Patents Issued in February 4, 2016
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Publication number: 20160032039Abstract: A method for producing a cross-linked fluoroelastomer including cross-linking a fluoroelastomer with a cross-linking agent in an inert gas atmosphere in the presence of an initiator.Type: ApplicationFiled: March 27, 2014Publication date: February 4, 2016Applicant: Nichias CorporationInventors: Tomoya Shimizu, Ayumi Maezawa, Yuriko Sekimoto, Naoya Kuzawa
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Publication number: 20160032040Abstract: Coating compositions can be prepared from an acrylic grafted polyether resin, wherein the smallest difunctional hydroxyl phenyl segment used to form the acrylic grafted polyether resin has a molecular weight greater than about 500, and wherein the smallest difunctional hydroxyl phenyl segment used to form the acrylic grafted polyether resin does not comprise two or more non-impaired hydroxyl groups attached to two or more different five-membered or six-membered carbon atom rings in a segment having a molecular weight less than about 500. The acrylic grafted polyether resin can be prepared by reacting a dihydroxyl compound and/or a diamine compound with a phenol stearic acid compound to produce a diphenol, reacting the diphenol with a diglycidyl ether compound to form a polyether resin, and mixing the polyether resin with an ethylenically unsaturated monomer component in the presence of an initiator to form the acrylic grafted polyether resin.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Inventors: Gary Pierce Craun, Daniel Bode, Timothy Edward Banach, Gary Joseph Robideau, Leigh Scott Howard
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Publication number: 20160032041Abstract: Copolymers made with allyl-terminated polyolefins and unsaturated acidic reactants, dispersants using same, and methods of making same are provided. Under one aspect, a copolymer of an unsaturated acidic reactant and high molecular weight polyolefin, wherein the polyolefin comprises an allyl-terminated polymeric product, is provided. The allyl-terminated polymeric product is formed, e.g., by forming a quasi-living tert-halide terminated polyolefin under suitable quasi-living conditions, and contacting the tert-halide terminated polyolefin with an allylsilane compound and a Lewis acid. In some embodiments, the allylsilane compound includes allyltrimethylsilane.Type: ApplicationFiled: October 14, 2015Publication date: February 4, 2016Inventors: James J. Harrison, Casey D. Stokes
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Publication number: 20160032042Abstract: A composition and process useful to make flexible polyurethane foams and in particular flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N, N-dimethylacetoacetamide as well as glycols containing hydroxyl numbers OH#?1100 as cell opening aides for 2-cyanoacetamide or other similar molecules containing active methylene or methine groups to make a polyurethane foam is also disclosed. The advantage of using cell opener aids results in a) no foam shrinkage; b) lower use levels of cell opener; c) foam performance reproducibility d) optimum physical properties. In addition, combining the acid blocked amine catalyst together with the cell opener and the cell opener aid results in a less corrosive mixture as well as provides a method that does not require mechanical crushing for cell opening.Type: ApplicationFiled: September 28, 2015Publication date: February 4, 2016Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Juan Jesus Burdeniuc, James Douglas Tobias, Renee Jo Keller
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Publication number: 20160032043Abstract: Use of biologically-derived polyphenols for the preparation of epoxy resins is described. Examples of biologically-derived polyphenols include resveratrol, genistein, daidzein, and polyphenols synthesized from tyrosine. Because the epoxy resins are prepared from biologically-derived materials, they provide epoxy resins that will degrade into biologically harmless materials. The epoxy resins can be used to provide coating compositions.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Inventor: Horst A. von Recum
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Publication number: 20160032044Abstract: PLA polymers that can be expanded into microporous articles having a node and fibril microstructure are provided. The fibrils contain PLA polymer chains oriented with the fibril axis. Additionally, the PLA polymers have an inherent viscosity greater than about 3.8 dL/g and a calculated molecular weight greater than about 150,000 g/mol. The PLA polymer article may be formed by bulk polymerization where the PLA bulk polymer is made into a preform that is subsequently expanded at temperatures above the glass transition temperature and below the melting point of the PLA polymer. In an alternate embodiment, a PLA polymer powder is lubricated, the lubricated polymer is subjected to pressure and compression to form a preform, and the preform is expanded to form a microporous article. Both the preform and the microporous article are formed at temperatures above the glass transition temperature and below the melting point of the PLA polymer.Type: ApplicationFiled: July 28, 2015Publication date: February 4, 2016Inventors: Guy A. Sbriglia, Scott A. Gore
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Publication number: 20160032045Abstract: The present invention relates to the use of polyesters with inherent flame retardancy as or in adhesives, sealants and coatings, to polyesters with inherent flame retardancy and to processes for production thereof.Type: ApplicationFiled: March 6, 2014Publication date: February 4, 2016Applicant: EVONIK DEGUSSA GMBHInventors: Christina DIEHL, Gabriele BRENNER, Bernhard SCHLEIMER
