STEEL SHEET, COATED STEEL SHEET, AND METHODS FOR MANUFACTURING SAME

- JFE STEEL CORPORATION

A steel sheet having TS of 980 MPa or more and YR of 68% or more is obtained by providing a predetermined chemical composition and a predetermined steel microstructure, where an average aspect ratio of crystal grains of each phase (polygonal ferrite, martensite, and retained austenite) is 2.0 or more and 20.0 or less, wherein the polygonal ferrite has an average grain size of 4 μm or less, the martensite has an average grain size of 2 μm or less, the retained austenite has an average grain size of 2 μm or less, and a value obtained by dividing a Mn content in the retained austenite in mass % by a Mn content in the polygonal ferrite in mass % equals 2.0 or more.

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Description
TECHNICAL FIELD

This disclosure relates to a steel sheet, a hot-dip galvanized steel sheet, a hot-dip aluminum-coated steel sheet, and an electrogalvanized steel sheet, and methods for manufacturing the same, and in particular to a steel sheet with excellent formability and hole expansion formability and high yield ratio that is preferably used in parts in the industrial fields of automobiles, electronics, and the like.

BACKGROUND

In recent years, enhancement of fuel efficiency of automobiles has become an important issue from the viewpoint of global environment protection. Consequently, there is an active movement to reduce the thickness of automotive body components through increases in strength of steel sheets as automotive body materials, and thereby reduce the weight of automotive body itself.

In general, however, strengthening of steel sheets leads to deterioration in formability, causing the problem of cracking during forming. It is thus not simple to reduce the thickness of steel sheets. Therefore, it is desirable to develop materials with increased strength and good formability. In addition to good formability, steel sheets with a tensile strength (TS) of 980 MPa or more are required to have, in particular, enhanced impact energy absorption properties. To enhance impact energy absorption properties, it is effective to increase yield ratio (YR). The reason is that a higher yield ratio enables the steel sheet to absorb impact energy more effectively with less deformation.

Moreover, in the case of using a steel sheet in an automotive body, stretch flanging according to the shape of the automotive body is performed, so that excellent hole expansion formability is required, too.

For example, JPS61157625A (PTL 1) proposes a high-strength steel sheet with extremely high ductility having a tensile strength of 1000 MPa or higher and a total elongation (EL) of 30% or more, utilizing deformation induced transformation of retained austenite.

In addition, JPH1259120A (PTL 2) proposes a high-strength steel sheet with well-balanced strength and ductility that is obtained from high-Mn steel through heat treatment in a ferrite-austenite dual phase region.

Moreover, JP2003138345A (PTL 3) proposes a high-strength steel sheet with improved local ductility that is obtained from high-Mn steel through hot rolling to have a microstructure containing bainite and martensite after subjection to the hot rolling, followed by annealing and tempering to cause fine retained austenite, and subsequently tempered bainite or tempered martensite in the microstructure.

CITATION LIST Patent Literature

PTL 1: JPS61157625A

PTL 2: JPH1259120A

PTL 3: JP2003138345A

SUMMARY Technical Problem

The steel sheet described in PTL 1 is manufactured by austenitizing a steel sheet containing C, Si, and Mn as basic components, and subjecting the steel sheet to a so-called austempering process whereby the steel sheet is quenched to and held isothermally in a bainite transformation temperature range. During the austempering process, C concentrates in austenite to form retained austenite.

However, while a high concentration of C beyond 0.3% is required for the formation of a large amount of retained austenite, such a high C concentration above 0.3% leads to a significant decrease in spot weldability, which may not be suitable for practical use in steel sheets for automobiles. Additionally, the main objective of PTL 1 is improving the ductility of steel sheets, without any consideration for the hole expansion formability, bendability, or yield ratio.

PTLs 2 and 3 describe techniques for improving the ductility of steel sheets from the perspective of formability, but do not consider the bendability, yield ratio, or hole expansion formability of the steel sheet.

To address these issues, it could thus be helpful to provide a steel sheet, a hot-dip galvanized steel sheet, a hot-dip aluminum-coated steel sheet, and an electrogalvanized steel sheet that are excellent in formability and hole expansion formability with TS of 980 MPa or more and YR of 68% or more, and methods for manufacturing the same.

Solution to Problem

To manufacture a high-strength steel sheet that can solve the above issues, with excellent formability and hole expansion formability as well as high yield ratio and high tensile strength, we made intensive studies from the perspectives of the chemical compositions and manufacturing methods of steel sheets. As a result, we discovered that a high-strength steel sheet with high yield ratio that is excellent in formability such as ductility and hole expansion formability can be manufactured by appropriately controlling the chemical composition and microstructure of steel.

Specifically, a steel sheet that has a steel composition containing Mn: more than 4.20 mass % and 6.00 mass % or less, with the addition amounts of other alloying elements such as Ti being adjusted appropriately, is hot rolled to obtain a hot-rolled sheet. The hot-rolled sheet is then subjected to pickling to remove scales, retained in a temperature range of [Ac1 transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s, and optionally cold rolled at a rolling reduction of less than 30% to obtain a cold-rolled sheet. Further, the hot-rolled sheet as annealed after the hot rolling or the cold-rolled sheet is retained in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s, and subsequently cooled.

Through this process, the hot-rolled sheet or the cold-rolled sheet has a microstructure that contains, in area ratio, 5% or more and 50% or less of polygonal ferrite, 10% or more of non-recrystallized ferrite, and 15% or more and 30% or less of martensite, and, in volume fraction, 12% or more of retained austenite, where the average aspect ratio of crystal grains of each phase (polygonal ferrite, martensite, and retained austenite) is 2.0 or more and 20.0 or less, the polygonal ferrite has an average grain size of 4 μm or less, the martensite has an average grain size of 2 μm or less, and the retained austenite has an average grain size of 2 μm or less. Moreover, the microstructure of the hot-rolled sheet or the cold-rolled sheet can be controlled so that a value obtained by dividing a Mn content in the retained austenite (in mass %) by a Mn content in the polygonal ferrite (in mass %) equals 2.0 or more, making it possible to obtain a volume fraction of 12% or more of retained austenite stabilized with Mn.

This disclosure has been made based on these discoveries.

Specifically, the primary features of this disclosure are as described below.

1. A steel sheet comprising: a chemical composition containing (consisting of), in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities; and a steel microstructure that contains, in area ratio, 5% or more and 50% or less of polygonal ferrite, 10% or more of non-recrystallized ferrite, and 15% or more and 30% or less of martensite, and that contains, in volume fraction, 12% or more of retained austenite, where an average aspect ratio of crystal grains of each of the polygonal ferrite, the martensite, and the retained austenite is 2.0 or more and 20.0 or less, wherein the polygonal ferrite has an average grain size of 4 μm or less, the martensite has an average grain size of 2 μm or less, the retained austenite has an average grain size of 2 μm or less, and a value obtained by dividing a Mn content in the retained austenite in mass % by a Mn content in the polygonal ferrite in mass % equals 2.0 or more.

2. The steel sheet according to 1., wherein the steel microstructure further contains, in area ratio, 2% or more of ε phase with an hcp structure.

3. The steel sheet according to 1. or 2., wherein the retained austenite has a C content that satisfies the following formula in relation to the Mn content in the retained austenite:


0.04*[Mn]+0.056−0.180≤[C]≤0.04*[Mn]+0.056+0.180

where

[C] is the C content in the retained austenite in mass %, and

[Mn] is the Mn content in the retained austenite in mass %.

4. A coated steel sheet comprising: the steel sheet according to any one of 1. to 3.; and one selected from a hot-dip galvanized layer, a galvannealed layer, a hot-dip aluminum-coated layer, and an electrogalvanized layer.

5. A method for manufacturing a steel sheet, the method comprising: heating a steel slab having the chemical composition according to 1.; hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet; coiling the steel sheet; then subjecting the steel sheet to pickling to remove scales; retaining the steel sheet in a temperature range of [Ac1 transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s; optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet, to manufacture the steel sheet according to any one of 1. to 3.

6. The method according to 5., wherein a value obtained by dividing a volume fraction of the retained austenite after performing tensile working with an elongation value of 10% by a volume fraction of the retained austenite before the tensile working equals 0.3 or more.

7. The method according to 5., comprising after the cooling, either subjecting the steel sheet to one selected from hot-dip galvanizing treatment, hot-dip aluminum coating treatment, and electrogalvanizing treatment, or subjecting the steel sheet to hot-dip galvanizing treatment and then to alloying treatment at 450° C. or higher and 600° C. or lower, to manufacture the coated steel sheet according to 4.

Advantageous Effect

According to the disclosure, it becomes possible to provide a high-strength steel sheet with excellent formability and hole expansion formability and high yield ratio that exhibits TS of 980 MPa or more and YR of 68% or more. High-strength steel sheets according to the disclosure are highly beneficial in industrial terms, because they can improve fuel efficiency when applied to, for example, automobile structural parts, by a reduction in the weight of automotive bodies.

BRIEF DESCRIPTION OF THE DRAWING

In the accompanying drawings:

FIG. 1 illustrates the relationship between the working ratio of tensile working and the volume fraction of retained austenite; and

FIG. 2 illustrates the relationship between the elongation of each steel sheet and the value obtained by dividing the volume fraction of retained austenite remaining in the steel sheet after subjection to tensile working with an elongation value of 10% by the volume fraction of retained austenite before the tensile working.

 DETAILED DESCRIPTION

The following describes the present disclosure in detail.

First, the reasons for limiting the chemical composition of the steel to the aforementioned ranges in the present disclosure are explained. The % representations below indicating the chemical composition of the steel or steel slab are in mass % unless stated otherwise. The balance of the chemical composition of the steel or steel slab is Fe and inevitable impurities.

C: 0.030% or More and 0.250% or Less

C is an element necessary for causing a low-temperature transformation phase such as martensite to increase strength. C is also a useful element for increasing the stability of retained austenite and the ductility of steel. If the C content is less than 0.030%, it is difficult to ensure a desired area ratio of martensite, and desired strength is not obtained. It is also difficult to guarantee a sufficient volume fraction of retained austenite, and good ductility is not obtained. On the other hand, if C is excessively added to the steel beyond 0.250%, hard martensite excessively increases in area ratio, which causes more microvoids at grain boundaries of martensite and facilitates propagation of cracks during bend test and hole expansion test, leading to a reduction in bendability and stretch flangeability. If excessive C is added to steel, hardening of welds and the heat-affected zone (HAZ) becomes significant and the mechanical properties of the welds deteriorate, leading to a reduction in spot weldability, arc weldability, and the like. From these perspectives, the C content is 0.030% or more and 0.250% or less. The C content is preferably 0.080% or more. The C content is preferably 0.200% or less.

Si: 0.01% or More and 3.00% or Less

Si is an element that improves the strain hardenability of ferrite, and is thus a useful element for ensuring good ductility. If the Si content is below 0.01%, the addition effect is limited. Thus the lower limit is 0.01%. On the other hand, excessively adding Si beyond 3.00% not only embrittles the steel, but also causes red scales or the like to deteriorate surface characteristics. Therefore, the Si content is 0.01% or more and 3.00% or less. The Si content is preferably 0.20% or more. The Si content is preferably 2.00% or less.

Mn: More than 4.20% and 6.00% or Less

Mn is one of the very important elements for the disclosure. Mn is an element that stabilizes retained austenite, and is thus a useful element for ensuring good ductility. Mn can also increase the strength of the steel through solid solution strengthening. In addition, concentration of Mn in retained austenite can ensure obtaining 2% or more of ε phase with an hcp structure, and furthermore, guarantee the volume fraction of retained austenite being as high as 12% or more. These effects can be obtained only when the Mn content in steel is more than 4.20%. On the other hand, excessively adding Mn beyond 6.00% results in a rise in cost. From these perspectives, the Mn content is more than 4.20% and 6.00% or less. The Mn content is preferably 4.80% or more. The Mn content is preferably 6.00% or less.

P: 0.001% or More and 0.100% or Less

P is an element that has a solid solution strengthening effect and can be added depending on the desired strength. P also facilitates ferrite transformation, and thus is also a useful element for forming a multi-phase structure in the steel sheet. To obtain this effect, the P content in the steel sheet needs to be 0.001% or more. However, if the P content exceeds 0.100%, weldability degrades and, when a galvanized layer is subjected to alloying treatment, the alloying rate decreases, impairing galvanizing quality. Therefore, the P content is 0.001% or more and 0.100% or less. The P content is preferably 0.005% or more. The P content is preferably 0.050% or less.

S: 0.0200% or Less

S segregates to grain boundaries, embrittles the steel during hot working, and forms sulfides to reduce the local deformability of the steel sheet. Therefore, the S content is 0.0200% or less, preferably 0.0100% or less, and more preferably 0.0050% or less. Under production constraints, however, the S content is preferably 0.0001% or more. Therefore, the S content is preferably 0.0001% or more and 0.0200% or less. The S content is more preferably 0.0001% or more. The S content is more preferably 0.0100% or less. The S content is further preferably 0.0001% or more. The S content is further preferably 0.0050% or less.

