Abstract: Disclosed herein are compositions, methods, and devices related to bilayer and monolayer membranes, their encapsulation in a hydrogel, and their formation. Methods of using the disclosed compositions and devices are also disclosed.

Abstract: A method for making a metal-hydride slurry includes adding metal to a liquid carrier to create a metal slurry and hydriding the metal in the metal slurry to create a metal-hydride slurry. In some embodiments, a metal hydride is added to the liquid carrier of the metal slurry prior to hydriding the metal. The metal can be magnesium and the metal hydride can be magnesium hydride.

Abstract: An ozone generation system comprises an electricity charge unit price storing part which stores an electricity charge unit and a gas charge unit price storing part which stores a gas charge unit price, based on the electricity charge unit price, the gas charge unit price and necessary generation amount of ozone which is required for an ozonized gas, regarding an ozone concentration and a gas flow rate which are ozone generation amount basic parameters, values at which a running cost is a minimum are determined, a gas flow rate controller is controlled so as for a gas flow rate to be the determined gas flow rate and power of a power supply for an ozone generator is controlled so as for an ozone concentration to be the determined ozone concentration.

Abstract: By reacting a fluorine-containing sulfonylimide ammonium salt such as ammonium N,N-di(fluorosulfonyl)imide with an alkali metal hydroxide such as lithium hydroxide, potassium hydroxide or sodium hydroxide under reduced pressure and at a low temperature of approximately 40° C., a fluorine-containing sulfonylimide alkali metal salt such as lithium N,N-di(fluorosulfonyl)imide, potassium N,N-di(fluorosulfonyl)imide or sodium N,N-di(fluorosulfonyl)imide is obtained.

Abstract: Disclosed is a nano-scaled graphene article comprising a non-woven aggregate of nano-scaled graphene platelets wherein each of the platelets comprises a graphene sheet or multiple graphene sheets and the platelets have a thickness no greater than 100 nm (preferably smaller than 10 nm) and platelets contact other platelets to define a plurality of conductive pathways along the article. The article has an exceptional thermal conductivity (typically greater than 500 Wm?1K?1) and excellent electrical conductivity (typically greater than 1,000 S/cm). Thin-film articles of the present invention can be used for thermal management in micro-electronic devices and for current-dissipating on an aircraft skin against lightning strikes.

Abstract: The present invention relates to the method for manufacturing high quality graphene by heating carbon-based self-assembly monolayers, comprising the steps of: forming carbon source layers which are convertible into the graphene layer on the substrate; forming a metal catalyst layer on the carbon source layer; converting the carbon source layers into the graphene layer by heating the first part of the substrate using a local heating source, wherein the carbon source layers and the metal catalyst layers are formed; converting the carbon source layers into graphene by moving the local heating source and then heating the second part which is different from the first part; and removing the metal catalyst layer. The present invention also provides a substrate comprising a graphene layer manufactured by the above method and provides applications in semiconductor devices and electronic materials using the substrate.

Abstract: A highly dispersed graphene organic dispersion and an application thereof are provided. A mixture is firstly provided, which includes a graphite material and an organic solvent. And then, the mixture is subjected to a peeling process at high temperature and high pressure, thereby obtaining the highly dispersed graphene organic dispersion. The highly dispersed graphene organic dispersion contains 75% or more of a single-layered graphene.

Abstract: A method for producing silica particles, includes preparing a silica particle dispersion containing silica particles, and a solvent containing an alcohol and water, and bringing supercritical carbon dioxide into contact with the silica particle dispersion to remove the solvent.

Abstract: A method of fabricating a metal oxide sheet having a polycrystalline structure includes mixing a metal precursor material, a base material, and distilled water with each other to fabricate a preparation solution; adding an anionic surfactant into the preparation solution to forming a precursor solution; forming metal oxide nanoparticles in the precursor solution, wherein each of the metal oxide nanoparticles comprises a metal cation and an oxygen anion; and fabricating a metal oxide sheet by coupling the metal oxide nanoparticles to each other, wherein, in an aspect of a plane, the metal oxide sheet has a hexagonal shape and a polycrystalline structure.

Abstract: The present invention relates to an apparatus and method for the treatment of water and, in particular, an apparatus and method which may be applied to fluids such as grey water to be treated prior to discharge. The invention is intended for particular use on marine vessels such as house boats to treat grey water which at present is discharged untreated.