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Publication number: 20160032046Abstract: The present invention relates to a method of producing polycarbonate containing following step (a) and step (b), (a) a step of reacting a specific fluorine-containing carbonate (Compound (1), etc.) and an aromatic dihydroxy compound in the presence of a condensation catalyst, to obtain a prepolymer, and (b) a step of heating the prepolymer at a temperature which is lower than a melting temperature of the prepolymer and performing solid phase polymerization on the prepolymer while a fluorine-containing alcohol that is produced as a by-product is discharged out of a system, to obtain a polycarbonate.Type: ApplicationFiled: October 15, 2015Publication date: February 4, 2016Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Naoko SHIROTA, Takashi Okazoe, Kimiaki Kashiwagi
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Publication number: 20160032047Abstract: The invention provides compositions that use phenylic derivatives to provide adhesive properties. Selection of phenylic derivatives with linkers or linking groups, and the linkages between the linkers or linking groups with polyalkylene oxides, provided herein may be configured to control curing time, biodegradation and/or swelling.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Inventors: John L MURPHY, Jeffrey L DALSIN, Arinne N LYMAN, Christopher P RADANO
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Publication number: 20160032048Abstract: Coating compositions can be prepared from a polyether resin, wherein the smallest difunctional hydroxyl phenyl segment used to form the polyether resin has a molecular weight greater than about 500, and wherein the smallest difunctional hydroxyl phenyl segment used to form the polyether resin does not comprise two or more non-impaired hydroxyl groups attached to two or more different five-membered or six-membered carbon atom rings in a segment having a molecular weight less than about 500. The polyether resin can be prepared by reacting a dihydroxyl compound and/or a diamine compound with a phenol stearic acid compound to produce a diphenol, and reacting the diphenol with a diglycidyl ether compound to form the polyether resin.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Inventors: Gary Pierce Craun, Daniel Bode, Timothy Edward Banach, Gary Joseph Robideau, Leigh Scott Howard
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Publication number: 20160032049Abstract: The present invention is directed to branched reactive water-soluble polymers comprising at least two polymer arms, such as poly(ethylene glycol), attached to a central aliphatic hydrocarbon core molecule through heteroatom linkages. The branched polymers bear at least one functional group for reacting with a biologically active agent to form a biologically active conjugate. The functional group of the branched polymer can be directly attached to the aliphatic hydrocarbon core or via an intervening linkage, such as a heteroatom, -alkylene-, —O-alkylene-O—, -alkylene-O-alkylene-, -aryl-O—, -D-aryl-, (—O-alkylene-)m, or (-alkylene-O—)m linkage, wherein m is 1-10.Type: ApplicationFiled: October 13, 2015Publication date: February 4, 2016Inventors: Michael D. Bentley, Xuan Zhao, Xiaoming Shen, William D. Battle, III
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Publication number: 20160032050Abstract: The invention relates to a reactor in the form of a VK tube (VK: simplified continuous), for the polymerisation of polyamides, the reactor being subdivided into an upper and lower reactor region, which are controllable independently of each other. Likewise, the invention relates to a method for the production of polyamides in which such a reactor is used.Type: ApplicationFiled: January 20, 2014Publication date: February 4, 2016Applicant: UHDE INVENTA-FISCHER GMBHInventors: Ekkehard SIEBECKE, Johannes KATZER, Bernd KÖNIGSMANN
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Publication number: 20160032051Abstract: A copolymerized polyamide resin includes a polymer of a monomer mixture comprising a dicarboxylic acid component and a diamine component including about 4 mol % to about 20 mol % of an alicyclic diamine represented by the Formula 1, wherein the polyamide resin has a melting temperature (Tm) from about 280 to about 330° C. and a crystallization temperature (Tc) from about 250 to about 300° C.: wherein, R1 and R2 are the same or different and are each independently a C1 to C5 alkyl group or a C6 to C10 aryl group, X is a C1 to C10 hydrocarbon group, and m and n are the same or different and are each independently an integer from 0 to 4. The copolymerized polyamide resin can exhibit excellent properties, such as crystallinity, heat resistance, processability and discoloration resistance, and an excellent balance therebetween.Type: ApplicationFiled: December 11, 2014Publication date: February 4, 2016Inventors: So Young KWON, Joon Sung KIM, Eun Ju LEE, Ki Yon LEE, Sung Chul CHOI
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Publication number: 20160032052Abstract: In one or a plurality of embodiments, a process for manufacturing polyamide, with a reduced use of an amide-based solvent in synthesis, is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (a) to (c): (a) dissolving diacid dichloride in a non-amide-based organic solvent; (b) adding diamine to a solution obtained in the step (a) and reacting the diacid dichloride with the diamine so as to generate polyamide; and (c) adding a trapping reagent capable of trapping hydrochloric acid, at any time at least before the step (b), at the same time of starting the step (b), or during the step (b).Type: ApplicationFiled: July 31, 2015Publication date: February 4, 2016Applicant: SUMITOMO BAKELITE COMPANY LIMITEDInventors: Toshihiko KATAYAMA, Jun OKADA, Ritsuya KAWASAKI, Hideo UMEDA
