APPARATUS FOR MAKING A HIGH LOFT, NON-WOVEN WEB EXHIBITING EXCELLENT RECOVERY
An apparatus for making a high loft, non-woven web exhibiting excellent recovery is disclosed. The web has a 3-dimensional structure with fibers oriented in the x, y and z directions. The apparatus includes a die having 2 to 20 rows of nozzles with each row containing a plurality of nozzles. A pair of moving surfaces is located from a distal end of each nozzle. The pair of moving surfaces form a convergent passage. A pair of heaters is used to heat each of the pair of moving surfaces. A plurality of filaments are deposited onto the pair of moving surfaces and are routed through the convergent passage to form a 3-dimensional structure having two thin outer skins.
This application is a Continuation-In-Part of non-provisional Application Ser. No. 14/167,431, filed Jan. 29, 2014, which is incorporated herein by reference in its entirety,
FIELD OF THE INVENTIONThis invention relates to an apparatus for making a high loft, non-woven web exhibiting excellent recovery, especially a web formed from a single polymer and using a single “Spun-blown” die.
BACKGROUND OF THE INVENTIONTypically, polymeric fibers, formed by spunbonding, meltblowing or by some other extrusion process are collected downstream from an emitter, such as a die with a plurality of nozzles, on a horizontal oriented conveyor belt. Such processes tends to produce two-dimensional web where the fibers are oriented in the x and y directions since they are laid down in a horizontal plane. There are few if any fibers within the formed web that are oriented in the z-direction. Because of this, the finished web tends to lack recovery once it is compressed. This presents an issue when such finished webs need to be rolled up or stacked for transport by truck or rail to a distance manufacturing facility. If the webs are compacted or compressed during shipment, they lack the ability to recovery to their original thickness. In addition, once compacted or compressed, such webs tend to become hard and/or stiff and their pore structure may become less open. Furthermore, the drapeability of such webs can be diminished. Functionally, if a compacted or compressed web cannot recovery to approximately its initial loft thickness after shipment, it can lose some of its thermal and/or acoustical insulation properties, thereby rendering the material less than desirable for this purpose,
Now, an apparatus for making a high loft, non-woven web exhibiting excellent recovery has been invented, especially a web formed from a single polymer and using a single “Spun-blown” die.
SUMMARY OF THE INVENTIONBriefly, this invention relates to an apparatus for making a high loft, non-woven web exhibiting excellent recovery.
The high loft, non-woven web is a 3-dimensional structure with fibers oriented in the x, y and z directions. The high loft, non-woven web can be constructed as a single layer or can be formed with two or more layers. The high loft, non-woven web has a thickness of less than about 250 millimeters and a basis weight of from between about 20 g/m2 to about 3,000 g/m2. The high loft, non-woven web can be bonded using a thermal bonder, a chemical bonder, a hydro-mechanical bonder, a mechanical bonder, or be left unbonded. A vertical cross-section of the web, when taken parallel to its machine direction, exhibits two thin outer skins, each having a thickness of less than about 2.5 millimeters, with a plurality of snugly stacked, approximately V, U, or C-shaped structures formed therebetween. Each of the approximately V, U, or C-shaped structure has an apex facing in the machine direction. The high loft, non-woven web has a recovery value of from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes, The high loft, non-woven web also has a wide fiber size distribution with the larger fibers providing the unique recovery value.
An apparatus for producing a high loft, non-woven web has a 3-dimensional structure with fibers oriented in the x, y and z directions. The apparatus includes a die having 2 to 20 rows of nozzles, with each row having a plurality of nozzles each emitting a filament, and each of the plurality of nozzles having a distal end. By “plurality of nozzles” it is meant 3 or more nozzles. A pair of moving surfaces is located from between about 10 cm to about 150 cm of the distal end of each of the plurality of nozzles. A pair of heaters is also present with each heater being associated with one of the pair of moving surfaces. The pair of heaters is capable of heating the pair of moving surfaces to an elevated temperature below the melting temperature of the polymer. The pair of moving surfaces forms a convergent passage having an entry and an exit. The apparatus also includes a mechanism for depositing the plurality of filaments onto and between the pair of heated moving surfaces. The plurality of filaments is routed through the convergent passage in descending travel from the entry to the exit to form a 3-dimensional structure. The apparatus further includes a bonder located downstream of and in vertically alignment with the pair of moving surfaces for bonding the 3-dimensional structure to create a high loft, non-woven web with the filaments transformed into fibers oriented in the x, y and z directions. The web has a thickness of less than about 250 mm and a basis weight ranging from between about 20 g/m2 to about 3,000 g/m2. A vertical cross-section of the high loft, non-woven web, when taken parallel to its machine direction, exhibits two thin outer skins with a plurality of snugly stacked, approximately V, U, or C-shaped structures formed therebetween. Each of the outer skins is less than about 2.5 millimeters in thickness. Each of the approximately V, U, or C-shaped structure has an apex facing in the machine direction. The high loft, non-woven web has a recovery value ranging from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes. The high loft, non-woven web also has a wide fiber size distribution with the larger fibers providing the unique recovery value.
A process for forming a high loft, non-woven web is also taught which has a 3-dimensional structure with fibers oriented in the x, y and z directions. The process includes the steps of introducing a molten polymer to a die having 2 to 20 rows of nozzles with each row containing a plurality of nozzles. The molten polymer is emitted, ejected or extruded through the plurality of nozzles to form a plurality of filaments. Air or gas streams are then used to facilitate downward movement of the plurality of filaments. The filaments are directed towards a pair of moving surfaces located at a distance of from between about 10 cm to about 150 cm from the plurality of nozzles. A pair of heaters is also present with each heater being associated with one of the pair of moving surfaces. The pair of heaters is capable of heating the pair of moving surfaces to an elevated temperature below the melting temperature of the polymer. The pair of moving surfaces forms a convergent passage having an entry and an exit. The plurality of filaments is deposited into the entry of the convergent passage. The plurality of filaments is then routed through the convergent passage in descending travel from the entry to the exit and between the pair of heated moving surfaces in a machine direction to form a 3-dimensional structure with the filaments transformed into fibers which are oriented in the x, y and z directions. Lastly, the 3-dimensional structure is immediately bonded upon contacting the heated moving surfaces to form a high loft, non-woven web having a thickness of less than about 250 millimeters and a basis weight ranging from between about 50 g/m2 to about 3,000 g/m2. A vertical cross-section of the high loft, non-woven web, when taken parallel to its machine direction, exhibits two thin outer skins, each having a thickness of less than about 2.5 millimeters, with a plurality of snugly stacked, approximately V, U, or C-shaped structures formed therebetween. Each of the approximately V, U, or C-shaped structure having an apex facing in the machine direction. The high loft, non-woven web has a recovery value ranging from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes. The high loft, non-woven web also has a wide fiber size distribution with the larger fibers providing the unique recovery value.