N: 0.0100% or Less

N is an element that deteriorates the anti-aging property of the steel. The deterioration in anti-aging property becomes more pronounced, particularly when the N content exceeds 0.0100%. Accordingly, smaller N contents are more preferable. However, under production constraints, the N content is preferably 0.0005% or more. Therefore, the N content is preferably 0.0005% or more and 0.0100% or less. The N content is more preferably 0.0010% or more. The N content is more preferably 0.0070% or less.

Ti: 0.005% or more and 0.200% or less Ti is one of the very important elements for the disclosure. Ti is useful for achieving strengthening by precipitation of the steel. Ti can also ensure a desired area ratio of non-recrystallized ferrite, and contributes to increasing the yield ratio of the steel sheet. Additionally, making use of relatively hard non-recrystallized ferrite, Ti can reduce the difference in hardness from a hard secondary phase (martensite or retained austenite), and also contributes to improving stretch flangeability. These effects can be obtained when the Ti content is 0.005% or more. On the other hand, if the Ti content in the steel exceeds 0.200%, hard martensite excessively increases in area ratio, which causes more microvoids at grain boundaries of martensite and facilitates propagation of cracks during bend test and hole expansion test, leading to a reduction in the bendability and stretch flangeability of the steel sheet. Therefore, the Ti content is 0.005% or more and 0.200% or less. The Ti content is preferably 0.010% or more. The Ti content is preferably 0.100% or less.

The basic components according to this disclosure have been described above. The balance other than the components described above is Fe and inevitable impurities. Additionally, the following elements may b e optionally contained as appropriate.

The chemical composition of the steel may further contain at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less.

Al is a useful element for increasing the area of a ferrite-austenite dual phase region and reducing annealing temperature dependency, i.e., increasing the stability of the steel sheet as a material. In addition, Al acts as a deoxidizer, and is also a useful element for maintaining the cleanliness of the steel. If the Al content is below 0.01%, however, the addition effect is limited. Thus the lower limit is 0.01%. On the other hand, excessively adding Al beyond 2.00% increases the risk of cracking occurring in a semi-finished product during continuous casting, and inhibits manufacturability. From these perspectives, the Al content is 0.01% or more and 2.00% or less. The Al content is preferably 0.20% or more. The Al content is preferably 1.20% or less.

Nb is useful for achieving strengthening by precipitation of the steel. The addition effect can be obtained when the content is 0.005% or more. Nb can also ensure a desired area ratio of non-recrystallized ferrite, as in the case of adding Ti, and contributes to increasing the yield ratio of the steel sheet. Additionally, making use of relatively hard non-recrystallized ferrite, Nb can reduce the difference in hardness from a hard secondary phase (martensite or retained austenite), and also contributes to improving stretch flangeability. On the other hand, if the Nb content in the steel exceeds 0.200%, hard martensite excessively increases in area ratio, which causes more microvoids at grain boundaries of martensite and facilitates propagation of cracks during bend test and hole expansion test. This leads to a reduction in the bendability and stretch flangeability of the steel sheet. This also increases cost. Therefore, when added to steel, the Nb content is 0.005% or more and 0.200% or less. The Nb content is preferably 0.010% or more. The Nb content is preferably 0.100% or less.

B may be added as necessary, since it has the effect of suppressing the generation and growth of ferrite from austenite grain boundaries and enables microstructure control according to the circumstances. The addition effect can be obtained when the B content is 0.0003% or more. If the B content exceeds 0.0050%, however, the formability of the steel sheet degrades. Therefore, when added to steel, the B content is 0.0003% or more and 0.0050% or less. The B content is preferably 0.0005% or more. The B content is preferably 0.0030% or less.

Ni is an element that stabilizes retained austenite, and is thus a useful element for ensuring good ductility, and that increases the strength of the steel through solid solution strengthening. The addition effect can be obtained when the Ni content is 0.005% or more. On the other hand, if the Ni content in the steel exceeds 1.000%, hard martensite excessively increases in area ratio, which causes more microvoids at grain boundaries of martensite and facilitates propagation of cracks during bend test and hole expansion test. This leads to a reduction in the bendability and stretch flangeability of the steel sheet. This also increases cost. Therefore, when added to steel, the Ni content is 0.005% or more and 1.000% or less.

Cr, V, and Mo are elements that may be added as necessary, since they have the effect of improving the balance between strength and ductility. The addition effect can be obtained when the Cr content is 0.005% or more, the V content is 0.005% or more, and/or the Mo content is 0.005% or more. However, if the Cr content exceeds 1.000%, the V content exceeds 0.500%, and/or the Mo content exceeds 1.000%, hard martensite excessively increases in area ratio, which causes more microvoids at grain boundaries of martensite and facilitates propagation of cracks during bend test and hole expansion test. This leads to a reduction in the bendability and stretch flangeability of the steel sheet, and also causes a rise in cost. Therefore, when added to steel, the Cr content is 0.005% or more and 1.000% or less, the V content is 0.005% or more and 0.500% or less, and/or the Mo content is 0.005% or more and 1.000% or less.

Cu is a useful element for strengthening of steel and may be added for strengthening of steel, as long as the content is within the range disclosed herein. The addition effect can be obtained when the Cu content is 0.005% or more. On the other hand, if the Cu content in the steel exceeds 1.000%, hard martensite excessively increases in area ratio, which causes more microvoids at grain boundaries of martensite and facilitates propagation of cracks during bend test and hole expansion test. This leads to a reduction in the bendability and stretch flangeability of the steel sheet. Therefore, when added to steel, the Cu content is 0.005% or more and 1.000% or less.

Sn and Sb are elements that may be added as necessary from the perspective of suppressing decarbonization of a region extending from the surface layer of the steel sheet to a depth of about several tens of micrometers, which results from nitriding and/or oxidation of the steel sheet surface. Suppressing nitriding and/or oxidation in this way is useful for preventing a reduction in the area ratio of martensite in the steel sheet surface, and for ensuring the TS and stability of the steel sheet as a material. However, excessively adding Sn or Sb beyond 0.200% reduces toughness. Therefore, when Sn and/or Sb is added to steel, the content of each added element is 0.002% or more and 0.200% or less.

Ta forms alloy carbides or alloy carbonitrides, and contributes to increasing the strength of the steel, as is the case with Ti and Nb. It is also believed that Ta has the effect of effectively suppressing coarsening of precipitates when partially dissolved in Nb carbides or Nb carbonitrides to form complex precipitates, such as (Nb, Ta) (C, N), and providing a stable contribution to increasing the strength of the steel sheet through strengthening by precipitation. Therefore, Ta is preferably added to the steel according to the disclosure. The addition effect of Ta can be obtained when the Ta content is 0.001% or more. Excessively adding Ta, however, fails to increase the addition effect, but instead results in a rise in alloying cost. Therefore, when added to steel, the Ta content is 0.001% or more and 0.010% or less.

Ca, Mg, and REM are useful elements for causing spheroidization of sulfides and mitigating the adverse effect of sulfides on hole expansion formability (stretch flangeability). To obtain this effect, it is necessary to add any of these elements to steel in an amount of 0.0005% or more. However, if the content of each added element exceeds 0.0050%, more inclusions occur, for example, and some defects such as surface defects and internal defects are caused in the steel sheet. Therefore, when Ca, Mg, and/or REM is added to steel, the content of each added element is 0.0005% or more and 0.0050% or less.

The following provides a description of the microstructure. Sufficient ductility of the steel sheet can be ensured by facilitating the formation of polygonal ferrite in the microstructure. This, however, causes decreases in tensile strength and yield strength. Besides, the tensile strength also varies depending on the area ratio of martensite, and the ductility is greatly affected by the amount of retained austenite. Hence, the mechanical properties of the high-strength steel sheet can be effectively obtained by controlling the amounts (area ratio, volume fraction) of these phases (microstructures). As a result of conducting studies from this perspective, we newly discovered that the area ratios of polygonal ferrite and non-recrystallized ferrite are controllable by the rolling reduction in cold rolling. We also found out that the area ratio of martensite and the volume fraction of retained austenite are mainly determined by the addition amount of Mn. We further found out that, by omitting cold rolling or by limiting the rolling reduction in cold rolling to 30% or less, not only the area ratio of polygonal ferrite is reduced (i.e. can be controlled to an appropriate range) (relative to the whole microstructure), but also the microstructure shape of the final product changes greatly, yielding a steel sheet having crystal grains with a high aspect ratio. The value of hole expansion formability λ is thus improved. In detail, the microstructure of a steel sheet with high ductility and favorable hole expansion formability is as follows.

Area Ratio of Polygonal Ferrite: 5% or More and 50% or Less

According to the disclosure, the area ratio of polygonal ferrite needs to be 5% or more to ensure sufficient ductility. On the other hand, to guarantee a strength of 980 MPa or more, the area ratio of soft polygonal ferrite needs to be 50% or less. The area ratio of polygonal ferrite is preferably 10% or more. The area ratio of polygonal ferrite is preferably 40% or less. As used herein, “polygonal ferrite” refers to ferrite that is relatively soft and that has high ductility.

Area Ratio of Non-Recrystallized Ferrite: 10% or More

In this disclosure, it is very important to set the area ratio of non-recrystallized ferrite to be 10% or more. In this regard, non-recrystallized ferrite is useful for increasing the strength of the steel sheet. However, non-recrystallized ferrite may cause a significant decrease in the ductility of the steel sheet, and thus is normally reduced in a general process. In contrast, according to the present disclosure, by using polygonal ferrite and retained austenite to provide good ductility and intentionally utilizing relatively hard non-recrystallized ferrite, it is possible to provide the steel sheet with the intended TS, without having to form a large amount of martensite, such as exceeding 30% in area ratio.

Moreover, according to the present disclosure, interfaces between different phases, namely, between polygonal ferrite and martensite, are reduced, making it possible to increase the yield point (YP) and YR of the steel sheet.

To obtain these effects, the area ratio of non-recrystallized ferrite needs to be 10% or more. The area ratio of non-recrystallized ferrite is preferably 13% or more.

As used herein, “non-recrystallized ferrite” refers to ferrite that contains strain in the grains with a crystal orientation difference of less than 15°, and that is harder than the above-described polygonal ferrite with high ductility.

In the disclosure, no upper limit is placed on the area ratio of non-recrystallized ferrite, yet a preferred upper limit is around 45%, considering the possibility of increased material anisotropy in the steel sheet surface.

Area Ratio of Martensite: 15% or More and 30% or Less

To achieve TS of 980 MPa or more, the area ratio of martensite needs to be 15% or more. On the other hand, to ensure good ductility, the area ratio of martensite needs to be limited to 30% or less.

According to the disclosure, the area ratios of ferrite (including polygonal ferrite and non-recrystallized ferrite) and martensite can be determined in the following way.

Specifically, a cross section of a steel sheet that is taken in the sheet thickness direction to be parallel to the rolling direction (which is an L-cross section) is polished, then etched with 3 vol. % nital, and ten locations are observed at 2000 times magnification under an SEM (scanning electron microscope), at a position of sheet thickness×¼ (which is the position at a depth of one-fourth of the sheet thickness from the steel sheet surface), to capture microstructure micrographs. The captured microstructure micrographs are used to calculate the area ratios of respective phases (ferrite and martensite) for the ten locations using Image-Pro manufactured by Media Cybernetics, the results are averaged, and each average is used as the area ratio of the corresponding phase. In the microstructure micrographs, polygonal ferrite and non-recrystallized ferrite appear as a gray structure (base steel structure), while martensite as a white structure.

According to the disclosure, the area ratios of polygonal ferrite and non-recrystallized ferrite can be determined in the following way. Specifically, low-angle grain boundaries in which the crystal orientation difference is from 2° to less than 15° and large-angle grain boundaries in which the crystal orientation difference is 15° or more are identified using EBSD (Electron Backscatter Diffraction). An IQ Map is then created, considering ferrite that contains low-angle grain boundaries in the grains as non-recrystallized ferrite. Then, low-angle grain boundaries and large-angle grain boundaries are extracted from the created IQ Map at ten locations, respectively, to determine the areas of low-angle grain boundaries and large-angle grain boundaries at the ten locations. Based on the results, the areas of polygonal ferrite and non-recrystallized ferrite are calculated to determine the area ratios of polygonal ferrite and non-recrystallized ferrite for the ten locations. By averaging the results, the above-described area ratios of polygonal ferrite and non-recrystallized ferrite are determined.

Volume Fraction of Retained Austenite: 12% or More

According to the disclosure, the volume fraction of retained austenite needs to be 12% or more, to ensure sufficient ductility. The volume fraction of retained austenite is preferably 14% or more.

According to the disclosure, no upper limit is placed on the area ratio of retained austenite, yet a preferred upper limit is around 50%, considering the risk of formation of increased amounts of unstable retained austenite resulting from insufficient concentration of C, Mn, and the like, which is less effective in improving ductility.

The volume fraction of retained austenite is calculated by determining the x-ray diffraction intensity of a plane of sheet thickness×¼ (which is the plane at a depth of one-fourth of the sheet thickness from the steel sheet surface), which is exposed by polishing the steel sheet surface to a depth of one-fourth of the sheet thickness. Using an incident x-ray beam of MoKα, the intensity ratio of the peak integrated intensity of the {111}, {200}, {220}, and {311} planes of retained austenite to the peak integrated intensity of the {110}, {200}, and {211} planes of ferrite is calculated for all of the twelve combinations, the results are averaged, and the average is used as the volume fraction of retained austenite.

