Patents Issued in September 20, 2016
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Patent number: 9446352Abstract: An object of this invention is to provide an atmosphere-cleaning device for vehicles that is capable of restoring the function of an ozone purifying body carried by a vehicle component. Mud, dust, snow-melting agents as well as SOx and NOx are scattered into the atmosphere as a result of being swirled up by a preceding vehicle or due to weather and climate conditions. When such extraneous substances adhere or the like to an ozone purifying body, the purification sites thereof are clogged and the ozone purification function deteriorates. Therefore, when a predetermined removal implementation condition is established, control is executed to inject cleaning liquid from an injector to enhance the fluidity of the extraneous substances and wash the extraneous substances away. The function of the ozone purifying body can thereby be restored.Type: GrantFiled: November 14, 2012Date of Patent: September 20, 2016Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Makoto Tomimatsu, Koichi Hoshi, Yoshihisa Shinoda, Kazuhiro Sugimoto, Takuya Ookubo
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Patent number: 9446353Abstract: An object of the present invention is to provide a catalyst for treating exhaust gas adapted not only to remove CO and VOCs based on unsaturated hydrocarbons such as C2H4 but also to accelerate a decomposition reaction of saturated hydrocarbons such as propane and to provide a method for producing such a catalyst for treating exhaust gas. The present invention provides a catalyst for treating an exhaust gas containing carbon monoxide and volatile organic compounds, the catalyst comprising a substrate containing a NOx removal catalyst component and a porous inorganic compound layer containing a noble metal, the layer being applied to the substrate.Type: GrantFiled: February 12, 2007Date of Patent: September 20, 2016Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Katsumi Nochi, Masanao Yonemura, Yoshiaki Obayashi, Hitoshi Nakamura, Toshio Koyanagi
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Patent number: 9446354Abstract: A product concentration device that utilizes a reservoir connected to a hollow-fiber filter element where the reservoir can serve as a container for filtrate emanating from another filtering device, such that product in the reservoir can be stored, concentrated and/or further processed as desired. Enclosed reactor systems, each of at least three chambers, fluid flow between the chambers controlled by selectively permeable barriers, flow controlled by an alternating flow diaphragm pump.Type: GrantFiled: February 29, 2012Date of Patent: September 20, 2016Assignee: Repligen CorporationInventor: Jerry Shevitz
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Patent number: 9446355Abstract: Membranes comprising first and second surfaces, the first surface comprising a patterned surface comprising peaks and valleys, first region surfaces comprising peaks, and second region surfaces comprising valleys; a porous bulk between the surfaces, the bulk comprising first region bulks and second region bulks; the region bulks extending from their respective region surfaces, the first region bulks comprising a first set of pores having outer rims, and a second set of pores connecting the outer rims of the first set of pores, and a first polymer matrix supporting the first set of pores; the second region bulks comprising a third set of pores having outer rims, and a fourth set of pores connecting the outer rims of the third set of pores, and a second polymer matrix supporting the third set of pores; filters including the membranes, and methods of making and using the membranes, are disclosed.Type: GrantFiled: February 28, 2014Date of Patent: September 20, 2016Assignee: PALL CORPORATIONInventors: Geoffrey P. LaRue, Yolando David, Shane Edward Harton
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Patent number: 9446356Abstract: An apparatus, system, and method of dispersing solid forms of drugs or medications reliably and consistently may generally employ ultrasonic energy. The disclosed embodiments facilitate preparation of a liquid dose from solid medications for administration to a patient.Type: GrantFiled: November 2, 2015Date of Patent: September 20, 2016Assignee: Disperse Systems, Inc.Inventor: Henry Milner
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Patent number: 9446357Abstract: An aeration apparatus includes an injection nozzle provided at one of the open ends of a main body formed in the shape of a cylinder. When the injection nozzle is immersed in a liquid, the main body stands upright such that the injection nozzle is on a lower side, and gas is injected inside the main body from the injection nozzle to disperse the gas. The injection nozzle is disposed such that a center line of an injection port formed at the tip of the injection nozzle intersects the inner flow channel surface at a position lower than a blade member disposed in the lowest stage, and such that the angle formed between the center line and the vertical direction is not greater than 45 degrees.Type: GrantFiled: May 14, 2013Date of Patent: September 20, 2016Assignee: SOLACE CO., LTD.Inventors: Yasuhiko Masuda, Hiroyasu Masuda
