Abstract: The present disclosure relates to a single-pot multi step process for the preparation of a shape controlled pro-catalyst. The process comprises the steps of: i. reacting magnesium metal and at least one alkanol to obtain spheroidal magnesium alkoxide; ii. treating the spheroidal magnesium alkoxide with at least one transition metal tetrahalide, at least one organic modifier, and optionally, at least one in-organic modifier in the presence of at least one solvent to obtain a reaction mixture; iii. cooling, settling the reaction mixture and decanting the supernatant; iv. adding at least one transition metal tetrahalide, at least one solvent and optionally, at least one organic or inorganic modifier; and v. iterating steps (iii) and (iv) to obtain the shape controlled pro-catalyst.

Abstract: Catalyst systems containing a Ziegler-Natta catalyst component are disclosed. Such catalyst systems can contain a co-catalyst and a supported catalyst containing a fluorided silica-coated alumina, a magnesium compound, and vanadium and/or tetravalent titanium.

Abstract: This invention relates to a polymerization process for forming polymer comprising: contacting (typically in a solution or slurry phase), a monomer and a catalyst system in a reaction zone comprising at least one spiral heat exchanger and recovering polymer, wherein the monomer, the catalyst system and the polymer flow through the at least one spiral heat exchanger in a cross-flow direction relative to spirals of the at least one spiral heat exchanger.

Abstract: A method of making a resin, includes forming an aqueous monomer droplet suspension, and colloidally stabilizing the suspension with a solid particulate material as the first stabilizer and poly(2-ethyl-2-oxazoline) as a second stabilizer. The method further includes heating the colloidally stabilized suspension to polymerize the monomer droplets, thereby forming the resin.

Abstract: The invention relates to a method for preparing a polymeric material doped with at least one first metal element and at least one second metal element, said at least one first metal element and said at least one second metal element being identical or different from each other, said method comprising: a) a step for copolymerization of at least one first monomer comprising at least one first metal element and of at least one second monomer comprising at least one chelating group of at least one second metal element, in return for which a polymeric material is obtained comprising recurrent units from the polymerization of said first monomer, said recurrent units comprise said at least one first metal element and comprising recurrent units from the polymerization of said second monomer, said recurrent units comprising chelating groups of at least one second metal element; and when said first metal element is different from said second metal element, said method further comprising a step b) for putting the mat

Abstract: Poly(ethylene tetrafluoroethylene) (ETFE) polymers having an average molecular weight of at least 300,000 g/mol and a melt enthalpy of at least 57 J/g are provided. The ETFE polymer may include at least one additional comonomer. The ETFE polymer is used to form a porous tape or membrane that has a node and fibril structure. A porous ETFE tape may be formed by lubricating the ETFE polymer and subjecting the lubricated polymer to pressure at a temperature below the melting point of the ETFE polymer. Optionally, the ETFE tape may be expanded at a temperature below the melting temperature of the ETFE polymer to form an expanded ETFE membrane. Alternatively, the ETFE polymer may subjected to heat and pressure without the addition of a lubricant to form a dense preform. The dense preform may be subsequently slit in a length direction and stretched to form a dense ETFE fiber.

Abstract: To provide a powder coating material to form a coating film excellent in adhesion to a metal substrate and excellent in heat resistance, and an ethylene/tetrafluoroethylene copolymer contained therein. An ethylene/tetrafluoroethylene copolymer in which the content of chlorine atoms covalently bonded to any carbon atoms in the copolymer is from 100 to 500 mass ppm. A method for producing the ethylene/tetrafluoroethylene copolymer in which all or some of the chlorine atoms are introduced by using a chain transfer agent having a chlorine atom. A powder coating material comprising the ethylene/tetrafluoroethylene copolymer. A molded article having a coating film formed by the powder coating material, on a surface of a metal substrate.