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Publication number: 20160032053Abstract: The present invention provides an inner liner for pneumatic tire, the inner liner being prepared by molding a resin composition containing a polyether polyamide (A) in which a diamine constituent unit thereof includes constituent units derived from a polyether diamine compound (a-1) represented by the general formula (1) and a xylylenediamine (a-2), and a dicarboxylic acid constituent unit thereof includes a constituent unit derived from an ?,?-linear aliphatic dicarboxylic acid (a-3) having from 4 to 20 carbon atoms.Type: ApplicationFiled: March 26, 2014Publication date: February 4, 2016Inventors: Tomonori Kato, Mayumi Kikuchi, Kazuya Sato
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Publication number: 20160032054Abstract: The disclosure provides reversible polymers from polyurea by modifying the nitrogen atom with hindered substituents. The reversibility of hindered urea bond (HUB) can be controlled by changing the bulkiness of the substituents, and N-tert-butyl-N-ethylurea (TBEU), with its high binding constant and short lifetime, is applicable in the design of reversible polymer and self-healing materials at mild temperatures without external stimuli. HUB can be used in the design of smart materials with its adjustable reversibility, facile synthesis, and compatibility with many other polymer structures.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Inventors: Jianjun Cheng, Hanze Ying
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Publication number: 20160032055Abstract: The present invention addresses the problem of providing: a polyimide film that has a small phase difference in the thickness direction and has a low coefficient of linear thermal expansion; and a polyamic acid and varnish to obtain the same. In order to solve this problem, the present invention provides a polyimide film which comprises polyimide that is produced by reacting a diamine component and a tetracarboxylic dianhydride component, the polyimide film having a coefficient of linear thermal expansion of 35 ppm/K or less over a temperature range of 100 to 200 DEG C, an absolute value of phase difference in the thickness direction of 200 nm or less per 10 ?m thickness, a glass transition temperature of 260 DEG C or more, and a total light transmittance of 85% or more.Type: ApplicationFiled: April 1, 2014Publication date: February 4, 2016Applicant: MITSUI CHEMICALS., INC.Inventors: Tatsuhiro URAKAMI, Masaki OKAZAKI, Kenichi FUKUKAWA, Yoshihiro SAKATA, Atsushi OKUBO
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Publication number: 20160032056Abstract: The present invention relates to a polyimide precursor comprising a repeating unit represented by the following chemical formula (1): wherein A is a tetravalent group having at least one aliphatic six membered ring and no aromatic ring in the chemical structure, and B is a divalent group having at least one amide bond and an aromatic ring in the chemical structure; or A is an aliphatic tetravalent group and B is a divalent group having at least one chemical structure represented by the following chemical formula (2) in the chemical structure: and X1 and X2 are each independently hydrogen, a C1-6 alkyl group or a C3-9 alkylsilyl group.Type: ApplicationFiled: August 7, 2015Publication date: February 4, 2016Inventors: Ryoichi Takasawa, Takuya Oka, Yukinori Kohama, Miharu Nakagawa, Keiji Iwamoto, Kenji Hirotsu, Yoshiyuki Watanabe
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Publication number: 20160032057Abstract: To provide a safe and stable medicine useful for prevention and treatment of prostate cancer. A novel PI polyamide is acquired that recognizes and binds to a specific base sequence of an Oct1 gene binding sequence present in a transcriptional regulatory region (AR response region) of an ACSL3 gene and regulating the transcription activity of AR. This leads to the provision of an ACSL3 gene expression inhibitor and a preventive and/or therapeutic agent of prostate cancer containing the PI polyamide as an active ingredient.Type: ApplicationFiled: March 11, 2014Publication date: February 4, 2016Applicant: NIHON UNIVERSITYInventors: Daisuke OBINATA, Satoru TAKAHASHI, Kyoko FUJIWARA, Satoshi INOUE, Kenichi TAKAYAMA
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Publication number: 20160032058Abstract: Certain polythioether polymers are presented, as well as compositions which are radiation curable to polythioether polymers and seals and sealants comprising same. The compositions radiation curable to polythioether polymers include those comprising: a) at least one dithiol monomer; b) at least one diene monomer; c) at least one multifunctional monomer having at least three ethenyl groups; and d) at least one photoinitiator. In another aspect, the compositions radiation curable to polythioether polymers include those comprising: f) at least one dithiol monomer; g) at least one diene monomer; h) at least one multifunctional monomer having at least three thiol groups; and i) at least one photoinitiator. In another aspect, the compositions radiation curable to poly-thioether polymers include those comprising: k) at least one thiol terminated polythioether polymer; l) at least one multifunctional monomer having at least three ethenyl groups; and m) at least one photoinitiator.Type: ApplicationFiled: March 7, 2014Publication date: February 4, 2016Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Shen Ye, Robin E. Wright, Jonathan D. Zook, Susan E. DeMoss