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Patent number: 9446358Abstract: This invention relates to a process and an apparatus for mixing a fluid or a liquid within a vessel or a tank. The invention includes an apparatus with an inlet device and a mixer. The invention mixes crude oils and/or other hydrocarbon materials to a homogenous state with surprising and unexpected high efficiency. The invention includes methods of using the apparatus to mix the contents of the vessel and/or two stratified materials. The invention includes the ability to mix materials having disparities in density and/or viscosity.Type: GrantFiled: November 20, 2014Date of Patent: September 20, 2016Assignee: BP Corporation North America Inc.Inventor: Daniel C. Coy
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Patent number: 9446360Abstract: A method and chip for fusing droplets in a chip comprising (i) providing a first set of droplets which are partially or not stabilized by surfactant, (ii) providing a second set of droplets which are stabilized by surfactant, (iii) contacting each droplet of the first set with single or multiple droplets of the second set in a pairing module and (iv) fusing droplets of the first set with droplets of the second set through a droplet fusion module in which the droplets experience at least one acceleration and/or deceleration and/or reorientation and/or rearrangement in space and time.Type: GrantFiled: May 7, 2010Date of Patent: September 20, 2016Assignees: UNIVERSITE DE STRASBOURG, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFQUEInventor: Linas Mazutis
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Patent number: 9446361Abstract: A method of controlling coffee density exiting from a coffee densifier is disclosed. The method includes the steps of feeding a ground coffee into a mixing chamber having a discharge door. A mixer motor load on a mixer motor driving mixing members agitating the ground coffee in the mixing chamber is measured. The discharge door is moved when the mixer motor load is outside a predefined mixer motor load operating range.Type: GrantFiled: July 10, 2012Date of Patent: September 20, 2016Assignee: Modern Process Equipment, Inc.Inventors: Daniel Richard Ephraim, Christopher Martin Spatz
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Patent number: 9446362Abstract: The present invention concerns a process for unloading a bed (2) of particulate material from a vessel (1), which comprises inserting a removable and portable extraction pipe (4) into the lower part of said bed, injecting a fluidization gas upwardly into the extraction pipe (4) from the bottom part thereof, along the entire length of the extraction pipe (4), and applying a positive pressure differential between the inlet and the outlet of said extraction pipe. The present invention further concerns a device suitable for implementing such a process.Type: GrantFiled: September 9, 2013Date of Patent: September 20, 2016Assignee: PETROVALInventor: Adriaan Stander
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Patent number: 9446363Abstract: A methanol carbonylation system 10 includes an absorber tower 75 adapted for receiving a vent gas stream and removing methyl iodide therefrom with a scrubber solvent, the absorber tower being coupled to first and second scrubber solvent sources 16, 56 which are capable of supplying different first and second scrubber solvents. A switching system including valves 90, 92, 94, 96, 98 alternatively provides first or second scrubber solvents to the absorber tower and returns the used solvent and sorbed material to the carbonylation system to accommodate different operating modes.Type: GrantFiled: November 20, 2012Date of Patent: September 20, 2016Assignee: Celanese International CorporationInventors: Raymond J. Zinoble, Tommy W. Doggett, Lun-kuang Liu
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Patent number: 9446364Abstract: Systems and methods for storing and handling slurries are provided. The surge drum system for storing a slurry can include a storage vessel having a first end, a second end, and at least one wall surrounding an internal volume between the first and second ends. The system can also include a slurry inlet and a slurry outlet, both in fluid communication with the internal volume. A recirculation inlet can be in fluid communication with the internal volume at the first end of the storage vessel. The system can also include a pump having a suction line in fluid communication with the outlet. A discharge line of the pump can be in fluid communication with an outlet valve and a recirculation valve that can be in fluid communication with the recirculation inlet.Type: GrantFiled: February 23, 2012Date of Patent: September 20, 2016Assignee: KELLOGG BROWN & ROOT LLCInventor: Gary L. Mason
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Patent number: 9446365Abstract: A Sabatier process involving contacting carbon dioxide and hydrogen in a first reaction zone with a first catalyst bed at a temperature greater than a first designated temperature; feeding the effluent from the first reaction zone into a second reaction zone, and contacting the effluent with a second catalyst bed at a temperature equal to or less than a second designated temperature, so as to produce a product stream comprising water and methane. The first and second catalyst beds each individually comprise an ultra-short-channel-length metal substrate. An apparatus for controlling temperature in an exothermic reaction, such as the Sabatier reaction, is disclosed.Type: GrantFiled: February 28, 2014Date of Patent: September 20, 2016Assignee: PRECISION COMBUSTION, INC.Inventors: Christian Junaedi, Kyle Hawley, Subir Roychoudhury