The general object of this invention is to provide an apparatus for making a high loft, non-woven web which exhibits excellent recovery. A more specific object of this invention is to provide an apparatus for making a high loft, non-woven web from a single polymer in a single step, using a single “Spun-blown” die which has good thermal insulation and/or acoustical insulation values.
Another object of this invention is to provide an apparatus for making a high loft, non-woven web which has a wide fiber size distribution with the larger fibers providing the unique recovery value, and the web can be used in bedding, upholstery, filtration, can replace foam materials, and can be used in products utilizing cushioning materials.
A further object of this invention is to provide an apparatus for making a high loft, non-woven web which exhibiting from between about 20% to about 99% recovery after compression, has a wide fiber size distribution, and which exhibits a high porosity.
Still another object of this invention is to provide an apparatus for making a high loft, non-woven web which exhibits excellent recovery such that it can be compactly shipped without losing any material properties.
Still further, an object of this invention is to provide an apparatus for making a high loft, non-woven web which exhibits from between about 20% to about 99% recovery after compression.
Other objects and advantages of the present invention will become more apparent to those skilled in the art in view of the following description and the accompanying drawings.
Referring to
The high loft, non-woven web 10 can contain a single polymer formed from a variety of materials. The high loft, non-woven web 10 can be formed from man-made fibers. Typically, the high loft, non-woven web 10 is formed from a polymer. The polymer can be selected from the group consisting of: polyolefins, polyesters, polyethylene terephthalates, polybutylene terephthalates, polycyclohexylene dimethylene terephthalates, polytrimethylene terephthalates, polymethyl methacrylates, polyamides, nylons, polyacrylics, polystyrenes, polyvinyls, polytetrafluoroethylenes, ultrahigh molecular weight polyethylenes, very high molecular weight polyethylenes, high molecular weight polyethylenes, polyether ether ketones, non-fibrous plasticized celluloses, polyethylenes, polypropylenes, polybutylenes, polymethylpentenes, low-density polyethylenes, linear low-density polyethylenes, high-density polyethylenes, polystyrenes, acrylonitrile-butadiene-styrenes, styrene-acrylonitriles, styrene-butadienes, styrene-maleic anhydrides, ethylene vinyl acetates, ethylene vinyl alcohols, polyvinyl chlorides, cellulose acetates, cellulose acetate butyrates, plasticized cellulosics, cellulose propionates, ethyl celluloses, natural fibers, any derivative thereof, any polymer blend thereof, any copolymer thereof or any combination thereof. Desirably, the high loft, non-woven web 10 is formed from polypropylene fibers. More desirably, the high loft, non-woven web 10 is formed solely from polypropylene fibers. Even more desirably, the high loft, non-woven web 10 is formed from 100% polypropylene fibers. Most desirably, the high loft, non-woven web 10 is formed from Biax's spun-blown® polypropylene fibers. The word “spun-blown” is a registered trademark of Biax-Fiberfilm Corporation having an office at N1001 Tower View Drive, Greenville, Wis. 54942.
Those skilled in the chemical arts may know of other polymers that can also be used to form the high loft, non-woven web 10. It should be understood that the high loft, non-woven web 10 is not limited to just those polymers identified above.
It should be noted that up until now, most fibrous non-woven webs required staple fibers and/or crimp fibers in order to have a significant recovery. U.S. Pat. No. 7,476,632 B2, issued Jan. 13, 2009, to Olson et al. is one example of a fibrous non-woven web which requires staple fibers in order to exhibit loft and recovery. The present invention does not use staple fibers.
The high loft, non-woven web 10 can be formed or manufactured using many different kinds and types of equipment and processes. Some commonly known technology which can be used to form the high loft, non-woven web 10 include, but are not limited to spinning processes such as: meltblowing, spunbond, spunmelt, solution blowing, electrospinning. However, these other processes do not provide the desired wide fiber size distribution useful in the recovery with good acoustical properties all out of a single die, as the Spun-blown® die exhibits.
By “spunbond” it is meant a process for producing a strong, fibrous non-woven webs directly from thermoplastic polymers by attenuating the spun filaments using low temperature, high speed air, while quenching the fibers near the spinnerette face. Individual fibers are then laid down randomly on a collection belt and are then conveyed to a bonder. The bonder gives the web strength and integrity. Fiber size is usually below 250 μm, the average fiber size is in the range of from between about 10 microns to about 50 microns, and the fibers are very strong compared to meltblown fibers because of the molecular chain alignment that is achieved during the attenuating of the crystallized (solidified) filaments. A typical spunbond die has multiple rows of polymer nozzle holes. A typical melt flow rate is below about 500 grams/10 minutes.
By “spunmelt” it is meant a process where fibers are spun from molten polymers through a plurality of nozzles located in a die head connected to one or more extruders. A spunmelt process may include meltblowing and/or spunbonding.
By “meltblowing” it is meant a process where a plurality of molten polymer streams are attenuated using an elevated temperature, high speed gas stream. The gas can be air or a gas known to those skilled in the art. The attenuated fibers are then collected on a movable belt, conveyor or a dual drum collector. Typically, a meltblowing die has around 35 nozzles per inch, a row of spinnerettes and two inclined air or gas jets for attenuating the fiber streams. U.S. Pat. No. 4,380,570 and WO 2005/106,085 A1 teach meltblowing processes where multiple rows of polymer nozzles are surrounded by air nozzles and the streams flowing therefrom are aligned parallel to one another.