Average Grain Size of Polygonal Ferrite: 4 μm or Less

Refinement of polygonal ferrite grains contributes to improving YP and TS. Thus, to ensure a high YP and a high YR as well as a desired TS, polygonal ferrite needs to have an average grain size of 4 μm or less. The average grain size of polygonal ferrite is preferably 3 μm or less.

According to the disclosure, no lower limit is placed on the average grain size of polygonal ferrite, yet, from an industrial perspective, a preferred lower limit is around 0.2 μm.

Average Grain Size of Martensite: 2 μm or Less

Refinement of martensite grains contributes to improving bendability and stretch flangeability (hole expansion formability). Thus, to ensure high bendability and high stretch flangeability (high hole expansion formability), the average grain size of martensite needs to be limited to 2 μm or less. The average grain size of martensite is preferably 1.5 μm or less.

According to the disclosure, no lower limit is placed on the average grain size of martensite, yet, from an industrial perspective, a preferred lower limit is around 0.05 μm.

Average Grain Size of Retained Austenite: 2 μm or Less

Refinement of retained austenite grains contributes to improving ductility, as well as bendability and stretch flangeability (hole expansion formability). Accordingly, to ensure good ductility, bendability, and stretch flangeability (hole expansion formability) of the steel sheet, the average grain size of retained austenite needs to be 2 μm or less. The average grain size of retained austenite is preferably 1.5 μm or less.

According to the disclosure, no lower limit is placed on the average grain size of retained austenite, yet, from an industrial perspective, a preferred lower limit is around 0.05 μm.

The average grain sizes of polygonal ferrite, martensite, and retained austenite are respectively determined by averaging the results from calculating equivalent circular diameters from the areas of polygonal ferrite grains, martensite grains, and retained austenite grains measured with Image-Pro as mentioned above. Polygonal ferrite, non-recrystallized ferrite, martensite, and retained austenite are separated using EBSD, and martensite and retained austenite are identified using an EBSD phase map. In this case, each of the above-described average grain sizes is determined from the measurements for grains with a grain size of 0.01 μm or more. The reason is that grains with a grain size of less than 0.01 μm have no effect on the disclosure.

Average Aspect Ratio of Crystal Grains of Each of Polygonal Ferrite, Martensite, and Retained Austenite: 2.0 or More and 20.0 or Less

In this disclosure, it is very important to set the average aspect ratio of crystal grains of each of polygonal ferrite, martensite, and retained austenite to 2.0 or more.

A lower aspect ratio of crystal grains indicates that, during retention in heat treatment after cold rolling (cold-rolled sheet annealing), ferrite and austenite recover and recrystallize and then undergo grain growth, resulting in the formation of crystal grains close to equiaxed grains. The ferrite formed here is soft. In the case where cold rolling is omitted or the rolling reduction in cold rolling is less than 30%, on the other hand, the amount of strain applied decreases, so that the formation of polygonal ferrite is suppressed and a microstructure mainly composed of crystal grains with a high aspect ratio results. Such a microstructure composed of crystal grains with a high aspect ratio is hard because it contains a large amount of strain or has parts where the distance between grain boundaries is short, as compared with the above-mentioned microstructure. Therefore, not only the TS is improved, but also the difference in hardness from hard phases such as retained austenite and martensite decreases, and the hole expansion formability is improved without loss of ductility. If the aspect ratio is more than 20.0, the TS increases extremely, and favorable ductility cannot be achieved.

Thus, the average aspect ratio of crystal grains of each of polygonal ferrite, martensite, and retained austenite is limited to 2.0 or more and 20.0 or less. In terms of improving ductility, the average aspect ratio is more preferably 2.2 or more, and more preferably 2.4 or more.

The aspect ratio of a crystal grain mentioned here is a value obtained by dividing the major axis length of the crystal grain by the minor axis length of the crystal grain. The average aspect ratio of each type of crystal grains can be calculated as follows.

For each of polygonal ferrite grains, martensite grains, and retained austenite grains, the major axis length and minor axis length of each of 30 crystal grains are calculated using the above-mentioned Image-Pro, the major axis length is divided by the minor axis length, and the division results are averaged.

A Value Obtained by Dividing the Mn Content in the Retained Austenite (in Mass %) by the Mn Content in the Polygonal Ferrite (in Mass %): 2.0 or More

In this disclosure, it is very important that the value obtained by dividing the Mn content in the retained austenite (in mass %) by the Mn content in the polygonal ferrite (in mass %) equals 2.0 or more. The reason is that better ductility requires a larger amount of stable retained austenite with concentrated Mn.

According to the disclosure, no upper limit is placed on the value obtained by dividing the Mn content in the retained austenite (in mass %) by the Mn content in the polygonal ferrite (in mass %), yet a preferred upper limit is around 16.0 from the perspective of ensuring stretch flangeability.

The Mn content in the retained austenite (in mass %) and the Mn content in the polygonal ferrite (in mass %) can be determined in the following way.

Specifically, an EPMA (Electron Probe Micro Analyzer) is used to quantify the distribution of Mn in each phase in a cross section along the rolling direction at a position of sheet thickness×¼. Then, 30 retained austenite grains and 30 ferrite grains are analyzed to determine Mn contents, the results are averaged, and each average is used as the Mn content in the corresponding phase.

In addition to the above-described polygonal ferrite, martensite, and so on, the microstructure according to the disclosure may further include carbides ordinarily found in steel sheets, such as granular ferrite, acicular ferrite, bainitic ferrite, tempered martensite, pearlite, and cementite (excluding cementite in pearlite). Any of these structures may be included as long as the area ratio is 10% or less, without impairing the effect of the disclosure.

According to the disclosure, the steel microstructure preferably contains, in area ratio, 2% or more of ε phase with an hcp (hexagonal closest packing) structure. In this respect, steel may become brittle when it contains a large amount of ε phase with an hcp structure. As in the present disclosure, however, when an appropriate amount of ε phase with an hcp structure is finely distributed within and along boundaries of polygonal ferrite and non-recrystallized ferrite grains, it becomes possible to achieve excellent damping performance, while keeping a good balance between strength and ductility.

Such ε phase with an hcp structure, martensite, and retained austenite can be identified using an EBSD phase map. In this disclosure, no upper limit is placed on the area ratio of ε phase, yet, in view of the risk of embrittlement of the steel, a preferred upper limit is around 35%.

We made further investigations on the microstructures of steel sheets upon performing press forming and working.

As a result, it was discovered that there are two types of retained austenite: one transforms to martensite immediately upon the subjection of the steel sheet to press forming or working, while the other persists until the working ratio becomes high enough to cause the retained austenite to eventually transform to martensite, bringing about a TRIP phenomenon (transformation induced plasticity phenomenon). It was also revealed that good elongation can be obtained in a particularly effective way when a large amount of retained austenite transforms to martensite after the working ratio becomes high enough.

Specifically, as a result of collecting samples with good and poor elongation and measuring the quantity of retained austenite by varying the degree of tensile working from 0% to 20%, the working ratio and the quantity of retained austenite showed a tendency as illustrated in FIG. 1. As used herein, “the working ratio” refers to the elongation ratio that is determined from a tensile test performed on a JIS No. 5 test piece sampled from a steel sheet with the tensile direction being perpendicular to the rolling direction of the steel sheet.

It can be seen from FIG. 1 that the samples with good elongation each showed a gentle decrease in the quantity of retained austenite as the working ratio increased.

Accordingly, we further measured the quantity of retained austenite in each sample with TS 980 MPa grade after subjection to tensile working with an elongation value of 10%, and examined the effect of the ratio of the quantity of retained austenite after the tensile working to the quantity before the tensile working on the total elongation of the steel sheet. The results are shown in FIG. 2.

It can be seen from FIG. 2 that elongation is good if the value obtained by dividing the volume fraction of retained austenite remaining in a steel after subjection to tensile working with an elongation value of 10% by the volume fraction of retained austenite before the tensile working equals 0.3 or more, but otherwise elongation is poor.

Therefore, it is preferable in the disclosure that the value obtained by dividing the volume fraction of retained austenite remaining in a steel after subjection to tensile working with an elongation value of 10% by the volume fraction of retained austenite before the tensile working equals 0.3 or more. The reason is that this set up may ensure the transformation of sufficient retained austenite to martensite after the working ratio becomes high enough.

The above-described TRIP phenomenon requires retained austenite to be present before performing press forming or working. To cause retained austenite to be present before performing press forming or working, the Ms point (martensite transformation start temperature) which depends on the elements contained in the steel microstructure needs to be as low as approximately 15° C. or lower.

Specifically, in the tensile working with an elongation value of 10% according to the disclosure, a tensile test is performed on a JIS No. 5 test piece sampled from a steel sheet with the tensile direction being perpendicular to the rolling direction of the steel sheet, and the test is interrupted when the elongation ratio reaches 10%, thus applying tensile working with an elongation value of 10% to the test piece.

The volume fraction of retained austenite can be determined in the above-described way.

Upon a detailed study of samples satisfying the above conditions, we discovered that a TRIP phenomenon providing high strain hardenability occurs upon working and even better elongation can be achieved if the C content and the Mn content in the retained austenite satisfy the following relation:


0.04*[Mn]+0.056−0.180≤[C]≤0.04*[Mn]+0.056+0.180

where

[C] is the C content in the retained austenite in mass %, and

[Mn] is the Mn content in the retained austenite in mass %.

When the above requirements are met, it is possible to cause a TRIP phenomenon, which is a key factor of improving ductility, to occur intermittently up until the final stage of working performed on the steel sheet, guaranteeing the generation of so-called stable retained austenite.

The C content in the retained austenite (in mass %) can be determined in the following way.

Specifically, an EPMA is used to quantify the distribution of C in each phase in a cross section along the rolling direction at a position of sheet thickness×¼. Then, 30 retained austenite grains are analyzed to determine C contents, the results are averaged, and the average is used as the C content. Note that the Mn content in the retained austenite (in mass %) can be determined in the same way as the C content in the retained austenite.

The following describes the production conditions.

Steel Slab Heating Temperature: 1100° C. or Higher and 1300° C. or Lower

Precipitates that are present at the time of heating of a steel slab (hereinafter, also referred to simply as a “slab”) will remain as coarse precipitates in the resulting steel sheet, making no contribution to strength. Thus, remelting of any Ti- and Nb-based precipitates formed during casting is required.

In this respect, if a steel slab is heated at a temperature below 1100° C., it is difficult to cause sufficient dissolution of carbides, leading to problems such as an increased risk of trouble during the hot rolling resulting from increased rolling load. Therefore, the steel slab heating temperature is preferably 1100° C. or higher.

In addition, from the perspective of obtaining a smooth steel sheet surface by scaling-off defects in the surface layer of the slab, such as blow hole generation, segregation, and the like, and reducing cracks and irregularities over the steel sheet surface, the steel slab heating temperature is preferably 1100° C. or higher.

If the steel slab heating temperature exceeds 1300° C., however, scale loss increases as oxidation progresses. Therefore, the steel slab heating temperature is preferably 1300° C. or lower. For this reason, the steel slab heating temperature is preferably 1100° C. or higher and 1300° C. or lower. The steel slab heating temperature is further preferably 1150° C. or higher. The steel slab heating temperature is further preferably 1250° C. or lower.

A steel slab is preferably made with continuous casting to prevent macro segregation, yet may be produced with other methods such as ingot casting or thin slab casting. The steel slab thus produced may be cooled to room temperature and then heated again according to a conventional process. Moreover, energy-saving processes are applicable without any problem, such as hot direct rolling or direct rolling in which either a warm steel slab without being fully cooled to room temperature is charged into a heating furnace, or a steel slab is hot rolled immediately after being subjected to heat retaining for a short period. A steel slab is subjected to rough rolling under normal conditions and formed into a sheet bar. When the heating temperature is low, it is preferable to additionally heat the sheet bar using a bar heater or the like prior to finish rolling, from the viewpoint of preventing troubles during the hot rolling.

Finisher Delivery Temperature in Hot Rolling: 750° C. or Higher and 1000° C. or Lower

The heated steel slab is hot rolled through rough rolling and finish rolling to form a hot-rolled sheet. At this point, when the finisher delivery temperature exceeds 1000° C., the amount of oxides (scales) generated suddenly increases and the interface between the steel substrate and oxides becomes rough, which tends to lower the surface quality of the steel sheet after subjection to pickling and cold rolling. In addition, any hot rolling scales persisting after pickling adversely affect the ductility and stretch flangeability of the steel sheet. Moreover, grain size is excessively coarsened, causing surface deterioration in a pressed part during working. On the other hand, if the finisher delivery temperature is below 750° C., rolling load increases and rolling is performed more often with austenite being in a non-recrystallized state. As a result, an abnormal texture develops in the steel sheet, and the final product has a significant planar anisotropy such that the material properties not only become less uniform (the stability as a material decreases), but the ductility itself also deteriorates. Besides, if the finisher delivery temperature in the hot rolling is lower than 750° C. or higher than 1000° C., a microstructure having 15% or more and 30% or less of martensite in area ratio and 12% or more of retained austenite in volume fraction cannot be obtained.

