Patents Issued in October 18, 2016
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Patent number: 9469553Abstract: In at least one embodiment, the invention provides a retrofit for existing water treatment systems where the retrofit includes at least one of the following: a particulate separator, a supplementary inlet, and a waveform disk-pack turbine. In a further embodiment, the invention includes a water treatment system combined with at least one of the following: a particulate separator, a supplementary inlet, and a waveform disk-pack turbine.Type: GrantFiled: August 24, 2012Date of Patent: October 18, 2016Assignee: QWTIP, LLCInventor: Whitaker B. Irvin, Sr.
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Patent number: 9469554Abstract: A bipolar electrode comprises an intermediate layer comprising one or more carbon materials. The bipolar electrode further comprises first and second layers disposed on opposite surfaces of the intermediate layer and configured to act as an anode and a cathode. The first and second layers comprise at least one of one or more electrically conductive carbon materials and one or more conductive polymers. A supercapacitor desalination device and a method for making the bipolar electrode are also presented.Type: GrantFiled: July 29, 2009Date of Patent: October 18, 2016Assignee: General Electric CompanyInventors: Liping Zheng, Hai Yang, Wei Cai, Jianyun Liu, Zhigang Deng, Hui Liu, Lin Chen, Xianguo Yu
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Patent number: 9469555Abstract: A method and apparatus for selective removal of heavy ions, biological, cations, anions or other elements of interest from liquids using magnetic nanoparticles, and recovery of nanoparticles to be reused in the wastewater purification. For certain embodiments, after water treatment and magnetic separation, the loaded nanoparticles may be washed, regenerated, collected and re-introduced in the water treatment cycle. Water treatment and particle regeneration take place singly or simultaneously. In another disclosed embodiment of the process, the electricity consumed by the pumping system is supplied by renewable energy sources such as solar, wind, geothermal, biogas or small hydro.Type: GrantFiled: June 19, 2014Date of Patent: October 18, 2016Inventors: Cristian Predescu, Ecaterina Matei, Andra Mihaela Predescu, Andrei Constantin Berbecaru, Ruxandra Vidu
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Patent number: 9469556Abstract: A composition for treating waters, e.g. ballast water or injection water for oil recovery, to kill in-situ aquatic invasive species comprises at least one biocide capable of killing both animal and plant micro-organisms. The at least one biocide preferably comprises Brilliant Green, Gentian Violet, and/or erythrosine, and a wetting agent or detergent-like compound such as CTAB or CTAC. The invention also relates to a system for treating ballast water in situ comprising means for injecting a composition for treating ballast water; means for measuring the flow rate or amount of ballast water to be treated; means for controlling the dosing of the composition; and means for storing or receiving the composition. The invention also relates to a method of detecting viable aquatic organisms in ballast water in situ comprising detecting metabolism in viable micro-organisms in ballast water and, therefore, measuring the efficacy of any treatment.Type: GrantFiled: January 29, 2010Date of Patent: October 18, 2016Assignee: University of StrathclydeInventors: William Stimson, Peilin Zhou, Dracos Vassalos, Atilla Incecik
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Patent number: 9469557Abstract: An ozonating water treatment and filtration apparatus is provided wherein a groundwater containing contaminates including hydrogen sulfide, ferrous oxide, carbon dioxide, manganese, arsenic, coliform bacteria and other pathogens and compounds, are removed by filtration utilizing a zeolite and pea gravel filter media and by application of an oxidant using low concentrations of ozone. A silent ozone generator and injector feature provides silent operation and no ozone pumping mechanism. The apparatus is self regenerating, low cost, and low maintenance requiring few consumables and minimal user intervention.Type: GrantFiled: September 18, 2013Date of Patent: October 18, 2016Assignee: Alberic CorporationInventor: James Baird