Abstract: An (ethylene, vinyl acetal) copolymer includes (i) a plurality of ethylenic moieties A having a structure according to the formula: wherein R2 and R3 independently represent hydrogen, a halogen, an optionally substituted linear, branched or cyclic alk(en)yl group, or an optionally substituted aromatic or heteroaromatic group; (ii) a plurality of acetal moieties B having a structure according to the formula: wherein L1 represents a divalent linking group; X=0 or 1; and R1 represents an optionally substituted aromatic or heteroaromatic group including at least one hydroxyl group; and (iii) a plurality of acetal moieties C and/or moieties D which are different from the acetal moieties B, and which include at least one nitrogen atom.

Abstract: Provided is a surfactant which has a high surface tension reducing ability and a high solubility in a liquid medium, containing a fluorine-containing copolymer containing, as essential components, a monomer having a fluoroalkyl group having 1 to 7 carbon atoms, a hydrophilic monomer, and a monomer having an ion donor group. Further provided are a coating composition, an ink composition and a photographic emulsion composition, each comprising the surfactant.

Abstract: An object of the present invention is to provide an organic EO polymer having a desired Tg. The present invention provides a copolymer comprising (i) a cycloalkane methacrylate and 2-isocyanatoethyl methacrylate as monomers at an adjusted blending ratio and (ii) an electro-optic molecule (EO molecule) bound to the copolymer, thereby exhibiting a desired glass transition temperature (Tg).

Abstract: Methods for synthesizing a random copolymer having a phosphorylcholine group. Syntheses involving a reaction mixture containing a chain transfer agent (CTA), a solvent, a hydrophobic methacrylate monomer, a 2-methacryloyloxyethyl phosphorylcholine (MPC) monomer, and, optionally, an initiator. The random copolymers produced by such synthesis methods having a polydispersity index (PDI) of less than about 1.3 and a peak molecular weight (Mp) of less than about 130,000. Polymer blends and medical devices including such random copolymers, and methods of treating a mammal using such random copolymers or medical devices.

Abstract: A composition of matter includes a mixture of styrene derivative monomers and methacrylate/acrylate derivative monomers, which have one or more urethane, carbamate, amide, and/or amine functional groups, and initiators, and the compositions are used to achieve composition control of the forming polymer, with the mole fraction of acrylate/methacrylate and styrene moieties in the forming polymer determined preferably by the chemistry and composition of the feeding monomers rather than the viscosity of the monomers.

Abstract: The present invention relates to a copolymer useful especially as a suds boosting polymer in hand dishwashing detergent compositions. The copolymer of the invention provides improved foaming properties, and in particular may boost the suds, when added onto such hand dishwashing detergent compositions.

Abstract: A Formula of a phosphorous fire-retardant hardener having fire-retardant and heat-resistant properties as well as a low-dielectric constant. With a preparation of glass-fiber laminated board, the hardener meets UL-94V fire-retardant requirements and has a dielectric constant of 4.0 (1 GHz).

Abstract: The present invention relates to a method for the production of oxazolidinone compounds with low colour intensity, comprising the step of reacting an isocyanate compound with an epoxide compound in the presence of a catalyst which is free of halide anions. The invention further relates to a method for the production of oligooxazolidinone and/or polyoxazolidinone compounds, comprising the step of reacting a polyisocyanate compound with a polyepoxide compound in the presence of said catalyst. The invention further relates to oligooxazolidinone and/or polyoxazolidinone compounds with low colour intensity, obtainable by a method according to the invention.

Abstract: The addition of a small amount of an alkyl sulfoxide, e.g., DMSO, to an isocyanate capped prepolymer provides a storage stable prepolymer composition in which the prepolymer is also highly activated towards curing with certain blocked curing agents such as methylenedianiline metal salt coordination complexes. The prepolymer/alkyl sulfoxide compositions are cured by said blocked curing agents at lower temperatures and/or at an accelerated rate compared to similar compositions lacking the alkyl sulfoxide providing high performance polyurethane elastomers.

