Patents Issued in June 27, 2017
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Patent number: 9688782Abstract: The present invention relates to a method for separation of a polymer from a polymer solution or dispersion, wherein (i) a solution or dispersion of a polymer in an organic solvent is atomized by being brought into contact with water vapor in an atomizer container; (ii) the mixture obtained in the atomizer container is routed into a polymer degasification container and flows through same, wherein the organic solvent present in the polymer particles is driven at least partially out of the polymer particles due to the thermal contact between the polymer particles and the water vapor and transitions into the gas phase (iii) the mixture exiting from the polymer degasification container is routed into a phase separator (1) and the organic solvent present in the gas phase is separated from the polymer particles and the condensed water vapor; and (iv) the polymer particles and the condensed water vapor are routed into a phase separator (2) in order to separate the polymer particles from the condensed water vapor.Type: GrantFiled: March 24, 2014Date of Patent: June 27, 2017Assignee: Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V.Inventors: Ulrich Wendler, Marcus Vater, Carsten Gehrhardt, Frank Herzig
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Patent number: 9688783Abstract: Process for functionalizing an ethylene-based (co)polymer comprising the step of contacting an ethylene-based (co)polymer at a temperature in the range 100-250° C. with an azide of formula (I) wherein Y is either (Ia) or (Ib) m is 0 or 1, n is 0 or 1, n+m=1 or 2, and X is a linear or branched, aliphatic or aromatic hydrocarbon moiety with 1-12 carbon atoms, optionally containing heteroatoms.Type: GrantFiled: October 31, 2014Date of Patent: June 27, 2017Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.Inventors: Waldo Joseph Elisabeth Beek, Auke Gerardus Talma
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Patent number: 9688784Abstract: The present invention includes a process for producing treated filler that includes (a) treating a slurry that includes untreated filler where the untreated filler has not been previously dried, with a treating composition that includes a treating agent, thereby forming a treated filler slurry, and (b) drying the treated filler slurry to produce treated filler. The treating agent can include a polymer having (i) at least one first group that interacts with the untreated filler and (ii) at least one second group that interacts with a rubber matrix into which the treated filler is incorporated. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.Type: GrantFiled: October 7, 2014Date of Patent: June 27, 2017Assignee: PPG Industries Ohio, Inc.Inventors: Timothy Allen Okel, Peter Lawrence Votruba-Drzal, Justin Jonathan Martin, Raphael O. Kollah, Truman Wilt, Brian K. Rearick, Clint Steven Edelman, Linda K. Anderson, Feng Wang, Kurt G. Olson
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Patent number: 9688785Abstract: A composition comprising at least one first divalent unit represented by formula: and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. R? and R?? are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.Type: GrantFiled: January 30, 2015Date of Patent: June 27, 2017Assignee: 3M Innovative Properties CompanyInventors: Chetan P. Jariwala, Gregory D. Clark, Jason T. Petrin, Rudolf J. Dams, Steven J. Martin, Mark J. Pellerite
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Patent number: 9688786Abstract: The invention pertains to a hyperbranched (per)fluoroelastomer [fluoroelastomer (B)] comprising recurring units derived from a bis-olefin [bis-olefin (OF)] having general formula (I): wherein R1, R2, R3, R4, R5 and R6, equal or different from each other, are H or C1-C5 alkyl; Z is a linear or branched C1-C18 alkylene or cycloalkylene radical, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical, said fluoroelastomer (B) having a slope in G? curve such that the ratio: G?100/G?0.01 is of less than 10, when determined at 260° C. according to ASTM D4440 standard, wherein G?100 is the storage modulus at a shear rate of 100 rad/sec and G?0.01 is the storage modulus at a shear rate of 0.01 rad/sec, to compositions comprising the same, and to a process for their manufacture.Type: GrantFiled: June 7, 2012Date of Patent: June 27, 2017Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Matteo Fantoni, Giovanni Comino, Marco Apostolo
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Patent number: 9688787Abstract: An object of the invention is to provide a polymerizable compound having small refractive index anisotropy and having high storage stability and high alignment properties when constituting a polymerizable liquid crystal composition, and provide a polymerizable liquid crystal composition containing the polymerizable compound. Further, the object is to provide a polymer produced by polymerizing the polymerizable liquid crystal composition and an optically anisotropic body including the polymer. The present invention provides a polymerizable compound represented by general formula (I), a polymerizable liquid crystal composition containing the compound as a constituent component, and further provides a polymer produced by polymerizing the polymerizable liquid crystal composition and an optically anisotropic body including the polymer.Type: GrantFiled: August 14, 2015Date of Patent: June 27, 2017Assignee: DIC CORPORATIONInventors: Tetsuo Kusumoto, Masahiro Horiguchi, Takashi Matsumoto, Yoshio Aoki, Masanao Hayashi, Masayuki Iwakubo