Therefore, the finisher delivery temperature in the hot rolling needs to be 750° C. or higher and 1000° C. or lower. The finisher delivery temperature is preferably 800° C. or higher. The finisher delivery temperature is preferably 950° C. or lower.

Average Coiling Temperature after Hot Rolling: 300° C. or Higher and 750° C. or Lower

When the average coiling temperature after the hot rolling is above 750° C., the grain size of ferrite in the microstructure of the hot-rolled sheet increases, making it difficult to ensure a desired strength of the final-annealed sheet. On the other hand, when the average coiling temperature after the hot rolling is below 300° C., there is an increase in the strength of the hot-rolled sheet and in the rolling load for cold rolling, and the steel sheet suffers malformation. As a result, productivity decreases. Therefore, the average coiling temperature after the hot rolling is preferably 300° C. or higher and 750° C. or lower. The average coiling temperature is more preferably 400° C. or higher. The average coiling temperature is more preferably 650° C. or lower.

According to the disclosure, finish rolling may be performed continuously by joining rough-rolled sheets during the hot rolling. Rough-rolled sheets may be coiled on a temporary basis. At least part of finish rolling may be conducted as lubrication rolling to reduce the rolling load during the hot rolling. Conducting lubrication rolling in such a manner is effective from the perspective of making the shape and material properties of the steel sheet uniform. In lubrication rolling, the coefficient of friction is preferably 0.10 or more. The coefficient of friction is preferably 0.25 or less.

The hot-rolled sheet thus produced is subjected to pickling. Pickling enables removal of oxides from the steel sheet surface, and is thus important to ensure that the high-strength steel sheet as the final product has good chemical convertibility and sufficient coating quality. The pickling may be performed in one or more batches.

Hot Band Annealing (First Heat Treatment): To Retain in a Temperature Range of [Ac1 Transformation Temperature+20° C.] to [Ac1 Transformation Temperature+120° C.] for 600 s to 21,600 s

In this disclosure, it is very important to retain the steel sheet in a temperature range of [Ac1 transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s.

If the hot band annealing is performed at an annealing temperature below [Ac1 transformation temperature+20° C.] or above [Ac1 transformation temperature+120° C.], or if the holding time is shorter than 600 s, concentration of Mn in austenite does not proceed in either case, making it difficult to ensure a sufficient volume fraction of retained austenite after the final annealing. As a result, ductility decreases. Besides, a microstructure in which the value obtained by dividing the Mn content in retained austenite (in mass %) by the Mn content in polygonal ferrite (in mass %) equals 2.0 or more cannot be obtained. On the other hand, if the steel sheet is retained for more than 21,600 s, concentration of Mn in austenite reaches a plateau, and becomes less effective in improving ductility after the final annealing, resulting in a rise in costs.

Therefore, in the hot band annealing (first heat treatment) according to the disclosure, the steel sheet is retained in a temperature range of [Ac1 transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s.

The above-described heat treatment process may be continuous annealing or batch annealing. After the above-described heat treatment, the steel sheet is cooled to room temperature. The cooling process and cooling rate are not particularly limited, however, and any type of cooling may be performed, including furnace cooling and air cooling in batch annealing and gas jet cooling, mist cooling, and water cooling in continuous annealing. The pickling may be performed according to a conventional process.

Annealing (Second Heat Treatment): To Retain in a Temperature Range of [Ac1 Transformation Temperature+10° C.] to [Ac1 Transformation Temperature+100° C.] for 20 s to 900 s

In this disclosure, it is very important to retain the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s. When the annealing temperature is below [Ac1 transformation temperature+10° C.] or above [Ac1 transformation temperature+100° C.], or if the holding time is shorter than 20 s, concentration of Mn in austenite does not proceed in either case, making it difficult to ensure a sufficient volume fraction of retained austenite. As a result, ductility decreases. Besides, a microstructure in which the average grain size of polygonal ferrite is 4 μm or less, the average grain size of martensite is 2 μm or less, the average grain size of retained austenite is 2 or less, and the value obtained by dividing the Mn content in retained austenite (in mass %) by the Mn content in polygonal ferrite (in mass %) equals 2.0 or more cannot be obtained. On the other hand, if the steel sheet is retained for more than 900 s, the area ratio of non-crystallized ferrite decreases and the interfaces between different phases, namely, between ferrite and hard secondary phases (martensite and retained austenite), are reduced, leading to a reduction in both YP and YR. Besides, a microstructure in which the area ratio of non-recrystallized ferrite is 10% or more, a microstructure in which the average grain size of martensite is 2 μm or less and the average grain size of retained austenite is 2 μm or less, and a microstructure in which the value obtained by dividing the Mn content in retained austenite (in mass %) by the Mn content in polygonal ferrite (in mass %) equals 2.0 or more cannot be obtained.

Rolling Reduction in Cold Rolling: Less than 30%

Cold rolling may be performed after the hot band annealing and before the annealing (second heat treatment). In this case, the rolling reduction needs to be less than 30%. By omitting the cold rolling or performing the cold rolling with a rolling reduction of less than 30%, polygonal ferrite which forms by recrystallization after the heat treatment does not form and a microstructure elongated in the rolling direction remains, and eventually polygonal ferrite, retained austenite, and martensite with a high aspect ratio are obtained. Thus, not only the strength-ductility balance is improved, but also the stretch flangeability (hole expansion formability) is improved. If the rolling reduction is 30% or more, a microstructure having an average aspect ratio of crystal grains of each of martensite and retained austenite of 2.0 or more and 20.0 or less cannot be obtained.

Hot-Dip Galvanizing Treatment

In hot-dip galvanizing treatment according to the disclosure, the steel sheet subjected to the above-described annealing (second heat treatment) is dipped in a galvanizing bath at 440° C. or higher and 500° C. or lower for hot-dip galvanizing. Subsequently, the coating weight on the steel sheet surface is adjusted using gas wiping or the like. Preferably, the hot-dip galvanizing is performed using a galvanizing bath containing 0.10 mass % or more and 0.22 mass % or less of Al.

Moreover, when a hot-dip galvanized layer is subjected to alloying treatment, the alloying treatment may be performed in a temperature range of 450° C. to 600° C. after the above-described hot-dip galvanizing treatment. If the alloying treatment is performed at a temperature above 600° C., untransformed austenite transforms to pearlite, where a desired volume fraction of retained austenite cannot be ensured and ductility degrades. On the other hand, if the alloying treatment is performed at a temperature below 450° C., the alloying process does not proceed, making it difficult to form an alloy layer.

Therefore, when the galvanized layer is subjected to alloying treatment, the alloying treatment is performed in a temperature range of 450° C. to 600° C.

Although other manufacturing conditions are not particularly limited, the series of processes including the annealing, hot-dip galvanizing, and alloying treatment described above may preferably be performed in a continuous galvanizing line (CGL), which is a hot-dip galvanizing line, from the perspective of productivity.

When hot-dip aluminum coating treatment is performed, the steel sheet subjected to the above-described annealing treatment is dipped in an aluminum molten bath at 660° C. to 730° C. for hot-dip aluminum coating treatment. Subsequently, the coating weight is adjusted using gas wiping or the like. If the steel sheet has a composition such that the temperature of the aluminum molten bath falls within the temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.], the steel sheet is preferably subjected to hot-dip aluminum coating treatment because finer and more stable retained austenite can be formed, and therefore further improvement in ductility can be achieved.

Electrogalvanizing Treatment

According to the disclosure, electrogalvanizing treatment may also be performed on the steel sheet after the heat treatment. No particular limitations are placed on the electrogalvanizing treatment conditions, yet the electrogalvanizing treatment conditions are preferably set so that the plated layer has a thickness of 5 μm to 15 μm.

According to the disclosure, the above-described steel sheet, hot-dip galvanized steel sheet, hot-dip aluminum-coated steel sheet, and electrogalvanized steel sheet may be subjected to skin pass rolling for the purposes of straightening, adjustment of roughness on the sheet surface, and the like. The skin pass rolling is preferably performed at a rolling reduction of 0.1% or more. The skin pass rolling is preferably performed at a rolling reduction of 2.0% or less.

When the rolling reduction is less than 0.1%, the skin pass rolling becomes less effective and more difficult to control. Thus, a preferable range for the rolling reduction has a lower limit of 0.1%. On the other hand, when the skin pass rolling is performed at a rolling reduction above 2.0%, the productivity of the steel sheet decreases significantly. Thus, the preferable range for the rolling reduction has an upper limit of 2.0%.

The skin pass rolling may be performed on-line or off-line. Skin pass may be performed in one or more batches to achieve a target rolling reduction.

Moreover, the steel sheet, the hot-dip galvanized steel sheet, the hot-dip aluminum-coated steel sheet, and the electrogalvanized steel sheet according to the disclosure may be subjected to a variety of coating treatment options, such as those using coating of resin, fats and oils, and the like.

Examples

Steels having the chemical compositions as presented in Table 1, with the balance consisting of Fe and inevitable impurities, were prepared by steelmaking in a converter, and formed into slabs through continuous casting. The slabs thus obtained were formed into a variety of steel sheets, as described below, by varying the conditions as listed in Table 2.

After being hot rolled, each steel sheet was annealed in a temperature range of [Ac1 transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.]. After being cold rolled (or without cold rolling), each steel sheet was annealed in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.]. Consequently, a cold-rolled steel sheet (CR) was obtained, and subjected to coating treatment to form a hot-dip galvanized steel sheet (GI), a galvannealed steel sheet (GA), a hot-dip aluminum-coated steel sheet (Al), an electrogalvanized steel sheet (EG), or the like.

Used as hot-dip galvanizing baths were a zinc bath containing 0.19 mass % of Al for hot-dip galvanized steel sheets (GI) and a zinc bath containing 0.14 mass % of Al for galvannealed steel sheets (GA). In either case, the bath temperature was 465° C. and the coating weight per side was 45 g/m2 (in the case of both-sided coating). For GA, the Fe concentration in the coating layer was adjusted to be 9 mass % or more and 12 mass % or less. The bath temperature of the hot-dip aluminum molten bath for hot-dip aluminum-coated steel sheets was set at 700° C.

For each of the steel sheets thus obtained, the cross-sectional microstructure, tensile property, hole expansion formability, bendability, and the like were investigated. The results are listed in Tables 3 to 5.

The Ac1 transformation temperature was calculated by:


[Ac1 transformation temperature (° C.)]=751−16*(% C)+11*(% Si)−28*(% Mn)−5.5*(% Cu)−16*(% Ni)+13*(% Cr)+3.4*(% Mo)

where (% C), (% Si), (% Mn), (% Ni), (% Cu), (% Cr), and (% Mo) each represent the content in steel (in mass %) of the element in the parentheses.

Tensile test was performed in accordance with JIS Z 2241 (2011) to measure YP, YR, TS, and EL using JIS No. 5 test pieces, each of which was sampled in a manner that the tensile direction was perpendicular to the rolling direction of the steel sheet. Note that YR is YP divided by TS, expressed as a percentage. In this case, the results were determined to be good when YR≥68% and when TS*EL≥22,000 MPa %. Also, EL was determined to be good when EL≥26% for TS 980 MPa grade, EL≥22% for TS 1180 MPa grade, and EL≥18% for TS 1470 MPa grade. In this case, a steel sheet of TS 980 MPa grade refers to a steel sheet with TS of 980 MPa or more and less than 1180 MPa, a steel sheet of TS 1180 MPa grade refers to a steel sheet with TS of 1180 MPa or more and less than 1470 MPa, and a steel sheet of TS 1470 MPa grade refers to a steel sheet with TS of 1470 MPa or more and less than 1760 MPa.

Bend test was performed according to the V-block method specified in JIS Z 2248 (1996). Each steel sheet was visually observed under a stereoscopic microscope for cracks on the outside of the bent portion, and the minimum bending radius without cracks was used as the limit bending radius R. In this case, the bendability of the steel sheet was determined to be good if the following condition was satisfied: limit bending radius R at 90° V-bending/t≤2.0 (where t is the thickness of the steel sheet).

Hole expansion test was performed in accordance with JIS Z 2256 (2010). Each of the steel sheets obtained was cut to a size of 100 mm*100 mm, and a hole of 10 mm in diameter was drilled through each sample with clearance 12%±1%. Then, each steel sheet was clamped into a die having an inner diameter of 75 mm with a blank holding force of 9 tons (88.26 kN). In this state, a conical punch of 60° was pushed into the hole, and the hole diameter at the crack initiation limit was measured. Then, to evaluate hole expansion formability, the maximum hole expansion ratio (%) was calculated by:


Maximum hole expansion ratio λ(%)={(Df−D0)/D0}*100

where Df is a hole diameter at the time of occurrence of cracking (mm) and D0 is an initial hole diameter (mm).

In this case, the maximum hole expansion ratio was determined to be good when λ≥25% for TS 980 MPa grade, λ≥18% for TS 1180 MPa grade, and λ≥15% for TS 1470 MPa grade.

The sheet passage ability during hot rolling was determined to be low when it was considered that the risk of troubles, such as malformation during hot rolling due to increased rolling load, would increase because, for example, the hot-rolling finisher delivery temperature was low and rolling would be performed more often with austenite being in a non-crystallized state, or rolling would be performed in an austenite-ferrite dual phase region. The sheet passage ability during cold rolling was determined to be low when it was considered that the risk of troubles, such as malformation during cold rolling due to increased rolling load, would increase because, for example, the coiling temperature during hot rolling was low and the hot-rolled sheet had a steel microstructure in which low-temperature transformation phases, such as bainite and martensite, were dominantly present.

