Light stable aliphatic thermoplastic urethane elastomers and method of making same

Abstract

An improved light stable polyether/polyol based aliphatic urethane thermoplastic elastomer prepared from reacting inter alia a polyol having low terminal end unsaturation and an organic diisocyanate. The elastomer is characterized by ultraviolet stabilizer being present in a range of 0.25% to 2.0% at a total concentration of 1.0% to 2.0%, an antioxidant being present at a total concentration of 0.10% to 1.0%, and colorants/pigment being present in a total concentration in a range from 1.0% to 2.05% to produce an elastomer capable of withstanding Xenon arc artificial weathering with DE.ltoreq.3.00 after 2450 kilojoules of exposure.

Claims

1. An improved light stable polyether/polyol based aliphatic thermoplastic urethane elastomer, said elastomer comprising the product of:

(a) a polyol;

(b) a chain extender;

(c) an organic diisocyanate;

(d) a first hindered amine light stabilizer and a second benzotriazole ultraviolet stabilizing agent;

(e) an antioxidant;

(f) at least one pigment;

(g) a urethane catalyst; and characterized by said first and second ultraviolet stabilizing agents being present in a ratio in a range of approximately 1:1 to 2:1 at a concentration in a range of approximately 0.25% to 2.0% of entire product composition, said antioxidant being present at a total concentration in a range of approximately 0.10% to 1.0% of entire product composition and said pigment being present at a total concentration in a range of approximately 1.0% to 2.0%, whereby said elastomer is light stable following exposure to a Xenon arc artificial weathering with a DE.ltoreq.3.00 after 2450 kilojoules of output.

2. The elastomer of claim 1 wherein said ratio of ultraviolet stabilizing agents is 2:1.

3. The elastomer of claim 1 wherein the concentration of said ultraviolet stabilizing agents is 2.0%.

4. The elastomer of claim 1 wherein the concentration of said antioxidant is approximately 0.25% to 0.75%.

5. The elastomer of claim 1 wherein the concentration of said pigmenting agent is approximately 1.0% to 1.94%.

6. The elastomer of claim 1 wherein said polyol has end group unsaturation of less than 0.04 meq/g.

7. The elastomer of claim 1 wherein said chain extender is selected from the group consisting of 1,4-butanediol, ethylene glycol, diethylene glycol, propylene glycol, pentane diol, 3-methylpentane-1,5-diol, hexane diol, HQEE (hydroquinone bis(2-hydroxyethyl) ether), CHDM (1,4-cyclohexanedimethanol), and HBPA (hydrogenated bisphenol A).

8. The elastomer of claim 1 wherein said organic diisocyanate is selected from the group consisting of (TMXDI) meta-tetramethylxylene diisocyanate, paratetramethylxylene diisocyanate, isophorone diisocyanate (IPDI), dibenzyl diisocyanate, xylene diisocyanate (XDI), 3, 3'-bis toluene-4,4-diisocyanate, hexamethylene diisocyanate (HDI), hydrogenated MDI, hydrogenated XDI, cyclohexane diisocyanate, paraphenylene diisocyanate, mixtures and derivatives thereof.

9. The elastomer of claim 1 wherein said hindered amine light stabilizer is bis(1,2,2,6,6-pentamethyl-1-4-piperidinyl) sebacate.

10. The elastomer of claim 1 wherein said second ultraviolet stabilizing agent is a hydroxyphenyl benzotriazole.

11. The elastomer of claim 10 wherein said ydroxyphenyl benzotriazole is a benzotriazole mixture of poly(oxy-1,2-ethanediyl), alpha-(3-(3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl)- 1-oxopropyl)-omega-hydroxy- and poly(oxy-1,2-ethanediyl), alpha-(3-(3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl)- 1-oxopropyl)-omega-(3-((2H-benzotriazol-2-yl)-5-(1,1,-dimethylethyl)-4-hydr oxyphenyl)-1-oxopropoxy)-, Chemical Asbstract Number 104810-47-1 and polyethylene glycol with a molecular weight of 300 Chemical Abstract Number 25322-68-3.

12. The elastomer of claim 1 wherein said pigment is selected from the group consisting of carbon black, titanium dioxide, Chomophthal Red BPP, Phthalocyanine Blue Red Shade, Yellow Iron Oxide, and Quinacridone Violet.

