Ion conductive material and electrochemical device comprising the same
An ion conductive material containing a compound which comprises a resonance structure group which contains an atom of the Vb group in the Periodic Table serving as an anionic site and is bonded to an electron attractive organic group through an atom of the VIb group in the Periodic Table, and a counter ion selected from the group consisting of metal ions and a hydrogen ion. This material is useful as an electrolyte of a cell since it is excellent in high voltage stability.
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Claims
1. An ion conductive material containing a compound which comprises:
- (A) a resonance structure group which contains
- (i) an atom of the Vb group in the Periodic Table serving as an anionic site, and
- (ii) at least one stabilizing group bonded to (i), wherein said stabilizing group stabilizes (i);
- (B) an atom of the VIb group in the Periodic Table;
- (C) an electron attractive organic group; and
- (D) a counter ion selected from the group consisting of metal ions and a hydrogen ion, wherein said resonance structure group (A) is bonded to said electron attractive organic group (C) through said atom of the VIb group in the Periodic Table (B).
2. The ion conductive material according to claim 1, wherein said counter ion (D) is a metal ion, said atom of the Vb group in the Periodic Table (A)(i) is a nitrogen atom, and said electron attractive organic group (C) contains an unhalogenated carbon atom to which said atom of the VIb group in the Periodic Table (B) is bonded.
3. The ion conductive material according to claim 2, wherein said atom of the VIb group in the Periodic Table (B) is an oxygen atom.
4. The ion conductive material according to claim 1, wherein said compound is a compound of the formula (1):
- M represents said counter ion (D) and is a metal atom,
- n is a valency of the metal M,
- X represents said atom of the Vb group in the Periodic Table (A)(i) and is a nitrogen atom,
- Y represents said stabilizing group (A)(ii) and is a SO.sub.2 group or a CO group,
- O is an oxygen atom and represents said atom of the VIb group in the Periodic Table (B), and
- Rf represents said electron attractive organic group (C) which comprises a fluorine atom and an unhalogenated carbon atom, wherein said unhalogenated carbon atom in bonded to said oxygen atom which represents said atom of the VIb group in the Periodic Table (B).
5. The ion conductive material according to claim 1, which is an electrolytic solution.
6. The ion conductive material according to claim 1, wherein said electron attractive organic group is a branched halogenated alkyl group.
7. The ion conductive material according to claim 1, which is dissolved in an ester.
8. The ion conductive material according to claim 1, which is composited with a carrier selected from the group consisting of insulating inorganic compounds, polyethylene oxide, polypropylene oxide, polymethyl methacrylate and their derivatives.
9. An electrochemical device comprising an electrode and an ion conductive material containing a compound functioning as an electrolyte which comprises:
- (A) a resonance structure group which contains
- (i) an atom of the Vb group in the Periodic Table serving as an anionic site, and
- (ii) at least one stabilizing group bonded to (i), wherein said stabilizing group stabilizes (i);
- (B) an atom of the VIb group in the Periodic Table;
- (C) an electron attractive organic group; and
- (D) a counter ion selected from the group consisting of metal ions and a hydrogen ion, wherein said resonance structure group (A) is bonded to said electron attractive organic group (C) through said atom of the VIb group in the Periodic Table (B).
10. The electrochemical device according to claim 9, wherein said counter ion (D) is a metal ion, said atom of the Vb group in the Periodic Table (A)(i) is a nitrogen atom, and said electron attractive organic group (C) contains an unhalogenated carbon atom to which said atom of the VIb group in the Periodic Table (B) is bonded.
11. The electrochemical device according to claim 10, wherein said atom of the VIb group in the Periodic Table (B) is an oxygen atom.
12. The electrochemical device according to claim 9, wherein said compound is a compound of the formula (I):
- M represents said counter ion (D) and is a metal atom,
- n is a valency of the metal M,
- X represents said atom of the Vb group in the Periodic Table (A)(i) and is a nitrogen atom,
- Y represents said stabilizing group (A)(ii) and is a SO.sub.2 group or a CO group,
- O is an oxygen atom and represents said atom the VIb group in the Periodic Table (B), and
- Rf represents said electron attractive organic group (C) which comprises a fluorine atom and an unhalogenated carbon atom, wherein said unhalogenated carbon atom in bonded to said oxygen atom which represents said atom of the VIb group in the Periodic Table (B).
13. The electrochemical device according to claim 9, which is a device selected from the group consisting of a secondary cell, an electrolytic system and an electrochemical sensor.
14. The electrochemical device according to claim 9, wherein said electron attractive organic group is a branched halogenated alkyl group.
15. The electrochemical device according to claim 9, which comprises a positive electrode material having a voltage of at least 4.2 V in relation to Li when it is charged.
16. The electrochem ical device according to claim 5, which comprises a positive electrode collector made of aluminum.
| 5260145 | November 9, 1993 | Armand et al. |
| 5352547 | October 4, 1994 | Kita et al. |
| 5437944 | August 1, 1995 | Kita et al. |
| 5514493 | May 7, 1996 | Waddell et al. |
| 5527644 | June 18, 1996 | Kita et al. |
- Jin Nie, "Polyfluorinated Weakly Coordinating Organic Anions," Mar. 1, 1995, Kyushu University, pp. 134-142.
Type: Grant
Filed: Feb 29, 1996
Date of Patent: May 11, 1999
Assignee: Hitachi Maxell, Ltd. (Osaka-fu)
Inventors: Jin Nie (Kasuga), Fusaji Kita (Otokuni-gun), Koji Murakami (Ibaraki), Akira Kawakami (Takatsuki), Hiroshi Kobayashi (Chikushino), Takaaki Sonoda (Fukuoka)
Primary Examiner: Kathryn Gorgos
Assistant Examiner: Thomas H. Parsons
Law Firm: Birch, Stewart, Kolasch & Birch, LLP
Application Number: 8/609,915
International Classification: H01M6/14;