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The two thin outer skins 13 and 15 function to retain the approximately V, U, or C-shaped fibrous structure therebetween. The V, U, or C-shaped fibers provide the recovery feature of this invention since they act as springs and can return to or near their original position after being squeezed or compressed. The V, U, or C-shaped fibers are not bonded like the fibers which form the two thin outer skins 13 and 15.
The two thin outer skins 13 and 15 are formed as the polymer contacts the heated moving surfaces, as will be explained in more detail below. The two thin outer skins 13 and 15 eliminate the need to further form or attach an outer skin to the non-woven web 10 to provide for abrasion resistance and or acoustical enhancements. In addition, the V, U, or C-shaped fibers, located between the two thin outer skins 13 and 15, exhibit a wide fiber size distribution wherein the thicker fibers act as the springs to provide recovery, while the finer fibers provide the non-woven web 10 with superior sound absorbing properties. The finer fibers (percentage wise) are concentrated in the middle or center of the non-woven web 10. Desirably, at least about 50% of the fine fibers are located in the middle of the non-woven web 10. More desirably, at least about 55% of the fine fibers are located in the middle of the non-woven web 10. Even more desirably, at least about 60% of the fine fibers are located in the middle of the non-woven web 10. Most desirably, at least about 65% of the fine fibers are located in the middle of the non-woven web 10.
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In
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The high loft, non-woven web 10 can be formed with different basis weights. Generally, the basis weight of the high loft, non-woven web 10 ranges from between about 20 grams per square meter (g/m2) to about 3,000 g/m2. Desirably, the basis weight of the high loft, non-woven web 10 ranges from between about 30 grams per square meter (g/m2) to about 2,000 g/m2. More desirably, the basis weight of the high loft, non-woven web 10 ranges from between about 40 grams per square meter (g/m2) to about 1,000 g/m2. Even more desirably, the basis weight of the high loft, non-woven web 10 is less than about 600 g/m2. Most desirably, the non-woven web 10 will have a basis weight of from between about 20 to about 600 grams per square meter.
The high loft, non-woven web 10 can also vary in density. Generally, the high loft, non-woven web 10 has a density ranging from between about 10 kilograms per cubic meters (kg/m3) to about 250 kg/m3. Desirably, the high loft, non-woven web 10 has a density ranging from between about 20 kg/m3 to about 200 kg/m3. More desirably, the high loft, non-woven web 10 has a density ranging from between about 30 kg/m3 to about 150 kg/m3. Even more desirably, the high loft, non-woven web 10 has a density ranging from between about 50 kg/m3 to about 100 kg/m3.
Furthermore, the high loft, non-woven web 10 can be formed from polypropylene having a melt flow rate ranging from between about 4 g/10 min. to about 6,000 g/10 min at a temperature of 230° C. and at a pressure of 2.16 kg according to the teachings of ASTM D 1238 testing method. Desirably, the high loft, non-woven web 10 can be formed from polypropylene having a melt flow rate ranging from between about 10 g/10 min. to about 2,500 g/10 min at a temperature of 230 ° C. and at a pressure of 2.16 kg. More desirably, the high loft, non-woven web 10 can be formed from polypropylene having a melt flow rate ranging from between about 20 g/10 min. to about 1,000 g/10 min at a temperature of 23° C. and at a pressure of 2.16 kg. Most desirably, the high loft, non-woven web 10 can be formed from polypropylene having a melt flow rate ranging from between about 35 g/10 min, to about 800 g/10 min at a temperature of 230° C. and at a pressure of 2.16 kg.
Referring again to
It should be understood that each of the two layers of the web 10′, see
Referring again to
The two layered web 10′ has a recovery value of from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes according to the guidelines of the IST 120.2 (01). Desirably, the two layered web 10′ has a recovery value ranging from between about 30% to about 98% according to the guidelines of the IST 120.2 (01). More desirably, the two layered web 10′ has a recovery value ranging from between about 40% to about 97% according to the guidelines of the IST 120.2 (01). Even more desirably, the two layered web 10′ has a recovery value ranging from between about 50% to about 96% according to the guidelines of the IST 120.2 (01).
It should be understood that the two layer web 10′ can be formed as two separate layers 14 and 16 from co-mingled fibrous materials where each layer has a different fiber size, is formed from a different material, has different fiber cross-sections, has a different thickness, etc. Furthermore, the two layered web 10′ could be laminated to one or more layers. The additional layers could be a thermoplastic film, a film, another non-woven material, paper, cardboard, etc.
Referring again to
The three layered web 10″ has a recovery value of from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes according to IST 120.2 (01), Desirably, the three layered web 10 has a recovery value ranging from between about 30% to about 98% according to IST 120.2 (01). More desirably, the three layered web 10 has a recovery value ranging from between about 40% to about 97% according to IST 120.2 (01). Even more desirably, the three layered web 10 has a recovery value ranging from between about 50% to about 96% according to IST 120.2 (01).
It should also be recognized that an additive can be incorporated into the high loft, non-woven web 10, 10′ or 10″. The additive (not shown) can be applied to the high loft, non-woven web 10, 10′ or 10″ during manufacture. The additive can be applied in various ways, including but not limited to: being sprayed on, being sprinkled on, being extruded, being combined with, being painted on, being immersed, etc. The additive can be a gas, a liquid, a solid or a semi-solid. The additive can be selected from the group consisting of: a superabsorbent, absorbent particles, polymers, nanoparticles, abrasive particulars, active particles, active compounds, ion exchange resins, zeolites, softening agents, plasticizers, ceramic particles pigments, dyes, flavorants, aromas, controlled release vesicles, binders, adhesives, tackifiers, surface modification agents, lubricating agents, emulsifiers, vitamins, peroxides, antimicrobials, deodorizers, fire retardants, flame retardants, antifoaming agents, anti-static agents, biocides, antifungals, degradation agents, stabilizing agents, conductivity modifying agents, or any combination thereof.