13. The elastomer of claim 1 wherein said antioxidant is selected from the group consisting of (tetrakis (methylene(3,5-di-tert-butyl-4-hydroxycinnamate)) methane, (Octodecyl 3,5 di-tert-butyl-4-hydroxyhydrocinnamate), (Ethylenebis (oxyethylene) bis-(3-tert-butyl-4-hydroxy-5-methylhydrocinnamate)), and Vanox 830 (from R. T. Vanderbilt) a blend of phenolic compound, alkylated diphenylamines and trialkyl phosphite.

14. A light stable automotive trim component, said component comprising the product of:

(a) a polyol;

(b) a chain extender;

(c) an organic diisocyanate;

(d) a first hindered amine light stabilizer and a second benzotriazole ultraviolet stabilizing agent;

(e) an antioxidant;

(f) at least one pigment;

(g) a urethane catalyst; and characterized by said first and second ultraviolet stabilizing agents being present in a ratio in a range of approximately 1:1 to 2:1 at a concentration in a range of aproximately 0.25% to 2.0% of entire product composition, said antioxidant being present at a total concentration in a range of approximately 0.10% to 1.0% of entire product composition, and said pigment being present at a total concentration in a range of approximately 1.0% to 2.0% of entire product composition, whereby said elastomer is light stable following exposure to Xenon arc artificial weathering with a DE.ltoreq.3.00 after 2450 kilojoules of output.

15. The automotive trim component of claim 14 wherein said ratio of ultraviolet stabilizing agents is 2:1.

16. The automotive trim component of claim 14 wherein the concentration of said ultra violet stabilizing agents is 2.0%.

17. The automotive trim component of claim 14 wherein the concentration of said antioxidant is approximately 0.25% to 0.75% of entire product composition.

18. The automotive trim component of claim 14 wherein the concentration of said pigmenting agent is approximately 1.0% to 1.94% of entire product composition.

19. The automotive trim component of claim 14 said chain extender is selected from the group consisting of 1,4-butanediol, ethylene glycol, diethylene glycol, propylene glycol, pentane diol, 3-methylpentane-1,5-diol, hexane diol, HQEE (hydroquinone bis(2-hydroxyethyl) ether), CHDM (1,4-cyclohexanedimethanol), or HBPA (hydrogenated bisphenol A).

20. The automotive trim component of claim 14 wherein said organic diisocyanate is selected from the group consisting of (TMXDI) meta-tetramethylxylene diisocyanate, paratetramethylxylene diisocyanate, isophorone diisocyanate (IPDI), dibenzyl diisocyanate, xylene diisocyanate (XDI), 3, 3'-bis toluene-4,4-diisocyanate, hexamethylene diisocyanate (HDI), hydrogenated MDI, hydrogenated XDI, cyclohexane diisocyanate, paraphenylene diisocyanate, mixtures and derivatives thereof.

21. The automotive trim component of claim 14 wherein said hindered amine light stabilizer is bis(1,2,2,6,6-pentamethyl-1-4-piperidinyl) sebacate.

22. The automotive trim component of claim 14 wherein said at least one ultraviolet stabilizing agent is a hydroxyphenyl benzotriazole.

23. The automotive trim component of claim 22 wherein said hydroxyphenyl benzotriazole is a benzotriazole mixture of poly(oxy-1,2-ethanediyl), alpha-(3-(3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl)- 1-oxopropyl)-omega-hydroxy- and poly(oxy-1,2-ethanediyl), alpha-(3-(3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl)- 1-oxopropyl)-omega-(3-((2H-benzotriazol-2-yl)-5-(1,1,-dimethylethyl)-4-hydr oxyphenyl)-1-oxopropoxy)-, Chemical Asbstract Number 104810-47-1 and polyethylene glycol with a molecular weight of 300 Chemical Abstract Number 25322-68-3.

24. The automotive trim component of claim 14 wherein said pigment is selected from the group consisting of carbon black, titanium dioxide, Chomophthal Red BPP, Phthalocyanine Blue Red Shade, Yellow Iron Oxide, and Quinacridone Violet.

25. The automotive trim component of claim 14, wherein said polyol has end group unsaturation less than 0.04 meq/g.

26. The automotive trim component of claim 14 wherein said antioxidant is selected from the group consisting of (tetrakis (methylene(3,5-di-tert-butyl-4-hydroxycinnamate)) methane, (Octodecyl 3,5 di-tert-butyl-4-hydroxyhydrocinnamate), (Ethylenebis (oxyethylene) bis-(3-tert-butyl-4-hydroxy-5-methylhydrocinnamate)), and Vanox 830 (from R. T. Vanderbilt) a blend of phenolic compound, alkylated diphenylamines and trialkyl phosphite.