Abstract: A process for removing Hg2+ ions from a liquid stream is disclosed. The process involves contacting the liquid stream with specified UOP Zeolitic Materials. These molecular sieves are particularly effective in removing Hg2+ ions from aqueous streams even in the presence of Mg2+ and Ca2+ ions. The effective molecular sieves have an intermediate range of Si/Al ratios between about 2 and 20 and preferably between 3 and 10.

Abstract: A sterilization device includes a housing having a flow passage R of a fluid that is to be sterilized; and an LED element being disposed in the housing to irradiate ultraviolet light into the flow passage R, wherein an inner wall surface of the flow passage has a pair of reflection surfaces (a first reflection surface and a second reflection surface) which directs the ultraviolet light irradiated from the LED element from one side of the flow passage R to another side thereof while reflecting the ultraviolet light a plurality of times; and a return surface that includes a surface that is perpendicular to an optical axis of the light which has been reflected a plurality of times from one side to the other side, and returns the light toward its original direction is formed on a side of the first reflection surface.

Abstract: A system and method for treatment of a contaminated liquid is described. The system includes a high voltage supply device, a general capacitor bank, one or more general limiting member, such as general switch devices or general resister devices, coupled to the high voltage supply device and to the general capacitor bank. The system further includes one or more working capacitor banks coupled to the general capacitor bank through the general limiting member, and one or more working switches arranged in series with the corresponding working capacitor bank. The system also includes one or more potential electrodes and grounded electrodes immersed in the contaminated liquid and coupled to the working capacitor banks for providing an electric discharge through the contaminated liquid.

Abstract: The present invention provides a system for solvent extraction utilizing a first electrode with a raised area formed on its surface, which defines a portion of a microfluidic channel; a second electrode with a flat surface, defining another portion of the microfluidic channel that opposes the raised area of the first electrode; a reversibly deformable substrate disposed between the first electrode and second electrode, adapted to accommodate the raised area of the first electrode and having a portion that extends beyond the raised area of the first electrode, that portion defining the remaining portions of the microfluidic channel; and an electrolyte of at least two immiscible liquids that flows through the microfluidic channel. Also provided is a system for performing multiple solvent extractions utilizing several microfluidic chips or unit operations connected in series.

Abstract: A supercapacitor has a first electrode, a second electrode, a first ionic carrier configured to contact the first electrode to provide a first ion-conductive pathway for transportation of ions to and from the first electrode, and a first retaining layer configured to retain the first ionic carrier between the first electrode and the first retaining layer. The supercapacitor also has an electrolyte dispersed between the first and the second electrodes to provide the ions, a first current collector configured to contact the first electrode and a second current collector configured to contact the second electrode. A method for making the supercapacitor is also presented.

Abstract: A water-in-oil emulsion is a product form having many practical advantages. A vinylamine-based macromolecule having specific effects as papermaking chemicals and a flocculant is provided in the form of a water-in-oil emulsion having good storage stability and high performance as a flocculation treatment agent. Disclosed is a flocculation treatment agent including a water-in-oil emulsion of a water-soluble macromolecule that is produced by subjecting a water-in-oil emulsion of an aqueous poly-N-vinylcarboxylic acid amide solution coexisting with a polyoxyalkylene alkyl ether to hydrolysis in the presence of an acid or a base. Preferably, the polyoxyalkylene alkyl ether is added before the hydrolysis reaction.

Abstract: A method for cleaning an oil spill in a marine environment includes forming a particle-stabilized emulsion containing seawater, carbon black and at least one oil spill component and allowing the at least one oil spill component to degrade, thereby removing said component from the marine environment. Carbon black can be added to an oil-seawater mixture to form a stabilized emulsion containing at least one oil spill component and the oil spill component allowed to degrade, thereby removing the at least one oil spill component from the oil spill. Also disclosed is an emulsion that includes one or more oil spill components, seawater and carbon black particles.

Abstract: This disclosure relates generally to methods and rare earth-containing additives for removing target materials in the form of hydroxides, carbonates, hydrates, or oxyhydroxyls from, a typically aqueous, liquid medium.