Abstract: 1) Specific polyurethane prepolymer (PP2) comprising at least two terminal (2-oxo-1,3-dioxolan-4-yl)methyl carbamate groups of low viscosity, its preparation process and its use in the manufacture of an adhesive composition. 2) Multicomponent system comprising, as first component (A), a composition comprising at least one such polyurethane prepolymer and, as second component (B), a composition comprising at least one curing agent comprising at least two primary amine (—NH2) groups (B1). 3) Process for assembling materials employing the polyurethane prepolymer (PP2) according to the invention.

Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a sterically hindered amine catalyst.

Abstract: A process for preparing an aliphatic or cycloaliphatic epoxy resin composition including the steps of: (I) reacting a mixture of the following components: (a) an aliphatic or cycloaliphatic hydroxyl-containing material, (b) an epihalohydrin, (c) a stoichiometric excess of a base compound or basic acting substance, (d) a catalyst, and (e) optionally, a solvent; wherein the reacting step (I) is carried out under reaction conditions sufficient to form a crude aliphatic or cycloaliphatic epoxy resin composition product in the resultant reaction mixture; (II) neutralizing the resultant reaction mixture of step (I) containing the crude aliphatic or cycloaliphatic epoxy resin composition product with a phosphate neutralizing agent sufficient to partially neutralize the base or basic acting substance and to form a neutralized fluid medium containing aliphatic or cycloaliphatic epoxy resin composition product; (III) removing at least a portion of unreacted epihalohydrin from the reaction mixture of step (II); and (IV)

Abstract: The present disclosure is directed to a curable composition comprising: a) an epoxy resin; b) an epoxy curing agent comprising at least one cycloaliphatic amine; c) at least 3 wt % of a metal triflate catalyst; d) optionally, a fatty acid polyamide; and e) optionally, a filler material. The compositions of the present disclosure are particularly suitable for use in structural assembly, in particular for potting and filling operations in sandwich structures. The present disclosure also relates to a composite assembly and to methods of using such epoxy resin based curable compositions.

Abstract: Disclosed is a polyester composition comprising a polyester further comprising (a) at least one cyclobutanediol; (b) at least one 2,2-bis(hydroxymethyl)alkylcarboxylic acid and/or a derivative thereof; and (c) at least one polycarboxylic acid and/or a derivative thereof. This polyester composition can be useful in several areas including but not limited to thermoplastic polyesters, curable polyesters, inks, paints, composites, coating compositions, for example, waterborne coatings, water-dispersible coatings, solvent-borne coatings, and powder coatings.

Abstract: Disclosed in the present invention are a fluorine-containing polymerizable compound of the general formula (1) and a polymer compound obtained therefrom: where A represents a single bond, an oxygen atom, a sulfur atom, SO2, CH2, CO, C(CH3)2, C(CH3)(CH2CH3), C(CF3)2, C(CH3)(C6H5), CH2—C6H4—CH2 or a divalent organic group obtained by elimination of two hydrogen atoms from benzene, biphenyl, naphtharene, cyclohexene or fluorene; and a and b each independently represent an integer of 0 to 2 and satisfy a relationship of 1?a+b?4. The thus-obtained polymer compound combines adequate hydrophilicity and high transparency with low water adsorption of fluorine-containing compound.

Abstract: The invention relates to DMC catalysts comprising polyether siloxanes, to processes for preparation thereof, to the use thereof, and to the DMC catalysts obtainable by the processes according to the invention.

Abstract: The invention is directed to multi-functional N-maleimidyl polymer derivatives comprising a water soluble and non-peptidic polymer backbone having a terminal carbon, such as a poly(alkylene glycol), the terminal carbon of the polymer backbone being directly bonded to the nitrogen atom of a N-maleimidyl moiety without a linking group therebetween. The invention also provides two methods of preparing such linkerless N-maleimidyl polymer derivatives.