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Publication number: 20160032059Abstract: Certain polythioether polymers are presented, as well as compositions which are radiation curable to polythioether polymers and seals and sealants comprising same. The compositions radiation curable to polythioether polymers include those comprising: a) at least one dithiol monomer; b) at least one diene monomer; c) at least one polyyne monomer comprising at least two ethyne groups; and d) at least one photoinitiator. In some embodiments, the polyyne monomer is a diyne monomer. In some embodiments, the composition also comprises at least one epoxy resin. In another aspect, the compositions radiation curable to polythioether polymers include those comprising: f) at least one thiol terminated polythioether polymer; g) at least one diyne monomer; and h) at least one photoinitiator. In some embodiments the thiol terminated polythioether polymer comprises pendent hydroxide groups.Type: ApplicationFiled: March 5, 2014Publication date: February 4, 2016Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Sheng Ye, Robin E. Wright, Jonathan D. Zook, Susan E. DeMoss
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Publication number: 20160032060Abstract: A curable silicone composition is provided that comprises a reaction product of a reaction of (I) a clustered functional polyorganopolysiloxane having at least one radical curable group selected from an acrylate group and a methacrylate group; (II) a silicone reactive diluent, and a (III) a radical initiator.Type: ApplicationFiled: February 10, 2014Publication date: February 4, 2016Inventors: Jing Jiang, Yin Tang, James Tonge, Afrooz Zarisfi
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Publication number: 20160032061Abstract: Provided herein is technology relating to polymer-graphene nanocomposites and particularly, but not exclusively, to methods for producing polymer-graphene nanocomposites using master batches comprising graphene and a polymer or polymer precursor. The resulting polymer-graphene nanocomposites comprise a high degree of exfoliation and dispersion of graphene nanoplatelets within the polymer matrix.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Inventors: Allen David Clauss, Guiquan Pan, Nicholas Richard Wietfeldt, Matthew Clayton Hall, David D. Taft
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Publication number: 20160032062Abstract: Provided herein is technology relating to polymer nanocomposites, and particularly, but not exclusively, to polymer nanocomposites comprising two or more nanomaterials and methods of producing nanocomposites comprising two or more nanomaterials.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Inventors: Allen David Clauss, Brian Jeffrey Koth, Guiquan Pan, Nicholas Richard Wietfeldt, Matthew Clayton Hall
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Publication number: 20160032063Abstract: Disclosed is an optical film having low wavelength dispersibility which is obtained by stretching a film formed of a fluorine-containing cyclic olefin polymer including at least one selected from a repeating structural unit represented by the formula described below, wherein a phase difference at a wavelength of 550 nm is greater than or equal to 50 nm, wavelength dispersibility represented by a ratio Re (400 nm)/Re (550 nm) of a phase difference Re (400 nm) at a wavelength of 400 nm to a phase difference Re (550 nm) at a wavelength of 550 nm is 1.00 to 1.05, wavelength dispersibility represented by a ratio Re (400 nm)/Re (800 nm) of a phase difference Re (400 nm) at a wavelength of 400 nm to a phase difference Re (800 nm) at a wavelength of 800 nm is 1.00 to 1.05, and total light transmittance is greater than or equal to 92%.Type: ApplicationFiled: March 25, 2014Publication date: February 4, 2016Applicants: Keio University, Mitsui Chemicals, Inc.Inventors: Tadahiro Sunaga, Takashi Oda, Yasuhiro Koike
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Publication number: 20160032064Abstract: An encapsulant sheet for a solar cell contains not less than 91% but less than 99% by mass of an ethylene-unsaturated ester copolymer (A), more than 1% but not more than 9% by mass of an olefin resins (B), 0.001 parts to 5 parts by mass of silicon dioxide and 0.001 to 0.5 parts by mass of a silane coupling agent, where the sum total of the content of the ethylene-unsaturated ester copolymer (A) and the content of the olefin resin (B) is taken as 100% by mass. The content of the silicon dioxide and the content of the silane coupling agent are relative to the total content of the ethylene-unsaturated ester copolymer (A) and the content of the olefin resin (B) being taken as 100% by mass. The encapsulant sheet is excellent in insulating property, storage stability, transparency, and durability of adhesion to glass.Type: ApplicationFiled: July 29, 2015Publication date: February 4, 2016Inventor: Hiroaki YODA
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Publication number: 20160032065Abstract: A prepreg 10 comprises: a reinforcing fiber layer 3 including reinforcing fibers 1 and a resin composition 2 with which the space between fibers thereof is impregnated and which contains (A) a benzoxazine resin, (B) an epoxy resin, and (C) a curing agent having 2 or more phenolic hydroxy groups; and surface layers 6a and 6b provided on the surfaces of the reinforcing fiber layer 3 and containing (A) a benzoxazine resin, (B) an epoxy resin, (C) a curing agent having 2 or more phenolic hydroxy groups, and (D) polyamide resin particles 4 having an average particle size of 5 to 50 wherein the polyamide resin particles 4 include a particle made of a copolymer in which caprolactam and laurolactam are copolymerized at a molar ratio of 9:1 to 7:3 and having a melting point of 180° C. or more.Type: ApplicationFiled: March 24, 2014Publication date: February 4, 2016Applicants: JX NIPPON OIL & ENERGY CORPORATION, FUJI JUKOGYO KABUSHIKI KAISHAInventors: Yoshihiro FUKUDA, Takayuki MATSUMOTO, Masaki MINAMI, Naoyuki SEKINE, Masanori NAKAJIMA
