Patents Issued in October 3, 2017
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Patent number: 9776918Abstract: The present invention provides a dry mix of cement, sand, metakaolin in the amount of 5 wt % or less, based on total solids in the dry mix, and aluminum cement in a low amount (?1 wt. %, based on total solids in the dry mix) useful as a tile grout, as well as uses thereof and to methods of using the same as a tile grout. The dry mix when made into a mortar exhibits excellent resistance to efflorescence as a tile grout.Type: GrantFiled: December 29, 2011Date of Patent: October 3, 2017Assignee: Dow Global Technologies LLCInventor: Jonas L. Lu
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Patent number: 9776919Abstract: A hydraulic binder includes a Portland clinker having a Blaine specific surface of 4000 to 5500 cm2/g, from 2.5 to 8% of sulphate expressed by mass of SO3 relative to the mass of clinker, from 1.5 to 10% of calcium nitrite and/or calcium nitrate expressed as anhydrous mass relative to the mass of clinker and from 15 to 50% of a mineral addition including calcium carbonate by mass relative to the total mass of binder.Type: GrantFiled: May 21, 2013Date of Patent: October 3, 2017Assignee: LAFARGEInventors: Serge Sabio, Serge Ghilardi, Xiaolin Pardal, Michel Testud
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Patent number: 9776920Abstract: The invention comprises a concrete form. The form comprises a first concrete forming panel having a first primary surface adapted for forming and contacting plastic concrete and a second primary surface opposite the first primary surface; a layer of insulating material contacting and substantially covering the second primary surface of the first concrete forming panel; and an insulating blanket adjacent the first concrete forming panel. A method of using the concrete form is also disclosed.Type: GrantFiled: September 9, 2014Date of Patent: October 3, 2017Inventor: Romeo Ilarian Ciuperca
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Patent number: 9776921Abstract: There is provided an apparatus and process for manufacturing a brick or paver with a high content of coal ash (ranging from 60% to 100% coal ash or fly ash) so that a waste product (coal ash, and more particularly Class F coal ash) from a coal-fired power plant is incorporated into a building product (high content fly ash brick or paver). Also provided is a variable firing tray to support the dried, high content coal ash bricks/pavers as the dried products are sent through a tunnel kiln, to improve circulation around the individual bricks/pavers and thereby result in reduced firing time in the kiln.Type: GrantFiled: July 13, 2011Date of Patent: October 3, 2017Assignees: THE BELDEN BRICK COMPANY, LLC, ECO-ASH, LLCInventors: Robert Thomas Belden, Michel Cristallo, George W. Ittmann, Robert W. Ittmann
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Patent number: 9776922Abstract: The invention provides a shuttle kiln that can fire ceramic porous bodies containing organic binders in a shorter period of time than in conventional methods without occurring breaks due to a temperature difference between the inside and the outside. The shuttle kiln of the invention is suited for firing of ceramic porous bodies containing organic binders. It includes a gas suction path 4 that suctions in-furnace gas and discharges it via an afterburner 5 and a circulation path 7 that suctions the in-furnace gas to the furnace outside to burn organic binder gas and then returns it into the furnace.Type: GrantFiled: September 10, 2013Date of Patent: October 3, 2017Assignee: NGK Insulators, Ltd.Inventors: Jotaro Miyata, Chikashi Ihara, Takashi Yasue
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Patent number: 9776923Abstract: A powdery composition based on silica for ceramic welding, in particular by projection, comprising from 10 to 90% of a phase of siliceous particles comprise at least 80% by weight of cristobalite and at most 15% by weight of tridymite, based on the total weight of the composition, from 90 to 10% by weight of conventional additives forming a binding phase, based on the total weight of the composition, said siliceous particles having a d50 comprised between 350 and 800 ?m, preferably between 400 and 500 ?m.Type: GrantFiled: December 10, 2014Date of Patent: October 3, 2017Assignee: FIB-SERVICES INTELLECTUAL S.A.Inventors: Osvaldo Di Loreto, Jacques Tirlocq
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Patent number: 9776924Abstract: A mullite sintered body according to the present invention has an impurity element content of 1% by mass or less and contains sintered mullite grains having an average grain size of 8 ?m or less. When a surface of the mullite sintered body is finished by polishing, pores in the surface have an average largest pore length of 0.4 ?m or less. The surface preferably has a center line average surface roughness (Ra) of 3 nm or less. The surface preferably has a maximum peak height (Rp) of 30 nm or less. The number of pores in the surface is preferably 10 or less per unit area of 4 ?m×4 ?m.Type: GrantFiled: March 9, 2016Date of Patent: October 3, 2017Assignee: NGK Insulators, Ltd.Inventors: Yoshinori Isoda, Yosuke Sato, Yuji Katsuda