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Patent number: 9688788Abstract: Polymer particle embolics and methods of making same are described. The particle embolics can be used as embolization agents.Type: GrantFiled: November 7, 2014Date of Patent: June 27, 2017Assignee: Terumo CorporationInventors: Steve Plotkin, Gregory M. Cruise, Edward Michael Keeley, Renee Yu, Clayton Harris
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Patent number: 9688789Abstract: Described herein are the synthesis and polymerization of a series of N-Boc-protected amino acid vinyl ester (BAAVE) monomers. Homopolymers and heteropolymers containing the monomers are described, particularly heteropolymers with vinyl ester monomers such as vinyl acetate. Deprotection can be used to produce hydrophilic and hydrophobic polymers that are particular useful in biological applications such as cellular delivery of biological materials.Type: GrantFiled: June 16, 2014Date of Patent: June 27, 2017Assignee: NATIONAL SCIENCE FOUNDATIONInventors: Mahesh Kalyana Mahanthappa, Glen Bradley Thomas, Corinne Elizabeth Lipscomb
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Patent number: 9688790Abstract: The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor.Type: GrantFiled: June 24, 2013Date of Patent: June 27, 2017Assignee: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Mansour Taftaf, Martin Alexander Zuideveld, Aurora Alexandra Batinas-Geurts, Jaiprakash Brijlal Sainani, Vimalkumar Mahendrabhai Patel, Vladimir Aleksandrovich Zakharov, Gennadii Dimitrievich Bukatov, Sergei Andreevich Sergeev, Nourdin Ghalit
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Patent number: 9688791Abstract: A polyisobutylene having a total content of vinylidene double bonds of more than 50 mol % and a number-average molecular weight of 500 to 10 000 daltons, where at least 10% of all the vinylidene double bonds in the polyisobutylene are part of one or more side chains composed of at least 2 carbon atoms from the main polyisobutylene chain. Such a polyisobutylene is suitable for production of fuel and lubricant additives.Type: GrantFiled: July 7, 2014Date of Patent: June 27, 2017Assignee: BASF SEInventors: Thomas Wettling, Stefan Hirsch, Markus Brym, Markus Weis
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Patent number: 9688792Abstract: A process may include contacting an olefin monomer and a racemic bridged metallocene catalyst at a temperature of 80° C. to 150° C. in the presence of hydrogen. The racemic bridged metallocene catalyst may include a metallocene compound (A) and an activator component (B). The process may include recovering an effluent containing polyalpha-olefins (PAOs). The metallocene compound (A) may be represented by the formula R(Cp1)(Cp2)MX1X2. In the formula, R may be a C1-C20 alkylene bridging group; Cp1 and Cp2 may be the same or different substituted or unsubstituted tetrahydroindenyl rings; M may be a transition metal; and X1 and X2 may be independently selected from hydrogen, halogen, hydride radicals, hydrocarbyl radicals, substituted hydrocarbyl radicals, halocarbyl radicals, substituted halocarbyl radicals, silylcarbyl radicals, substituted silylcarbyl radicals, germylcarbyl radicals, substituted germylcarbyl radicals.Type: GrantFiled: May 29, 2015Date of Patent: June 27, 2017Assignee: Total Research & Technology FeluyInventors: Alexandre Welle, Jeroen Wassenaar, Martine Slawinski
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Patent number: 9688793Abstract: The present invention relates to a method of preparing a vinyl chloride polymer having good thermal stability by restraining a dehydrochlorination reaction due to heat or ultraviolet rays, and a vinyl chloride polymer prepared thereby. According to the preparation method, the adding point of a modifier is controlled, and a vinyl chloride polymer markedly restraining the generation of dehydrochloric acid due to heat or ultraviolet rays may be prepared. Therefore, the preparation method of the vinyl chloride polymer via the emulsion polymerization and the vinyl chloride polymer prepared thereby in the present invention may be readily applied to industries requiring the vinyl chloride polymer such as industries concerning a vinyl chloride resin and a molded article.Type: GrantFiled: September 14, 2015Date of Patent: June 27, 2017Assignee: LG Chem, Ltd.Inventors: Kyung Seog Youk, Hyun Min Lee, Chan Hee Lee, Heung Kwon Bae, Kwang Jin Lee, Kyung Hyun Kim, Jung Rae Lee