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Patent number: 9446366Abstract: A modular flow reactor is formed of a plurality of modules, wherein each module comprises a body having at least one conduit passing therethrough, and wherein a plurality of said modules are aligned along a longitudinal axis such that said conduits of said modules are aligned to form a passage for fluid, wherein each module has a length along said longitudinal axis which is less than the length of the module perpendicular to the longitudinal axis. The modules are “slices” rather than “tubes” and a plurality of said modules can be aligned linearly so that the conduits form a tube.Type: GrantFiled: October 4, 2012Date of Patent: September 20, 2016Assignee: Brunel UniversityInventors: Charalampos Makatsoris, Leonid Paramonov, Rakan Alsharif
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Patent number: 9446367Abstract: Segmented silicon carbide liners for use in a fluidized bed reactor for production of polysilicon-coated granulate material are disclosed, as well as methods of making and using the segmented silicon carbide liners. Non-contaminating bonding materials for joining silicon carbide segments also are disclosed. One or more of the silicon carbide segments may be constructed of reaction-bonded silicon carbide.Type: GrantFiled: August 15, 2014Date of Patent: September 20, 2016Assignee: REC Silicon IncInventors: Matthew J. Miller, Michael V. Spangler, Gerald A. Zeininger, William J. Onstot, Walter J. Stupin
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Patent number: 9446368Abstract: A mixing device used in a fluidized catalytic cracking apparatus which mixes feed and a catalyst includes a cylindrical reaction container which supplies a catalyst in a vertical direction; a plurality of feed injection nozzles arranged along an outer circumference of the reaction container; and a catalyst flow regulator which is provided in the reaction container and regulates a flow of the catalyst in the vicinity of the feed injection nozzles. The catalyst flow regulator has no feed supply function and forms a catalyst moving bed having a hollow tubular shape which is coaxial with the reaction container in the vicinity of the feed injection nozzles. The catalyst flow regulator can effectively prevent backward flow of injected fuel. Although the mixing device has a simple structure, it has a high cracking rate and maintenance of the fluidized catalytic cracking apparatus can be performed easier.Type: GrantFiled: September 9, 2014Date of Patent: September 20, 2016Assignee: JX NIPPON OIL & ENERGY CORPORATIONInventors: Koji Shimada, Naoya Saito
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Patent number: 9446369Abstract: Apparatuses and processes are provided for stripping gaseous hydrocarbons from particulate material. One process comprises the step of contacting particles containing hydrocarbons with a stripping vapor in countercurrent flow to remove at least a portion of the hydrocarbons with the stripping vapor to form stripped particles. Contacting the particles includes advancing the particles down a sloping element of a structured packing toward a reinforcing rod that is disposed along a lower channel portion of the sloping element. The particles are advanced over the reinforcing rod. The particles are contacted with the stripping vapor that is rising up adjacent to the lower channel portion.Type: GrantFiled: January 15, 2015Date of Patent: September 20, 2016Assignee: UOP LLCInventors: Erick D. Gamas-Castellanos, Mitchell J. Kowalczyk
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Patent number: 9446370Abstract: The invention relates to a reactor system, comprising a heat-exchange unit and a reaction unit that are assembled together into a structure. The heat-exchange unit has a plurality of plate or corrugated-plate heat exchangers, and is formed so as to attachable/detachable to/from the reaction unit and insertable into the latter. Accordingly, a catalyst may be attached to a heat-transfer surface of a heat exchanger by a washcoat method or the like, thus maximizing heat-transfer efficiency and enabling the easy removal or reattachment of the catalyst when the enabling the easy removal or reattachment of the catalyst at the end of the lifespan of the catalyst.Type: GrantFiled: April 18, 2012Date of Patent: September 20, 2016Assignee: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYInventors: Kyoung Su Ha, Geun Jae Kwak, Jae-Hoon Jung, Joo Young Cheon, Ki Won Jun
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Patent number: 9446371Abstract: A substance is treated using a device having: (a) a volute or cyclone head, (b) a throat connected to the volute or cyclone head, (c) a parabolic reflector connected to the throat, (d) a first wave energy source comprising a first electrode within the volute or cyclone head that extends through the outlet into the opening of the throat along the central axis, and a second electrode extending into the parabolic reflector and spaced apart and axially aligned with first electrode, and (e) a second wave energy source disposed inside the throat, embedded within the throat or disposed around the throat. The substance is directed to the inlet of the volute or cyclone head and irradiated with one or more wave energies produced by the first and second wave energy sources as the substance passes through the device.Type: GrantFiled: May 16, 2014Date of Patent: September 20, 2016Assignee: Foret Plasma Labs, LLCInventor: Todd Foret