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Patent number: 9469558Abstract: A reactor and control method thereof to maximize nitrogen removal and minimize aeration requirement through control of transient anoxia and aerobic SRT, repression of NOB, and control of dynamic DO concentrations or aeration interval by keeping the reactor NH4 and NOx concentrations approximately equal has been proposed. Controls described in this invention maximizes the potential for TIN removal through nitrification, limited nitritation, nitritation, denitrification, limited denitritation, denitritation making use of 1) real time measurement of ammonia, nitrite, nitrate, 2) operational DO and the proper use of DO setpoints, and 3) proper implementation of transient anoxia within a wide range of reactor configurations and operating conditions.Type: GrantFiled: October 1, 2013Date of Patent: October 18, 2016Assignees: D.C. Water & Sewer Authority, Hampton Roads Sanitation DistrictInventors: Pusker Regmi, Mark Miller, Charles B. Bott
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Patent number: 9469559Abstract: A float glass system (10) includes a float bath (14) having a pool of molten metal (16). A chemical vapor deposition coater (32) is located in the float bath (14) above the pool of molten metal (16). The coater (32) includes at least one low-coherence interferometry probe (38) located in or on the coater (32) and connected to a low-coherence interferometry system (36). Another low-coherence interferometry probe 138 can be located outside an exit end of the float bath (14) and connected to the same or another low-coherence interferometry system (36).Type: GrantFiled: June 25, 2014Date of Patent: October 18, 2016Assignee: PPG Industries Ohio, Inc.Inventors: Yu Jiao, James W. McCamy, David Hanekamp
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Patent number: 9469560Abstract: The present invention provides a method of manufacturing a vitreous silica crucible having a transparent layer by use of waste vitreous silica. According to the present invention, there is provided a method of manufacturing a vitreous silica crucible for manufacturing a monocrystalline or polycrystalline silicon ingot, including a process of vitrifying a silica powder sintered body having a crucible shape in the whole or part of the thickness direction by arc fusing the silica powder sintered body from the inner surface side, wherein the method further includes at least one means of (1) depressurizing the silica powder sintered body from the outer surface side during the arc fusing, and (2) forming a synthetic vitreous silica layer on the inner surface by spraying synthetic silica powder onto the inner surface of the silica powder sintered body during the arc fusing.Type: GrantFiled: November 30, 2011Date of Patent: October 18, 2016Assignee: JAPAN SUPER QUARTZ CORPORATIONInventors: Toshiaki Sudo, Takuma Yoshioka, Koichi Suzuki, Shinsuke Yamazaki
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Patent number: 9469561Abstract: A glass sheet is placed on a mold and heated to a first temperature. The glass sheet is then formed into a glass article having a three-dimensional shape using the mold. An isothermal heat transfer device comprising at least one heat pipe is provided in thermal contact with the mold. With the glass article on the mold and the isothermal heat transfer device in thermal contact with the mold, the glass article, mold, and isothermal heat transfer device are transported along a thermally-graded channel to cool the glass article to a second temperature. During the transporting, the isothermal heat transfer device transfers heat from a relatively hot region of the mold to a relatively cold region of the mold.Type: GrantFiled: June 27, 2014Date of Patent: October 18, 2016Assignee: Corning IncorporatedInventors: Nikolaos P Kladias, Kenneth Spencer Morgan, Elias Panides, Rohit Rai, John R Ridge, Ljerka Ukrainczyk
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Patent number: 9469562Abstract: Provided is a glass substrate with a sealing material layer, including a sealing material layer formed by sintering a sealing material, in which: the sealing material includes at least inorganic powder; the inorganic powder includes glass powder and a refractory filler; the content of refractory filler in the inorganic powder is 10 to 35 vol %; and the sealing material layer has a surface roughness Ra of less than 0.5 ?m.Type: GrantFiled: July 27, 2012Date of Patent: October 18, 2016Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Noriaki Masuda, Toru Shiragami, Hiroshi Arakawa
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Patent number: 9469563Abstract: A thermal insulation product based on mineral wool, characterized in that the fibers have a micronaire of less than 10 l/min, preferably less than 7 l/min and especially between 3 and 6 l/min, the product including infrared absorbent and/or reflective elements, and in that the product has a thermal conductivity of less than 30 mW/m.K.Type: GrantFiled: February 27, 2009Date of Patent: October 18, 2016Assignee: SAINT-GOBAIN ISOVERInventors: Arnaud Letourmy, Jerome Douce, Valerie Goletto, Jerome Gilles