Referring now to
The two major surfaces, 28 and 30 can have a thickness as was explained above with reference to the outer skins 13 and 15.
EXAMPLE 1In this example, we were looking at the effect of spinning technology on web properties. Three (3) different non-woven webs were made using polypropylene resin. All three (3) had the same basis weight but each was spun using a different spinnerette design and different processing conditions. As shown in Table 1, sample S-1 was produced using a Biax multi-row spinnerette design that did not have air insulation inserts or an air shrouding curtain surrounding the periphery of the nozzles 38. Sample S-2 was produced using a conventional meltblown process which had only one line of nozzles along with inclined air jets. Sample S-3 was produced using the inventive process.
The sample S-3 achieved almost double the machine direction (MD) tensile strength as compared to sample S-1 or sample S-2. Also, one will notice that the fiber diameter of sample S-3 was slightly larger than the fiber diameter of the conventional meltblown sample S-2. The primary reason for this difference in diameter is that when using the inventive process, the colder air temperature in the annular channels is directed essentially parallel to the direction of flow of the filaments 40 in a multi-row fashion. In addition, by attenuating the fibers using colder gas one can increase fiber crystallinity and align the molecular chains inside the solidified fibers. This feature facilitates attenuation of the filaments 40 into strong, fine fibers. In a conventional meltblown process, the attenuating air is introduced at a steep or inclined angle, using hot air jets.
Referring now to
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Webs formed from conventional meltblown processes have a “fiber size distribution”, shown in the upper graph of
It should be understood that the fibers in the non-woven web 10, 10′, 10″ or 11 can have a Standard Deviation of from between about 0.9 microns to about 5 microns. Desirably, the fibers in the non-woven web 10, 10′, 10″ or 11 have a Standard Deviation of from between about 0.92 microns to about 3 microns. More desirably, the fibers in the non-woven web 10, 10′, 10′ or 11 have a Standard Deviation of from between about 0.95 microns to about 1.6 microns.
EXAMPLE 2In this second example, we were comparing a sample produced by the inventive process S-5 to a sample produced by a conventional meltblown process S-4, and to a sample produced by a conventional spunbond process S-6. Three (3) samples were made and each had the same basis weight. As shown in Table 2, the properties of sample S-5 were about half-way between the properties of the meltblown web S-4 and the spunbond web S-6. Table 2 also shows that the air permeability of the sample S-5 (using our inventive process) falls almost half-way between the conventional meltblown sample S-4 and the conventional spunbond sample S-6. This proves that our new technology is capable of producing non-woven webs that have fine fiber diameters, comparable to meltblown fibers, yet still have strong fibers when compared to spunbond fibers,
Referring to
From the above two examples, it is clear that a non-woven web 10, 10′, 10″ or 11 made using our inventive apparatus and process is unique and has properties that are about half-way between the properties exhibited by a non-woven web made using a conventional meltblown process, or a non-woven web made using a conventional spunbond process.
Furthermore, the apparatus 34, 34′ or 34″ of this invention is flexible and versatile enough to use a wide variety of polymeric resins to produce a wide range of non-woven webs. The apparatus 34, 34′ or 34″ can be operated using meltblown grade resins and well as spunbond grade resins.
Apparatus
Referring to
As stated above with reference to the web 10, 10′, 10″ or 11, the polymer can be polypropylene. Desirably, the polymer is solely polypropylene. More desirably, the polymer is 100% polypropylene.
A pair of moving surfaces 44 and 46 is located from between about 10 centimeters (cm) to about 150 cm of the distal end 42 of each of the plurality of nozzles 38. The pair of moving surfaces 44 and 46 can be a first rotatable drum 48 and a second rotatable drum 50, as is shown in
When the pair of moving surfaces, 44 and 46, consists of a first rotatable drum 48 and a second rotatable drum 50, the first rotatable drum 48 will have a diameter d1 and the second rotatable drum 50 will have a diameter d2. Desirably, the diameter d1 is approximately equal to the diameter d2. More desirably, the diameters d1 and d2 are identical. The first and second rotatable drums, 48 and 50 respectively, will be aligned parallel to one another on the same plane X1-X1. It should be understood that the apparatus 34 is horizontally oriented so that the filaments 40 will move from left to right in a machine direction (MD) between the first and second rotatable drums, 48 and 50 respectively.
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A unique aspect of this invention is that the pair of moving surfaces 44 and 46 is heated to an elevated temperature by a pair of heaters 45 or 47. A heater 45 is associated with the first rotatable drum 48 or the first conveyor belt 52, and another heater 47 is associated with the second rotatable drum 50 or the second conveyor belt 54. Each of the pair of heaters 45 and 47 can vary in size, construction, shape, etc. The heaters 45 and 47 can vary in design. The heaters 45 and 47 can be infrared heaters, gas heaters, thermal heaters or any other kinds of heaters known to those skilled in the art. By “infrared” it is meant of or relating to the range of invisible radiation wavelengths from about 750 nanometers, just longer than red in the visible spectrum, to 1 millimeter, on the border of the microwave region. The heaters 45 and 47 can be located on either side of the pair of moving surfaces 44 and 46. As shown, the pair of heaters 45 and 47 is located on the outside of the first and second rotatable drums, 48 and 50 respectively. Alternatively, the pair of heaters 45 and 47 could be located within each of the first and second rotatable drums, 48 and 50 respectively. Likewise, the pair of heaters 45 and 47 could be located on either side of the first and second conveyor belts, 52 and 54 respectively. The pair of heaters 45 and 47 should be located within about a foot or less from the pair of moving surfaces 44 and 46. The pair of heaters 45 and 47 can operate at different temperatures but need to be able to heat the pair of moving surfaces 44 and 46 to an elevated temperature. The elevated temperature should be below the melting temperature of the polymer being extruded. The melting temperature of various polymers will differ. The pair of heaters 45 and 47 should warm up the moving surfaces 44 and 46 before the filaments 40 are deposited onto or between the moving surfaces 44 and 46.