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Publication number: 20160032066Abstract: A composite comprising a combination of a self-healing polymer matrix and a carbon fiber reinforcement is described. In one embodiment, the matrix is a polybutadiene graft copolymer matrix, such as polybutadiene graft copolymer comprising poly(butadiene)-graft-poly(methyl acrylate-co-acrylonitrile). A method of fabricating the composite is also described, comprising the steps of manufacturing a pre-impregnated unidirectional carbon fiber preform by wetting a plurality of carbon fibers with a solution, the solution comprising a self-healing polymer and a solvent, and curing the preform. A method of repairing a structure made from the composite of the invention is described. A novel prepreg material used to manufacture the composite of the invention is described.Type: ApplicationFiled: October 13, 2015Publication date: February 4, 2016Inventors: Keith L. Gordon, Emilie J. Siochi, Brian W. Grimsley, Roberto J. Cano, Michael W. Czabaj
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Publication number: 20160032067Abstract: A process for making a crosslinked assembly includes steps of: selecting a desired performance parameter for a molded assembly of a first polymeric component and a second polymeric component bonded to the first polymeric component, controlling a first crosslinking percentage for the first polymeric component and a second crosslinking percentage for the second polymeric component independently to provide the desired performance parameter for the assembly, orienting the assembly at an angle between an orientation axis of the assembly and a electron beam direction, exposing the oriented assembly a predetermined number of times (N) to the electron beam operable to deliver a predetermined amount of radiation (R) in the electron beam direction providing a total radiation exposure proportional to (N×R) providing the first component crosslinking percentage and the second component crosslinking percentage, the resulting assembly having the desired performance parameter.Type: ApplicationFiled: October 1, 2014Publication date: February 4, 2016Inventor: William W. Rowley
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Publication number: 20160032068Abstract: The present invention relates to a polyamide resin composition for a foam molded body, comprising a crystalline polyamide resin (A), carbon black (B) which does not exhibit crystallization promoting action to said crystalline polyamide resin and an inorganic reinforcing material (C), wherein, when the total amount of (A), (B) and (C) is taken as 100% by mass, the composition comprises (A) and (B) in a rate of 60 to 90% by mass in terms of the sum thereof and comprises (C) in a rate of 10 to 40% by mass, and wherein melting point and crystallization temperature of said polyamide resin composition have a specific relationship. The above-mentioned polyamide resin composition can provide a polyamide foam molded body having light weight, high load bearing property and good molded appearance.Type: ApplicationFiled: May 12, 2014Publication date: February 4, 2016Applicant: TOYOBO CO., LTD.Inventors: Tomohide NAKAGAWA, Kazunari TANAKA
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Publication number: 20160032069Abstract: Polyparaxylylene (PPX) polymers that can be expanded into porous articles that have a node and fibril microstructure are provided. The fibrils contain PPX polymer chains oriented with the fibril axis. The PPX polymer may contain one or more comonomer. PPX polymer articles may be formed by applying PPX to a substrate by vapor deposition. The nominal thickness of the PPX polymer film is less than about 50 microns. The PPX polymer film may be removed from the substrate to form a free-standing PPX polymer film, which may then be stretched into a porous article. Alternatively, a PPX polymer article can be formed by lubricating PPX polymer powder, heating the lubricated powder, and calendering or ram extruding to produce a preform that can subsequently be stretched into a porous article. The heating and expansion temperatures are from about 80° C. to about 220° C. or from about 220° C. to about 290° C. or from about 290° C. to about 450° C.Type: ApplicationFiled: July 28, 2015Publication date: February 4, 2016Inventor: Guy A. Sbriglia
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Publication number: 20160032070Abstract: Polylactic acid-based resin expanded beads obtained by releasing a softened, pressurized foamable resin composition, which has a polylactic acid-based resin and a physical blowing agent, to a low pressure atmosphere to foam and expand the resin composition, where the polylactic acid-based resin satisfies the conditions (1) to (3) shown below, and exhibits excellent secondary expansion properties and fusion bonding properties. A polylactic acid-based resin expanded beads molded article obtained by in-mold molding of the polylactic acid-based resin expanded beads exhibits excellent mechanical properties. MT?30 mN??(1) log MT?0.93 log ??1.75??(2) CT1/2?600 sec??(3) where MT represents a melt tension [mN] at 190° C., ? represents a melt viscosity [Pa·s] at 190° C. and a shear speed of 20 sec?1, and CT1/2 represents a half crystallization time [sec] at 110° C.Type: ApplicationFiled: October 13, 2015Publication date: February 4, 2016Applicant: JSP CORPORATIONInventors: Mitsuru SHINOHARA, Masaharu OIKAWA