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Patent number: 9469564Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3, and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.Type: GrantFiled: May 13, 2014Date of Patent: October 18, 2016Assignee: AvanStrate Inc.Inventors: Akihiro Koyama, Satoshi Ami, Manabu Ichikawa
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Patent number: 9469565Abstract: A writable window (e.g., IG window unit) is provided where images (e.g., advertisements, logos, designs, pictures and/or words) can be selectively written into the window. A substrate supports a solar coating such as a low emissivity (low-E) coating which may include at least one infrared (IR) reflecting layer (e.g., silver) and a contact/seed layer (e.g., zinc oxide and/or zinc stannate). A radiation source (e.g., laser(s) and/or lamp(s)) selectively exposes certain areas of the coating to radiation (e.g., UV radiation). Exposed area(s) of the coating, after exposure/heating, have different optical characteristic(s) than non-exposed areas, so that exposed area(s) form an image(s) designed to be viewed by humans and/or animals.Type: GrantFiled: May 31, 2012Date of Patent: October 18, 2016Assignee: Guardian Industries Corp.Inventor: Alexey Krasnov
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Patent number: 9469566Abstract: The invention provides a glazing sheet and a low-emissivity coating on the glazing sheet. The low-emissivity coating comprises, in sequence moving outwardly from the glazing sheet, a layer comprising oxide film, nitride film, or oxynitride film, an infrared-reflective film, a nickel-aluminum blocker film, and an oxide film. Also provided are methods of depositing such a low-emissivity coating.Type: GrantFiled: March 20, 2015Date of Patent: October 18, 2016Assignee: Cardinal CG CompanyInventors: Kari B. Myli, Gary L. Pfaff, Daniel J. Plaggemeyer
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Patent number: 9469567Abstract: Building panel, in particular for use in elevator cars, includes a glass assembly having two layers of glass and a clear interlayer therebetween and which glass assembly is compliant with safety code ANSI Z97.1, a decorative sheet arranged alongside the first layer of glass, and a backing sheet arranged alongside the decorative sheet on an opposite side from the glass assembly. An optional support structure is arranged alongside the backing sheet on an opposite side from the decorative sheet. The decorative sheet may be a wood veneer.Type: GrantFiled: March 20, 2015Date of Patent: October 18, 2016Inventors: Harold S Friedman, Jeffrey M Friedman, Viktor Tsvik
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Patent number: 9469568Abstract: The present invention relates to a composite panel (10) based on cementitious mortar, passed through its entire thickness by a plurality of through openings (11), each of which is filled with a material transparent to light in the form of a preformed plate (12) housed in said opening (11), or formed in said opening, wherein said cement-based mortar contains at least 30 kg/m 3 of fibers selected from one or more of the following types: metallic fibers, steel fibers, glass fibers, polymeric resin fibers. The invention also relates to methods of production of said panel.Type: GrantFiled: June 9, 2011Date of Patent: October 18, 2016Assignee: ITALCEMENTI S.P.A.Inventors: Stefano Cangiano, Aronne Carminati
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Patent number: 9469569Abstract: The present invention relates to an admixture for a cementitious composition, the cementitious composition comprising said admixture and a method for casting a durable cementitious solid, in particular a concrete, in cold weather conditions, such as in winter time or in cold geographical areas, more in particular for casting part of the cement tube in bore hole drilling in cold weather conditions.Type: GrantFiled: October 21, 2014Date of Patent: October 18, 2016Assignee: YARA INTERNATIONAL ASAInventor: Wolfram Franke
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Patent number: 9469570Abstract: A concrete composition is provided comprising a nonionic water-soluble cellulose ether, water, cement, a fine aggregate, and a coarse aggregate. The nonionic water-soluble cellulose ether has a 2 wt % aqueous solution viscosity of 3-1,000 mPa·s at 20° C. The concrete composition has a static slump/remix slump ratio of at least 0.50.Type: GrantFiled: April 29, 2015Date of Patent: October 18, 2016Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hidekazu Konishi, Tsutomu Yamakawa
