscreen composition of claim 1, wherein said TiO2 and said ZnO combine to form an aggregate having a plurality of particle sizes.

12. The sunscreen composition of claim 1, comprising about 30% TiO2 by weight.

13. The sunscreen composition of claim 1, comprising about 9% ZnO by weight.

14. The sunscreen composition of claim 2, comprising about 27% SWD by weight.

15. A method of protecting turfgrass from heat stress, sunburn or ultraviolet radiation, comprising the steps of:

diluting a concentrated sunscreen composition comprising: titanium dioxide (TiO2), zinc oxide (ZnO), and a surfactant, wetting agent, dispersant (SWD), said TiO2 and ZnO in combination comprising greater than about 30% by weight; and

applying said diluted sunscreen composition on an area of turfgrass to thereby protect the applied area of turfgrass from heat stress, sunburn or ultraviolet radiation damage.

16. The method of claim 15, wherein said concentrated sunscreen composition further comprises a pigment adapted to match a natural color of the area of turfgrass, said pigment in an amount of about 6% by weight.

17. The method of claim 15, wherein the composition comprises about 27% TiO2 by weight; and about 9% ZnO by weight.

18. The method of claim 17, wherein the composition further comprises about 15% to about 35% SWD by weight.

19. The method of claim 15, wherein said TiO2 and said ZnO combine to form an aggregate having a plurality of particle sizes.

20. The method of claim 15, wherein the diluting is performed by mixing the concentrated sunscreen composition with an equal part water.