Cationic compositions containing hydroxyester
Disclosed are aqueous compositions containing a cationic compound and a hydroxy ester of the formula (1)R.sup.A --C(O)O--R.sup.C --(O--C(O)R.sup.E).sub.0-1 (1)wherein R.sup.A is C.sub.1 -C.sub.15 alkyl with 0-3 hydroxyl substituents, R.sup.C is C.sub.1 -C.sub.10 alkyl with 0-3 hydroxyl substituents, and R.sup.E is C.sub.1 -C.sub.15 alkyl with 0-1 hydroxyl substituents, wherein the compounds of formula (1) contain 7 to 16 carbon atoms and a total of 1-3 hydroxyl substituents.
Claims
1. A homogeneous liquid cationic composition comprising:
- (a) a coupling agent selected from the group consisting of compounds of the formula (1)
- and mixtures thereof,
- wherein R.sup.A is saturated, straight, branched or cyclic alkyl containing 1 to 14 carbon atoms, and R.sup.A is optionally substituted with 1 to 3 hydroxyl groups; and wherein R.sup.C is a residue of 2,2,4-trimethyl-1,3-pentanediol and R.sup.C can optionally be substituted with a group of the structure OC(O)R.sup.E wherein R.sup.E is straight, cyclic or branched alkyl containing 1 to 14 carbon atoms which is optionally substituted with a hydroxyl group, wherein the compounds of formula (1) contain 7 to 16 carbon atoms and are substituted with a total of 1 to 3 hydroxyl groups; and
- (b) 5-90 wt. % of one or more quaternary ammonium cationic agents.
2. A homogeneous liquid cationic composition comprising 2,2,4-trimethyl-1,3-pentanediol isobutyrate monoester or diester and 5-90 wt. % of one or more quaternary ammonium cationic agents.
3. A homogeneous liquid cationic composition comprising hydroxypivalyl hydroxypivalate and 5-90 wt. % of one or more quaternary ammonium cationic agents.
4. A homogeneous liquid cationic composition comprising:
- (a) a coupling agent selected from the group consisting of compounds of the formula (1)
- wherein R.sup.A is saturated, straight, branched or cyclic alkyl containing 1 to 14 carbon atoms, and R.sup.A is optionally substituted with 1 to 3 hydroxyl groups; and wherein R.sup.C is a residue of 2,2,4-trimethyl-1,3-pentane diol and R.sup.C can optionally be substituted with a group of the structure OC(O)R.sup.E wherein R.sup.E is straight, cyclic or branched alkyl containing 1 to 14 carbon atoms which is optionally substituted with a hydroxyl group, wherein the compounds of formula (1) contain 7 to 16 carbon atoms and are substituted with a total of 1 to 3 hydroxyl groups;
- (b) a compound of the formula (2)
- wherein R.sup.T is saturated, straight, branched or cyclic alkylene containing 4 to 12 carbon atoms, and each X is ethylene, straight or branched propylene, or straight or branched butylene;
- x is 0 to 40;
- each Y is ethylene, straight or branched propylene, or straight or branched
- y is 0 to 40; wherein the sum of (x+y) is 1 to 10; and
- (c) 5-90 wt. % of one or more quaternary ammonium cationic agents.
5. The composition in accordance with claim 4, wherein at least one of component (a) includes 2,2,4-trimethyl-1,3-pentane diol and component (b) includes 2-ethylhexyl-1,3diol.
6. The composition in accordance with claim 4 wherein component (b) contains at least one compound of the formula (2) wherein R.sup.T is the residue of 2,2,4-trimethyl-1,3-pentanediol.
2679482 | May 1954 | Ross |
2956025 | October 1960 | Lew |
2997447 | August 1961 | Russell et al. |
3463735 | August 1969 | Stonebraker et al. |
3666668 | May 1972 | Klausner |
3705113 | December 1972 | Sharman |
3766062 | October 1973 | Wixon |
3770643 | November 1973 | Heiba et al. |
3819522 | June 1974 | Zmoda et al. |
3928212 | December 1975 | Goto et al. |
4140641 | February 20, 1979 | Ramachandran |
4414128 | November 8, 1983 | Goffinet |
4454049 | June 12, 1984 | MacGilp et al. |
4692277 | September 8, 1987 | Siklosi |
4917955 | April 17, 1990 | Porter, Jr. et al. |
5185088 | February 9, 1993 | Hartman et al. |
5202050 | April 13, 1993 | Culshaw et al. |
5358647 | October 25, 1994 | Puentes-Bravo et al. |
5399272 | March 21, 1995 | Swartley et al. |
5427697 | June 27, 1995 | Swartley |
5496492 | March 5, 1996 | Hamada et al. |
5507971 | April 16, 1996 | Ouzounis et al. |
240727 A2 | October 1987 | EPX |
03255021 | November 1991 | JPX |
5262638 A | October 1993 | JPX |
WO92/08442 | May 1992 | WOX |
WO93/12774 | July 1993 | WOX |
- I. Ikeda, X. P. Gu, I. Miyamoto, M. Okahara, Journal of American Oil Chemistry Society 1989, vol. 66, 822-824, Jun. 1989. S. N. Zlatanos, A. N. Sagredos, V. P. Papageorgiou, Journal of American Oil Chemistry Society 1985, vol. 62, 1575-1577, Nov. 1985. Egan, "Cationic Surface Active Agents as Fabric Softeners", J. Am. Oil. Chemists'Soc., 55:118-121 (Jan. 1978). "Technical Bulletin Shell Chemical Company", SC:1306-91 Selected pages, Product Bulletin, DOWANOL Glycol Ethers Dow Chemical Company. Product Bulletin, PETRO products, pp. 1-9. Walley, "Fabric Conditioning Agents," Happi, pp. 55-58 (Feb. 1995).
Type: Grant
Filed: Apr 26, 1996
Date of Patent: Oct 20, 1998
Inventor: Robert O. Keys (Columbus, OH)
Primary Examiner: Paul Lieberman
Assistant Examiner: John R. Hardee
Attorneys: Edward K. Welch, II, Andrew S. Reiskind, Timothy X. Witkowski
Application Number: 8/638,530
International Classification: C11D 726; C11D 140;