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Patent number: 9469571Abstract: A handle substrate 1 is made of a translucent ceramics. An average density of pores having a size of 0.5 to 3.0 ?m included in a surface region 2A on the side of a bonding face 1a of the handle substrate 1 is 50 counts/mm2 or smaller. It is formed a region 3, whose average density of pores having a size of 0.5 to 3.0 ?m is 100 counts/mm2 or larger, in the handle substrate 1. The translucent ceramics has an average grain size of 5 to 60 ?m.Type: GrantFiled: April 29, 2015Date of Patent: October 18, 2016Assignee: NGK INSULATORS, LTD.Inventors: Yasunori Iwasaki, Akiyoshi Ide, Sugio Miyazawa
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Patent number: 9469572Abstract: A composition having nanoparticles of a refractory-metal boride and a carbonaceous matrix. The composition is not in the form of a powder. A composition comprising a metal component, boron, and an organic component. The metal component is nanoparticles or particles of a refractory metal or a refractory-metal compound capable of decomposing into refractory metal nanoparticles. The organic component is an organic compound having a char yield of at least 60% by weight or a thermoset made from the organic compound. A method of combining particles of a refractory metal or a refractory-metal compound capable of reacting or decomposing into refractory-metal nanoparticles, boron, and an organic compound having a char yield of at least 60% by weight to form a precursor mixture. A composition having nanoparticles of a refractory-metal boride that is not in the form of a powder.Type: GrantFiled: September 11, 2014Date of Patent: October 18, 2016Assignee: The United States of America, as represented by the Secretary of the NavyInventors: Teddy M. Keller, Andrew Saab, Matthew Laskoski
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Patent number: 9469573Abstract: This invention relates to a method of manufacturing a salt-coated heat paper, including preparing a powder mixture by mixing a fuel powder with an oxidant powder; preparing a slurry by adding an organic coagulant, after mixing the powder mixture with glass fibers; obtaining a heat paper by a papermaking process utilizing the slurry; primarily drying the heat paper by pressing; coating the heat paper with a salt solution; and secondarily drying the heat paper.Type: GrantFiled: October 28, 2014Date of Patent: October 18, 2016Assignee: AGENCY FOR DEFENSE DEVELOPMENTInventors: Chaenam Im, Jungmin Lee, Seungho Kang, Haewon Cheong
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Patent number: 9469574Abstract: The present invention is directed to the one step selective conversion of starch, cellulose, or glucose to molecules containing 7 to 26 contiguous carbon atoms. The invention is also directed to the conversion of those intermediates to saturated hydrocarbons. Such saturated hydrocarbons are useful as, for example, fuels.Type: GrantFiled: September 14, 2012Date of Patent: October 18, 2016Assignee: Los Alamos National Security, LLCInventors: Louis A. Silks, Andrew Sutton, Jin Kyung Kim, John Cameron Gordon, Ruilian Wu, David B. Kimball
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Patent number: 9469575Abstract: Olefins may be produced by the non-reductive dehydroxylation of vicinal polyols and/or their respective esters, in a liquid reaction medium, under a substantially non-reductive atmosphere, in the presence of a halogen-based, preferably iodine-based, catalyst. The reaction medium may be aqueous, non-aqueous, or a combination thereof, and may in some embodiments include a solubility enhancing agent.Type: GrantFiled: December 5, 2012Date of Patent: October 18, 2016Assignee: Dow Global Technologies LLCInventors: Raj Deshpande, Paul Davis, Vandana Pandey, Nitin Kore
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Patent number: 9469576Abstract: Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a reaction zone containing a gaseous phase and recovering ethylbenzene from the reaction zone.Type: GrantFiled: April 14, 2014Date of Patent: October 18, 2016Assignee: FINA TECHNOLOGY, INC.Inventor: James R. Butler
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Patent number: 9469577Abstract: Systems and methods conducive to the formation of one or more alkene hydrocarbons using a methane source and an oxidant in an oxidative coupling of methane (OCM) reaction are provided. One or more vessels each containing one or more catalyst beds containing one or more catalysts each having similar or differing chemical composition or physical form may be used. The one or more catalyst beds may be operated under a variety of conditions. At least a portion of the catalyst beds may be operated under substantially adiabatic conditions. At least a portion of the catalyst beds may be operated under substantially isothermal conditions.Type: GrantFiled: May 23, 2013Date of Patent: October 18, 2016Assignee: Siluria Technologies, Inc.Inventors: Wayne P. Schammel, Julian Wolfenbarger, Milind Ajinkya, Jon McCarty, Joel M. Cizeron, Sam Weinberger, Justin Dwight Edwards, Dave Sheridan, Erik C. Scher, Jarod McCormick, Fabio R. Zurcher, Alex Tkachenko, Joel Gamoras, Dmitry Karshtedt, Greg Nyce