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Publication number: 20160032071Abstract: VDF-co-(TFE or TrFE) polymers having a molecular weight of at least about 1,000,000 g/mol and a melt temperature less than about 240° C. The VDF copolymer contains at least about 50 mol % VDF monomer and may include an amount of at least one other monomer. The VDF copolymer may be used to form a membrane that has a node and fibril structure. The membrane has a percent porosity of at least 25%. A VDF-co-(TFE or TrFE) polymer membrane may be formed by lubricating the VDF copolymer, subjecting the lubricated polymer to pressure at a temperature below the melting point of the VDF copolymer to form a preform material, and expanding the preform material at a temperature below the melting temperature of the VDF copolymer. Dense VDF copolymer articles, filled VDF copolymer membranes, and VDF copolymer fibers are also provided.Type: ApplicationFiled: July 28, 2015Publication date: February 4, 2016Inventors: Guy A. Sbriglia, Gregory J. Shafer
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Publication number: 20160032072Abstract: The present invention provides aerogel materials based on imidazoles and polyimidazoles. The polyimidazole based aerogel materials can be thermally stable up to 500° C. or more, and can be carbonized to produce a carbon aerogel having a char yield of 60% or more, specifically 70% or more. The present invention also provides methods of producing polyimidazole based aerogel materials by reacting at least one monomer in a suitable solvent to form a polybenzimidazole gel precursor solution, casting the polybenzimidazole gel precursor solution into a fiber reinforcement phase, allowing the at least one gel precursor in the precursor solution to transition into a gel material, and drying the gel materials to remove at least a portion of the solvent, to obtain an polybenzimidazole-based aerogel material.Type: ApplicationFiled: August 4, 2014Publication date: February 4, 2016Inventors: Wendell E. Rhine, David Mihalcik
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Publication number: 20160032073Abstract: Composite materials including cellulose nanocrystals incorporated into a polymer aerogel scaffold, wherein the cellulose nanocrystals serve as a reinforcement agent to result in the formation of less dense aerogels, improve the tensile mechanical properties of aerogel films, and reduce aerogel shrinkage upon thermal exposure. After gelation, the gel is dried via a suitable method such as supercritical CO2 extraction, freeze drying or other method, to produce the CNC/polymer composite aerogel. Properties of the composite aerogel can be tailored via surface modification of the cellulose nanocrystals as well as through the backbone structure of the polymer.Type: ApplicationFiled: July 31, 2015Publication date: February 4, 2016Inventors: Baochau NGUYEN, Mary Ann MEADOR, Stuart ROWAN, Elvis CUDJOE
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Publication number: 20160032074Abstract: A body having a lubricant reservoir is described, comprising: a porous polymeric body; and a lubricating liquid, said lubricating liquid occupying the pores to provide a lubricated porous surface having a lubricant reservoir and a lubricant overlayer over the polymer surface. Also described herein is a system for use in the formation of a low-adhesion and low-friction surface includes a flowable precursor composition comprising a prepolymer and a curing agent, said composition capable of application as a coating over a large surface area; a lubricating liquid that is capable of forming a coating with the hardened precursor composition, wherein the lubricating liquid and hardened polymer together form a coating of lubricating liquid stabilized on and in the hardened polymer; and instructions for applying the precursor composition onto a surface for the purpose of obtaining a low-adhesion and low-friction surface.Type: ApplicationFiled: March 13, 2014Publication date: February 4, 2016Inventors: Joanna AIZENBERG, Michael AIZENBERG, Philseok KIM, Alex VENA
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Publication number: 20160032075Abstract: The disclosure relates to a rubber mixture which contains at least one fluorine rubber and at least one active filler and carbon nanotubes. The rubber mixture has an additionally improved tear propagation resistance and, at the same time, improved processability. The disclosure further relates to a hose having at least the following layer structure: an inner layer as a barrier layer against aggressive media, which contains at least one fluorine rubber and at least one active filler and carbon nanotubes; and, an outer layer made of a cross-linked rubber mixture.Type: ApplicationFiled: October 12, 2015Publication date: February 4, 2016Inventors: Sebastian Seibold, Dieter Borvitz
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Publication number: 20160032076Abstract: Flame retardant polymer compositions comprising certain thermally stable salts of pyrophosphonic acid as flame retardant materials, which flame retardant materials comprise one or more than one metals, are prepared and have excellent flame retardant activity.Type: ApplicationFiled: April 20, 2015Publication date: February 4, 2016Inventors: Zachary D. Stockdale, Matthew S. Burge