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Patent number: 9446372Abstract: An apparatus for growing nano-clusters includes a pair of electrodes separated by an electrode pair spacing and a field generation module that generates a corona discharge across the electrodes. The corona discharge generates an electromagnetic field near the electrodes. A voltage potential across the electrodes is a medium voltage. The field generation module includes a medium voltage module that generates a medium voltage waveform, which is transmitted to the electrodes to generate the corona discharge. The field generation module includes a broad frequency generation module that generates a broad spectrum of frequencies within the medium voltage waveform. A raw material feeder module feeds particles of a raw material through the electromagnetic field. The electromagnetic field with the broad spectrum of frequencies is operative to separate at least a portion of the raw material fed through the electromagnetic field into free atoms.Type: GrantFiled: June 16, 2014Date of Patent: September 20, 2016Assignee: JTW, LLC.Inventor: James T Wilkinson
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Patent number: 9446373Abstract: It is described a process for the production of hexamethylenediamine by hydrogenation of adiponitrile, comprising an improved step of regeneration of the catalyst. Also described are an equipment for the production of hexamethylenediamine, and a washing apparatus (14) for implementing the catalyst regeneration step.Type: GrantFiled: December 9, 2014Date of Patent: September 20, 2016Assignee: Radici Chimica S.p.A.Inventors: Tommaso Crippa, Stefano Alini, Luciano Guida, Alberto Corona
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Patent number: 9446374Abstract: The present invention relates to a residence time plate comprising a stack of at least two substantially parallel and elongated flow chambers arranged such that the elongated side of each flow chamber lies next to the elongated side of a neighboring flow chamber and is separated by said neighboring chamber by a separation wall. Each separation wall has at least one through hole forming a communication between two neighboring flow chambers, and the through holes are arranged in the separation walls on alternating sides of an imaginary central line drawn through the stack of flow chambers such that the flow direction in a flow chamber is along the extension of the flow chamber and opposite the flow direction of a neighboring chamber. Moreover, the residence time plate comprises at least one liquid inlet and at least one liquid outlet arranged such that liquid flowing from said inlet to said outlet passes through the stack of flow chambers.Type: GrantFiled: March 14, 2013Date of Patent: September 20, 2016Assignee: ALFA LAVAL CORPORATE ABInventors: Magnus Lingvall, Kasper Höglund
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Patent number: 9446375Abstract: The present invention discloses a flow reactor composed of plurality of modular/fluidic components that helps retain agility and re-configurability of the continuous chemical processes with improved processing ability. More specifically, disclosed herein is a continuous flow reactor composed of varied permutations and combinations of a plurality of modular/fluidic components for chemical processing. The components are connected to each other using connectors that facilitate the connection of either with two or more, similar or different components.Type: GrantFiled: October 15, 2012Date of Patent: September 20, 2016Assignee: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCHInventors: Amol Arvind Kulkarni, Vivek Vinayak Ranade
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Patent number: 9446376Abstract: An embodiment of the present invention is directed to a pyrolysis device including a reactor in which an injected raw material and a melted liquid metal are present together, a circulating pump connected to the reactor, a buffer tank disposed on an upper portion of the reactor and receiving the liquid metal from the circulating pump, a nozzle coupled with the buffer tank and jetting the liquid metal within the buffer tank into the reactor, a separating apparatus separating pyrolyzed char and slag, and a combustion furnace connected to the reactor to combust the fuel supplied from the reactor and supply heat to the reactor, thereby reacting the liquid metal sprays jetted from the nozzle with gases generated in the reactor to purify the gases.Type: GrantFiled: November 9, 2012Date of Patent: September 20, 2016Assignee: Korea Institute of Industrial TechnologyInventors: Uen Do Lee, Won Yang, Dong Ho Park, Ji Hong Moon, Chang Won Yang
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Patent number: 9446377Abstract: A continuous reactor vessel for a rotary reactor having a first disk and a second disk separating three zones wherein the first disk includes a material feed opening spaced from its peripheral edge by an inlet peripheral spacing and configured to receive a material inlet tube, the second disk including an axial extension spaced from the second peripheral edge having at least one axially extending side wall and an end cap with at least one reaction zone discharge opening in the extension. The at least one opening allowing for a continuous and controlled reactor discharge rate of the associated granular product from the reaction zone into the discharge zone, the discharge opening being spaced from the second peripheral edge by an outlet peripheral spacing such that the peripheral spacings define a controlled depth of a dead bed accumulation of the associated granular product in the reaction zone.Type: GrantFiled: October 25, 2013Date of Patent: September 20, 2016Assignee: Unimin CorporationInventors: Michael McKinney, Shane McMahan, Cameron McQueen