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Patent number: 9776925Abstract: [Problem] The problem addressed lies in providing a dielectric composition having a relatively high dielectric constant of 900 or greater when a DC bias of at least 8 V/ym is applied, and also in providing a dielectric element employing said dielectric composition, an electronic component, and a laminated electronic component. [Solution] A dielectric composition in which the composition of the main component is in accordance with the following formula (1): (BiaNabSrc)(ZndTi1_d)03 (1) [where a, b, c and d satisfy the following: 0.09?a?0.58, 0.09?b?0.42, 0.05?c?0.84, 0?d?0.08, and 0.95?a+b+c?1.05].Type: GrantFiled: January 21, 2015Date of Patent: October 3, 2017Assignee: EPCOS AGInventors: Tomoya Imura, Goushi Tauchi, Masakazu Hirose
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Patent number: 9776926Abstract: A zirconia sintered body, where when cross-sectional area of each zirconia crystal-grain is calculated in image of cross section of zirconia sintered body, converted crystal-grain size of each zirconia crystal-grain is calculated based on cross-sectional area where each zirconia crystal-grain has circular cross-sectional shape, zirconia crystal-grains are classified into class of <0.4 ?m, class of ?0.4 and <0.76 ?m, and class of ?0.76 ?m based on converted crystal-grain size, total cross-sectional area of zirconia crystal-grains is calculated in each of classes, and rate of cross-sectional area to total cross-sectional area of all zirconia crystal-grains whose cross-sectional area has been calculated is calculated in each class, rate of cross-sectional area of zirconia crystal-grains in class of <0.4 ?m is 4% to 35%, rate of cross-sectional area of zirconia crystal-grains in class of ?0.4 and <0.76 ?m is 24% to 57%, and rate of cross-sectional area of zirconia crystal-grains in class of ?0.Type: GrantFiled: March 10, 2014Date of Patent: October 3, 2017Assignee: KURARAY NORITAKE DENTAL INC.Inventors: Yoshihisa Yamada, Atsushi Matsumoto, Yoshihisa Ito
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Patent number: 9776927Abstract: Provided is a long and large-area graphite film having improved thermal diffusivity and flex resistance, and accompanied by ameliorated ruffling. According to a method for producing a graphite film, in which graphitization of a heat-treated film consisting of a carbonized polymer film is carried out in a state being wrapped around an internal core, the method being characterized in that a heat treatment is executed by controlling distance(s) between the internal core and the film, and/or between the layers of the film, a graphite film accompanied by significantly ameliorated ruffling can be obtained.Type: GrantFiled: January 13, 2016Date of Patent: October 3, 2017Assignee: KANEKA CORPORATIONInventors: Yusuke Ohta, Makoto Mishiro, Takashi Inada, Yasushi Nishikawa
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Patent number: 9776928Abstract: The present invention relates to a method for preparing a carbon-based particle/copper composite material in which carbon-based particles such as graphite and copper are mixed, the method including mixing a solution of a polymer organic compound having a main chain of carbon and a copper precursor in a solvent, with a dispersion solution of carbon-based particles in a first dispersion medium to produce a mixture, adding a first reducing agent to the mixture to form composite particles in which copper (I) oxide particles are attached to the surface of the carbon-based particles, and sintering the composite particles under a non-oxidizing atmosphere. According to the preparing method, a composition material is obtained, in which carbon-based particles and copper are well mixed.Type: GrantFiled: August 3, 2011Date of Patent: October 3, 2017Assignee: LG CHEM, LTD.Inventors: Woo-Ram Lee, Sang-Ho Kim, Jong-Wuk Park
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Patent number: 9776929Abstract: A method is described for assembling at least two parts made of silicon carbide based materials by non-reactive brazing in an oxidizing atmosphere, each of the parts comprising a surface to be assembled, wherein the parts are placed in contact with a non-reactive brazing composition, the assembly formed by the parts and the brazing composition is heated to a brazing temperature sufficient for completely or at least partially melting the brazing composition, or rendering the brazing composition viscous, and the parts and the brazing composition are cooled so as to form, after cooling the latter to ambient temperature, a moderately refractory joint.Type: GrantFiled: December 20, 2012Date of Patent: October 3, 2017Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVESInventors: Valérie Chaumat, Jean-François Henne, Fiqiri Hodaj