Abstract: Methods of controlling a nitrification reaction in a biological nitrogen removal reactor to favor partial nitrification of ammonia to nitrite instead of complete oxidation of ammonia to nitrate are disclosed. In some embodiments, the methods include the following: maintaining a pH in the reactor within a range that promotes growth of ammonia oxidizing bacteria; maintaining a concentration of dissolved oxygen in the reactor within a range that limits the ammonia oxidizing bacteria from completing nitrification; selecting an operational solids retention time within a range suitable for maintaining increasing concentrations of the ammonia oxidizing bacteria in the reactor while reducing concentrations of nitrite oxidizing bacteria in the reactor; and increasing a concentration of free ammonia in the reactor thereby inhibiting growth of the nitrite oxidizing bacteria in the reactor.

Abstract: The invention relates to a bioreactor (1) comprising a reactor vessel (41) having a mixing chamber (3) separated by a partition (44) from a reaction chamber (2) located generally above the mixing chamber (3), the mixing chamber (3) having an inlet system (4) for influent or a mixture of influent and recycled material, wherein the inlet system (4) has an outlet opening (60-64) in the mixing chamber (3). In an embodiment the partition (44) has an opening (66) forming a connection between the mixing chamber (3) and the reaction chamber (2), wherein the outlet opening (60-64) of the inlet system (4) is directed at the opening in the partition. In an embodiment the mixing chamber (3) has a skeleton for reinforcing the mixing chamber.

Abstract: A dual stage filter assembly for use in a fluid cleaning and sludge removal operation. An upper stage centrifugal separator incorporated into a first vessel. A lower stage baffle filter is incorporated into a second vessel, such that a dirty fluid flow delivered to the upper stage separator includes a clean outlet along with a separate dirty outlet which is delivered to an inlet of the lower stage filter for subsequent filtering and outflow. A convex collection element facilitates delivery of dirty fluid to the lower stage filter and includes a cone shaped separator element and can be either fixed or removable relative to the upper stage separator. An ascending pipe from the upper separator evacuates a clean fluid flow resulting from a negative pressure created within the upper separator concurrent with the dirty outlet from the upper stage being directed through the baffle filter in the lower stage.

Abstract: A fused refractory product having the following average chemical composition, in % by weight on the basis of oxides and for a total of 100%: ZrO2: 30-50%; SiO2: 8-16%; Al2O3: balance to 100%; Y2O3?50/ZrO2 and Y2O3?5%; Na2O+K2O+B2O3?0.2% and SiO2/(Na2O+K2O+B2O3)?5×Y2O3; CaO: ?0.5%; and other oxide species: ?1.5%.

Abstract: A system and method for automatically adjusting the motion and timing of pusher mechanisms in an I.S. machine to maintain desired spacing and lateral alignment of glass containers on a conveyor taking them from the I.S. machine where they are molded. The measured glass container placement and the desired glass container placement are used to vary the operation of the pusher mechanisms in a manner tending to obtain the desired placement.

Abstract: The present invention discloses improved methods and apparatus for forming sheet glass. In one embodiment, the invention introduces a counteracting force to the stresses on the forming structure in a manner such that the thermal creep which inevitably occurs has a minimum impact on the glass flow characteristics of the forming structure.

Abstract: A method of fabricating an optical fiber preform that can give stable and high deposition efficiency from the start to the end of the deposition when synthesizing a large size preform. When fabricating a preform by hydrolyzing a glass raw material gas in flame to generate glass particles and depositing the glass particles on a rotating starting material in the radial direction using a burner with a concentric multiple-tube structure having at least a plurality of small diameter combustion assisting gas-ejecting ports having the same focal length. L1 is made greater than L2 (L1>L2) during an early stage of deposition and L2 is increased in the course of the deposition so that L2 is greater than L1 (L1<L2), where the focal length is denoted by L1 and the distance from the tip of the burner to a deposition plane on the starting material is denoted by L2.

Abstract: Provided is optical glass that does not contain lead, which is an environmental pollutant. The optical glass is ideal for the transmission of light even after being exposed to X-rays, and has a high refractive index. The optical glass comprises, by mass % in terms of oxide versus the glass total mass, 1.0% to 60.0% of an SiO2 component, and one or more selected from the group consisting of an La2O3 component, ZrO2 component, TiO2 component, Nb2O5 component, and Ta2O5 as essential components. The optical glass has a refractive index (nd) of 1.50 or greater, and has a light intensity recovery rate of 45% or greater when the glass having been irradiated with X-rays with a dose of 2.5 Gy is irradiated with light of a xenon lamp for 11 hours.