The surface characteristics of each final-annealed sheet were determined to be poor when defects such as blow hole generation and segregation on the surface layer of the slab could not be scaled-off, cracks and irregularities on the steel sheet surface increased, and a smooth steel sheet surface could not be obtained. The surface characteristics of each final-annealed sheet were also determined to be poor when the amount of oxides (scales) generated suddenly increased, interfaces between the steel substrate and oxides were roughened, and the surface quality after pickling and cold rolling degraded, or when hot-rolling scales persisted at least in part after pickling.

In this case, productivity was evaluated according to the lead time costs, including: (1) malformation of a hot-rolled sheet occurred; (2) a hot-rolled sheet requires straightening before proceeding to the subsequent steps; and (3) a prolonged holding time during the annealing treatment. The productivity was determined to be “good” when none of (1) to (3) applied and “poor” when any of (1) to (3) applied.

Tensile working was performed in accordance with JIS Z 2241 (2011) using JIS No. 5 test pieces, each of which was sampled in a manner that the tensile direction was perpendicular to the rolling direction of the steel sheet. A value was obtained by dividing the volume fraction of retained austenite remaining in each steel sheet after subjection to tensile working with an elongation value of 10% by the volume fraction of retained austenite before the working (10% application). The volume fraction of retained austenite was measured in accordance with the above procedure.

The measurement results are also listed in Table 4.

The C content in the retained austenite (in mass %) and the Mn content in the retained austenite (in mass %) were measured in accordance with the above procedure.

The measurement results are also listed in Table 4.

TABLE 1 Steel Chemical composition (mass %) temperature sample ID C Si Mn P S N Ti Al Nb B Ni Cr V Mo Cu Sn Sb Ta Ca Mg REM (° C.) Remarks A 0.121 0.50 5.03 0.022 0.0021 0.0037 0.025 — — — — — — — — — — — — — — 613 Conforming steel B 0.178 0.50 5.55 0.023 0.0022 0.0039 0.037 — — — — — — — — — — — — — — 598 Conforming steel C 0.199 0.90 5.89 0.022 0.0022 0.0036 0.036 — — — — — — — — — — — — — — 593 Conforming steel D 0.175 1.50 5.22 0.021 0.0024 0.0043 0.038 — — — — — — — — — — — — — — 619 Conforming steel E 0.101 0.87 5.08 0.026 0.0021 0.0044 0.033 — — — — — — — — — — — — — — 617 Conforming steel F 0.167 0.10 5.01 0.024 0.0028 0.0033 0.023 — — — — — — — — — — — — — — 609 Conforming steel G 0.115 0.99 5.23 0.026 0.0021 0.0036 0.031 — — — — — — — — — — — — — — 614 Conforming steel H 0.120 0.75 4.77 0.027 0.0021 0.0036 0.025 — — — — — — — — — — — — — — 624 Conforming steel I 0.121 0.55 5.25 0.028 0.0028 0.0035 0.039 — — — — — — — — — — — — — — 608 Conforming steel IA 0.030 0.55 5.12 0.025 0.0021 0.0031 0.041 — — — — — — — — — — — — — — 613 Conforming steel IB 0.250 0.51 4.85 0.028 0.0022 0.0035 0.042 — — — — — — — — — — — — — — 617 Conforming steel IC 0.120 0.01 4.78 0.028 0.0021 0.0032 0.038 — — — — — — — — — — — — — — 615 Conforming steel ID 0.121 3.00 5.01 0.031 0.0023 0.0035 0.036 — — — — — — — — — — — — — — 642 Conforming steel IE 0.131 0.62 4.25 0.030 0.0021 0.0036 0.045 — — — — — — — — — — — — — — 637 Conforming steel IF 0.128 0.45 6.00 0.030 0.0028 0.0034 0.055 — — — — — — — — — — — — — — 586 Conforming steel IG 0.121 0.51 4.89 0.001 0.0030 0.0040 0.045 — — — — — — — — — — — — — — 618 Conforming steel IH 0.125 0.52 5.55 0.100 0.0031 0.0041 0.051 — — — — — — — — — — — — — — 599 Conforming steel II 0.142 0.55 4.99 0.028 0.0001 0.0038 0.054 — — — — — — — — — — — — — — 615 Conforming steel IJ 0.153 0.48 4.89 0.025 0.0200 0.0032 0.051 — — — — — — — — — — — — — — 617 Conforming steel IK 0.120 0.63 5.11 0.022 0.0031 0.0005 0.053 — — — — — — — — — — — — — — 613 Conforming steel IL 0.124 0.67 5.23 0.022 0.0035 0.0100 0.045 — — — — — — — — — — — — — — 610 Conforming steel IM 0.142 0.51 4.99 0.021 0.0032 0.0038 0.005 — — — — — — — — — — — — — — 615 Conforming steel IN 0.133 0.68 5.45 0.023 0.0036 0.0035 0.200 — — — — — — — — — — — — — — 604 Conforming steel IO 0.090 0.44 4.10 0.028 0.0021 0.0037 0.065 — — — — — — — — — — — — — — 640 Comparative steel IP 0.145 0.61 5.03 0.030 0.0031 0.0034 0.210 — — — — — — — — — — — — — — 615 Comparative steel J 0.022 0.67 5.71 0.021 0.0027 0.0034 0.041 — — — — — — — — — — — — — — 598 Comparative steel K 0.201 4.33 5.29 0.026 0.0026 0.0036 0.031 — — — — — — — — — — — — — — 647 Comparative steel L 0.211 0.88 2.09 0.022 0.0020 0.0037 0.032 — — — — — — — — — — — — — — 699 Comparative steel M 0.201 0.71 5.62 0.024 0.0037 0.0037 0.003 — — — — — — — — — — — — — — 598 Comparative steel N 0.205 0.51 5.55 0.020 0.0030 0.0040 0.038 0.35 — — — — — — — — — — — — — 598 Conforming steel O 0.201 0.92 5.56 0.025 0.0029 0.0036 0.033 — 0.042 — — — — — — — — — — — — 602 Conforming steel P 0.203 0.91 5.43 0.022 0.0026 0.0039 0.027 — — 0.0021 — — — — — — — — — — — 606 Conforming steel Q 0.236 1.31 5.43 0.026 0.0025 0.0034 0.035 — — — 0.345 — — — — — — — — — — 604 Conforming steel R 0.155 0.41 4.89 0.031 0.0023 0.0034 0.033 — — — — 0.245 — — — — — — — — — 619 Conforming steel S 0.161 0.77 4.73 0.029 0.0023 0.0034 0.030 — — — — — 0.044 — — — — — — — — 624 Conforming steel T 0.152 0.67 5.09 0.031 0.0025 0.0038 0.039 — — — — — — 0.422 — — — — — — — 615 Conforming steel U 0.121 1.45 4.90 0.023 0.0029 0.0037 0.035 — — — — — — — 0.265 — — — — — — 626 Conforming steel V 0.189 0.89 4.89 0.030 0.0032 0.0036 0.036 — — — — — — — — 0.007 — — — — — 621 Conforming steel W 0.135 0.65 4.99 0.026 0.0024 0.0037 0.044 — — — — — — — — — — 0.006 — — — 616 Conforming steel X 0.221 0.65 5.60 0.027 0.0029 0.0046 0.042 — 0.045 — — — — — — — — — — — — 598 Conforming steel Y 0.209 0.51 5.07 0.029 0.0030 0.0039 0.042 — 0.049 — — — — — — 0.008 — — — — — 611 Conforming steel Z 0.209 0.35 5.63 0.027 0.0027 0.0046 0.031 — 0.041 — — — — — — — — 0.009 — — — 594 Conforming steel AA 0.227 1.02 5.24 0.029 0.0028 0.0047 0.044 — — — — — — — — — — — 0.0021 — — 612 Conforming steel AB 0.218 1.42 5.22 0.030 0.0020 0.0043 0.041 — — — — — — — — — — — — 0.0028 — 617 Conforming steel AC 0.220 1.18 5.54 0.039 0.0026 0.0035 0.024 — — — — — — — — — — — — — 0.0020 605 Conforming steel AD 0.197 1.18 5.14 0.027 0.0028 0.0033 0.031 — — — — — — — — — 0.010 — — — — 617 Conforming steel Underline: outside range according to present disclosure

TABLE 2 (First) hot-rolled sheet heat treatment Steel Slab heating Finisher delivery Average coiling Heat treatment Heat treatment sample temperature temperature temperature temperature time No. ID (° C.) (° C.) (° C.) (° C.) (s)  1 A 1220 890 550 653 20000  2 B 1230 880 510 639 15000  3 C 1190 880 610 642 14000  4 A 1220 705 550 642 18000  5 A 1230 1085  500 642 11000  6 A 1260 860 520 510 14000  7 A 1230 870 500 830 18000  8 A 1260 880 580 642  100  9 A 1210 870 620 650 18000 10 A 1200 870 620 647 19000 11 A 1100 890 550 650 18000 12 A 1300 880 480 660 18000 13 A 1200 750 500 650 18000 14 A 1250 1000  620 700 11000 15 A 1220 900 300 650 11000 16 A 1200 880 750 680 17000 17 A 1210 870 600 733 17000 18 A 1220 900 500 650  600 19 A 1200 880 550 660 10000 20 A 1230 890 450 680 10000 21 A 1210 870 500 680 12000 22 A 1190 850 480 700 12000 23 A 1195 880 450 680 14000 24 A 1200 880 600 640 17000 25 A 1210 870 620 650  5000 26 A 1220 870 620 652  6000 27 A 1230 870 600 642  6000 28 A 1200 870 570 642 11000 29 A 1220 850 570 642  9000 30 A 1190 880 580 642 18000 31 D 1230 850 540 659 18000 32 E 1230 880 530 654  8000 33 F 1240 890 560 654 16000 34 G 1230 880 600 650  7000 35 H 1250 850 570 666  8000 36 I 1230 910 610 642 15000 37 IA 1250 870 550 645 17000 38 IB 1220 870 540 650 18000 39 IC 1250 870 450 650 18000 40 ID 1230 850 550 665 17000 41 IE 1240 860 560 660 15000 42 IF 1200 850 530 650 15000 43 IG 1210 860 540 650 14000 44 IH 1200 870 550 620 17000 45 II 1220 860 500 640 18000 46 IJ 1250 860 510 640 14000 47 IK 1240 870 510 650 18000 48 IL 1200 860 520 650 19000 49 IM 1210 850 460 650 17000 50 IN 1195 860 480 630 18000 51 IO 1190 870 450 660 17000 52 IP 1200 850 500 650 17000 53 J 1210 850 640 639 17000 54 K 1200 860 630 687 19000 55 L 1230 830 580 735  2000 56 M 1240 820 550 638  5000 57 N 1250 840 590 634  7000 58 O 1260 860 550 645 14000 59 P 1210 890 530 645 20000 60 Q 1250 830 610 645 18000 61 R 1260 820 570 662 14000 62 S 1230 870 630 666  8000 63 T 1240 810 610 651  7000 64 U 1240 840 540 667 15000 65 V 1230 910 580 659 13000 66 W 1220 900 510 656 10000 67 X 1240 880 600 645 15000 68 Y 1250 890 530 652  9000 69 Z 1240 870 550 636 20000 70 AA 1250 890 530 652  8000 71 AB 1240 870 550 658 15000 72 AC 1250 850 540 652  5000 73 AD 1230 840 530 659  8000 74 A 1220 890 550 651  1000 75 A 1230 870 540 655  8000 (Second) annealing treatment Rolling reduction Heat treatment Heat treatment in cold rolling temperature time No. (%) (° C.) (s) Type* Remarks  1 25.9 643 350 GA Example  2 22.2 629 300 CR Example  3 25.0 632 250 CR Example  4 24.1 632 300 GI Comparative Example  5 21.4 632 350 EG Comparative Example  6 25.9 632 500 EG Comparative Example  7 25.0 632 300 EG Comparative Example  8 18.5 632 500 CR Comparative Example  9 19.2 630 550 CR Example 10  0.0 632 550 CR Example 11 13.8 640 300 CR Example 12 27.6 640 350 CR Example 13 22.2 632 350 GA Example 14 14.3 640 400 GA Example 15 13.8 640 300 GA Example 16  7.4 632 350 GA Example 17 22.2 632 350 GA Example 18 17.9 632 500 GA Example 19 29.1 640 350 GA Example 20 27.6 713 150 GA Example 21 20.7 660  20 GA Example 22  7.4 630 900 GA Example 23 31.0 640 350 CR Comparative Example 24 12.5 640 1000  GA Comparative Example 25 70.2 635 550 CR Comparative Example 26 42.9 635 550 CR Comparative Example 27 23.1 520 750 CR Comparative Example 28 28.6 800 400 GI Comparative Example 29 25.0 632  3 CR Comparative Example 30 22.2 632 2200  CR Comparative Example 31 25.9 649 500 CR Example 32 28.6 644 600 GI Example 33 25.0 644 600 CR Example 34 25.9 640 550 CR Example 35 21.4 656 650 CR Example 36 21.4 632 300 GA Example 37 22.2 635 350 CR Example 38 19.2 635 300 CR Example 39 19.2 635 350 GA Example 40 18.5 655 350 CR Example 41 25.9 650 500 GA Example 42 25.0 640 450 CR Example 43 16.0 640 500 CR Example 44 15.4 640 500 GA Example 45 25.0 640 350 GA Example 46 22.2 635 350 CR Example 47 21.4 635 400 CR Example 48 25.0 635 400 CR Example 49 25.9 640 400 GA Example 50 25.0 640 400 GA Example 51 17.9 655 350 CR Comparative Example 52 18.5 635 500 CR Comparative Example 53 25.9 629 250 CR Comparative Example 54 25.0 677 200 EG Comparative Example 55 25.9 725 300 CR Comparative Example 56 26.9 628 400 EG Comparative Example 57 25.9 624 150 GI Example 58 25.0 635 100 CR Example 59 22.2 635 200 GA Example 60 25.9 635 320 CR Example 61 26.9 652 300 CR Example 62 28.0 656 300 Al Example 63 25.9 641 200 GI Example 64 25.9 657 250 GI Example 65 25.0 649 350 GI Example 66 24.1 646 300 EG Example 67 22.2 635 300 Al Example 68 25.9 642 340 GA Example 69 26.9 626 500 CR Example 70 26.9 642 500 Al Example 71 28.6 648 400 GI Example 72 25.9 642 350 CR Example 73 25.0 648 300 CR Example 74 25.9 625 200 CR Example 75 22.2 624 250 CR Example Underline: outside range according to present disclosure *CR: cold-rolled steel sheet (no coating), GI: hot-dip galvanized steel sheet (no galvannealing), GA: galvannealed steel sheet Al: hot-dip aluminum-coated steel sheet, EG: electrogalvanized steel sheet