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Patent number: 9776930Abstract: Nano-porous corundum ceramics and methods of manufacture are disclosed. The method of forming nano-porous corundum ceramics includes milling corundum powder in aqueous slurry with beads. The method further includes processing the slurry by a liquid shaping process to form a gelled body. The method further includes sintering the gelled body between 600° C. to 1000° C.Type: GrantFiled: August 27, 2014Date of Patent: October 3, 2017Assignees: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGY, FRAUNHOFER-GESELLSCHAFTInventors: Mohammed A. Binhussain, Akeel Khalid Alakeel, Majid Mohammed Binmajid, Jens Klimke
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Patent number: 9776931Abstract: A facility secondary NO3? salinized soil modifier and a modification method are disclosed. The present invention involves the preparation processes of two biological soil modifiers A and B and application methods thereof, which are specifically described as follows: (1) soil modifier A: solid, obtained by microbial fermentation with straw powder and rice bran and the like as raw materials, C/N between 30-50, applied by uniformly mixing at 1-1.4‰ by mass with facility ploughing soil, co-culturing at 35-50° C. for 5-7 days, and then returning to fields; and (2) soil modifier B: liquid, subjected to salt tolerance acclimation to have effective microbial populations, and used in the crop growth period. Based on the microbial techniques, the present invention can improve soil structureness, enhance microbial activity and promote biological immobilization on inorganic nitrogen in soils, significantly increasing the facility cultivation crop yield, and improving the product quality.Type: GrantFiled: June 19, 2014Date of Patent: October 3, 2017Assignee: Hohai UniversityInventors: Tingting Chang, Xiaohou Shao, Huilian Xu, Weina Wang, Lihua Chen, Xinyu Mao, Chunfang Wang
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Patent number: 9776932Abstract: An explosive matrix assembly of the present disclosure has a single detonating cord formed into a grid, and the grid comprises a first plurality of detonating cord portions lying in a first plane and a second plurality of detonating cord portions lying in a second plane and the first plurality of detonating cord portions perpendicularly overlay the second plurality of detonating portions. Additionally, the explosive matrix assembly has at least one insensitive blasting agent coupled to the grid.Type: GrantFiled: November 11, 2015Date of Patent: October 3, 2017Assignee: Matrix X, LLCInventor: Jon K. Mitchell
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Patent number: 9776933Abstract: Production of 1,3-butadiene ethanol, that is more than 50% of the total weight of feedstock: A) conversion of feedstock and of ethanol effluent from separation B to a conversion effluent being a majority of 1,3-butadiene, water and ethylene, and to a hydrogen effluent, operating at a pressure between 0.1 and 1.0 MPa, a temperature between 300 and 500° C. in the presence of at least one catalyst; B) separation of conversion effluent originating from A and hydration effluent from C to an ethanol effluent, a butadiene effluent, a water effluent and an ethylene effluent; C) hydration of ethylene fed by ethylene effluent and/or water effluent both from separation B, to produce an ethanol hydration effluent then being recycled to separation B.Type: GrantFiled: November 28, 2014Date of Patent: October 3, 2017Assignees: IFP Energies Nouvelles, Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.Inventors: Rejane Dastillung, Nicolas Cadran, Marc Jacquin, Raphael Huyghe, Beatrice Fischer
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Patent number: 9776934Abstract: A method of producing monocyclic aromatic hydrocarbons includes bringing a light feedstock oil having a 10 vol % distillation temperature of 140° C. to 205° C. and a 90 vol % distillation temperature of 300° C. or lower, which has been prepared from a feedstock oil having a 10 vol % distillation temperature of 140° C. or higher and a 90 vol % distillation temperature of 380° C. or lower, into contact with a catalyst for monocyclic aromatic hydrocarbon production containing a crystalline aluminosilicate, in which a content ratio of monocyclic naphthenobenzenes in the light feedstock oil is adjusted by distillation of the feedstock oil such that the content ratio of monocyclic naphthenobenzenes in the light feedstock oil is higher than a content ratio of monocyclic naphthenobenzenes in the feedstock oil.Type: GrantFiled: March 23, 2012Date of Patent: October 3, 2017Assignee: JX Nippon Oil Energy CorporationInventors: Shinichiro Yanagawa, Masahide Kobayashi, Ryoji Ida, Yasuyuki Iwasa