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Patent number: 9469578Abstract: The invention is directed to a process to produce para-xylene and, optionally, ortho-xylene, including coupling two in-series xylenes separation systems with two parallel isomerization systems for energy savings and/or productivity increases.Type: GrantFiled: November 21, 2013Date of Patent: October 18, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: John D. Y. Ou, Jeevan S. Abichandani
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Patent number: 9469579Abstract: In a process for producing para-xylene, a toluene-containing stream is contacted with a methylating agent under conditions effective to convert toluene to xylenes and produce a methylated effluent stream. Para-xylene is recovered from the methylated effluent stream to produce a para-xylene depleted stream and part of the para-xylene depleted stream is contacted with a xylene isomerization catalyst under liquid phase isomerization conditions effective to produce a first isomerized stream, while part of the para-xylene depleted stream is contacted with a xylene isomerization catalyst under vapor phase isomerization conditions effective to produce a second isomerized stream. The first and second isomerized streams are then recycled to the para-xylene recovery step.Type: GrantFiled: May 20, 2016Date of Patent: October 18, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Michel Molinier, Jeffrey L. Andrews, Timothy P. Bender, Robert G. Tinger, Dennis J. Stanley, George J. Wagner
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Patent number: 9469580Abstract: Disclosed herein is a process for dehydrogenating a hydrocarbon with a dehydrogenation catalyst comprising a step of activating the catalyst precursor in a H2-containing atmosphere. A particularly advantageous activation process includes heating the catalyst precursor to a temperature in a range from 400° C. to 600° C. The process of the present disclosure is particularly advantageous for dehydrogenating cyclohexane to make benzene.Type: GrantFiled: November 18, 2013Date of Patent: October 18, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Tan-Jen Chen, Christopher L. Becker, Hari Nair, Francisco M. Benitez, Charles Morris Smith
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Patent number: 9469581Abstract: Biobased p-cymene and methods of producing same, which can further be converted to terephtalate. Further, a method is described for converting crude sulfate turpentine recovered from chemical wood pulping into p-cymene and eventually to terephtalic acid of biological origin, and products thereof respectively. In said method, both conversion and desulfurization is realized in one reaction step. The disclosure is also related to use of zeolite catalysts in said method.Type: GrantFiled: June 3, 2011Date of Patent: October 18, 2016Assignee: Stora Enso OYJInventors: Jari Räsänen, Tapani Penttinen, Ali Harlin, Reetta Kaila
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Patent number: 9469582Abstract: A fractionation system for a polymerization reactor includes a membrane separation system designed to separate light components, such as unreacted monomer and inerts, from diluent. The membrane separation system may employ one or more membrane modules designed to separate hydrocarbons based on size, solubility, or combinations thereof. The fractionation system also may include a heavies fractionation column designed to separate heavy components, such as unreacted comonomer and oligomers, from the diluent.Type: GrantFiled: December 14, 2015Date of Patent: October 18, 2016Assignee: Chevron Phillips Chemical Company LPInventors: Andrew J. Mills, Andrea L. Hoener, Ralph W. Romig
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Patent number: 9469583Abstract: A composition, including 40-50 wt-% C14 paraffins, based on the total weight of the composition, and 35-45 wt-% C15 paraffins, based on the total weight of the composition, wherein the C14 and C15 paraffins are produced from a biological raw material.Type: GrantFiled: January 3, 2014Date of Patent: October 18, 2016Assignee: NESTE OYJInventors: Pekka Aalto, Kati Sandberg, Tomi Nyman, Maija Hakola