TABLE 3 Average Aspect Rolling Area Area Volume grain ratio of Steel reduction in ratio Area ratio ratio fraction Area ratio size crystal sample cold rolling of F of F′ of M of RA of ε (μm) grains No. ID (%) (%) (%) (%) (%) (%) F M RA F M RA Balance Remarks 1 A 25.9 30.5 20.1 19.1 24.5 2.2 1.8 0.9 0.8 6.9 5.5 5.9 P, θ, ε Example 2 B 22.2 25.3 26.1 16.1 29.8 1.8 1.7 0.7 0.6 7.3 5.1 6.3 P, θ, ε Example 3 C 25.0 13.6 30.1 16.8 36.8 2.1 1.6 0.8 1.1 7.8 5.3 5.7 P, θ, ε Example 4 A 24.1 33.1 18.6 33.2  9.2 0.9 2.1 2.5 1.3 6.5 5.1 6.5 P, θ, ε Comparative Example 5 A 21.4 30.5 18.4 35.1  8.9 1.2 2.2 2.2 1.2 6.1 5.0 5.4 P, θ, ε Comparative Example 6 A 25.9 32.1 19.2 19.1 23.4 2.1 2.1 1.3 1.2 7.1 5.3 5.4 P, θ, ε Comparative Example 7 A 25.0 33.8 19.2 18.9 24.5 1.8 2.2 1.2 1.1 6.5 5.4 6.1 P, θ, ε Comparative Example 8 A 18.5 30.8 19.1 18.0 24.9 1.6 2.1 1.1 1.0 5.5 5.3 6.3 P, θ, ε Comparative Example 9 A 19.2 30.4 19.4 22.5 25.0 1.3 1.5 1.1 0.8 8.1 5.9 10.2  P, θ, ε Example 10 A  0.0 28.1 19.4 23.4 24.8 1.2 2.1 1.0 0.9 15.0  14.8  16.1  P, θ, ε Example 11 A 13.8 25.0 22.0 25.0 23.0 1.0 1.5 1.1 0.9 8.2 6.1 6.1 P, θ, ε Example 12 A 27.6 31.0 18.0 24.0 24.5 1.2 2.5 1.8 1.5 6.9 5.1 5.2 P, θ, ε Example 13 A 22.2 30.5 19.4 22.4 24.8 1.3 2.1 1.1 0.9 7.2 5.5 5.5 P, θ, ε Example 14 A 14.3 30.1 19.2 22.0 24.1 1.5 2.1 1.1 0.8 8.4 5.4 6.2 P, θ, ε Example 15 A 13.8 29.1 18.9 22.5 23.8 1.6 2.2 1.0 0.9 8.4 5.9 6.1 P, θ, ε Example 16 A  7.4 29.4 19.1 23.5 24.1 1.5 2.1 1.1 0.9 12.1  10.5  11.5  P, θ, ε Example 17 A 22.2 10.5 27.4 28.2 23.0 1.5 1.8 1.5 1.2 7.5 5.8 5.2 P, θ, ε Example 18 A 17.9 25.1 15.8 28.9 21.0 2.0 1.9 1.2 0.9 7.5 5.9 6.1 P, θ, ε Example 19 A 29.1 32.1 19.0 19.4 23.0 1.5 2.5 1.1 1.2 4.1 4.5 5.1 P, θ, ε Example 20 A 27.6 32.5 15.4 18.9 21.4 2.0 3.1 1.2 0.9 5.3 6.1 5.7 P, θ, ε Example 21 A 20.7 18.9 25.4 23.0 22.7 1.8 1.9 1.5 1.2 6.9 5.8 5.1 P, θ, ε Example 22 A  7.4 15.2 36.9 23.8 21.8 1.1 3.5 1.2 0.9 15.4  11.1  11.2  P, θ, ε Example 23 A 31.0 38.7 15.4 22.1 20.4 1.8 3.8 1.9 1.2 22.0  19.8  21.1  P, θ, ε Comparative Example 24 A 12.5 52.0  5.0 15.4 15.8 1.2 5.1 2.1 0.8 6.9 5.4 5.1 P, θ, ε Comparative Example 25 A 70.2 50.7 12.0 20.8  9.1 1.5 4.2 2.0 0.5 1.4 1.4 1.5 P, θ, ε Comparative Example 26 A 42.9 37.8 19.4 21.7 12.1 2.0 3.8 1.8 0.5 1.9 1.8 1.9 P, θ, ε Comparative Example 27 A 23.1 34.2 15.3 33.1 10.8 1.6 4.5 2.3 2.1 7.2 5.2 5.9 P, θ, ε Comparative Example 28 A 28.6 35.2 18.2 32.4 10.4 1.3 4.6 2.1 2.4 7.1 5.5 6.6 P, θ, ε Comparative Example 29 A 25.0 33.8 19.1 27.8  9.8 1.7 4.2 2.3 2.2 7.9 5.0 5.7 P, θ, ε Comparative Example 30 A 22.2 32.9  5.1 18.2 24.5 1.8 1.7 3.9 3.8 5.1 4.8 5.1 P, θ, ε Comparative Example 31 D 25.9 24.8 24.1 20.1 28.9 2.1 1.6 0.8 0.6 6.9 4.2 6.0 P, θ, ε Example 32 E 28.6 33.8 19.7 19.4 25.4 0.6 1.9 1.0 0.9 8.1 5.1 6.8 P, θ, ε Example 33 F 25.0 30.2 22.5 17.7 26.8 2.1 1.5 0.8 0.7 7.1 5.1 6.4 P, θ, ε Example 34 G 25.9 13.7 28.9 15.4 32.9 4.2 1.5 0.7 0.8 7.4 5.2 5.9 P, θ, ε Example 35 H 21.4 30.4 20.3 18.9 26.8 2.1 1.7 0.7 0.6 7.6 5.9 6.1 P, θ, ε Example 36 I 21.4 32.6 20.5 17.5 27.8 0.8 1.6 0.6 0.5 7.7 5.8 6.2 P, θ, ε Example 37 IA 22.2 35.1 12.0 19.2 25.1 0.8 2.2 1.1 1.2 6.8 6.1 5.7 P, θ, ε Example 38 IB 19.2 10.5 15.0 28.5 25.4 0.9 2.3 1.1 0.9 6.9 5.5 5.9 P, θ, ε Example 39 IC 19.2 20.5 18.9 19.1 23.8 1.5 2.2 1.2 1.1 7.2 6.1 6.2 P, θ, ε Example 40 ID 18.5 32.5 20.5 19.9 24.0 1.5 2.1 1.0 1.2 7.5 5.8 6.4 P, θ, ε Example 41 IE 25.9 33.6 20.3 18.9 23.1 1.5 1.9 1.5 1.2 8.1 5.8 5.9 P, θ, ε Example 42 IF 25.0 12.8 20.6 22.5 25.4 1.2 1.9 1.4 1.1 6.9 5.9 6.4 P, θ, ε Example 43 IG 16.0 30.5 22.1 19.2 24.1 1.5 2.0 1.2 0.8 6.8 6.1 6.1 P, θ, ε Example 44 IH 15.4 32.1 21.5 18.9 25.1 1.2 2.1 1.2 0.9 7.2 5.5 6.7 P, θ, ε Example 45 II 25.0 31.5 20.5 18.9 25.1 1.2 2.2 1.3 0.9 7.4 5.7 5.8 P, θ, ε Example 46 IJ 22.2 30.4 20.6 19.1 24.1 1.2 2.0 1.1 1.1 7.1 5.9 5.9 P, θ, ε Example 47 IK 21.4 32.0 25.1 15.2 22.5 1.5 2.1 1.5 1.0 6.9 6.1 6.4 P, θ, ε Example 48 IL 25.0 20.1 25.1 28.5 23.7 1.1 1.8 1.4 1.1 6.8 5.9 6.2 P, θ, ε Example 49 IM 25.9 35.6 18.1 23.1 22.1 0.8 1.8 1.2 0.9 6.7 6.1 5.9 P, θ, ε Example 50 IN 25.0 15.4 18.9 25.8 25.4 1.8 1.9 1.1 1.1 7.1 5.9 5.9 P, θ, ε Example 51 IO 17.9 35.8 18.2 18.9 22.0 0.9 2.2 2.0 1.1 21.5  22.0  23.1  P, θ, ε Comparative Example 52 IP 18.5 38.1 22.8 20.5  5.5 1.8 1.1 1.5 1.4 3.0 4.5 5.2 P, θ, ε Comparative Example 53 J 25.9 72.8  8.6  8.5  8.4 0.7 6.7 0.4 0.3 2.1 3.8 3.5 P, θ, ε Comparative Example 54 K 25.0 50.0 15.6 19.1 12.4 1.8 4.3 1.7 1.6 3.1 2.9 3.8 P, θ, ε Comparative Example 55 L 25.9 62.5 14.1 15.1  8.1 0.2 5.8 3.7 3.6 2.3 3.1 3.1 P, θ, ε Comparative Example 56 M 26.9 58.1  3.9 19.4 13.2 1.9 6.2 3.5 3.4 2.0 3.1 2.5 P, θ, ε Comparative Example 57 N 25.9 30.1 20.4 19.2 26.5 0.6 1.7 1.1 0.7 7.3 5.9 6.4 P, θ, ε Example 58 O 25.0 29.7 22.3 18.1 28.1 0.9 1.5 0.8 0.7 7.2 6.1 5.9 P, θ, ε Example 59 P 22.2 30.5 20.5 18.2 24.5 2.5 1.3 0.6 0.7 6.9 5.7 6.4 P, θ, ε Example 60 Q 25.9 30.1 19.8 18.1 26.4 3.1 1.2 0.8 0.6 8.0 6.2 5.1 P, θ, ε Example 61 R 26.9 32.1 20.4 18.6 27.5 0.1 1.2 0.5 0.7 5.9 5.1 6.5 P, θ, ε Example 62 S 28.0 31.2 22.4 18.2 26.8 0.7 1.4 0.8 0.8 7.3 5.7 4.9 P, θ, ε Example 63 T 25.9 30.5 20.1 18.1 27.5 0.0 0.9 0.7 0.9 8.2 5.5 5.4 P, θ, ε Example 64 U 25.9 31.8 21.0 18.2 26.8 2.1 1.4 0.8 0.7 5.9 5.2 6.5 P, θ, ε Example 65 V 25.0 31.8 19.7 17.8 25.9 0.6 1.2 0.8 0.7 7.1 6.1 5.4 P, θ, ε Example 66 W 24.1 22.8 27.1 17.7 28.5 0.7 1.4 0.6 0.7 6.5 4.1 6.1 P, θ, ε Example 67 X 22.2 25.3 28.1 17.3 26.4 2.1 1.3 0.6 0.7 6.8 5.2 5.7 P, θ, ε Example 68 Y 25.9 20.4 26.3 17.1 32.1 2.2 1.5 0.6 0.5 6.9 6.1 6.4 P, θ, ε Example 69 Z 26.9 30.4 19.7 18.4 29.4 0.9 1.4 0.9 0.7 7.2 5.8 6.3 P, θ, ε Example 70 AA 26.9 30.8 20.1 16.2 26.8 2.6 1.3 0.7 0.8 7.1 6.1 7.1 P, θ, ε Example 71 AB 28.6 31.0 21.5 18.1 27.4 0.6 1.4 0.6 0.5 6.9 6.5 5.9 P, θ, ε Example 72 AC 25.9 30.2 19.1 17.8 28.4 2.2 1.2 0.8 0.5 7.4 5.9 5.8 P, θ, ε Example 73 AD 25.0 25.7 20.1 18.1 29.8 0.7 1.1 0.6 0.4 8.4 6.1 6.4 P, θ, ε Example 74 A 25.9 32.1 21.4 19.4 22.4 3.1 2.2 1.0 0.8 8.1 4.6 7.2 P, θ, ε Example 75 A 22.2 31.8 18.9 19.5 21.8 2.4 2.3 0.9 0.7 7.9 4.4 5.8 P, θ, ε Example Underline: outside range according to present disclosure F: polygonal ferrite, F′: non-recrystallized ferrite, RA: retained austenite, M: martensite, P: pearlite, θ: carbide (such as cementite) ε: ε phase with hep structure