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Patent number: 9776935Abstract: Disclosed is a process for the catalytic dehydrogenation of alkanes so as to form the corresponding olefins. The reaction mixture is subjected to membrane separation of hydrogen, in a separate unit. Preferably a plurality of alternating reaction and separation units is used. The process of the invention serves the purpose of reducing coke formation on the catalyst, and also of achieving a higher alkane conversion without a similar increase in coke formation. The process can also be used for the production of hydrogen.Type: GrantFiled: March 28, 2012Date of Patent: October 3, 2017Assignee: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTERInventors: Emma Palo, Gaetano Iaquaniello
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Patent number: 9776936Abstract: The xylene isomerization process unit and the transalkylation process units are combined in the present invention. A fractionation column can be shared by the two units, reducing the capital cost of the complex. In some embodiments, a split shell fractionation column and a split separator can be used.Type: GrantFiled: May 16, 2014Date of Patent: October 3, 2017Assignee: UOP LLCInventors: Jason T. Corradi, David W. Ablin, David W. Liu
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Patent number: 9776937Abstract: In a feed clean-up process at least two adsorbents (2, 4) are installed in front of an oligomerization reactor (3). Olefin feed is sent over one adsorbent (2) and the nitrile poisons are adsorbed so that clean feed will enter the reactor (3). Before the adsorbent (2) will be saturated, the feed (1) is sent to the other, fresh adsorbent (4). At the same time oligomerization product from the reactor (3) is used to desorb nitriles from the spent adsorbent (2).Type: GrantFiled: June 14, 2012Date of Patent: October 3, 2017Assignee: ExxonMobil Chemical Patents Inc.Inventors: Hans K. T. Goris, Geraldine Tosin, Luc R. M. Martens, Machteld M. Mertens, Silvio Carrettin
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Patent number: 9776938Abstract: The invention concerns a method for producing 2,3,3,3-tetrafluoropropene comprising: a fluoridation reaction of a halopropane and/or halopropene into 2,3,3,3-tetrafluoropropene by means of hydrogen fluoride; the recovery of a gas stream resulting from the reaction; the cooling and partial condensation of the gas stream resulting from the reaction into a partially condensed stream; the separation of the partially condensed stream into a gas fraction and a liquid fraction; the compression of the gas fraction into a compressed gas fraction; the compression of the liquid fraction into a compressed liquid fraction; the distillation of the compressed gas fraction and compressed liquid fraction in order to provide a stream of 2,3,3,3-tetrafluoropropene, a stream of hydrochloric acid, and a stream of unreacted hydrogen fluoride. The invention also concerns an installation suitable for implementing said method.Type: GrantFiled: April 27, 2016Date of Patent: October 3, 2017Assignee: Arkema FranceInventors: Dominique Deur-Bert, Bertrand Collier, Laurent Wendlinger
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Patent number: 9776939Abstract: A method for cultivating Monarda fistulosa for production of thymoquinone includes planting seeds at rates between about 2.5 and about 5 pounds per acre, preferably about 4 pounds per acre. The heavy rate of planting produces plants bearing oil without weed contamination and reduces herbicide use due to production of natural herbicides by the monarda plants. Seeding and mowing the first season, and harvesting in seasons thereafter reduce costs. The method results in increased production of essential oils including thymoquinone and thymohydroquinone at levels up to about 40% or more of recovered oils, and which may be distilled from the plant.Type: GrantFiled: May 23, 2014Date of Patent: October 3, 2017Assignee: Prairie Pharms, LLCInventor: William G. Rohlfsen
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Patent number: 9776940Abstract: A process for production of acrylic acid includes preparing a product gas mixture by a catalytic gas-phase oxidation of a C3 precursor; cooling and contacting the cooled product gas mixture in an absorption column having at least two cooling loops in countercurrent with an absorbent to obtain an absorbate A, containing the absorbent and absorbed acrylic acid; condensing a high boiler fraction of the product gas mixture in a first cooling loop; condensing a low boiler fraction of the product gas mixture in a second cooling loop; maintaining a temperature of the absorbate A in the second cooling loop at a value of at least 56° C.; removing an acid water stream comprising glyoxal from the absorption column at a side take-off located above the second cooling loop; and removing a stream F of absorbate A from the absorption column at a side take-off, located at a height of the absorption column between the first cooling loop and the second cooling loop.Type: GrantFiled: August 3, 2016Date of Patent: October 3, 2017Assignee: BASF SEInventors: Tobias Korn, Till Blum, Travis Carline, Christopher Fuchs, Darryl Welch, Peter Zurowski, Volker Schliephake, Steffen Rissel, Thorsten Friese, Ulrich Jaeger, Sylke Haremza