Abstract: When fixing a glass layer 3 to a glass member 4 by irradiation with laser light employing a one portion 31 of the glass layer 3 as start and end points, the glass layer 3 is cut at the one portion 31. In the glass layer 3, the one portion 31 is made thicker than a main portion 32, whereby end parts 3a, 3b rise fully. Melting the end parts 3a, 3b by irradiation with laser light L2 for a preliminary stage for final firing while pressing them toward the glass member 4 reliably buries a gap G and homogenizes the thickness of the glass layer 3. Thus constructed glass layer 3 is irradiated with the laser light L2 for final firing, so as to fuse the glass members 4, 5 to each other.

Abstract: The present invention pertains to a process for the silicate bonding of joined surfaces, facing one another, of two components by means of an aqueous, alkaline, silicon-cation-containing joining solution for the purpose of producing an optical element, characterized in that one or both of said joined surfaces (1; 2b; 10) are covered with a layer of an oxide (3), which has a higher refractive index than SiO2 and is selected from among oxides of the third and fourth main group elements, of the second and third group of the transition elements as well as zirconium and from among mixed oxides of the said elements, whereupon the joining solution is applied to at least one of the surfaces to be joined and the surfaces are bonded to one another.

Abstract: A method of cementing in a subterranean formation comprising the steps of: (A) introducing a cement composition into the subterranean formation, the cement composition comprising: (i) cement; (ii) water; and (iii) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and any combination thereof, wherein the cement composition has a density of at least 16 pounds per gallon; and (B) allowing the cement composition to set. According to an embodiment, the high-density additive is in a concentration of at least 30% by weight of the cement. A cement composition for use in an oil or gas well comprises: (A) cement; (B) water; and (C) a high-density additive selected from the group consisting of silicon carbide, sintered bauxite, and a combination thereof, wherein the high-density additive is in a concentration of at least 30% by weight of the cement, and wherein the cement composition has a density of at least 16 pounds per gallon.

Abstract: The invention provides compositions containing a salt formed from an acid and from a base, wherein the acid is defined as a polycondensation product containing (I) at least one structural unit including an aromatic or heteroaromatic and a polyether side chain, and (II) at least one phosphated structural unit including an aromatic or heteroaromatic, and polyethyleneimine as base, wherein the molar mass of the polyethyleneimine is greater than 500 daltons. Likewise provided is a process for producing these compositions and building product mixtures comprising the invention compositions. The invention also provides for the use of the compositions as admixture agents, preferably as flow agents, for aqueous suspensions of binders based on calcium sulphate or for aqueous suspensions of (latently) hydraulic binders.

Abstract: A hardening accelerator for mineral binder compositions, in particular for cementitious binder compositions, is provided. The hardening accelerator contains a combination of a) a first amino alcohol (A) including at least one primary alcohol group, and b) a second amino alcohol (E) including at least one secondary alcohol group.

Abstract: Provided are plaster patching compositions including lime, sand, perlite and gypsum. Also provided are methods of making and using the compositions to reproduce, preserve, and/or repair plaster, for example, historic plaster.

Abstract: A dielectric ceramic composition may include a base powder represented by (1-x) BaTiO3-xBiMO3 (M being configured of Mg and Ti) containing a first main component represented by BaTiO3 and a second main component represented by BiMO3, x satisfying 0.005?x?0.5, and Some embodiments of the present disclosure may provide a novel dielectric ceramic composition capable of securing X8R temperature characteristics and reliability.

Abstract: The invention relates to a process for the continuous thermal removal of binder from a metallic and/or ceramic shaped body which has been produced by injection molding, extrusion or pressing using a thermoplastic composition and comprises at least one polyoxymethylene homopolymer or copolymer as binder in a binder removal oven, which comprises the steps (a) removal of binder from the shaped body in a binder removal oven at a temperature which is from 5 to 20° C. below, preferably from 10 to 15° C. below, the temperature of a second temperature stage over a period of from 4 to 12 hours in a first temperature stage in an oxygen-comprising atmosphere, (b) removal of binder from the shaped body at a temperature in the range >160 to 200° C. over a period of from 4 to 12 hours in an oxygen-comprising atmosphere in a second temperature stage and (c) removal of binder from the shaped body at a temperature in the range from 200 to 600° C.