Abstract: The present invention relates to a phosphorus-containing polyphenylene oxide resin, its preparation method, a method for preparing the prepolymer of the phosphorus-containing polyphenylene oxide, a resin composition and an article thereof, wherein the phosphorus-containing polyphenylene oxide resin has a chemical structure represented by the following formula (I): wherein R? is R? is R?? is hydrogen, Through the use of the above phosphorus-containing polyphenylene oxide resin, an article made from the resin composition can has good flame retardance, good thermal resistance and a lower percent of thermal expansion while dielectric properties can be maintained, such that the present invention is suitable for use in products such as copper clad laminate and printed circuit board.

Abstract: The present invention relates to a process for the preparation of oligo(alkylene glycol)-functionalized polyisocyanopeptides comprising the steps of functionalizing an isocyanopeptide with oligo-(alkylene glycol) side chains and subsequently polymerizing the oligo-alkylene glycol-functionalized isocyanopeptides. Several isocyanopeptides may be functionalized with various linear or non-linear oligo-(alkylene glycol) side chains having variable chain length. The alkylene glycol may be selected from the group consisting of ethylene-, propylene-, butylene- or pentylene glycol. Preferably, the isocyanopeptides are functionalized with at least three ethylene glycol side chains. The peptides may comprise L-amino acids, D-amino acids or D, L-amino acids. The obtained oligoalkylene-functionalized polyisocyanopeptides are a new class of materials with unique thermo-responsive properties.

Abstract: Disclosed herein are monomer embodiments that can be used to make polymers, such as homopolymers, heteropolymers, and that can be used in particular embodiments to make sequence-defined polymers. Also disclosed herein are methods of making polymers using such monomer embodiments. Methods of using the polymers disclosed herein also are described.

Abstract: Provided is a polymer including a structural unit represented by the following Formula (1a); and a structural unit represented by the following Formula (1b). (In Formula (1a), n represents 0, 1, or 2. R1, R2, R3, and R4 each independently represent hydrogen or an organic group having 1 to 10 carbon atoms, at least one of R1, R2, R3, and R4 representing an organic group including a carboxyl group, an epoxy ring, or an oxetane ring. In Formula (1b), R5 and R6 each independently represent an alkyl group having 1 to 10 carbon atoms.

Abstract: The present invention relates to a polymer, and a composition containing a particulate solid, an aqueous medium, and a polymer chain having at least one fused aromatic imide pendant group. The invention further provides compositions for millbases, dispersions, coatings and inks.

Abstract: The present invention discloses a polymetallocarbosilane from organic metal catalysed polymerization and uses thereof, said polymetallocarbosilane has a structural formula as shown in (I). In the formula, R is methyl, ethyl, propyl, ethenyl, chloromethyl, phenyl or phenethyl; M is Ti, Zr or Hf; m is an integer equal to or greater than 1, n is an integer equal to or greater than 0, and Cp1 and Cp2 are each a cyclopentadienyl or substituted cyclopentadienyl group. The present invention adopts a method for producing polymetallocarbosilane by metallocene catalysed addition polymerization of an organosilane, with adjustability of metal content in polymer, simple reaction steps, mild reaction conditions and low preparation costs.

Abstract: The present disclosure provides methods and compositions for directed to synthetic block copolymer proteins, expression constructs for their secretion, recombinant microorganisms for their production, and synthetic fibers (including advantageously, microfibers) comprising these proteins that recapitulate many properties of natural silk. The recombinant microorganisms can be used for the commercial production of silk-like fibers.

Abstract: The present disclosure generally relates to pelletizing and compounding extrusion die systems. In particular, the present disclosure relates to the cyclical extrusion of materials to generate small sized grain features, generally in the range of micro and nanosized grain features.

Abstract: A method of producing polymer particles includes, in a system in which a polymer A and a polymer B are dissolved in and mixed with an organic solvent to undergo phase separation into two phases which are a solution phase containing the polymer A as a major component and a solution phase containing the polymer B as a major component, continuously adding an emulsion including the polymer A, the polymer B and the organic solvent, and a poor solvent for the polymer A to a vessel continuously to allow the polymer A to precipitate; and separating polymer A particles from the vessel continuously.