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Patent number: 9446378Abstract: The present disclosure provides an assembled stack of fluidic modules comprising at least first and second fluidic modules assembled in a stacked configuration. The first fluidic module has first and second major planar surfaces and encloses a first fluidic passage extending therethrough from a first passage entrance to a first passage exit with the first passage exit located on the second major planar surface of the first fluidic module. The second fluidic module also has first and second major planar surfaces and encloses a second fluidic passage extending therethrough from a second passage entrance to a second passage exit, with the second passage entrance located on the first major planar surface of the second fluidic module.Type: GrantFiled: November 30, 2012Date of Patent: September 20, 2016Assignee: CORNING INCORPORATEDInventors: Thierry Luc Alain Dannoux, Sylvain Maxime F. Gremetz, Olivier Lobet, Ronan Tanguy
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Patent number: 9446379Abstract: An improved scintillation detector capable of withstanding harsh operating environments includes a scintillator in a sealed casing having an atmosphere with an oxygen content not greater than about 100 ppb and an oxygen scavenger in the atmosphere within the sealed casing. The scintillator can include a material that may be damaged by exposure to oxygen. The oxygen scavenger can include an oxidizable compound.Type: GrantFiled: June 27, 2014Date of Patent: September 20, 2016Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.Inventors: Kan Yang, Peter R. Menge
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Patent number: 9446380Abstract: Provided are a water-blocking filler, the swelling properties of which do not decrease easily even when in contact with water containing calcium ions, and a filler for engineered multi-barriers with said water-blocking filler as the engineered multi-barrier filler. A water-blocking filler mainly comprising sodium bentonite obtained by mixing 30 weight % or less, in terms of inner percentage, of a pozzolan substance such as fly ash or silica fume with said bentonite, and a filler using said water-blocking filler that is used for engineered multi-barriers in radioactive waste disposal facilities.Type: GrantFiled: October 26, 2011Date of Patent: September 20, 2016Assignees: GUNMA UNIVERSITY, DC CO., LTD.Inventors: Kenichiro Nakarai, Kiyoshi Koibuchi, Nobukazu Nito
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Patent number: 9446381Abstract: This disclosures provides an adsorbent which, on the basis of the total weight of the adsorbent, comprises: 1) a Si—Al molecular sieve having an A-FAU structure, wherein A represents a monovalent cation, in an amount of 1-20 wt %, 2) at least one binder selected from the group consisting of titanium dioxide, stannic oxide, zirconium oxide and alumina, in an amount of 3-35 wt %, 3) a silica source, in an amount of 5-40 wt %, 4) zinc oxide, in an amount of 10-80 wt %, and 5) at least one promoter metal selected from the group consisting of cobalt, nickel, iron and manganese, based on the metal, in an amount of 5-30 wt %, wherein at least 10 wt % of the promoter metal is present in a reduced valence state. This adsorbent exhibits improved activity and stability, and at the same time, is capable of significantly improving the octane number of the product gasoline.Type: GrantFiled: July 27, 2012Date of Patent: September 20, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Wei Lin, Huiping Tian, Zhenbo Wang
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Patent number: 9446382Abstract: The present invention provides a porous cellulose gel having a high mechanical strength capable of being operated at a higher flow rate, and a method for producing the same. To a suspension liquid of cellulose particles, a crosslinking agent in an amount of from 4 to 12 times the amount of the cellulose monomer in terms of moles and an alkali in an amount of from 0.1 to 1.5 times the amount of the crosslinking agent in terms of moles are added continuously dropwise or added dividedly over a prescribed period of time, whereby flow rate characteristics of a resulting porous cellulose gel can be enhanced. According to the invention, the production efficiency of a polymer substance, such as a nucleic acid and a protein can be enhanced.Type: GrantFiled: January 14, 2014Date of Patent: September 20, 2016Assignee: JNC CORPORATIONInventors: Yasuto Umeda, Yasuo Matsumoto, Masami Shiina, Masami Todokoro, Yoshihiro Matsumoto
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Patent number: 9446383Abstract: The system and method requiring a diverter plate for an in-line mill. The plate for use with the in-line mill includes an aperture for passage of particulate laden fluid therethrough and a plurality of tabs such that the fluid and the particulate entrained thereon is deflected at a variety of axial angles. The diverter plate thus provides a reliable method such that the milling process and component wear resistance is made more efficient thereby.Type: GrantFiled: May 27, 2015Date of Patent: September 20, 2016Assignee: UCC Dry Sorbent Injection LLCInventors: Dennis Engelmann, Stephen Bosshart, Eric Fleckten, Harun Bilirgen, Robert LeDain
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Patent number: 9446384Abstract: The present invention provides a process for regeneration of the sulfur capturing spent adsorbents after sulfur capturing using a hydrolyzing agent under adiabatic conditions. In accordance with the process of the present invention hydrolyzing agent is introduced to the spent adsorbent in a controlled manner such that the exothermic heat generated within the adsorbent bed does not rise above the predetermined temperature limit.Type: GrantFiled: December 14, 2011Date of Patent: September 20, 2016Assignee: Reliance Industries LimitedInventors: Asit Das, Ajay Gupta, Bharat Kumar Vaja, Govind Tulsi, Harender Bisht, Jeyavel Sinha, Shubhangi Jagutse, Sukumar Mandal