The elevated temperature of the pair of moving surfaces 44 and 46 should be less than the melting temperature of the polymer. Polypropylene has a melting temperature in the range of from between about 300° F. to about 340° F. Therefore, the elevated temperature of each of the pair of moving surfaces 44 and 46, for example, the first and second rotatable drums, 48 and 50 respectively, or each of the first and second conveyors belts, 52 and 52 respectively, should be less than the melting temperature of the polymer. The moving surfaces 44 and 46 can be heated to a temperature which is about 10° F. less than the melting temperature of the polymer. Desirably, the moving surfaces 44 and 46 can be heated to a temperature which is about 20° F. less than the melting temperature of the polymer. More desirably, the moving surfaces 44 and 46 can be heated to a temperature which is about 30° F. less than the melting temperature of the polymer. Most desirably, the moving surfaces 44 and 46 can be heated to a temperature which is about 40° F. less than the melting temperature of the polymer.
The elevated temperature of each of the pair of moving surfaces 44 and 46 could range from between about 180° F. to about 300° F. More desirably, the elevated temperature of each of the pair of moving surfaces 44 and 46 could range from between about 180° F. to about 275° F. Even more desirably, the elevated temperature of each of the pair of moving surfaces 44 and 46 could range from between about 180° F. to about 250° F. Still more desirably, the elevated temperature of each of the pair of moving surfaces 44 and 46 could range from between about 180° F. to about 225° F.
The first and second rotatable drums, 48 and 50 respectively, can be hollow cylinders with their outer peripheries covered with a forming wire or screen. The forming wire or screen can be produced from a variety of different materials known to those skilled in the art. For example, the forming wire or screen could be made from a synthetic material, such as polyethylene terephthalate (PET). Alternatively, the forming wire or screen could be made from: metal, steel, aluminum, a plastic, a thermoplastics, etc. The first and second rotatable drums, 48 and 50 respectively, could also be constructed out of various materials, such as steel, cast iron, aluminum, etc. Another option is to cover the outer peripheries of the first and second rotatable drums, 48 and 50 respectively, with metal belts. The metal belts could be ferrous or non-ferrous. The metal belts could contain a plurality of apertures, openings or holes arranged in a predetermined pattern or could be randomly arranged. The size and shape of the apertures, openings or holes can vary. As is known to those skilled in the art, each of the first and second rotatable drums, 48 and 50 respectively, can be equipped with a vacuum chamber, if desired. It is advantageous to heat the outer peripheries of the first and second rotatable drums, 48 and 50 respectively; so that the incoming filaments 40 will more readily form onto them. The reason for this is that the open mesh design of a wire, screen or a metal belt containing apertures, openings or holes can form a specific texture or pattern onto the outer surfaces of the high loft, non-woven web 10, 10′, 10″ or 11 that is being produced. Such texture or pattern may enhance the sound insulation and/or thermal absorption properties of the finished web 10, 10′, 10″ or 11. This is an important attribute when the finished high loft, non-woven web 10, 10′, 10″ or 11 is to be used for sound and/or thermal insulation purposes.
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The outer peripheries of the first and second rotatable drums, 48 and 50 respectively, are spaced apart from one another thereby creating a convergence passage 60. By “convergent passage” it is meant a point of converging, to approach a point. This converging passage 60 narrows down to a dimension equal to a nip 62 established between the first and second rotatable drums, 48 and 50 respectively. The nip 62 can vary in dimension. The first and second rotating drums, 48 and 50 respectively, should be mounted such that the dimension of the nip 62 established therebetween can be easily adjusted. Generally, the nip 62 can range from between about 0.5 cm to about 25 cm. Desirably, the nip 62 is greater than about 0.5 cm. More desirably, the nip 62 ranges from between about 0.5 cm to about 20 cm. Even more desirably, the nip 62 ranges from between about 0.5 cm to about 15 cm. Most desirably, the nip 62 is less than about 12 cm.
The convergent passage 60 has an entry 64 and an exit 66 established by the circumference of the first and second rotatable drums, 48 and 50 respectively. As the plurality of filaments 40 are deposited at the entry 64 of the convergent passage 60 they are directed and routed onto and between the pair of moving surfaces 44 and 46. The routing is facilitated by the rotation of the first and second rotatable drums, 48 and 50 respectively. The routing causes the plurality of filaments 40, which are warm, to pass through the convergent passage 60 in descending travel from the entry 64 to the exit 66. The rotational movement of the first and second rotatable drums, 48 and 50 respectively, will cause some of the plurality of filaments 40 to temporarily contact the outer peripheries of the first and second rotatable drums, 48 and 50 respectively. These filaments 40 will be compressed against the remaining filaments 40 passing through the nip 62 to create a high loft non-woven web 10. It should be understood that the elevated temperature of the molten filaments 40, together with the elevated temperature of the pair of moving surfaces 44 and 46, will cause the filaments 40 which are situated on the major surfaces 28 and 30, see
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It should be understood that some high loft, non-woven webs 10 can be formed from certain materials and for certain uses, wherein bonding is not necessary. However, for some high loft, non-woven webs 10, it may be advantageous to subject the high loft non-woven web 10 to an additional bonding process. Additional bonding generally imparts extra strength and integrity into the finished web 10. Various bonding techniques can be utilized. A single bonder or a pair of oppositely aligned bonders can be utilized.
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It should be understood that the high loft, non-woven web 10 could also be partially or fully immersed in a liquid solution containing an additive 80. The liquid solution could be chemically or electrically charged so as to cause the additive 80 to better adhere to the high loft, non-woven web 10.