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Patent number: 9688794Abstract: The present invention relates to tackifier compounds and methods of using the same. In various embodiments, the present invention provides a tackifier compound including independently substituted or unsubstituted fused rings A and B each independently chosen from (C5-C10)cycloalkyl and (C2-C10)heterocyclyl. Fused ring A is substituted with (R1)1-8 and fused ring B is substituted with —(OC(O)R?C(O)R2)1-8. At each occurrence R? is independently chosen from (C2-C10)alkanylene, (C2-C10)alkenylene, (C2-C10)alkynylene, C5-C20(arylene), and (C1-C20)heteroarylene, wherein R? is unsubstituted or substituted. At each occurrence R1 is independently selected from —OH, —OR3, and —OC(O)R?C(O)R2. At each occurrence R2 is independently chosen from —OH, —OR3, —NH2, —NHR3, and —NR32. At each occurrence R3 is independently chosen from (C1-C10)alkanyl, (C2-C10)alkenyl, (C2-C10)alkynyl, C5-C20(aryl), and (C1-C20)heteroaryl, wherein R3 is unsubstituted or substituted.Type: GrantFiled: October 15, 2013Date of Patent: June 27, 2017Assignee: Iowa State University Research Foundation, Inc.Inventors: Jason Shih-Hao Chen, Michael Richard Kessler, Michael Dennis Zenner
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Patent number: 9688795Abstract: The invention provides compositions, each comprising an ethylene/alpha-olefin interpolymer, which has a reduced level of a low density, low molecular weight oligomeric fraction, as indicated by an HCC value, as described herein, and reduced levels of inorganic content or lower Tm. The invention also provides processes for forming such interpolymers.Type: GrantFiled: July 9, 2014Date of Patent: June 27, 2017Assignee: Dow Global Technologies LLCInventors: Frank J. Cerk, Rongjuan Cong, Shrikant Dhodapkar, Selim Yalvac, Morgan M. Hughes, Timothy W. Gambrel, Yi Jin
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Patent number: 9688796Abstract: Provided are a tetrafluoroethylene copolymers having a melting point of at least 317° C., a melt flow index (MFI) at 372° C. and a 5 kg load (MFI 372/5) of from about 0.60 g/10 min up to about 15 g/10 min. Also provided are methods of forming a shaped article using the copolymers described above, shaped articles made with those copolymers and compositions containing such copolymers.Type: GrantFiled: October 20, 2015Date of Patent: June 27, 2017Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Klaus Hintzer, Harald Kaspar, Ludwig Mayer, Tilman C. Zipplies
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Patent number: 9688797Abstract: A fluorine-containing polymer having (a) a repeating unit derived from a fluorine-containing monomer indicated by the formula CH2?C(—X)—C(?O)—Y—Z—Rf, (b) a repeating unit derived from a cyclic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2?CQ11—C(?O)—O-Q12, and (c) a repeating unit derived from an aliphatic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH2?CQ21—C(?O)—O-Q22. The fluorine-containing polymer is produced by polymerizing in the presence of one or both of (d) a silicon-containing monomer and a silicon-containing chain transfer agent.Type: GrantFiled: June 18, 2014Date of Patent: June 27, 2017Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Tetsuya Uehara, Masahiro Miyahara, Masaki Fukumori, Kanako Fukumoto, Ikuo Yamamoto
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Patent number: 9688798Abstract: The method for manufacturing a polymer of the present invention is a method for manufacturing a polymer where a hydroxy group is added to a terminal of either one of a homopolymer of a non-conjugated olefin, a homopolymer of a conjugated diene compound, and a copolymer of a conjugated diene compound and a non-conjugated olefin, the method comprising: a first reaction step of reacting a hydrocarbon containing at least either one of the non-conjugated olefin and the conjugated diene compound with an organic aluminum compound, using a rare earth element compound-containing catalyst; a second reaction step of reacting a first reactant obtained from the first reaction step with oxygen; and a third reaction step of reacting a second reactant obtained from the second reaction step with at least either one of water and alcohol.Type: GrantFiled: August 22, 2012Date of Patent: June 27, 2017Assignee: BRIDGESTONE CORPORATIONInventors: Shojiro Kaita, Yasuo Wakatsuki
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Patent number: 9688799Abstract: Process for the polymerization of olefins in a polymerization reactor system including (i) a gas phase reactor having a gas outlet and one or more withdrawal lines for withdrawal of a polymer-containing stream, (ii) a recycle loop for recycling gas exiting the reactor through the gas outlet back to the reactor, (iii) a polymer separation system for separating reactants from the polymer product in the withdrawn polymer-containing stream, and (iv) a recycle system for recycling reactants removed from the reactor in the withdrawn polymer-containing stream back to the reactor. A scavenger is introduced directly into one or more of the recycle loop, the polymer separation system and the recycle system.Type: GrantFiled: December 15, 2014Date of Patent: June 27, 2017Assignee: INEOS EUROPE AGInventors: Jean-Louis Chamayou, Renaud Viguier
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Patent number: 9688800Abstract: The present invention relates to a hybrid latex composition containing polymer particles that are polymerized in at least two stages including a first phase acrylic core polymer, and a second phase vinyl acrylic shell polymer including a monomer that is crosslinkable under ambient conditions. Paint compositions and architectural coatings containing the latex composition according to the invention are also described herein, as well as methods for making the same.Type: GrantFiled: July 7, 2014Date of Patent: June 27, 2017Assignee: Columbia Insurance CompanyInventors: Robert J. Sheerin, Hrire Gharapetian, Navin Tilara, Kimberly Hamilton