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Patent number: 9446385Abstract: This invention relates to the cleaning of flue gas released from various combustion processes, particularly a surface deposition NH3—SCR honeycomb catalyst and its preparation method. The catalyst is composed of framework material, TiO2, V2O5 and WO3, wherein the framework material is composed of clay, coal ash, mineral waste residue or their mixture. The mass fractions for framework material, TiO2, V2O5, and WO3 are 60 wt. % to 80 wt. %, 13 wt. % to 33 wt. %, 1 wt. % to 5 wt. %, and 0.1 wt. % to 2 wt. %, respectively. The nano V2O5—WO3—TiO2 particles were deposited on the surface of particle pore or honeycomb, and the performance of the catalyst could be greatly improved.Type: GrantFiled: September 23, 2011Date of Patent: September 20, 2016Assignee: Institute of Process Engineering, Chinese Academy of SciencesInventors: Jian Yu, Feng Guo, Juan Yang, Yin Wang, Li Dong, Shiqiu Gao, Guangwen Xu
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Patent number: 9446386Abstract: The present invention relates to methods for producing metal-supported thin layer skeletal catalyst structures, to methods for producing catalyst support structures without separately applying an intermediate washcoat layer, and to novel catalyst compositions produced by these methods. Catalyst precursors may be interdiffused with the underlying metal support then activated to create catalytically active skeletal alloy surfaces. The resulting metal-anchored skeletal layers provide increased conversion per geometric area compared to conversions from other types of supported alloy catalysts of similar bulk compositions, and provide resistance to activity loss when used under severe on-stream conditions. Particular compositions of the metal-supported skeletal catalyst alloy structures can be used for conventional steam methane reforming to produce syngas from natural gas and steam, for hydrodeoxygenation of pyrolysis bio-oils, and for other metal-catalyzed reactions inter alia.Type: GrantFiled: October 11, 2012Date of Patent: September 20, 2016Assignee: ALLOY SURFACES COMPANY, INC.Inventors: Vincent A. Durante, Rajinder Gill, Andrew Davis, Elaine C. Soltani
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Patent number: 9446387Abstract: Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.Type: GrantFiled: April 21, 2015Date of Patent: September 20, 2016Assignee: Siluria Technologies, Inc.Inventors: Joel M. Cizeron, Erik C. Scher, Fabio R. Zurcher, Wayne P. Schammel, Greg Nyce, Anja Rumplecker, Jarod McCormick, Marian Alcid, Joel Gamoras, Daniel Rosenberg, Erik-Jan Ras
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Patent number: 9446388Abstract: Disclosed is a metal complex including: a tin oxide; titanium oxide nanorods in a rutile phase formed on the tin oxide; and titanium oxide nanoparticles in an anatase phase formed on the titanium oxide nanorods in a rutile phase, and a preparation method thereof, and can be used as a catalyst support in various forms.Type: GrantFiled: July 30, 2014Date of Patent: September 20, 2016Assignee: Korea Institute of Energy ResearchInventors: Kwang Bok Yi, Soon Jin Kwon, Nu Ri Jeon, Hyun-Seog Roh, Wang Lai Yoon, Kee Young Koo, Un-Ho Jung, Woohyun Kim
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Patent number: 9446389Abstract: A method for forming a catalyst can comprise: heating a Ge-ZSM-5 zeolite powder at a temperature of 400 to 600° C.; ion-exchanging the heat-treated zeolite powder with an alkali metal and impregnating the heat-treated zeolite powder with noble metal; heating the ion-exchanged, impregnated zeolite powder to a temperature of 250 to 350° C.; mixing the second heat-treated zeolite powder with a solid silica binder and a colloidal silica binder to form a mixture, wherein if the solid silica has a purity of less than or equal to 66 wt % of silica oxide based on the total weight of the solid silica, then the mixture is free of an extrusion aide and the colloidal silica has a particle size of less than 20 nm as measured along a major axis; forming the mixture into a shaped body; and heating the shaped body to 100 to 350° C. to result in the catalyst.Type: GrantFiled: December 13, 2013Date of Patent: September 20, 2016Assignee: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Ashim Kumar Ghosh, Scott Stevenson, David Sullivan, Corina Mihut, Neeta Kulkarni, Meghann Simmons, Michael Mier
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Patent number: 9446390Abstract: The present invention relates to a process for preparing acrylic acid comprising (i) providing a stream comprising a formaldehyde source and acetic acid and (ii) contacting this stream with an aldol condensation catalyst comprising a zeolitic material, wherein the framework structure of the zeolitic material in (ii) includes Si and O, and has a molar Al:Si ratio of 0:1 to 0.001:1, and wherein the framework structure of the zeolitic material in (ii), in addition to Si and any Al, comprises one or more elements selected from the group consisting of tetravalent elements Y other than Si and trivalent elements X other than Al.Type: GrantFiled: May 28, 2015Date of Patent: September 20, 2016Assignee: BASF SEInventors: Andrei-Nicolae Parvulescu, Armin Lange De Oliveira, Michael Lejkowski, Nicolai Tonio Woerz, Marco Hartmann, Kazuhiko Amakawa, Michael Goebel, Ulrich Mueller, Mathias Feyen, Yong Liu