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Referring now to
A pair of heaters 45 and 47 is used to elevate the temperature of the first and second conveyor belts 52 and 54. The heater 45 is associated with and positioned adjacent to the first conveyor belt 52, and the other heater 47 is associated with and positioned adjacent to the second conveyor belt 54. Each of the pair of heaters 45 and 47 can vary in size, construction, shape, etc. The heaters 45 and 47 can vary in design. The heaters 45 and 47 can be infrared heaters, gas heaters, thermal heaters or any other kinds of heaters known to those skilled in the art. By “infrared” it is meant of or relating to the range of invisible radiation wavelengths from about 750 nanometers, just longer than red in the visible spectrum, to 1 millimeter, on the border of the microwave region. The heaters 45 and 47 should be located within about a foot or less from each of the first and second conveyor belts 52 and 54. The heaters 45 and 47 can operate at different temperatures but need to be able to heat the first and second conveyor belts, 52 and 54 respectively, to an elevated temperature which is below the melting temperature of the polymer. Therefore, the elevated temperature of each of the first and second conveyor belts, 52 and 54 respectively, should be less than the melting temperature of the polymer. The first and second conveyor belts, 52 and 54 respectively, can be heated to a temperature which is about 10° F. less than the melting temperature of the polymer. Desirably, the first and second conveyor belts, 52 and 54 respectively, can be heated to a temperature which is about 20° F. less than the melting temperature of the polymer. More desirably, the first and second conveyor belts, 52 and 54 respectively, can be heated to a temperature which is about 30° F. less than the melting temperature of the polymer. Most desirably, the first and second conveyor belts, 52 and 54 respectively, can be heated to a temperature which is about 40° F. less than the melting temperature of the polymer.
The elevated temperature of the first and second conveyor belts, 52 and 54 respectively, should be less than the melting temperature of the polymer. Polypropylene has a melting temperature in the range of from between about 300° F. to about 340° F. Therefore, the elevated temperature of each of the first and second conveyor belts, 52 and 54 respectively, should be less than the melting temperature of the polymer. Desirably, the elevated temperature of each of the first and second conveyor belts, 52 and 54 respectively, should range from between about 180° F. to about 300° F. More desirably, the elevated temperature of each of the first and second conveyor belts, 52 and 54 respectively, should range from between about 180° F. to about 275° F. Even more desirably, the elevated temperature of each of the first and second conveyor belts, 52 and 54 respectively, should range from between about 180° F. to about 250° F. Still more desirably, the elevated temperature of each of the first and second conveyor belts, 52 and 54 respectively, should range from between about 180° F. to about 225° F.
The first and second conveyor belts, 52 and 54 respectively, converge toward one another at a point located farthest away from the distal end 42 of each of said plurality of nozzles 38. An opening 55, equivalent to the nip 62, is present between the first and second conveyor belts 52 and 54 respectively. The opening 55 occurs and is situated at a plane X2-X2. The plane X2-X2 is equivalent to the plane X1-X1, shown in
As clearly shown in
Still referring to
If additional bonding is desired, the high loft non-woven web 10 could be routed pass a thermal bonder 74 by a conveyor belt 84. The conveyor belt 84 is mounted on a plurality of rollers 86. Four rollers 86 are depicted in
It should be understood that some high loft, non-woven webs 10 can be formed from certain materials and for certain uses, wherein additional bonding is not necessary.
Process
The process of forming the high loft, non-woven web 10, 10′, 10″ or 11 will be explains with reference to
The elevated temperature of the first and second rotatable drums, 48 and 50 respectively, should be less than the melting temperature of the polymer. Polypropylene has a melting temperature in the range of from between about 300° F. to about 340° F. Therefore, the elevated temperature of each of the first and second rotatable drums, 48 and 50 respectively, should be less than the melting temperature of the polymer. Desirably, the elevated temperature of each of the first and second rotatable drums, 48 and 50 respectively, should range from between about 180° F. to about 300° F. More desirably, the elevated temperature of each of the first and second rotatable drums, 48 and 50 respectively, should range from between about 180° F. to about 275° F. Even more desirably, the elevated temperature of each of the first and second rotatable drums, 48 and 50 respectively, should range from between about 180° F. to about 250° F. Still more desirably, the elevated temperature of each of the first and second rotatable drums, 48 and 50 respectively, should range from between about 180° F. to about 225° F.
The pair of heated moving surfaces 44 and 46 forms a convergent passage 60 having an entry 64 and an exit 66. The plurality of filaments 40 are deposited into the entry 64 of the convergent passage 60. The plurality of filaments 40 are then routed through the convergent passage 60 in descending travel from the entry 64 to the exit 66 and between the pair of heated moving surfaces 44 and 46 in a machine direction (MD) to form a the high loft non-woven web 10. The process can also include additional bonding to the high loft non-woven web 10 to form a web 10, 10′ , 10″ or 11 having a thickness t, t1 or t2 of less than about 250 millimeters and a basis weight ranging from between about 20 g/m2 to about 3,000 g/m2. The high loft non-woven web 10 can be bonded using a variety of different bonders. Some bonders which can be used include but are not limited to: thermal bonding, through air bonding, oven bonding, chemical bonding, wet bonding, mechanical bonding or hydro-mechanical bonding.
A vertical cross-section of the high loft, non-woven web 10, 10′, 10″ or 11, when taken parallel to the machine direction (MD), exhibits a plurality of snugly stacked, approximately V, U or C-shaped structures 24 situated between outer skins. Each of the approximately V, U or C-shaped structure 24 has an apex 26 facing in the machine direction (MD). In other words, the approximately V or U shaped structure is rotated 90 degrees to a horizontal orientation with the apex of each facing to the right. The C-shaped structure is reversed in position so that the apex of each faces to the right. The high loft, non-woven web 10, 10′, 10″ or 11 has a recovery value ranging from between about 20% to about 99% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes.
Referring again to
It should be understood that an additive 80 can be added to the high loft, non-woven web 10, 10′, 10″ or 11 downstream of the bonder 74. The additive 80 can be any of those mentioned above. The additive 80 can be deposited onto the high loft, non-woven web 10, 10′, 10″ or 11, or it could be sprayed thereon. Alternatively, the high loft, non-woven web 10, 10′, 10″ or 11 could be immersed in a liquid solution containing an additive 80.
It should also be understood that the high loft, non-woven web 10, 10′, 10″ or 11 can be dried downstream of the bonder 74. Likewise, the high loft, non-woven web 10, 10′, 10″ or 11 could be cooled downstream of the bonder 74. Such cooling could reduce the temperature of the high loft, non-woven web 10, 10′, 10″ or 11 to room temperature or thereabout.