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Patent number: 9688801Abstract: Disclosed is a vinyl polymer powder which is superior to dispersibility to curable resin compositions, which immediately gives a gel state for curable resin compositions by short-time heating with predetermined temperature, which is with high ion concentration, and which is useful as a pre-gel agent suitable for fields of electronic materials, to provide a curable resin composition comprising the vinyl polymer powder, and to provide a cured substance of the curable resin composition. The vinyl polymer powder of the present invention has an acetone-soluble component of 30% by mass or more, mass average molecular weight of the acetone-soluble component of 100,000 or more, a content of an alkali metal ion of 10 ppm or less, and a volume average primary particle size (Dv) of 200 nm or more.Type: GrantFiled: February 4, 2010Date of Patent: June 27, 2017Assignee: MITSUBISHI RAYON CO., LTD.Inventors: Kaori Fukutani, Toshihiro Kasai
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Patent number: 9688802Abstract: The present invention relates to a poly(ethylene-aliphatic diene)-g-polystyrene-based copolymer having an improved mechanical property and heat resistance, and a method for preparing the same. More particularly, the present invention relates to a poly(ethylene-aliphatic diene)-g-polystyrene-based copolymer, which includes an ethylene-aliphatic diene copolymer as a soft segment and a polystyrene-based polymer grafted to the soft segment as a hard segment, and a method for preparing the same. The poly(ethylene-aliphatic diene)-g-polystyrene-based copolymer has elasticity equivalent to that of SBS or SEBS, and improved mechanical properties such as tensile strength and heat resistance, thereby being used as a substituent for SBS or SEBS.Type: GrantFiled: May 23, 2014Date of Patent: June 27, 2017Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Dong Hyun Kim, No Hyung Park, Jung Soo Kim, Dong Gyu Jeon
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Patent number: 9688803Abstract: The present disclosure is directed to a pressure sensitive adhesive composition. The pressure sensitive adhesive composition includes an olefin block copolymer, a silane-grafted olefin block copolymer, a tackifier, and an oil. The pressure sensitive adhesive composition has a shear adhesion greater than 60 minutes. The pressure sensitive adhesive composition exhibits improved shear adhesion while simultaneously maintaining loop tack greater than 4.0 N/25 mm.Type: GrantFiled: December 9, 2013Date of Patent: June 27, 2017Assignee: DOW GLOBAL TECHNOLOGIES LLCInventor: Allan W. McLennaghan
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Patent number: 9688804Abstract: There are described a dispersion of polymeric beads where the beads comprise a copolymer composition comprising (preferably consisting essentially of): copolymers (and processes for making them) comprising (a) at least 8.5 wt-% preferably >=20 wt-% of a higher itaconate diester (preferably dibutyl itaconate—DBI); (b) less than 23 wt-% acid monomer but also sufficient to have an acid value less than 150 mg KOH/g of polymer, (c) optionally with less than 50 wt-% of other itaconate monomers, and (d) optionally less than 77 wt-% of other monomers not (a) to (c). The DBI may be biorenewable. A further embodiment is an aqueous suspension polymerization process for preparing vinyl polymer beads from olefinically unsaturated monomers and a free-radical initiator, where at least 10 wt-% of the monomer is DBI.Type: GrantFiled: February 4, 2013Date of Patent: June 27, 2017Assignee: DSM IP ASSETS B.V.Inventors: Tijs Nabuurs, Gerardus Cornelis Overbeek, Jeffrey Stubbs, Matthew Stewart Gebhard
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Patent number: 9688805Abstract: The present invention relates to elastomeric resins, fibers made from said resins, fabrics made with said fibers, and applications and uses for the resins, fibers and fabrics. The elastomer resins of the invention provide high strength fibers and well balanced fabrics with good physical properties and chemical resistance, making them attractive for use in various applications that use elastic fibers and fabrics.Type: GrantFiled: December 19, 2011Date of Patent: June 27, 2017Assignee: Lubrizol Advanced Materials, Inc.Inventors: Ravi R. Vedula, James E. Bryson, Jr., Mouh-Wahng Lee, Daniel M. Fischer, Christopher A. Sprague