Abstract: A ceramic precursor batch composition comprising inorganic ceramic-forming ingredients, a binder, an aqueous solvent and a heteroatom polyol agent. The heteroatom polyol agent can be represented by X(R) where X is at least one of S, N, and P, and R is at least two of CH3, CH2CH2OH, CH2CH2CH2OH, CH2(CHOH)CH3, C(CH2OH)1-3, CH2OH, CH(CH2OH)CHOH, C(O)(CHOH)1-4CH2OH, and CH2CH2CH2OCH3. The presence of the heteroatom polyol agent provides a composition with a lower viscosity and/or a greater batch stiffening temperature (Tonset) allowing for increased rates of extrusion. Methods for producing a ceramic honeycomb body using this ceramic precursor batch composition are also provided.

Abstract: The disclosure relates to ceramic-body-forming batch materials comprising at least one pore former and inorganic batch components comprising at least one silica source having a specified particle size distribution, methods of making ceramic bodies using the same, and ceramic bodies made in accordance with said methods. The disclosure additionally relates to methods for reducing pore size variability in ceramic bodies and/or reducing process variability in making ceramic bodies.

Abstract: This invention is directed to systems, devices and methods for treating organic-containing sludges and converting such sludges to high value fertilizers containing both inorganic and organic fertilizer components, which creates an inorganically-augmented bioorganic fertilizer. The invention describes methods to create a thixotropic or paste-like material via the application of mixing energy to the organic sludge followed by an alkaline treatment and a subsequent ammoniation. The invention further describes a method to increase the plant nutrient content in the organic containing product to a level which permits the finished granular fertilizer product to compete in the commercial agricultural fertilizer marketplace. Further, the invention reduces odors associated with said organic-containing sludges.

Abstract: A composite having a substrate and a plurality of core-shell nanoparticles. The substrate has microporosity, nanoporosity, or free volume and is a polymer matrix, a metal-organic framework, a micro-porous structure, or a nano-porous structure. The plurality of core-shell nanoparticles each has a core and at least one shell layer. The core is made from a decomposed product of a first precursor disposed in the microporosity, nanoporosity, or free volume of the substrate. The at least one shell layer is made from a decomposed product of a second precursor and is disposed on the core.

Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a germanium zeolite, such as Ge-ZSM-5, on which at least two metals, platinum and at least one other metal selected from Group 7, Group 8, Group 9, Group 10 and tin, are deposited on the germanium zeolite. Examples of the other metal are iridium, rhenium, palladium, ruthenium, rhodium, iron, cobalt and tin. The catalyst is prepared by synthesizing a germanium zeolite; depositing platinum and at least one other metal on the germanium zeolite; and calcining after preparation of the zeolite, before depositing the metals or after depositing the metals. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes, olefins and mixtures thereof having 2 to 12 carbon atoms per molecule and recovering the product.

Abstract: A process and apparatus is presented for the improved selectivity of oxygenate conversion to olefins. The process includes passing a process stream through a two stage reactor, wherein the process stream is separated from the catalyst in the first stage before passing the process stream to the second stage. The catalyst is continuously passed through the two stages, and cycles through a regeneration unit to control the carbon content on the catalyst.

Abstract: The present invention (in a first embodiment) relates to a process for the simultaneous dehydration and skeletal isomerization of isobutanol to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerize at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, Wherein, the WHSV of the isobutanol is at least 1 h?1 or the temperature is from 200° C. to 600° C. and the catalyst is capable to make simultaneously the dehydration and skeletal isomerization of butene.

Abstract: In a process for producing mono-cycloalkyl-substituted aromatic compound, benzene and cyclic monoolefin are contacted with a catalyst under alkylation conditions to produce an effluent containing mono-cycloalkyl-substituted aromatic compound. The catalyst comprises a molecular sieve.