Experiments:
1. Spun-Blown® UnitA number of high loft, non-wovens webs were produced using a pilot line that had a 15 inch Spun-blown® die with multi-row spinnerettes known as the Biax Spun-blown® die. This die is commercially available from Biax-Fiberfilm Corporation having an office at N992 Quality Drive, Suite B, Greenville, Wis. 54942. The Spun-blown® spinnerettes had 242 polymer nozzles. The inside diameter of each spinnerette was 0.508 millimeters (mm) while the outside diameter of each spinnerette was 0.711 mm. Each polymer nozzle was surrounded by an air nozzle where the blowing air was coming from the annular space between the polymer nozzle and the air nozzle. The diameter of each of the air nozzles was 1.4 mm. The Biax Spun-blown® spinnerette is taught in U.S. Pat. Nos. 5,476,616; 9,303,334 B2; and U.S. Patent Publication 2005/0056956 A1. A typical commercial Biax Spun-blown® spinnerette can have from about 6,000 to about 11,000 nozzles per meter.
2. Process ConditionsSeveral examples of high loft, non-woven webs were made using the Spun-blown® pilot line to prove the concept of this invention. It should be understood that the exact process conditions used to make these samples could be changed. Any variation of the process conditions, such as air temperature, polymer chemistry or type, polymer melt temperature, air throughput, etc. could be changed. The process and recovery Data is shown below in Table 1.
The first two high loft non-woven webs exhibiting excellent recovery (samples 1 and 2) were made of polypropylene that was provided by Lyondel Basell under the trade name: Metocene MF650W. This polypropylene had a typical melt flow rate of 500 grams per 10 minutes (according to ASTM test D 1238, 230° C., 2.16 kg). The next two high loft non-woven webs (samples 3 and 4) exhibiting excellent recovery (samples 3 and 4) were made of polypropylene that was provided by Exxon Mobil under the trade name Exxon Mobil™ 3155 Homopolymer. This polypropylene had a typical melt flow rate of 35 grams per 10 minutes (according to ASTM test D 1238, 230° C., 2.16 kg).
The last two high loft non-woven webs exhibiting excellent recovery (samples 5 and 6) were made of polylactic acid that was provided by Natureworks under the trade name: INGEO PLA 6202D. The polylactic acid had a melt flow rate of 15 grams (g) to 30 g per 10 minutes (according to ASTM test D 1238, 210° C. 2.16 kg).
3. Characterization Tests 3.1 Basis WeightBasis weight is defined as the mass per unit area and it can be measured in grams per meter squared (g/m2). The basis weight test is done according the INDA standard IST 130.1 which is equivalent to the ASTM standard ASTM D3776. Ten (10) different samples were die cut from different locations in a larger sample web and each one had an individual area equal to 100 cm2. The weight of each replicate was measured using a sensitive balance within ±0.1% of weight on the balance. The basis weight in grams/m2 was measured by multiplying the average weight by 100.
3.2 Thickness of the High Loft NonWovenThickness is defined as the distance between one surface and an opposite surface of a single web measured under a specified pressure. For high loft, non-woven webs, the thickness was measured according the INDA standard IST 120.2 (01). The apparatus include a thickness testing instrument that had: an anvil, a presser foot, and a scale indicating the distance between these two parallel plates. The foot presser was 305 mm×305 mm (12 inches×12 inches) in size and had a weight of 288 grams. Five representative specimens of the fabric were die cut and tested in the standard atmosphere for testing as prescribed in ASTM D1776. Samples were handled carefully to avoid altering the natural state of the fabric. Each specimen was placed on the bottom plate and the presser foot was placed with care on the top of the sample. The average thickness of these specimens is reported along with a standard deviation.
3.3 Compression and Recovery of the High Loft Non-Woven WebIn this test, one measures the compression and recovery performance of the high loft, non-woven web samples by observing the linear distance that a movable plane is displaced from a parallel surface by the high loft, non-woven web samples while under a specified pressure. After a specified time interval, the pressure is removed and the recovery of the linear distance is measured. The performance of the high loft, non-woven webs for use in furniture, clothing, and insulation applications (acoustic or thermal) may be estimated from these compression and recovery values. The original thickness T1, measured in millimeters (mm), was measured according to the IST 120.2 (01). The presser foot was raised and the 288 gram weight was replaced with 36 pounds to provide a pressure of 0.25 psi. The presser foot with the new weight was placed on top of the high loft, non-woven webs samples for 30 minutes and then the compressed thickness T2 was measured. Finally, the presser foot was raised and replaced by the 36 pound weight with the 288 gram weight. After five (5) minutes, the presser foot was lowered to measure the thickness recovered, T3.
Percent compression=[(T1-T2)/T1]×100
Percent Recovery=[T3/T1]×100
While the invention has been described in conjunction with several specific embodiments, it is to be understood that many alternatives, modifications and variations will be apparent to those skilled in the art in light of the foregoing description. Accordingly, this invention is intended to embrace all such alternatives, modifications and variations which fall within the spirit and scope of the appended claims.
Claims
1. An apparatus for producing a high loft, non-woven web, said web having a 3-dimensional structure with fibers oriented in the x, y and z directions, said apparatus comprising:
- a) a die having 2 to 20 rows of nozzles, each row containing a plurality of nozzles each ejecting a filament, and each of said plurality of nozzles having a distal end;
- b) a pair of moving surfaces located from between about 10 cm to about 150 cm of said distal end of each of said plurality of nozzles, and said pair of moving surfaces forming a convergent passage having an entry and an exit;
- c) a pair of heaters each associated with one of said pair of moving surfaces, said pair of heaters capable of heating said pair of moving surfaces to an elevated temperature;
- d) depositing means for depositing said plurality of filaments, free of any additional fibers, onto and between said pair of moving surfaces; and
- e) routing means for causing said plurality of filaments to pass through said convergent passage from said entry to said exit to form a 3-dimensional structure.
2. The apparatus of claim 1 wherein said pair of moving surfaces comprise a first rotatable drum and a second rotatable drum, and said heated surfaces on said first and second rotatable drums create a thin outer skin on opposite major surfaces of said web, and each of said thin outer skins is less than about 2.5 millimeters in thickness.