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Patent number: 9688806Abstract: The present invention is related to a new method to produce natural water-based glues made of two components, designed to glue lignocellulosic surfaces, mainly cork and wood. The mentioned process comprises the extraction of the aqueous phase of a mixture resulting from liquefying cork dust and/or cork granules, process that is commonly referred to as depolimerization process of cork; evaporation of the aqueous phase, therefore obtaining a first component consisting of a gel composed by the soluble components of the liquefying mixture; mixing and homogenizing of this gel with the second component that consists of a curing aliphatic compound; and, optionally, addition and mixture to “cork dust” to the previously mentioned mix.Type: GrantFiled: September 2, 2014Date of Patent: June 27, 2017Assignees: CORK SUPPLY PORTUGAL, S.A., INSTITUTO SUPERIOR TÉCNICOInventors: João Carlos Moura Bordado, Elisabete Ribeiro Silva, Rui Miguel Galhano Dos Santos Lopes, Maria Margarida Pires Dos Santos Mateus, Ana Cristina De Avelar Lopes Cardoso Mesquita, Maria Do Rosário Melo Costa
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Patent number: 9688807Abstract: A two-component curable epoxy resin system is disclosed. The resin system includes an epoxy resin component containing at least 80% by weight of a polyglycidyl ether of a polyphenol. The system also includes a hardener mixture containing mainly polyethylene tetraamines. The system includes one or more of i) alkali metal salts, ii) carboxylic acid-, carboxylic anhydride- or carboxylic acid ester-substituted phenol compounds, iii) an amino as a catalyst. The system has beneficial curing characteristics that make it useful for producing fiber-reinforced composites in a resin transfer molding process.Type: GrantFiled: November 11, 2013Date of Patent: June 27, 2017Assignee: Dow Global Technologies LLCInventors: Sergio Grunder, Rainer Koeniger, Timothy A. Morley, Nebjosa Jelic, Martin Reimers, Peter Cate
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Patent number: 9688808Abstract: Fiber reinforced epoxy resin composites are produced using a specific epoxy resin system. The epoxy resin system contains at least one polyglycidyl ether of a polyphenol. The system also contains a hardener that contains a mixture of aminocyclohexanealkylamine and polyalkylene polyamine hardeners. The ratio of epoxy resin groups to amine hydrogen groups is from 1.05 to 1.50. The epoxy resin system contains a tertiary amine catalyst such as a tertiaryaminophenol, a benzyl tertiary amine or an imidazole compound.Type: GrantFiled: June 21, 2012Date of Patent: June 27, 2017Assignee: Dow Global Technologies LLCInventors: Timothy A. Morley, Radhakrishnan Karunakaran, Carol L. O'Connell, Nigel Shields, Nikhil K. Verghese, Martin Reimers
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Patent number: 9688809Abstract: Provided is a method for purifying an aliphatic polyester which reduces coloring of the aliphatic polyester, reduces the amount of residual monomer and residual catalyst, and improves stability and appearance. This method for purifying an aliphatic polyester subjects an aliphatic polyester containing a monomer to heat treatment under dry air containing oxygen at a temperature at or above the melting point of the monomer and at or below the melting point of the aliphatic polyester.Type: GrantFiled: April 19, 2013Date of Patent: June 27, 2017Assignee: MUSASHINO CHEMICAL LABORATORY, LTD.Inventors: Yukiko Tokushige, Tsuyoshi Aoki, Koichiro Suzuki, Jun Machida
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Patent number: 9688810Abstract: A resin composed of a particular polymer, the particular polymer including a repeating unit containing a structure derived from a dehydroabietic acid, a specific structural unit, and a specific aromatic ring-containing structural unit in the main chain.Type: GrantFiled: January 24, 2014Date of Patent: June 27, 2017Assignee: FUJIFILM CorporationInventors: Takafumi Hosokawa, Kiyotaka Fukagawa
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Patent number: 9688811Abstract: A method for synthesizing poly(butylene succinate) (PBS) having a weight average molecular weight (Mw) equal to or larger than 1.4×105. The method employs biogenic guanidine (BG) as the main catalyst and includes: a) adding succinic acid (SA), 1.4-butanediol (BDO), and biogenic guanidine to a reactor, heating the reactor to a temperature of between 180 and 200° C. and conducting the esterification between succinic acid and 1.4-butanediol for 2 to 3 hours under atmospheric pressure until all of the water is distilled or boiled off; and b) adding a first cocatalyst, a second cocatalyst, and a third cocatalyst to the reactor, adjusting the absolute pressure in the reactor to be between 0.5 and 3 torr, and polycondensing the mixture in the reactor at the temperature between 210 and 230° C. over 20 to 30 hours.Type: GrantFiled: September 12, 2016Date of Patent: June 27, 2017Assignee: NANJING UNIVERSITYInventors: Hong Li, Quanxing Zhang, Yiting Song, Xiangqian Sun, Wei Huang, Aimin Li
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Patent number: 9688812Abstract: A method includes producing libraries of nanoparticles having highly controlled properties, which can be formed by mixing together two or more macromolecules in different ratios. One or more of the macromolecules may be a polymeric conjugate of a moiety to a biocompatible polymer. The nanoparticle may contain a drug. The moiety may include a polypeptide or a polynucleotide, such as an aptamer. The moiety may be a targeting moiety, an imaging moiety, a chelating moiety, a charged moiety, or a therapeutic moiety. Another aspect is directed to systems and methods of producing such polymeric conjugates. In some embodiments, a solution containing a polymer is contacted with a liquid, such as an immiscible liquid, to form nanoparticles containing the polymeric conjugate. Other methods use such libraries, use or administer such polymeric conjugates, or promote the use of such polymeric conjugates. Kits involving such polymeric conjugates are also described.Type: GrantFiled: February 13, 2015Date of Patent: June 27, 2017Assignees: Massachusetts Institute of Technology, The Brigham and Women's Hospital, Inc.Inventors: Frank X. Gu, Omid C. Farokhzad, Robert S. Langer, Benjamin A. Teply