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Patent number: 9469584Abstract: The invention relates to a method for producing butanol through microbial fermentation, in which the butanol product is removed by extraction into a water immiscible organic extractant composition during the fermentation. The invention also relates to a method for producing butanol through microbial fermentation, in which the butanol product is removed during the fermentation by extraction into a water-immiscible extractant composition comprising a first solvent having a butanol partition coefficient of at least 3, and a second solvent having a butanol partition coefficient, wherein the butanol partition coefficient of the first solvent is higher than the butanol partition coefficient of the second solvent. Optionally, the first solvent has a higher concentration of hydrogen bonding sites than the second solvent. The invention further relates to a composition including butanol in the water immiscible organic extractant composition described above.Type: GrantFiled: March 14, 2014Date of Patent: October 18, 2016Assignee: Butamax Advanced Biofuels LLCInventors: Douglas Robert Anton, John W. Hallam
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Patent number: 9469585Abstract: A system and process for removing divalent ions from a MEG feed stream is presented. The system includes a chemical treatment tank where chemicals are mixed with the feed stream to form insoluble carbonate and hydroxide salts. The system also includes a membrane-type solid-liquid separation unit that receives the feed stream from the chemical treatment tank and separates it into a filtrate containing MEG and a retentate containing the insoluble salts. The system may also include washing the retentate to remove additional MEG, which is then recycled to a MEG regeneration or reclamation process. The system may also include a dryer that receives waste slurry from the solid-liquid separation unit and dries it to form a solid waste, thereby facilitating its handling, storage, and disposal.Type: GrantFiled: September 14, 2015Date of Patent: October 18, 2016Assignee: Cameron Solutions, Inc.Inventors: Bryan A. Bussell, Simon Crawley-Boevey, Ankur D. Jariwala
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Patent number: 9469586Abstract: The disclosure relates to a novel glycerol purification process that produces partially refined waste glycerol for a variety of industrial applications. The disclosure encompasses a salt-containing partially refined glycerol composition that is suitable as a fermentation grade glycerol.Type: GrantFiled: August 19, 2014Date of Patent: October 18, 2016Assignee: REG LIFE SCIENCES, LLCInventors: Myong K. Ko, Perry Y. Liao, Simon Li, Fernando A. Sanchez-Riera
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Patent number: 9469587Abstract: A styrenated phenol compound in which a hydrazine or a diaminoalkane compound binds to a styrenated phenol, and a method of preparing the same are provided. The styrenated phenol compound may have improved exterior quality and storage stability of a product by maintaining a hardening stimulation property and plasticity and preventing discoloration when mixed with a hardener for an epoxy paint.Type: GrantFiled: June 24, 2015Date of Patent: October 18, 2016Assignee: Korea Kumho Petrochemical Co., LtdInventors: Kee Yoon Roh, Jung Hee Jang, Je Young Park
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Patent number: 9469588Abstract: An alkylating process such as hydroalkylating process comprising feeding a gas material and a liquid material into the reactor, distributing the liquid material to the upper surface of a bed of a catalyst substantially uniformly. The substantial uniform distribution of the liquid material to the upper surface allows for substantially uniform distribution of liquid reaction medium in the bed, thereby preventing hot spot and undesirable continuous liquid zone, both of which can cause the production of undesired by-products. The invention is particularly useful for the hydroalkylation reaction of benzene in making cyclohexylbenzene, which can be used for making cyclohexanone and phenol.Type: GrantFiled: December 6, 2013Date of Patent: October 18, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventor: Christopher L. Becker
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Patent number: 9469589Abstract: In a process for producing phenol and/or cyclohexanone, cyclohexylbenzene is contacted with an oxygen-containing gas in the presence of an oxidation catalyst under oxidation conditions effective to produce an oxidation effluent comprising cyclohexylbenzene hydroperoxide. At least a portion of the oxidation effluent is then subjected to a concentrating step to produce a cleavage feed having a higher concentration of cyclohexylbenzene hydroperoxide than the oxidation effluent. A cleavage reaction mixture comprising the cleavage feed is then contacted with a solid acid catalyst in a cleavage reaction zone under conditions effective to produce a cleavage product comprising phenol and cyclohexanone.Type: GrantFiled: June 4, 2014Date of Patent: October 18, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Hari Nair, Christopher L. Becker, Jason D. Davis, Charles Morris Smith