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Patent number: 9446391Abstract: The invention relates to a process for producing a protected reduced supported metal catalyst powder, in particular catalysts used in a variety of chemical reactions, such as the hydrogenation of hydrocarbon compounds in petrochemical and oleochemical processes; the hydrogenation of unsaturated fats and oils, and unsaturated hydrocarbon resins; and in the Fischer Tropsch process. This invention also relates to a composition comprising said catalyst and a liquid. In accordance with the invention there is provided a process for preparing a protected, reduced metal catalyst on a support, wherein said supported catalyst is in the form of a powder, which process comprises contacting and mixing said supported catalyst with a liquid in an inert atmosphere and wherein the amount of liquid corresponds to up to five times the amount required for incipient wetness.Type: GrantFiled: December 14, 2012Date of Patent: September 20, 2016Assignee: BASF CORPORATIONInventors: Robert Johan Andreas Maria Terörde, Albertus Jacobus Sandee
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Patent number: 9446392Abstract: The invention relates to a method for preparing particles comprising a material capable of catalyzing the reduction of oxygen or the oxidation of hydrogen, said particles being functionalized by polymers comprising at least one repeating unit bearing at least one proton-conducting group, and said particles being covalently bonded to a carbon material, said method comprising: a step a) of contacting particles, comprising a material capable of catalyzing the reduction of oxygen or the oxidation of hydrogen, with a polymer comprising at least one repeating unit bearing at least one proton-conducting group and comprising at least one portion corresponding to an organic radical of a compound that is an initiator for ATRP polymerization, said radical comprising at least one group capable of being grafted onto the surface of said particles, whereby particles, onto which polymers comprising at least one repeating unit bearing at least one proton-conducting group are grafted, are obtained.Type: GrantFiled: November 5, 2012Date of Patent: September 20, 2016Assignees: COMMISARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Pierrick Buvat, Anne-Claire Ferrandez, Steve Baranton, Christophe Coutanceau
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Patent number: 9446393Abstract: In some embodiments, the present disclosure pertains to a compound, comprising a transition metal complex having the formula ?-[M(x,y)-L1(w,v)-L2(t,u)-L3]p+An?mZ?p_m. In an embodiment of the present disclosure ? may be A. In another embodiment ? may be ?. In some embodiments of the present disclosure, M is a transition metal. In a related embodiment, p is an integer corresponding to the oxidation state of M. In some embodiments of the present disclosure, each of x, y, w, v, t, and u independently comprise R. In other embodiments, each of x, y, w, v, t, and u independently comprise S. In an embodiment of the present disclosure, each of L1, L2, and L3 independently is a ligand comprising a substituted diamine. In some embodiments, An? comprises a lipophilic anion, where m is from 1 to 3, and where Z? comprises an optional second anion.Type: GrantFiled: July 29, 2013Date of Patent: September 20, 2016Assignee: THE TEXAS A&M UNIVERSITY SYSTEMInventors: Kyle G. Lewis, John A. Gladysz, Subrata K. Ghosh
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Patent number: 9446394Abstract: The present invention relates generally to olefin metathesis. In some embodiments, the present invention provides methods for Z-selective ring-closing metathesis.Type: GrantFiled: March 6, 2015Date of Patent: September 20, 2016Assignees: Trustees of Boston College, Massachusetts Institute of TechnologyInventors: Amir H. Hoveyda, Miao Yu, Chenbo Wang, Richard R. Schrock
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Patent number: 9446395Abstract: A low-temperature catalyst is provided for reducing cold-start hydrocarbon emissions. The catalyst comprises a platinum group metal impregnated onto an oxygen storage material. The catalyst may be used alone or may be included in a hydrocarbon trap containing a hydrocarbon adsorption material therein. The catalyst/hydrocarbon trap is positioned in the exhaust system of a vehicle downstream from a close-coupled catalyst such that the exhaust temperature at the catalyst location does not exceed 850° C. during normal vehicle operation and when combined with a hydrocarbon adsorption material in a trap, the exhaust temperature does not exceed 700° C.Type: GrantFiled: February 19, 2014Date of Patent: September 20, 2016Assignee: Ford Global Technologies, LLCInventors: Lifeng Xu, Robert Walter McCabe, Jason Aaron Lupescu
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Patent number: 9446396Abstract: The present invention relates to petrochemistry and gas chemistry, and discloses a support for catalysis of exothermic processes, particularly the Fischer-Tropsch process, methanol synthesis, hydrogenation and purification of exhaust gases. The support comprises metallic aluminum in the form of a mixture of dispersed powders of flaky and spherical aluminum and the support is in the form of pellets, preferably cylinders, tablets, balls, obtained by extrusion, pelletization, tabletting, rounding or liquid molding. The catalyst prepared on the support comprises an active metal selected from the group consisting of Co, Fe, Ni, Ru, Rh, Pt, Pd, Cu and mixtures thereof.Type: GrantFiled: August 3, 2010Date of Patent: September 20, 2016Assignee: INFRA XTL TECHNOLOGY LIMITEDInventors: Vladimir Zalmanovich Mordkovich, Lilia Vadimovna Sineva, Igor Grigorievich Solomonik, Vadim Sergeevich Ermolaev, Eduard Borisovich Mitberg