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Publication number: 20160032077Abstract: The invention relates to a use of at least one condensation product (A) in the form of the free compound or in the form of a salt of at least one acid as a thixotropy- increasing additive, which condensation product can be obtained by reacting at least one polymerized fatty acid or at least one reaction product (U) of at least two polymerized fatty acids and at least one polyamine having at least two primary amino groups as component (a1) with at least one polyalkylene polyamine, which is capable of forming at least one imidazoline and/or tetrahydropyrimidine unit and which has at least two primary amino groups or at least one primary and at least one secondary amino group, a composition containing at least one such condensation product (A) and at least one thixotropic agent (B), and a use of said composition, which additionally comprises at least one binder (C), as an adhesive, sealant, paint, coating agent, adhesive resin, casting resin, artificial marble, floor covering, polymer concrete, or fiber compositType: ApplicationFiled: March 11, 2014Publication date: February 4, 2016Inventors: Christian BIECKER, Sascha KOCKOTH, Frederik PIESTERT, Wolfgang PRITSCHINS, Jürgen OMEIS, Eva BESTEN, Angelika ORLOWSKI
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Publication number: 20160032078Abstract: The invention relates to stabilizer compositions for polymers such as polyolefin polymers, which decrease a phosphorus based stabilizer content necessary to stabilize the polymer. The premixed stabilizer compositions include an antacid, an organic acid-metal salt, and a primary antioxidant such as a sterically-hindered phenolic compound, a sterically-hindered amine compound, a hydroxylamine compound, and combinations thereof. The premixed stabilizer may further include a portion of the phosphorus based stabilizer content necessary to stabilize the polymer. The invention also relates to a method for the preparation of the stabilized polymer compositions provided by the use thereof.Type: ApplicationFiled: March 17, 2014Publication date: February 4, 2016Applicant: BAERLOCHER GMBHInventors: Steven R. TORCHIA, Rich HUDSON, Tatiana ROMANOVA
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Publication number: 20160032079Abstract: This invention relates to compositions comprised of diene-based elastomers containing an antioxidant comprised of a combination of tris(nonyl phenyl) phosphite (TNPP) and tetramethylethylene diamine (TMEDA). The invention further relates a rubber composition and to a polystyrene composite containing such elastomer compositions. The invention additionally relates to articles of manufacture thereof, including tires and polystyrene based articles. In one embodiment, the invention relates to a process of recovery of diene-based elastomer(s) from an organic solvent solution thereof by steam stripping the organic solvent therefrom in the presence of a combination of the TNPP and TMEDA.Type: ApplicationFiled: July 30, 2014Publication date: February 4, 2016Inventors: Tang Hong Wong, Ryan Matthew Plocinik, David Bruce Botts
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Publication number: 20160032080Abstract: The present invention relates to a liquid (meth)acrylic syrup for impregnating a fibrous substrate. The present invention relates in particular to a viscous liquid syrup mainly containing methacrylic or acrylic components. The invention also relates to a process for manufacturing such a syrup. The invention also relates to a process for impregnating a fibrous substrate or long fibers with said viscous liquid syrup. The invention also relates to a fibrous substrate preimpregnated with said syrup, which is useful for manufacturing mechanical or structured parts or products. The present invention also relates to a manufacturing process for manufacturing mechanical or structured parts or articles and to three-dimensional mechanical or structured parts obtained by this process. The invention applies to the preparation of mechanical parts or structural elements made of fire-resistant thermoplastic composite material.Type: ApplicationFiled: March 10, 2014Publication date: February 4, 2016Inventors: Pierre GERARD, Michel GLOTIN, Jean-Pierre CAUCHOIS, Claire QUINTEN, Marius MIHALUTA, Qing LIN, Michel FERRIOL, Marianne COCHEZ
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Publication number: 20160032081Abstract: The present invention provides a polyvinyl alcohol aqueous solution capable of suppressing contamination by components other than polyvinyl alcohol to form a film that contains few air bubbles and is excellent in adhesion to a base material, and a laminated film formed of the polyvinyl alcohol aqueous solution. The present invention relates to a polyvinyl alcohol aqueous solution including polyvinyl alcohol, a surface tension regulator, and water, the surface tension regulator being at least one selected from the group consisting of a polyether silicone compound, a glycerol compound, a cyclic hydrocarbon compound, a propylene glycol compound, and a fatty acid ester compound, the polyvinyl alcohol aqueous solution containing 500 to 10000 parts by weight of water based on 100 parts by weight of the polyvinyl alcohol and having a surface tension of 45 to 72 mN/m.Type: ApplicationFiled: April 30, 2014Publication date: February 4, 2016Applicant: SEKISUI CHEMICAL CO., LTD.Inventor: Yasuyuki IEDA