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Patent number: 9688813Abstract: Disclosed is a thermoplastic polyester elastomer, which is formed by reacting 100 parts by weight of polyester and 0.01 to 2 parts by weight of an epoxy resin with two epoxy groups, wherein the polyester is formed by reacting a parts by mole of a hard-segment diol, b parts by mole of a soft-segment diol, and 1 part by mole of a diacid, wherein 1?a?3 and 0.005?b?1.5.Type: GrantFiled: December 24, 2014Date of Patent: June 27, 2017Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chun-Hsiung Liao, Jen-Chun Chiu, Cing-Jiuh Kang, Chung-Cheng Lin, Chin-Lang Wu, Yu-Chuan Hsu
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Patent number: 9688814Abstract: The invention relates to a method for producing functionalized polyoxymethylene block copolymers comprising the step of polymerizing formaldehyde in a reaction vessel in the presence of a catalyst, the polymerization of formaldehyde in addition taking place in the presence of a starter compound comprising at least 2 Zerewitinoff active H atoms, to obtain an intermediate product. The intermediate product obtained is subsequently reacted with a cyclic carboxylic acid ester or carbonic acid ester, thus obtaining a functionalized polyoxymethylene block copolymer. The invention further relates to functionalized polyoxymethylene block copolymers obtained by such a method and to the use of said copolymers.Type: GrantFiled: December 18, 2013Date of Patent: June 27, 2017Assignee: Covestro Deutschland AGInventors: Thomas Ernst Müller, Christoph Gürtler, Walter Leitner, Henning Vogt, Gabor Barath
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Patent number: 9688815Abstract: A method for producing a polyimide precursor, including: reacting tetracarboxylic dianhydride represented by the following General Formula (1) with a diamine compound represented by the following General Formula (2) in a compressive fluid to thereby produce a polyimide precursor represented by the following Formula (3): where, X in the General Formulae (1) and (3) denotes a tetravalent aromatic group or a tetravalent alicyclic group, Y in the General Formulae (2) and (3) denotes a divalent organic group, and n denotes the number of repetitions.Type: GrantFiled: May 19, 2014Date of Patent: June 27, 2017Assignee: RICOH COMPANY, LTD.Inventor: Chiyoshi Nozaki
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Patent number: 9688816Abstract: This disclosure relates to polyetherimide compositions whose residual phenolic monomers exhibit little or no estradiol binding activity. Also disclosed are methods for making the disclosed polyetherimides and articles of manufacture comprising the disclosed polyetherimides.Type: GrantFiled: January 20, 2015Date of Patent: June 27, 2017Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Robert R. Gallucci, James A. Mahood, Roy R. Odle, Steve Dimond
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Patent number: 9688817Abstract: A problem is to provide a method for producing a polyarylene sulfide resin having excellent reactivity to other compounds and resins, such as an impact resistance improver such as an epoxysilane coupling agent, a functional group-containing thermoplastic elastomer, or the like, and also provide a polyarylene sulfide resin composition produced by the production method, not containing chlorine atoms, and having the excellent reactivity. A method for producing a polyarylene sulfide resin includes performing polymerization reaction of a mixture containing a diiodo aromatic compound, a sulfur compound, and a polymerization inhibitor having a specified functional group. The problem can be solved by using a polyarylene sulfide resin composition containing a polyarylene sulfide resin having a specified terminal functional group and iodine atoms within a range of 0.01 to 10,000 ppm relative to the polyarylene sulfide resin.Type: GrantFiled: March 20, 2014Date of Patent: June 27, 2017Assignee: DIC CORPORATION (TOKYO)Inventors: Hajime Watanabe, Toshio Hinokimori
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Patent number: 9688818Abstract: Poly(ether sulfones) (PES) and poly(ether amide sulfones) (PEAS) were prepared from post-consumer polycarbonates and polyesters, respectively, using a single vessel in batch mode (all reactants present when heating was initiated). The depolymerization of the initial polymer occurs concurrently with step growth polymerization to form a product polymer having a number average molecular weight of at least 5000.Type: GrantFiled: May 10, 2016Date of Patent: June 27, 2017Assignee: International Business Machines CorporationInventors: Krishna M. Bajjuri, Jeannette M. Garcia, James L. Hedrick