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Patent number: 9776941Abstract: A process for removing acetaldehyde efficiently and producing high-purity acetic acid stably is provided. Methanol is allowed to continuously react with carbon monoxide in a carbonylation reactor 1 in the presence of a catalyst system; the reaction mixture is continuously fed to a flasher 2 to form a volatile phase (2A) containing acetic acid and methyl iodide; the volatile phase (2A) is continuously fed to a splitter column 3 to form an overhead (3A) containing methyl iodide and acetaldehyde and a stream (3B) containing acetic acid; the volatile phase (2A) and/or the overhead (3A) is cooled by a first condenser C1, C3 at a predetermined cooling temperature; and the noncondensed gaseous component is further cooled by a second condenser C2, C4 to form a concentrate having a lower temperature and a higher acetaldehyde concentration. Acetaldehyde is efficiently removed by distilling the concentrate having a high acetaldehyde concentration.Type: GrantFiled: December 2, 2013Date of Patent: October 3, 2017Assignee: DAICEL CORPORATIONInventors: Masahiko Shimizu, Ryuji Saito, Hiroyuki Miura
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Patent number: 9776942Abstract: A process for producing an acetic acid product having low butyl acetate content via a carbonylation reaction. The carbonylation reaction is carried out at a temperature from 100 to 300° C., a hydrogen partial pressure from 0.3 to 2 atm, and a metal catalyst concentration from 100 to 3000 wppm, based on the weight of the reaction medium. The butyl acetate concentration in the acetic acid product may be controlled by removing acetaldehyde from a stream derived from the reaction medium and/or by adjusting at least one of reaction temperature, hydrogen partial pressure, and metal catalyst concentration.Type: GrantFiled: February 12, 2016Date of Patent: October 3, 2017Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Yaw-Hwa Liu, Mark O. Scates
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Patent number: 9776943Abstract: The present disclosure provides a process for recovering and recycling a catalyst from the mother liquor generated during the production of aromatic carboxylic acids. The process comprises treating the mother liquor with an alkyl aromatic compound and further treating the first aqueous layer obtained with an ionic liquid to obtain a catalyst rich aqueous mixture. The catalyst rich aqueous mixture is recycled to the oxidation reactor.Type: GrantFiled: February 19, 2015Date of Patent: October 3, 2017Assignee: Reliance Industries LimitedInventors: Suresh Shantilal Jain, Pavankumar Aduri, Vivek Shankaranarayanan, Parasuveera Uppara
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Patent number: 9776944Abstract: A process for producing acetic acid including an acetic acid collection step for feeding a first distillation column with a volatile component at least containing acetic acid, methyl acetate, methyl iodide, water, and hydrogen iodide. Separating a first lower boiling point component as an overhead, and collecting a first liquid stream containing acetic acid. An acetic acid purification step for feeding a second distillation column with the first liquid stream, and separating a second lower boiling point component as an overhead. Collecting a second liquid stream containing acetic acid. An alkali component is added or mixed for distilling a mixture to be treated containing the first liquid stream and the alkali component in the second distillation column. In the mixture, at least one component (A) having a boiling point lower than acetic acid. The at least one component (A) having a concentration of 0.1 to 15% by weight.Type: GrantFiled: December 1, 2011Date of Patent: October 3, 2017Assignee: DAICEL CORPORATIONInventors: Masahiko Shimizu, Ryuji Saito, Hiroyuki Miura, Takashi Ueno
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Patent number: 9776945Abstract: Processes for separating a di-carboxylic acid or salt thereof from a mixture containing the di-carboxylic acid or salt thereof and one or more other components are provided. Also separation media useful for these separation processes is provided. In particular, processes for preparing an aldaric acid are described, such as glucaric acid from glucose, which includes separating the aldaric acid from the reaction product. Also, various glucaric acid products are described.Type: GrantFiled: September 29, 2015Date of Patent: October 3, 2017Assignee: Rennovia Inc.Inventors: Gary M. Diamond, Eric L. Dias, Raymond Archer, Vincent J. Murphy, Thomas R. Boussie