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Publication number: 20160032082Abstract: Provided is a composite fiber in which a polyamide resin fiber and a continuous reinforcing fiber are dispersed. A composite fiber comprising (A) a polyamide resin fiber made from a polyamide resin composition, (B) a continuous reinforcing fiber, and (a) a treating agent for the polyamide resin fiber (A); wherein an amount of the treating agent (a) is 0.1 to 2.0% by mass of the polyamide resin fiber (A); and the polyamide resin composition comprises a polyamide resin containing a diamine structural unit, 50 mol % or more of which is derived from xylylenediamine, and having a number average molecular weight (Mn) of 6,000 to 30,000; and 0.5 to 5% by mass of the polyamide resin has a molecular weight of 1,000 or less.Type: ApplicationFiled: February 7, 2014Publication date: February 4, 2016Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Nobuhiko Matsumoto, Jun Mitadera
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Publication number: 20160032083Abstract: The present invention relates to transparent chips for artificial marble and artificial marble including the same. The transparent chips for artificial marble include (A) a halogenated epoxy acrylate resin and (B) metal fibers. The transparent chips are fabricated by adding metal fibers to a transparent resin. The transparent chips for artificial marble can implement both linear stripe patterns and three-dimensional effects inherent thereto, thereby providing an aesthetically pleasing appearance.Type: ApplicationFiled: July 28, 2015Publication date: February 4, 2016Inventors: Doo Kyo JEONG, Chang Ho SON, Dong Jun KIM, Chang Ho SHIN
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Publication number: 20160032084Abstract: A carbon material for bearings includes a porous carbon base material and an impregnation material. The impregnation material is made of resin or metal, and with which the carbon base material is impregnated. The carbon material for bearings includes a plurality of pores. When a pore distribution in the carbon material for bearings is measured by a mercury penetration method using a mercury porosity meter, a cumulative pore volume of pores having a diameter larger than 0.1 ?m is not more than 8 mm3/g.Type: ApplicationFiled: March 25, 2014Publication date: February 4, 2016Applicant: TOYO TANSO CO., LTD.Inventors: Yasuhisa Ogita, Motoaki Akiyama
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Publication number: 20160032085Abstract: Provided is a polyarylene sulfide resin composition which is good in strength, dimensional stability, and moldability in terms of a molded body thereof and is also capable of reducing wearing of a mold or molding machine at the time of molding of a molded body. The polyarylene sulfide resin composition contains 100 parts by mass of a polyarylene sulfide resin and 150 to 400 parts by mass of a glass bead, a sodium content of the polyarylene sulfide resin being 1,200 ppm or less, and the glass bead being surface-treated with a vinylsilane or an epoxysilane and having an average particle diameter of 30 ?m or less and a ratio between a cumulative 10% particle diameter and a cumulative 90% particle diameter {(cumulative 90% particle diameter)/(cumulative 10% particle diameter)} of 2.5 or more.Type: ApplicationFiled: March 28, 2014Publication date: February 4, 2016Applicant: LION IDEMITSU COMPOSITES CO., LTD.Inventors: Satoru KINOUCHI, Naoto OKUBO
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Publication number: 20160032086Abstract: Provided are a rubber composition provided with excellent reinforcement properties by improving the dispersibility of fibers in a rubber component when the fibers are added to the rubber, a method for manufacturing the same, a vulcanized rubber, and a tire. A rubber composition comprising a rubber component and short fibers, wherein the short fibers are cationized. A method for manufacturing the rubber composition, comprising a mixing step for mixing cationized short fibers and rubber latex to prepare a rubber-short fiber mixed solution, and a drying step for drying the rubber-short fiber mixed solution to give a rubber composition.Type: ApplicationFiled: March 14, 2014Publication date: February 4, 2016Applicants: OJI HOLDINGS CORPORATION, BRIDGESTONE CORPORATIONInventors: Saaya TAKAOKA, Hideko AKAI, Rie SHIRAHAMA, Yasutomo NOISHIKI, Yuichi NOGUCHI
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Publication number: 20160032087Abstract: Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluorine-containing polymer comprising an end-group having a structures from group consisting of: and combinations thereof; wherein X1, X2, and X3 are each independently selected from H, F, Cl, a C1 to C4 alkyl group, and a C1 to C4 fluorinated alkyl group; R7 is a linking group comprising at least 2 or more catenary atoms; and Z1 and Z2 are independently selected from F, CF3, and a perfluoroalkyl group.Type: ApplicationFiled: October 15, 2015Publication date: February 4, 2016Inventors: Claude Lavallée, Gregg D. Dahlke, Denis Duchesne, Tatsuo Fukushi, Werner M.A. Grootaert, Miguel A. Guerra, Zai-Ming Qiu
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Publication number: 20160032088Abstract: Disclosed is a polyethylene composition having faster crystallization rate and improved environmental stress cracking resistance. The polyethylene composition comprises a multimodal polyethylene and a nucleating agent. The multimodal polyethylene comprises from 25 to 50 wt % of a low molecular weight ethylene homopolymer component, from 25 to 50 wt % of a medium molecular weight ethylene copolymer component and from 25 to 50 wt % of a high molecular weight ethylene copolymer component. The polyethylene composition has an environmental stress cracking resistance (ASTM D1693, Condition B in 100% Igepal) greater than or equal to 40 days and a crystallization half time less than or equal to 70% of the crystallization half time of the multimodal polyethylene without nucleating agent.Type: ApplicationFiled: October 12, 2015Publication date: February 4, 2016Inventor: SAMEER D. MEHTA