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Patent number: 9688819Abstract: Addition-crosslinkable silicone resin compositions containing a branched organopolysiloxane bearing each of Si—H groups, alkenyl groups, and aryl groups, and also containing blocks of linear organopolysiloxane free of Si—H and alkenyl groups with a chain length of at least three siloxy groups, and further bearing at least one aryl group, serve as excellent potting compositions for electronic devices, particularly LEDs, with high refractive index and optical transmittance, and wide processing latitude.Type: GrantFiled: July 30, 2014Date of Patent: June 27, 2017Assignee: WACKER CHEMIE AGInventors: Frank Sandmeyer, Enno Funk, Georg Loessel
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Patent number: 9688820Abstract: Provided are a curable composition and its use. The curable composition may provide a cured product having excellent processability and workability, no surface stickiness, and an excellent adhesive property. The curable composition has excellent thermal resistance, crack resistance, and gas permeability. The curable composition may have stable performance when being applied to a semiconductor device at a high temperature for a long time.Type: GrantFiled: April 4, 2014Date of Patent: June 27, 2017Assignee: LG CHEM, LTD.Inventors: Min Jin Ko, Kyung Mi Kim, Young Ju Park
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Patent number: 9688821Abstract: A method of producing a glycerin derivative-modified silicone or a composition comprising the same, including a process that treats the glycerin derivative-modified silicone or the composition comprising the same with one or more type of acidic inorganic salt, which is solid at 25° C. and water soluble, and which is such that a pH at 25° C. of an aqueous solution prepared by dissolving 50 g of the acidic inorganic salt in 1 L of ion exchanged water is 4 or lower; and an external use preparation, cosmetic composition, or raw materials thereof that contain the low odor glycerin derivative-modified silicone obtained by the production method.Type: GrantFiled: December 26, 2012Date of Patent: June 27, 2017Assignee: DOW CORNING TORAY CO., LTD.Inventors: Seiki Tamura, Tatsuo Souda, Seiji Hori
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Patent number: 9688822Abstract: The present invention relates to a curable silicone composition comprising: (A) an organopolysiloxane represented by a specific average unit formula, (B) an optional straight-chain organopolysiloxane having at least two alkenyl groups and not having any silicon-bonded hydrogen atoms in a molecule, (C) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule, and (D) a hydrosilylation reaction catalyst. The curable silicone composition has high reactivity and forms a cured product with low gas permeability.Type: GrantFiled: October 23, 2013Date of Patent: June 27, 2017Assignee: DOW CORNING TORAY CO., LTD.Inventors: Michitaka Suto, Takashi Sagawa, Kasumi Takeuchi, Tomohiro Iimura, Kazuhiro Nishijima, Yoshitsugu Morita
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Patent number: 9688823Abstract: The invention relates to a method for the melted production, especially by reactive extrusion, of block copolyamide comprising at least one aliphatic polyamide block and at least one semi-aromatic block, especially wherein the aromatic group has at least one hydroxyl or sulfonate function. The invention also relates to the block copolyamide that can be produced by said method; to a composition comprising the block copolyamide; to granules comprising such a copolyamide or such a composition; to a method for producing an item from a copolyamide or a composition of said copolyamide; and to uses of the copolyamide.Type: GrantFiled: November 13, 2013Date of Patent: June 27, 2017Assignees: RHODIA OPERATIONS, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Naji Hussein, Didier Long, Louise-Anne Fillot, Lise Trouillet-Fonti
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Patent number: 9688824Abstract: The invention relates to a method for making a lignin component from lignin material by an acid treatment, the method comprising: forming a lignin component of lignin material by treating the lignin material in at least one acid treatment stage; and optimizing process conditions by means of a combination of process parameters comprising retention time, temperature and pH level at the acid treatment stage so that the retention time is over 6 hours during at least one acid treatment stage. Further, the invention relates to corresponding lignin components, a use of the lignin component and a product.Type: GrantFiled: December 5, 2012Date of Patent: June 27, 2017Assignee: UPM-Kymmene CorporationInventor: Mauno Miettinen