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Patent number: 9469590Abstract: 5,9-dimethyl-9-hydroxy-decen-4-al, having the formula (I)Type: GrantFiled: June 10, 2014Date of Patent: October 18, 2016Assignee: GIVAUDAN S.A.Inventors: Alain Alchenberger, Chloe Berbez, Clare Finn, Dominique Lelievre, Martin Alan Lovchik, Roseline Poignon-Martel, Gilles Romey
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Patent number: 9469591Abstract: Integrated process for the production of methyl acetate and methanol. The process is carried out by carbonylating dimethyl ether with synthesis gas, recovering methyl acetate and unreacted synthesis gas and supplying unreacted synthesis gas and fresh synthesis gas for methanol synthesis.Type: GrantFiled: December 19, 2013Date of Patent: October 18, 2016Assignee: BP CHEMICALS LIMITEDInventor: Timothy Crispin Bristow
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Patent number: 9469592Abstract: Provided is a positive photoresist composition excellent in terms of heat resistance. A radically curable compound is represented by a general formula (1) below (where R1, R2, and R3 each independently represent an alkyl group having 1 to 8 carbon atoms; m and n each independently represent an integer of 1 to 4; p represents an integer of 0 to 4; X, Y, and Z each independently represent an acryloyloxy group, a methacryloyloxy group, or a hydroxy group, and at least one of X, Y, and Z represents an acryloyloxy group or a methacryloyloxy group; and t represents 1 or 2).Type: GrantFiled: June 25, 2013Date of Patent: October 18, 2016Assignee: DIC CorporationInventors: Tomoyuki Imada, Takakazu Kage, Dongmi Shin
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Patent number: 9469593Abstract: Method for preparing cinacalcet hydrochloride having the steps of heating (R)-1-naphthyl ethylamine (Formula I) and 3-(trifluoromethyl)benzene (Formula II) wherein L is a halogen atom, methanesulfonate group (OMs), p-Toluenesulfonate (OTs), or triflate (OTf), in an organic solvent in presence of an inorganic base, refluxing until 3-(trifluoromethyl)benzene is completely consumed, obtaining a reaction mixture containing cinacalcet, and after treatment, obtaining cinacalcet hydrochloride having a formula of The post treatment separates (R)-1-naphthyl ethylamine hydrochloride and cinacalcet hydrochloride by adjusting pH value, extraction, and other simple operations, and the (R)-1-naphthyl ethylamine obtained is recycled for preparing the next batch of cinacalcet hydrochloride.Type: GrantFiled: November 28, 2014Date of Patent: October 18, 2016Assignees: Shanghai Jingxin Biomedical Co., Ltd., Shangyu Jingxin Pharmaceutical Co., Ltd.Inventors: Miaohuan Xu, Yue Huang, Min Zhang
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Patent number: 9469594Abstract: The present invention relates to a method for producing aromatic amines by the hydrogenation of aromatic nitro compounds. This method supplies aromatic nitro compounds and hydrogen to a reactor and contacts them with a hydrogenation catalyst; and stops the supply of aromatic nitro compounds and hydrogen to the reactor. The supply of aromatic nitro compounds and hydrogen to the reactor is stopped to ensure safe shutdown of the reactor.Type: GrantFiled: April 12, 2013Date of Patent: October 18, 2016Assignee: Covestro Deutschland AGInventors: Michael Merkel, Thomas Knauf, Cliff Andre Peters, Thorsten Schmidt, Karl-Heinz Wilke
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Patent number: 9469595Abstract: This disclosure describes a low temperature process for the preparation of tertiary amines from nitriles and secondary amines via reductive amination using transfer hydrogenation. The process can use a nitrile and a dialkylamine and proceeds under surprisingly mild conditions using a palladium catalyst and the corresponding dialkylammonium formate as the hydrogen donor, and show a pronounced acceleration in the presence of water.Type: GrantFiled: June 22, 2015Date of Patent: October 18, 2016Assignee: Eastman Chemical CompanyInventor: Neil Warren Boaz