Abstract: An additive composition comprises a wax and a nucleating agent. The nucleating agent can be dispersed in the wax. A process for producing a nucleated polymer comprises the steps of (a) providing a reactor; (b) providing an additive composition comprising a wax and a nucleating agent; (c) providing an extruder; (d) reacting in the reactor a reactant mixture comprising an olefin monomer and hydrogen to produce a polyolefin polymer; (e) collecting and recovering the polyolefin polymer produced by the reaction; (f) conveying the polyolefin polymer to the extruder; (g) conveying the additive composition to the extruder; and (g) extruding the polyolefin polymer and the additive composition to produce a nucleated polymer composition.

Abstract: In an example, a process includes polymerizing a mixture that includes an ethylene monomer, a propylene monomer, and a diene monomer to form an ethylene-propylene-diene (EPDM) terpolymer using ring-opening metathesis polymerization (ROMP). The process further includes chemically reacting the EPDM terpolymer with a norbornene-based phosphinate cross-linking material to form a flame-retardant, cross-linked EPDM rubber.

Abstract: There is provided a novel polymer including a repeating unit expressed as a following formula 1: where each of R1 and R2 independently represents an alkylene group with 2 to 6 carbon atoms, and each of n and m independently represents 10 to 10,000.

Abstract: A. cellulose acylate film includes cellulose acylate and a compound A which has a group represented by the formula (G) as defined herein and in which a value obtained by dividing a molecular weight of the compound by a number of the groups represented by formula (G) contained in the compound is 200 or less, and a content of the compound A is 15% by weight or more based on a content of the cellulose acylate, the iodine diffusion index X as defined herein is less than 0.005 and the iodine diffusion index Y as defined herein is 0.

Abstract: It is provided that a biaxially stretched polybutylene terephthalate film which has all of excellent thickness precision, excellent pin-hole resistance and excellent bag rupture resistance and can achieve excellent barrier properties when a gas barrier layer is provided thereon, and manufacturing method therefor. A biaxially stretched polybutylene terephthalate film, wherein the biaxially stretched polybutylene terephthalate film containing not less than 90% by mass of polybutylene terephthalate, and the plane center average roughness of a 500-nm square region that does not contain a protrusion resulting from inert particles in at least one surface of the film is not more than 1.0 nm.

Abstract: A surface treatment liquid capable of making a surface of a treatment target hydrophilic or hydrophobic without including a resin having a coating film formation property, and a surface treatment method using the surface treatment liquid. The surface treatment liquid includes a resin, a solvent and a strong acid having a pKa of 1 or less. The resin includes a functional group I that is at least one of a hydroxyl group, a cyano group, and a carboxyl group, and a functional group II that is a hydrophilic group or a hydrophobic group other than the functional group I.

Abstract: The present invention is a gas barrier laminate comprising a base unit that comprises a base and a modification-promoting layer, and a gas barrier layer that is formed on a side of the modification-promoting layer with respect to the base unit, the modification-promoting layer having a modulus of elasticity at 23° C. of less than 30 GPa, the base unit having a water vapor transmission rate at a temperature of 40° C. and a relative humidity of 90% of 1.0 g/(m2·day) or less, and the gas barrier layer being a layer formed by applying a modification treatment to a surface of a layer that comprises a polysilazane-based compound and is formed on the side of the modification-promoting layer with respect to the base unit, and a method for producing the gas barrier laminat, and an electronic device member comprising the gas barrier laminate, and an electronic device comprising the electronic device member.

Abstract: The shelf life of polyurethane polyol pre-blends containing halogenated olefins is extended by encapsulation of active components such as catalysts anti/or surfactants. The active component is encapsulated in a crystallizable or thermoplastic polymer. The encapsulated particles have a size of 2,800 microns or less and the active components are not significantly leaked out, particularly in the presence of halogenated olefins.

Abstract: A recycling method of waste fishnet is provided. The waste fishnet is processed with steps of cutting, removing impurities, cleaning, and drying to form fishnet chips. The recycling method of waste fishnet includes the following steps. The fishnet chips are mixed with nylon-66, wherein the fishnet chips are of 70% by weight, and nylon-66 is of 30% by weight. The mixture is heated and molten. The molten mixture is then processed with the step of granulation. The grains are then processed with the step of spinning Thereby, the waste fishnet can be recycled and transferred into useful plastic materials.