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Patent number: 9446397Abstract: Methods for isolation and/or purification of nanomaterials, such as nanowires, are provided. The disclosed methods include isolation of nanomaterials via a filter press and are amenable to large-scale production of nanomaterials. Related methods for isolation, purification and/or doping of nanomaterials are also provided.Type: GrantFiled: February 1, 2013Date of Patent: September 20, 2016Assignee: Siluria Technologies, Inc.Inventors: Joel Gamoras, Fabio R. Zurcher
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Patent number: 9446398Abstract: A stripping vessel for removing hydrocarbons from a catalyst and a process for removing hydrocarbons from a catalyst. In an FCC unit, the stripping vessel includes first and second stripping sections. The first stripping section includes at least one grid having a plurality of interesting members and openings therebetween. The second stripping section includes structured packing such as a plurality of ribbons. The one or more grids are spaced from the structured packing, and from each other, so as to minimize the accumulation of catalyst within the stripping vessel, preferably between about 0.91 m (3 ft) to about 1.5 m (5 ft).Type: GrantFiled: December 5, 2014Date of Patent: September 20, 2016Assignee: UOP LLCInventors: Paolo Palmas, Andrew Jonathan Craig
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Patent number: 9446399Abstract: One exemplary embodiment can be a process for regenerating catalyst in a fluid catalytic cracking unit. Generally, the process includes providing a feed to a riser of a reaction vessel, and providing a stream to a distributor positioned within a void proximate to an inlet receiving unregenerated catalyst in a regenerator. The feed can include at least one of a gas oil, a vacuum gas oil, an atmospheric gas oil, a coker gas oil, a hydrotreated gas oil, a hydrocracker unconverted oil, and an atmospheric residue.Type: GrantFiled: October 24, 2014Date of Patent: September 20, 2016Assignee: UOP LLCInventors: Daniel N. Myers, Paolo Palmas, David N. Myers
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Patent number: 9446400Abstract: A conjugated polymer is provided, having a structure of formula (I): in formula (I), n is an integer greater than 10, wherein (i) R1 is R2 is wherein A1 is a functional group having a tertiary amine group or a quaternary ammonium salt group, R4 is independently selected from hydrogen, fluorine, alkyl, alkoxy, fluoroalkyl, or fluoroalkoxy, or (ii) R1 is R2 is A2, wherein R3 is independently selected from hydrogen, alkyl, fluoroalkyl, A2, or and A2 is a functional group having a tertiary amine group or a quaternary ammonium salt group, wherein R5 is independently selected from hydrogen, alkyl, alkoxy, or fluoroalkyl.Type: GrantFiled: June 24, 2015Date of Patent: September 20, 2016Assignee: NATIONAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Der-Jang Liaw, Yian Tai, Jyh-Chiang Jiang
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Patent number: 9446401Abstract: A container for ensuring the transport and the aseptic transfer of a biopharmaceutical product from or to a closed chamber provided with a leaktight joining device, includes: an annular flange delimiting an opening, a removable cover, built-in elements for locking/unlocking the removable cover and a peripheral envelope. The built-in locking/unlocking elements include a built-in functional locking/unlocking arrangement formed by a through-housing formed in the annular flange and a blind housing formed in the removable cover, and by a pin at an inner radial position and a pin at an outer radial position. The container is capable of being in an initial locking position, in an intermediate unlocking position and in a final locking position owing to the displacements of the pin at an inner radial position and the pin at an outer radial position in the blind hole of the removable cover and in the through-housing of the annular flange.Type: GrantFiled: July 12, 2012Date of Patent: September 20, 2016Assignee: SARTORIUS STEDIM FMT SASInventor: Gaelle Nodin
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Patent number: 9446402Abstract: A specimen supplying tool in which structure is simple, and a liquid specimen and air bubbles do not remain within a through-bore for introduction of a specimen, is provided. The specimen supplying tool includes a substrate 11 and a through-bore 13 provided in the substrate 11. One opening of the through-bore 13 is a specimen inflow port, and the other opening of the through-bore 13 is a specimen outflow port. The specimen supplying tool further includes a projection portion 14 projecting from a part p of a marginal part of the specimen outflow port. A liquid specimen is introduced from the specimen inflow port to the through-bore 13. When the introduced liquid specimen is discharged from the specimen outflow port, and supplied to a specimen analyzing instrument, the liquid specimen is drawn to the projection portion 14, led by the projection portion 14, and supplied to the specimen analyzing instrument.Type: GrantFiled: July 17, 2008Date of Patent: September 20, 2016Assignee: ARKRAY, Inc.Inventors: Kazuhiro Ohmiya, Kaori Ishizaki