TABLE 4 0.04 × 0.04 × Average Value obtained by dividing Average Mn Average Mn (Mn content in RA) + (Mn content in RA) + C content RA remaining volume fraction Steel sample content in RA content in F Average Mn content in RA/ 0.056 − 0.180 0.056 + 0.180 in RA after 10% tensile working by No. ID (mass %) (mass %) Average Mn content in F (mass %) (mass %) (mass %) RA volume fraction before working Remarks 1 A 8.78 3.18 2.76 0.23 0.59 0.43 0.72 Example 2 B 9.12 3.11 2.93 0.24 0.60 0.40 0.78 Example 3 C 9.03 3.15 2.87 0.24 0.60 0.45 0.67 Example 4 A 8.11 3.15 2.57 0.20 0.56 0.28 0.44 Comparative Example 5 A 8.02 3.25 2.47 0.20 0.56 0.18 0.49 Comparative Example 6 A 6.41 3.36 1.91 0.13 0.49 0.12 0.38 Comparative Example 7 A 6.84 3.49 1.96 0.15 0.51 0.14 0.46 Comparative Example 8 A 6.94 3.59 1.93 0.15 0.51 0.23 0.42 Comparative Example 9 A 7.54 3.18 2.37 0.18 0.54 0.25 0.52 Example 10 A 8.10 3.25 2.49 0.20 0.56 0.32 0.75 Example 11 A 8.20 2.97 2.76 0.20 0.56 0.33 0.65 Example 12 A 8.50 2.99 2.84 0.22 0.58 0.35 0.70 Example 13 A 8.50 3.02 2.81 0.22 0.58 0.39 0.78 Example 14 A 8.90 3.11 2.86 0.23 0.59 0.28 0.74 Example 15 A 8.50 3.05 2.79 0.22 0.58 0.31 0.65 Example 16 A 8.90 3.12 2.85 0.23 0.59 0.29 0.68 Example 17 A 8.70 3.12 2.79 0.22 0.58 0.41 0.71 Example 18 A 8.44 3.01 2.80 0.21 0.57 0.33 0.66 Example 19 A 9.10 3.15 2.89 0.24 0.60 0.45 0.69 Example 20 A 8.50 3.08 2.76 0.22 0.58 0.38 0.74 Example 21 A 7.51 3.14 2.39 0.18 0.54 0.39 0.78 Example 22 A 9.45 3.11 3.04 0.25 0.61 0.41 0.81 Example 23 A 7.45 3.02 2.47 0.17 0.53 0.55 0.29 Comparative Example 24 A 8.99 3.08 2.92 0.24 0.60 0.61 0.29 Comparative Example 25 A 8.45 3.87 2.18 0.21 0.57 0.19 0.21 Comparative Example 26 A 8.56 3.22 2.66 0.22 0.58 0.19 0.27 Comparative Example 27 A 6.88 4.02 1.71 0.15 0.51 0.14 0.38 Comparative Example 28 A 6.48 4.06 1.60 0.14 0.50 0.13 0.47 Comparative Example 29 A 6.29 3.98 1.58 0.13 0.49 0.21 0.46 Comparative Example 30 A 6.01 3.18 1.89 0.12 0.48 0.20 0.52 Comparative Example 31 D 9.02 3.05 2.96 0.24 0.60 0.42 0.74 Example 32 E 8.56 3.22 2.66 0.22 0.58 0.40 0.82 Example 33 F 8.35 3.12 2.68 0.21 0.57 0.42 0.75 Example 34 G 9.12 3.09 2.95 0.24 0.60 0.39 0.67 Example 35 H 9.06 3.05 2.97 0.24 0.60 0.38 0.69 Example 36 I 9.15 3.09 2.96 0.24 0.60 0.44 0.70 Example 37 IA 7.45 3.21 2.32 0.17 0.53 0.33 0.35 Example 38 IB 5.88 2.85 2.06 0.11 0.47 0.46 0.78 Example 39 IC 6.48 3.23 2.01 0.14 0.50 0.42 0.65 Example 40 ID 7.88 3.91 2.02 0.19 0.55 0.45 0.81 Example 41 IE 7.68 2.51 3.06 0.18 0.54 0.44 0.71 Example 42 IF 8.59 4.21 2.04 0.22 0.58 0.41 0.68 Example 43 IG 8.46 3.56 2.38 0.21 0.57 0.51 0.66 Example 44 IH 9.12 3.21 2.84 0.24 0.60 0.50 0.80 Example 45 II 9.01 3.14 2.87 0.24 0.60 0.51 0.74 Example 46 IJ 9.45 3.02 3.13 0.25 0.61 0.48 0.71 Example 47 IK 9.15 3.18 2.88 0.24 0.60 0.42 0.68 Example 48 IL 8.59 3.55 2.42 0.22 0.58 0.44 0.72 Example 49 IM 9.01 4.02 2.24 0.24 0.60 0.45 0.51 Example 50 IN 8.78 3.58 2.45 0.23 0.59 0.51 0.55 Example 51 IO 6.54 2.55 2.56 0.14 0.50 0.33 0.18 Comparative Example 52 IP 6.88 3.98 1.73 0.15 0.51 0.35 0.25 Comparative Example 53 J 8.01 3.11 2.58 0.20 0.56 0.38 0.49 Comparative Example 54 K 8.11 3.22 2.52 0.20 0.56 0.28 0.47 Comparative Example 55 L 3.52 2.08 1.69 0.02 0.38 0.10 0.52 Comparative Example 56 M 8.04 3.34 2.41 0.20 0.56 0.12 0.44 Comparative Example 57 N 8.78 3.22 2.73 0.23 0.59 0.42 0.81 Example 58 O 8.24 3.14 2.62 0.21 0.57 0.42 0.74 Example 59 P 8.68 3.29 2.64 0.22 0.58 0.37 0.68 Example 60 Q 8.78 3.09 2.84 0.23 0.59 0.43 0.74 Example 61 R 8.88 3.05 2.91 0.23 0.59 0.39 0.73 Example 62 S 8.15 3.27 2.49 0.20 0.56 0.38 0.83 Example 63 T 8.25 3.24 2.55 0.21 0.57 0.39 0.64 Example 64 U 8.33 3.19 2.61 0.21 0.57 0.39 0.69 Example 65 V 8.35 3.18 2.63 0.21 0.57 0.42 0.84 Example 66 W 9.22 3.09 2.98 0.24 0.60 0.39 0.76 Example 67 X 9.04 3.28 2.76 0.24 0.60 0.38 0.72 Example 68 Y 9.12 3.04 3.00 0.24 0.60 0.44 0.78 Example 69 Z 8.49 3.11 2.73 0.22 0.58 0.38 0.74 Example 70 AA 8.57 3.08 2.78 0.22 0.58 0.43 0.77 Example 71 AB 8.67 3.21 2.70 0.22 0.58 0.37 0.78 Example 72 AC 8.18 3.18 2.57 0.20 0.56 0.42 0.72 Example 73 AD 8.92 3.09 2.89 0.23 0.59 0.43 0.69 Example 74 A 8.27 3.34 2.48 0.21 0.57 0.20 0.29 Example 75 A 8.19 3.56 2.30 0.20 0.56 0.19 0.28 Example Underline: outside range according to present disclosure F: polygonal ferrite, RA: retained austenite, M: martensite

TABLE 5 Sheet Steel sample thickness Sheet passage ability Sheet passage ability Surface characteristics of YP YR TS EL TS × EL λ No. ID (mm) during hot rolling during cold rolling final-annealed sheet Productivity (MPa) (%) (MPa) (%) (MPa · %) R/t (%) Remarks 1 A 2.0 Good Good Good Good 985 96.8 1018 32.2 32780 0.3 42 Example 2 B 2.1 Good Good Good Good 1102 91.5 1204 28.4 34194 0.5 35 Example 3 C 2.1 Good Good Good Good 1205 80.9 1489 20.2 30078 1.0 25 Example 4 A 2.2 Poor Poor Poor Poor 834 82.5 1011 19.8 20018 0.9 15 Comparative Example 5 A 2.2 Good Poor Poor Poor 846 83.8 1009 20.4 20584 0.9 18 Comparative Example 6 A 2.0 Good Poor Good Good 812 81.0 1002 20.8 20842 0.6 21 Comparative Example 7 A 2.1 Good Good Good Good 814 79.0 1031 19.7 20311 0.6 23 Comparative Example 8 A 2.2 Good Poor Good Good 798 79.4 1005 18.9 18995 0.6 21 Comparative Example 9 A 2.1 Good Good Good Good 985 96.8 1018 28.2 28708 1.0 29 Example 10 A 2.8 Good Good Good Good 974 95.7 1018 29.1 29624 0.7 35 Example 11 A 2.5 Good Good Good Good 856 81.4 1051 27.1 28482 0.8 35 Example 12 A 2.1 Good Good Good Good 867 84.7 1024 26.0 26624 1.0 32 Example 13 A 2.1 Good Good Good Good 920 91.1 1010 26.8 27068 1.0 35 Example 14 A 2.4 Good Good Good Good 912 89.6 1018 26.7 27181 0.8 38 Example 15 A 2.5 Good Good Good Good 950 87.9 1081 28.9 31241 0.8 41 Example 16 A 2.5 Good Good Good Good 1020 99.5 1025 27.1 27778 0.8 35 Example 17 A 2.1 Good Good Good Good 980 88.9 1102 26.1 28762 1.0 49 Example 18 A 2.3 Good Good Good Good 990 94.1 1052 28.0 29456 0.9 35 Example 19 A 2.1 Good Good Good Good 780 74.2 1051 31.5 33107 1.0 38 Example 20 A 2.1 Good Good Good Good 851 83.4 1020 26.1 26622 1.0 37 Example 21 A 2.3 Good Good Good Good 840 74.0 1135 26.1 29624 0.9 32 Example 22 A 2.5 Good Good Good Good 852 80.6 1057 26.1 27588 0.8 34 Example 23 A 2.0 Good Good Good Good 751 79.1 950 31.0 29450 1.0 36 Comparative Example 24 A 2.1 Good Good Good Good 1002 83.5 1200 19.8 23760 1.0 31 Comparative Example 25 A 1.4 Good Good Good Good 822 81.4 1010 35.1 35451 3.2 15 Comparative Example 26 A 2.0 Good Good Good Good 854 83.9 1018 18.9 19240 2.3 20 Comparative Example 27 A 2.0 Good Good Good Good 789 77.4 1019 18.4 18750 0.5 28 Comparative Example 28 A 2.0 Good Good Good Poor 814 80.1 1016 17.9 18186 0.5 30 Comparative Example 29 A 2.1 Good Good Good Good 813 77.9 1044 18.6 19418 0.5 25 Comparative Example 30 A 2.1 Good Good Poor Poor 600 58.8 1020 29.8 30396 0.9 10 Comparative Example 31 D 2.0 Good Good Good Good 1054 86.1 1224 26.9 32926 0.5 30 Example 32 E 2.0 Good Good Good Good 815 81.7 998 31.8 31736 0.4 35 Example 33 F 2.1 Good Good Good Good 812 79.8 1018 29.8 30336 0.4 42 Example 34 G 2.0 Good Good Good Good 1251 84.4 1482 21.5 31863 1.0 22 Example 35 H 2.2 Good Good Good Good 821 81.2 1011 32.5 32858 0.5 35 Example 36 I 2.2 Good Good Good Good 819 82.3 995 31.9 31741 0.5 38 Example 37 IA 2.1 Good Good Good Good 850 86.6 981 27.1 26585 1.0 35 Example 38 IB 2.1 Good Good Good Good 900 74.8 1203 22.1 26586 1.0 32 Example 39 IC 2.1 Good Good Good Good 920 90.4 1018 26.8 27282 1.0 35 Example 40 ID 2.2 Good Good Good Good 910 89.2 1020 26.7 27234 0.9 38 Example 41 IE 2.0 Good Good Good Good 750 75.8 990 35.4 35046 1.0 41 Example 42 IF 2.1 Good Good Good Good 1100 74.6 1474 18.4 27122 1.0 35 Example 43 IG 2.1 Good Good Good Good 980 89.1 1100 28.1 30910 1.0 49 Example 44 IH 2.2 Good Good Good Good 990 82.2 1204 22.4 26970 0.9 35 Example 45 II 2.1 Good Good Good Good 780 78.2 998 31.5 31437 1.0 38 Example 46 IJ 2.1 Good Good Good Good 851 83.4 1020 26.1 26622 1.0 37 Example 47 IK 2.2 Good Good Good Good 840 70.9 1185 25.4 30099 0.9 32 Example 48 IL 2.1 Good Good Good Good 852 80.6 1057 26.1 27588 1.0 34 Example 49 IM 2.0 Good Good Good Good 754 68.1 1107 27.5 30443 1.0 33 Example 50 IN 2.1 Good Good Good Good 1002 98.2 1020 26.8 27336 1.0 35 Example 51 IO 2.3 Good Good Good Good 751 84.4 890 31.0 27590 0.9 36 Comparative Example 52 IP 2.2 Good Good Good Good 1002 83.5 1200 17.5 21000 0.9 31 Comparative Example 53 J 2.0 Good Good Good Good 721 87.6 823 22.4 18435 0.4 42 Comparative Example 54 K 2.1 Good Good Poor Good 1245 71.0 1754 10.4 18242 1.4 9 Comparative Example 55 L 2.0 Good Good Good Good 624 61.3 1018 18.2 18528 1.5 15 Comparative Example 56 M 1.9 Good Good Good Good 602 60.3 998 24.9 24850 1.3 16 Comparative Example 57 N 2.0 Good Good Good Good 819 80.5 1018 32.4 32983 0.4 35 Example 58 O 2.1 Good Good Good Good 798 77.9 1024 31.5 32256 0.4 37 Example 59 P 2.1 Good Good Good Good 834 80.7 1034 30.5 31537 0.4 32 Example 60 Q 2.0 Good Good Good Good 845 85.4 989 31.8 31450 0.4 38 Example 61 R 1.9 Good Good Good Good 860 82.6 1041 31.9 33208 0.4 31 Example 62 S 1.8 Good Good Good Good 796 77.2 1031 32.9 33920 0.4 34 Example 63 T 2.0 Good Good Good Good 814 82.3 989 31.4 31055 0.4 39 Example 64 U 2.0 Good Good Good Good 816 79.0 1033 32.8 33882 0.4 34 Example 65 V 2.1 Good Good Good Good 809 79.0 1024 33.6 34406 0.4 38 Example 66 W 2.2 Good Good Good Good 1009 83.3 1212 26.8 32482 0.5 25 Example 67 X 2.1 Good Good Good Good 957 79.9 1198 27.1 32466 0.5 29 Example 68 Y 2.0 Good Good Good Good 968 79.0 1225 25.9 31728 0.5 29 Example 69 Z 1.9 Good Good Good Good 804 77.1 1043 33.5 34941 0.4 45 Example 70 AA 1.9 Good Good Good Good 825 81.0 1019 32.6 33219 0.4 40 Example 71 AB 2.0 Good Good Good Good 789 75.4 1046 31.5 32949 0.4 41 Example 72 AC 2.0 Good Good Good Good 814 81.5 999 30.8 30769 0.4 41 Example 73 AD 2.1 Good Good Good Good 829 75.9 1092 34.2 37346 0.8 38 Example 74 A 2.0 Good Good Good Good 834 84.3 989 27.2 26901 0.8 42 Example 75 A 2.1 Good Good Good Good 819 82.3 995 26.8 26666 0.7 30 Example