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Patent number: 9688825Abstract: The present invention relates to a method for producing a rubber composition containing a rubber component (A) of at least one selected from natural rubbers and synthetic dienic rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C) and at least one vulcanization promoter (D) selected from guanidines, sulfenamides, thiazoles, thiurams, dithiocarbamate salts, thioureas and xanthate salts, wherein the rubber composition is kneaded in at least three stages, in the first stage (X) of kneading, the rubber component (A), all or a part of the inorganic filler (B), and all or a part of the silane coupling agent (C) are kneaded, then in the stage (Y) on and after the second stage of kneading but before the final stage, the vulcanization promoter (D) is added and kneaded, and in the final stage (Z) of kneading, a vulcanizing agent is added and kneaded.Type: GrantFiled: October 3, 2011Date of Patent: June 27, 2017Assignee: BRIDGESTONE CORPORATIONInventors: Seiichi Katou, Satoshi Horie
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Patent number: 9688826Abstract: It is provided that a biaxially stretched polyester film suitable for uses for which nylon films and other flexible films have conventionally been used and a method for producing the film. A biaxially stretched polyester film made of a polyester resin composition (A) containing not less than 60 mass % of polybutylene terephthalate and having yield stress in a MD of not more than 70 MPa, yield stress in a TD of not more than 70 MPa, rupture strength in the MD of not less than 160 MPa, rupture strength in the TD of not less than 160 MPa, and rupture elongation in the MD and TD of not less than 100%.Type: GrantFiled: November 8, 2013Date of Patent: June 27, 2017Assignee: Toyobo Co., Ltd.Inventors: Takamichi Gotou, Toshiyuki Shimizu, Tadashi Nakaya, Yoshitomo Ikehata
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Patent number: 9688827Abstract: A method for infusing a nanoporous tendrillar mat with resin includes: performing a short duration, elevated temperature, pre-cure contacting treatment of the tendrillar mat using resin, thereby substantially uniformly infusing the tendrillar mat with resin; and curing the resin-infused tendrillar mat.Type: GrantFiled: August 29, 2016Date of Patent: June 27, 2017Assignee: Northrop Grumman Systems CorporationInventors: John A. Starkovich, Hsiao-Hu Peng, Edward M. Silverman
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Patent number: 9688828Abstract: Provided are non-crosslinked foamed polyethylene resin particles that have a bulk density BD of 10 g/L or more and 100 g/L or less and are obtained by foaming polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm3 or more and less than 0.940 g/cm3, and the non-crosslinked foamed polyethylene resin particles have a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1). The non-crosslinked foamed polyethylene resin particles can simply afford an antistatic molded non-crosslinked foamed polyethylene resin body that has a small shrinkage ratio with respect to mold dimension, is deformed in a small degree, and has good surface stretch.Type: GrantFiled: July 13, 2012Date of Patent: June 27, 2017Assignee: KANEKA CORPORATIONInventor: Kiyotaka Nakayama
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Patent number: 9688829Abstract: Provided is a composition for a foam tire. The composition includes 100 parts by weight of a blend of an olefin block copolymer and a rubber as a polymer matrix, 0.02 to 4 parts by weight of a crosslinking agent, and 1 to 6 parts by weight of a foaming agent. The olefin block copolymer and the rubber are present in amounts of 50 to 80% by weight and 20 to 50% by weight, respectively, based on the total weight of the polymer matrix.Type: GrantFiled: July 19, 2013Date of Patent: June 27, 2017Inventor: Young-Gi Lee
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Patent number: 9688830Abstract: Described are (a) a process for production of polyurethane foam by reacting one or more polyol components with one or more isocyanate components, wherein wax having a congealing point in the range from 40° C. to 90° C. is employed as an additive, (b) a polyurethane foam obtainable by said process, (c) the use of waxes having a congealing point in the range from 40° C. to 90° C. as an additive in the manufacture of polyurethane foams to coarsen the foam structure, and also (d) a polyurethane foam production composition containing a wax having a congealing point in the range from 40° C. to 90° C.Type: GrantFiled: April 10, 2014Date of Patent: June 27, 2017Assignee: Evonik Degussa GmbHInventors: Eva Emmrich-Smolczyk, Harald Modro, Ralf Althoff, Rainer Ziegler
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Patent number: 9688831Abstract: There is disclosed a phenol resin foam comprising a phenol resin, a hydrocarbon having 6 or less carbon atoms, and at least one halogenated hydroolefin selected from the group consisting of hydrofluoroolefins and hydrochlorofluoroolefins, and the phenol resin foam having the density of 10 kg/m3 or more and 150 kg/m3 or less, wherein the sum of the content of the hydrocarbon having 6 or less carbon atoms and the content of the hydrogenated hydroolefin is from 0.23 to 0.90 mol, the content of the hydrocarbon having 6 or less carbon atoms is from 0.03 to 0.85 mol, and the content of the halogenated hydroolefin is from 0.05 to 0.85 mol, per 22.4×10?3 m3 of spatial volume in the phenol resin foam.Type: GrantFiled: December 25, 2014Date of Patent: June 27, 2017Assignee: ASAHI KASEI CONSTRUCTION MATERIALS CORPORATIONInventors: Masato Hamajima, Shigemi Mukaiyama, Ken Ihara, Atsushi Kumada