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Patent number: 9469596Abstract: The purpose of the present invention is to provide a method for efficiently removing a quaternary salt from an organic solvent. The present invention relates to a method for removing a quaternary salt, the method including: contacting a solution of a quaternary salt in an organic solvent with an aqueous solution containing at least one member selected from the group consisting of (a1) compounds having one or more anionic functional groups and (a2) polymers having at least one member selected from the group consisting of carboxyl group and sulfonic acid group, thereby removing the quaternary salt from the organic solvent.Type: GrantFiled: January 28, 2013Date of Patent: October 18, 2016Assignee: ARAKAWA CHEMICAL INDUSTRIES, LTD.Inventors: Kiyoshi Takumi, Naoki Sasagawa, Yoichiro Ezaki
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Patent number: 9469597Abstract: The invention relates to (hetero)aryl cyclopropylamine compounds, including particularly the compounds of formula (I) as described and defined herein, and theft use in therapy, including, e.g., in the treatment or prevention of cancer, a neurological disease or condition, or a viral infection.Type: GrantFiled: October 22, 2012Date of Patent: October 18, 2016Assignee: Oryzon Genomics S.A.Inventors: Alberto Ortega Muñoz, Matthew Colin Thor Fyfe, Marc Martinell Pedemonte, María de los Ángeles Estiarte Martínez, Nuria Valls Vidal, Guido Kurz, Julio Cesar Castro Palomino Laria
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Patent number: 9469598Abstract: A therapeutic and/or prophylactic agent for renal anemia comprising ALAs and an erythropoietin production promoter comprising ALAs.Type: GrantFiled: October 5, 2012Date of Patent: October 18, 2016Assignees: SBI Pharmaceuticals Co., Ltd., Tohoku UniversityInventors: Tohru Tanaka, Motowo Nakajima, Kiwamu Takahashi, Takaaki Abe
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Patent number: 9469599Abstract: The present invention relates to carbon-based fluorescent nano-agent tracers for analysis of oil reservoirs. The carbon-based fluorescent nano-agents may be used in the analysis of the porosity of a formation. The nanoagents are suitable for injection into a petroleum reservoir and may be recovered from the reservoir for the determination of hydrocarbon flow rates and retention times.Type: GrantFiled: February 20, 2015Date of Patent: October 18, 2016Assignees: Saudi Arabian Oil Company, Cornell UniversityInventors: Mazen Y. Kanj, Mohammad Harunar Rashid, Emmanuel Giannelis
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Patent number: 9469600Abstract: Prostacyclin compounds and compositions comprising the same are provided herein. Specifically, prostacyclin compounds comprising treprostinil covalently linked to a linear C5-C18 alkyl, branched C5-C18 alkyl, linear C2-C18 alkenyl, branched C3-C18 alkenyl, aryl, aryl-C1-C18 alkyl or an amino acid or a peptide (e.g., dipeptide, tripeptide, tetrapeptide) are described. The linkage, in one embodiment, is via a carbamate, amide or ester bond. Prostacyclin compounds provided herein can also include at least one hydrogen atom substituted with at least one deuterium atom. Methods for treating pulmonary hypertension (e.g., pulmonary arterial hypertension) and portopulmonary hypertension are also provided.Type: GrantFiled: October 24, 2014Date of Patent: October 18, 2016Assignee: Insmed IncorporatedInventors: Vladimir Malinin, Walter Perkins, Franziska Leifer, Donna Konicek, Zhili Li, Adam Plaunt
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Patent number: 9469601Abstract: The present inventions concerns derivatives of aminocyclobutane, particularly as NMDA receptor antagonists, their application in human therapy and their method of preparation. These compounds correspond to the general formula (1): wherein: X1 represents a hydrogen atom or fluorine atom; X2 is a hydrogen atom or fluorine atom or chlorine atom; R1 represents a hydrogen atom or fluorine atom or chlorine atom or methyl group or methoxy group or cyano group; R2 represents independently or together a methyl group or ethyl group.Type: GrantFiled: December 4, 2013Date of Patent: October 18, 2016Assignee: PIERRE FABRE MEDICAMENTInventors: Bernard Vacher, Elodie Blanc, Ronan Depoortere
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Patent number: 9469602Abstract: Disclosed herein is a method of activating a compound for a chemical reaction comprising functionalizing a compound with a redox auxiliary group and oxidizing the redox auxiliary group that is bonded to the compound, thereby activating the compound, wherein the activated compound undergoes a chemical reaction to form a product and the oxidation of the redox auxiliary group is reversible. Methods of making and using these materials are also disclosed.Type: GrantFiled: October 31, 2014Date of Patent: October 18, 2016Assignee: The Board of Trustees of the University of AlabamaInventors: Silas Blackstock, Lester Gray, Melody Kelley, Carl Saint-Louis