Abstract: In a process for producing cyclohexylbenzene, benzene is reacted with cyclohexene under alkylation conditions effective to produce an alkylation effluent comprising cyclohexylbenzene and a polycyclohexylbenzene. A first feed comprising at least a portion of the alkylation effluent is then fed to a first separation device, where the first feed is separated into at least a first fraction containing cyclohexylbenzene and a second fraction containing the polycyclohexylbenzene, the second fraction also comprising an oxygenated hydrocarbon. At least a portion of the oxygenated hydrocarbon is removed from at least a portion of the second fraction in a second separation device to obtain a second feed. The second feed may then be reacted in a transalkylation or dealkylation reactor to convert at least part of the polycyclohexylbenzene to additional cyclohexylbenzene.

Abstract: The invention relates to hydroalkylation processes. In the processes, a hydrogen stream comprising hydrogen and an impurity is treated to reduce the amount of the impurity in the hydrogen stream. The hydrogen is then hydroalkylated with benzene to form at least some cyclohexylbenzene. The processes also relate to treating a benzene stream comprising benzene and an impurity with an adsorbent to reduce the amount of the impurity in the benzene stream. The hydroalkylation processes described herein may be used as part of a process to make phenol.

Abstract: Provided is a process for producing cyclohexylbenzene, in which a benzene feed stream is subjected to each of the following treatment steps: treating the feed stream with at least one adsorbent and fractionating the feed stream to remove components having a different boiling point than benzene. The treatment steps are carried out in any order and produce a treated benzene feed stream. The treated benzene feed stream is then contacted with hydrogen in the presence of a hydroalkylation catalyst in a hydroalkylation unit under conditions effective to produce a reaction product containing cyclohexylbenzene.

Abstract: A process to make isoprene may include providing a reaction zone containing an acidic aqueous solution. The process may include introducing, continuously or intermittently, in the reaction zone a mixture containing isobutanol and an aqueous solution of formaldehyde. The process may include operating the reaction zone at conditions effective to dehydrate isobutanol to iso-butene, and produce isoprene by reaction of formaldehyde and iso-butene, while distilling away a mixture containing produced isoprene and water.

Abstract: A method for producing monocyclic aromatic hydrocarbons includes a step of introducing a feedstock oil into a cracking/reforming reactor, bringing the feedstock oil into contact with a catalyst, and causing the feedstock oil to react, a step of purifying and recovering the monocyclic aromatic hydrocarbons separated from the product produced in the reaction step, a step of hydrogenating a heavy fraction separated from the product, and a recycling step of returning a hydrogenation reactant of the heavy fraction to the cracking/reforming reaction step. In the recycling step, the hydrogenation reactant is introduced at a location different from an introduction location of the feedstock oil into the reactor so that a time during which the hydrogenation reactant is in contact with the catalyst in the reactor becomes shorter than a time during which the feedstock oil is in contact with the catalyst in the reactor.

Abstract: A selective hydrogenation process that is particularly effective in selectively hydrogenating alkynl compounds, such as acetylene or methyl acetylene, over alkenyl compounds, such as ethylene, is described. The process utilizes a slurry conversion unit for heat efficiency purposes during the conversion of acetylene into ethylene.

Abstract: Provided herein is a gaseous isoprene composition comprising isoprene, carbon dioxide and water, wherein the isoprene is in an amount between about 0.1% and about 15% by volume; wherein the carbon dioxide is in an amount between about 0.04% and about 35% by volume; wherein the water is in an amount greater than about 70% of its saturation amount. Also provided herein is a liquid isoprene composition comprising isoprene in an amount of at least 65% by weight and carbon dioxide in an amount between about 0.01% and about 1% by weight.

Abstract: The invention relates to a process to produce HCFC-244bb from HCFO-1233xf wherein, in one embodiment, one or more co-feed species having a normal boiling point of between about ?80° C. to about 0° C., such as HFC-245cb, is added to the reaction at a pressure of at least about 100 psig; and in another embodiment it is added to maintain a mole ratio of HFC-245cb to HCFO-1233xf of between about 0.005:1 to about 1:1. The HFC-245cb may be added as recycled by-product of the reaction and/or added as fresh feed. The HFC-245cb provides elevated pressures to the reaction thereby facilitating reactor operation, mixing and HCFC-244bb product removal. Other co-feed species are also disclosed.