From above, it can be seen that the steel sheets according to the disclosure each exhibited TS of 980 MPa or more and YR of 68% or more, and are thus considered as high-strength steel sheets having excellent formability and high yield ratio and hole expansion formability. In contrast, the comparative examples are inferior in terms of at least one of YR, TS, EL, λ, and R/t. Moreover, each steel sheet containing ε phase at an area ratio of 2% or more achieved a still better balance between strength and ductility.

INDUSTRIAL APPLICABILITY

According to the disclosure, it becomes possible to manufacture high-strength steel sheets with excellent formability and high yield ratio and hole expansion formability that exhibit TS of 980 MPa or more and YR of 68% or more and that satisfy the condition of TS*EL≥22,000 MPa %. Steel sheets according to the disclosure are highly beneficial in industrial terms, because they can improve fuel efficiency when applied to, for example, automobile structural parts, by a reduction in the weight of automotive bodies.

Claims

1-7. (canceled)

8. A steel sheet comprising:

a chemical composition containing, in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities; and
a steel microstructure that contains, in area ratio, 5% or more and 50% or less of polygonal ferrite, 10% or more of non-recrystallized ferrite, and 15% or more and 30% or less of martensite, and that contains, in volume fraction, 12% or more of retained austenite, where an average aspect ratio of crystal grains of each of the polygonal ferrite, the martensite, and the retained austenite is 2.0 or more and 20.0 or less,
wherein the polygonal ferrite has an average grain size of 4 μm or less, the martensite has an average grain size of 2 μm or less, the retained austenite has an average grain size of 2 μm or less, and a value obtained by dividing a Mn content in the retained austenite in mass % by a Mn content in the polygonal ferrite in mass % equals 2.0 or more.

9. The steel sheet according to claim 8, wherein the steel microstructure further contains, in area ratio, 2% or more of ε phase with an hcp structure.

10. The steel sheet according to claim 8, wherein the retained austenite has a C content that satisfies the following formula in relation to the Mn content in the retained austenite:

0.04*[Mn]+0.056−0.180≤[C]≤0.04*[Mn]+0.056+0.180
where [C] is the C content in the retained austenite in mass %, and [Mn] is the Mn content in the retained austenite in mass %.

11. The steel sheet according to claim 9, wherein the retained austenite has a C content that satisfies the following formula in relation to the Mn content in the retained austenite:

0.04*[Mn]+0.056−0.180≤[C]≤0.04*[Mn]+0.056+0.180
where [C] is the C content in the retained austenite in mass %, and [Mn] is the Mn content in the retained austenite in mass %.

12. A coated steel sheet comprising:

the steel sheet according to claim 8; and
one selected from a hot-dip galvanized layer, a galvannealed layer, a hot-dip aluminum-coated layer, and an electrogalvanized layer provided on the steel sheet.

13. A coated steel sheet comprising:

the steel sheet according to claim 9; and
one selected from a hot-dip galvanized layer, a galvannealed layer, a hot-dip aluminum-coated layer, and an electrogalvanized layer provided on the steel sheet.

14. A coated steel sheet comprising:

the steel sheet according to claim 10; and
one selected from a hot-dip galvanized layer, a galvannealed layer, a hot-dip aluminum-coated layer, and an electrogalvanized layer provided on the steel sheet.

15. A coated steel sheet comprising:

the steel sheet according to claim 11; and
one selected from a hot-dip galvanized layer, a galvannealed layer, a hot-dip aluminum-coated layer, and an electrogalvanized layer provided on the steel sheet.

16. A method for manufacturing the steel sheet according to claim 8, the method comprising:

(i) heating a steel slab having a chemical composition containing, in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet.

17. A method for manufacturing the steel sheet according to claim 9, the method comprising:

(i) heating a steel slab having a chemical composition containing, in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet.

18. A method for manufacturing the steel sheet according to claim 10, the method comprising: a chemical composition containing, in mass %,

(i) heating a steel slab having
C: 0.030% or more and 0.250% or less,
Si: 0.01% or more and 3.00% or less,
Mn: more than 4.20% and 6.00% or less,
P: 0.001% or more and 0.100% or less,
S: 0.0200% or less,
N: 0.0100% or less, and
Ti: 0.005% or more and 0.200% or less, and
optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less,
with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet.

19. A method for manufacturing the steel sheet according to claim 11, the method comprising: a chemical composition containing, in mass %,

(i) heating a steel slab having
C: 0.030% or more and 0.250% or less,
Si: 0.01% or more and 3.00% or less,
Mn: more than 4.20% and 6.00% or less,
P: 0.001% or more and 0.100% or less,
S: 0.0200% or less,
N: 0.0100% or less, and
Ti: 0.005% or more and 0.200% or less, and
optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less,
with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet.

20. The method according to claim 16, wherein a value obtained by dividing a volume fraction of the retained austenite after performing tensile working with an elongation value of 10% by a volume fraction of the retained austenite before the tensile working equals 0.3 or more.

21. The method according to claim 17, wherein a value obtained by dividing a volume fraction of the retained austenite after performing tensile working with an elongation value of 10% by a volume fraction of the retained austenite before the tensile working equals 0.3 or more.

22. The method according to claim 18, wherein a value obtained by dividing a volume fraction of the retained austenite after performing tensile working with an elongation value of 10% by a volume fraction of the retained austenite before the tensile working equals 0.3 or more.

23. The method according to claim 19, wherein a value obtained by dividing a volume fraction of the retained austenite after performing tensile working with an elongation value of 10% by a volume fraction of the retained austenite before the tensile working equals 0.3 or more.

24. A method for manufacturing the coated steel sheet according to claim 12, comprising:

(i) heating a steel slab having a chemical composition containing, in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet: and
(viii) thereafter, either subjecting the steel sheet after cooling to one selected from hot-dip galvanizing treatment, hot-dip aluminum coating treatment, and electrogalvanizing treatment, or subjecting the steel sheet after cooling to hot-dip galvanizing treatment and then to alloying treatment at 450° C. or higher and 600° C. or lower.

25. A method for manufacturing the coated steel sheet according to claim 13, comprising;

(i) heating a steel slab having a chemical composition containing, in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet: and
(viii) thereafter, either subjecting the steel sheet after cooling to one selected from hot-dip galvanizing treatment, hot-dip aluminum coating treatment, and electrogalvanizing treatment, or subjecting the steel sheet after cooling to hot-dip galvanizing treatment and then to alloying treatment at 450° C. or higher and 600° C. or lower.

26. A method for manufacturing the coated steel sheet according to claim 14, comprising:

(i) heating a steel slab having a chemical composition containing, in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet: and
(viii) thereafter, either subjecting the steel sheet after cooling to one selected from hot-dip galvanizing treatment, hot-dip aluminum coating treatment, and electrogalvanizing treatment, or subjecting the steel sheet after cooling to hot-dip galvanizing treatment and then to alloying treatment at 450° C. or higher and 600° C. or lower.

27. A method for manufacturing the coated steel sheet according to claim 15, comprising:

(i) heating a steel slab having a chemical composition containing, in mass %, C: 0.030% or more and 0.250% or less, Si: 0.01% or more and 3.00% or less, Mn: more than 4.20% and 6.00% or less, P: 0.001% or more and 0.100% or less, S: 0.0200% or less, N: 0.0100% or less, and Ti: 0.005% or more and 0.200% or less, and optionally further containing, in mass %, at least one selected from the group consisting of Al: 0.01% or more and 2.00% or less, Nb: 0.005% or more and 0.200% or less, B: 0.0003% or more and 0.0050% or less, Ni: 0.005% or more and 1.000% or less, Cr: 0.005% or more and 1.000% or less, V: 0.005% or more and 0.500% or less, Mo: 0.005% or more and 1.000% or less, Cu: 0.005% or more and 1.000% or less, Sn: 0.002% or more and 0.200% or less, Sb: 0.002% or more and 0.200% or less, Ta: 0.001% or more and 0.010% or less, Ca: 0.0005% or more and 0.0050% or less, Mg: 0.0005% or more and 0.0050% or less, and REM: 0.0005% or more and 0.0050% or less, with the balance consisting of Fe and inevitable impurities;
(ii) hot rolling the steel slab with a finisher delivery temperature of 750° C. or higher and 1000° C. or lower to obtain a steel sheet;
(iii) coiling the steel sheet;
(iv) then subjecting the steel sheet to pickling to remove scales;
(v) retaining the steel sheet in a temperature range of Ac1 [transformation temperature+20° C.] to [Ac1 transformation temperature+120° C.] for 600 s to 21,600 s;
(vi) optionally cold rolling the steel sheet at a rolling reduction of less than 30%; and
(vii) then retaining the steel sheet in a temperature range of [Ac1 transformation temperature+10° C.] to [Ac1 transformation temperature+100° C.] for 20 s to 900 s and subsequently cooling the steel sheet: and
(viii) thereafter, either subjecting the steel sheet after cooling to one selected from hot-dip galvanizing treatment, hot-dip aluminum coating treatment, and electrogalvanizing treatment, or subjecting the steel sheet after cooling to hot-dip galvanizing treatment and then to alloying treatment at 450° C. or higher and 600° C. or lower.
Patent History
Publication number: 20190106760
Type: Application
Filed: Mar 8, 2017
Publication Date: Apr 11, 2019
Applicant: JFE STEEL CORPORATION (Chiyoda-ku Tokyo)
Inventors: Takako YAMASHITA (Chiyoda-ku, Tokyo), Yoshiyasu KAWASAKI (Chiyoda-ku, Tokyo), Takashi KOBAYASHI (Chiyoda-ku, Tokyo), Masayasu UENO (Chiyoda-ku, Tokyo), Yasunobu NAGATAKI (Chiyoda-ku, Tokyo)
Application Number: 16/090,892
Classifications
International Classification: C21D 8/02 (20060101); C22C 38/02 (20060101); C22C 38/04 (20060101); C22C 38/00 (20060101); C22C 38/14 (20060101); C23C 2/02 (20060101); C23C 2/12 (20060101); C23C 2/06 (20060101); C23C 2/40 (20060101); C21D 9/46 (20060101);