3. The apparatus of claim 2 wherein said first rotatable drum rotates counterclockwise and said second rotatable drum rotates clockwise, and both drums cause said plurality of filaments to move in a machine direction.
4. The apparatus of claim 1 wherein said pair of moving surfaces comprise a first conveyor belt and a second conveyor belt, and said non-woven web has a basis weight of from between about 20 to about 600 grams per square meter.
5. The apparatus of claim 1 wherein said pair of heaters heat said pair of moving surfaces to an elevated temperature which is less than the melting temperature of said polymer.
6. The apparatus of claim 12 wherein said of heaters heat said pair of moving surfaces to an elevated temperature ranging from between about 180° F. to about 300° F.
7. The apparatus of claim 4 wherein said first conveyor belt moves counterclockwise and said second conveyor belt moves clockwise, both of said first and second conveyor belts cause said plurality of filaments to move in a machine direction, said first and second conveyor belts are aligned at an angle to one another, and both of said first and second conveyor belts are heated to an elevated temperature.
8. The apparatus of claim 7 wherein said first and second conveyor belts converge toward one another at a point farthest away from said distal end of each of said plurality of nozzles.
9. The apparatus of claim 8 wherein said first and second conveyor belts converge toward one another at an angle of less than 45 degrees.
10. An apparatus for producing a high loft, non-woven web, said web having a 3-dimensional structure with fibers oriented in the x, y and z directions, said apparatus comprising:
- a) a die connected to an extruder and having 2 to 20 rows of nozzles, each row containing a plurality of nozzles each ejecting a filament formed from a single polymer, and each of said plurality of nozzles having a distal end;
- b) a pair of rotatable drums located within from about 10 cm to about 150 cm of said distal end of each of said plurality of nozzles, said pair of rotatable drums forming a convergent passage having an entry and an exit, and each of said pair of rotatable drums having a patterned surface;
- c) a pair of heaters each associated with one of said pair of rotatable drums, said pair of heaters capable of heating said pair of rotatable drums to an elevated temperature;
- d) depositing means for depositing said plurality of filaments, free of any additional fibers, onto and between said pair of rotatable drums; and
- e) routing means for causing said plurality of filaments to pass through said convergent passage from said entry to said exit to form a 3-dimensional structure.
11. The apparatus of claim 10 wherein said convergent passage has a nip of greater than about 0.5 cm, and said heated surfaces on said first and second rotatable drums create a thin outer skin on opposite major surfaces of said web, and each of said thin outer skins is less than about 2.5 millimeters in thickness.
12. The apparatus of claim 11 wherein said pair of heaters heat said pair of rotatable drums to an elevated temperature which is less than the melting temperature of said polymer.
13. The apparatus of claim 12 wherein said pair of heaters heat said pair of rotatable drums to an elevated temperature ranging from between about 180° F. to about 300° F.
14. The apparatus of claim 11 wherein said first rotatable drum rotates counterclockwise and said second rotatable drum rotates clockwise, and both drums causing said plurality of continuous filaments to move in a machine direction.
15. An apparatus for producing a high loft, non-woven web from a single polymer, said web having a 3-dimensional structure with fibers oriented in the x, y and z directions, said apparatus comprising:
- a) a die connected to an extruder and having 2 to 20 rows of nozzles, each row containing a plurality of nozzles each ejecting a filament formed from a single polymer, and each of said plurality of nozzles having a distal end;
- b) a pair of conveyor belts located within from about 10 cm to about 150 cm of said distal end of each of said plurality of nozzles, said pair of conveyor belts forming a convergent passage having an entry and an exit;
- c) a pair of heaters each associated with one of said pair of conveyor belts, said pair of heaters capable of heating said pair of conveyor belts to an elevated temperature;
- d) depositing means for depositing said plurality of filaments, free of any additional fibers, onto said pair of conveyor belts;
- e) routing means for causing said plurality of filaments to pass through said convergent passage from said entry to said exit to form a 3-dimensional structure; and
- f) a spray located downstream of and in vertical alignment with said pair of conveyor belts for adding an additive to said 3-dimensional structure to create a high loft, non-woven web with said filaments transformed into fibers oriented in the x, y and z directions, said web having a thickness of less than about 200 mm, a basis weight ranging from between about 100 g/m2 to about 2,000 g/m2, and a vertical cross-section of said web, when taken parallel to a machine direction, exhibiting a plurality of snugly stacked, approximately V, U or C-shaped structures, with each V, U or C-shaped structure having an apex facing in said machine direction, and said web having a recovery value ranging from between about 50% to about 80% after being compressed under a pressure of 0.25 psi for a time period of 30 minutes.
16. The apparatus of claim 15 wherein said convergent passage has a nip of greater than about 0.5 cm, and said heated surfaces on said first and second rotatable drums create a thin outer skin on opposite major surfaces of said web, and each of said thin outer skins is less than about 2.5 millimeters in thickness.
17. The apparatus of claim 16 wherein said pair of conveyor belts are aligned at an angle to one another, and said pair of heaters heat said pair of conveyor belts to an elevated temperature which is less than the melting temperature of said polymer.
18. The apparatus of claim 16 wherein said pair of conveyor belts converge toward one another at a point farthest away from said distal end of each of said plurality of nozzles, and said pair of heaters heat said pair of conveyor belts to an elevated temperature ranging from between about 180° F. to about 300° F.
19. The apparatus of claim 16 wherein said pair of conveyor belts converge toward one another at an angle of less than 60 degrees, and said non-woven web has a basis weight of from between about 20 to about 600 grams per square meter.
20. The apparatus of claim 16 wherein said pair of conveyor belts converge toward one another at an angle of less than 45 degrees.
Type: Application
Filed: Jan 18, 2017
Publication Date: May 4, 2017
Inventors: Douglas B. Brown (Fremont, WI), Jeffrey D. Stark (Neenah, WI), Mohammad A. Hassan (Johnson City, TN)
Application Number: 15/408,900