Abstract: A hybrid carbon black is provided, which includes a carbon black core and a polymer film wrapping an entire surface of the carbon black core. The polymer film includes a network of a plurality of polymer main chains crosslinked each other, and a plurality of dispersion-side chains bonded to the polymer main chains. The dispersion-side chains come from an acrylate monomer with a chemical structure of: wherein when n is 4 to 7, R1 is H or CH3, and when n is 8 to 14, R1 is CH3.

Abstract: Polycyclic aromatic hydrocarbon (PAH) functionalized isobutylene copolymers, methods for making a PAH functionalized isobutylene copolymer comprising combining a halogenated copolymer with a PAH in a solvent under basic conditions at a temperature ranging from 30° C. to 150° C., the use of these PAH functionalized copolymers as a dispersant in elastomeric nanocomposite compositions comprising a halobutyl rubber matrix and nanoparticles of graphite or graphene, and a tire innerliner or innertube produced from these elastomeric nanocomposite compositions is disclosed.

Abstract: The invention is directed to a resin composition that has both high heat resistance and high resistance against ultraviolet radiation. The invention is further directed to an article comprising said composition, and to the use of a combination of compounds for stabilising a resin composition. The resin composition of the invention comprises (A) a polypropylene resin, (B) an optionally substituted linear or branched alkyl ester of 3-(alkylated 4?-hydroxyphenyl) propionic acid having a molecular weight of 750 g/mol or less, (C) a hindered amine light stabiliser, having a molecular weight of 1250 g/mol or more, wherein the hindered amine is comprised in the backbone of the hindered amine light stabiliser molecule, and (D) a thiosynergist.

Abstract: The invention relates to substantially diphenylguanidine-free rubber mixtures comprising at least one rubber, one silica-based filler and/or carbon black and short-chain alkyl esters of glycerol, production of these, use and vulcanizates thus obtainable.

Abstract: Tripentyl esters of trimellitic acid, especially mixtures of triisopentyl esters of trimellitic acid comprising isomeric pentyl radicals in which more than 5 mol % of the isomeric pentyl radicals incorporated in the ester mixture are branched, have good compatibility with PVC and PVC-containing polymers and simultaneously exhibit a lesser tendency to migrate.

Abstract: Curing fluoroelastomers using curing agents of formula, R1N?CR2R3 , wherein R1 is H; R2 is selected from the group consisting of H, NH2, and NR4R5; R3 is selected from the group consisting of Ph, SO2H, NR6R7, 2-pyridine, and CH2CONH2; R4 is H; R5 is selected from the group consisting of Ph, NH2, and CN; R6 is selected from the group consisting of H, NHPh, CCONH2, C1 to C8 linear alkyl group, and C1 to C8 branched alkyl group; and R7 is selected from the group consisting of Ph, COOC(CH3)3, NH2, CH2COOH, CSNH2, CNHNH3+Cl31 , p-phenylCN, COPh,

Abstract: Curing fluoroelastomers with curing agents of formulas (I), (II), (III), and (IV): wherein each of R1, R2, R3, R4, R6, R7, R8, and R9, is selected from the group consisting of H; halogen atom; C1 to C4 alkyl groups in which the alkyl group is linear, branched, or cyclic; OR?; and aromatic groups; R5 is H; and R? is selected from the group consisting of C1 to C4 alkyl groups in which the alkyl group is linear, branched, or cyclic; and phenyl.

Abstract: The latex polymer compositions of the present invention exhibit latent crosslinking properties. Latent crosslinking in the polymers takes advantage of the fast interaction between the anionic latex charge and the cationic charge associated with polyfunctional amine crosslinkers. Once the latex is coated onto a substrate, the volatile base evaporates and the groups react to form a crosslinked coating with improved wash-off properties.