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Patent number: 9776946Abstract: The invention relates to the industrial production of highly pure 2-propylheptyl acrylate with a high yield according to a process by transesterification, preferably in semi-continuous mode. The process according to the invention uses ethyl titanate in solution in 2-propylheptanol or 2-propylheptyl titanate as transesterification catalyst, and implements a purification sequence comprising a single distillation column and a film evaporator.Type: GrantFiled: February 24, 2014Date of Patent: October 3, 2017Assignee: Arkema FranceInventors: Alain F. Riondel, Coralie Graire
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Patent number: 9776947Abstract: In a process for the production of dialkyl succinate from a feedstock comprising maleic anhydride, feed in the liquid phase is provided to a reactor operated at a temperature of at least about 150° C. The feed is contacted with hydrogen at a pressure of at least about 300 psig in the presence of an acid tolerant catalyst and an alkanol wherein at least some of the carbon carbon double bonds of the maleic anhydride are hydrogenated to form succinic acid and that the heat generated promotes esterification to dialkyl succinate in situ. A stream of dialkyl succinate is recovered from the reactor.Type: GrantFiled: October 13, 2014Date of Patent: October 3, 2017Assignee: JOHNSON MATTHEY DAVY TECHNOLOGIES LIMITEDInventors: Graham Reed, Andrew George Hiles, Rikard Umberto Andersson, Simon Nicholas Tilley, Paul Gordon
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Patent number: 9776948Abstract: A process for production of dialkyl succinate from bio-succinic acid feedstock where solid bio-succinic acid is fed to a reactor to react with alkanol by autocatalytic esterification. Products from the reactor including unreacted succinic acid, mono alkyl ester, dialkyl ester, alkanol, water and impurities are sent to a reaction distillation column for esterification of succinic acid and further esterification of mono alkyl ester with upflowing alkanol. The bottoms products from the reaction distillation column including residual succinic acid, mono alkyl ester, dialkyl ester, impurities and alkanol are sent to a bottoms stream separation zone where di-alkyl ester is separated from alkanol, succinic acid, mono alkyl ester and impurities. The tops products from the reaction distillation column including alkanol, water and organic components are sent to a top stream distillation zone where alkanol is separated from water and organic components. The organic components are recycled to the reaction zone column.Type: GrantFiled: December 2, 2014Date of Patent: October 3, 2017Assignee: Johnson Matthey Davy Technologies LimitedInventors: Martin Lucas Smidt, Ian Campbell, Graham Reed, Paul Gordon, Christopher Ferguson
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Patent number: 9776949Abstract: The invention relates to a method for producing carboxylic acid esters by reacting carboxylic acids and/or carboxylic acid anhydrides with at least one alcohol having at least 5 carbon atoms, selected from alkanols and cycloalkanols, in the presence of an ionic liquid and an acidic esterification catalyst. The invention also relates to the use of the thus obtained carboxylic acid esters as a plasticizer or in a plasticizer composition for thermoplastic polymers and elastomers.Type: GrantFiled: April 20, 2015Date of Patent: October 3, 2017Assignee: BASF SEInventors: Martin Kaller, Michael Koch
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Patent number: 9776950Abstract: Provided is a production device including: a first reactor to form a second gas containing an ester and nitric oxide from a first gas containing carbon monoxide, a nitrite, and nitric oxide; an absorption column to separate the second gas and an absorbing solution into a condensate containing the ester and a noncondensable gas; a second reactor to introduce an alcohol, the noncondensable gas, and oxygen gas thereinto to form a third gas containing nitric oxide and a nitrite; a third reactor to form a fourth gas containing a nitrite from the noncondensable gas and a bottom liquid from the second reactor and to feed the fourth gas to the second reactor; a first measurement unit to measure the concentration of a nitrite in the first gas; and a first flow rate-adjusting unit to adjust the amount of the noncondensable gas to the third reactor based on the concentration.Type: GrantFiled: July 3, 2015Date of Patent: October 3, 2017Assignee: UBE INDUSTRIES, LTD.Inventors: Hirofumi Il, Yuya Fukui, Syuji Tanaka
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Patent number: 9776951Abstract: The invention relates to novel polyglycerol esters with a particular oligomer distribution of the polyglycerol present, and to their use in particular in cosmetic formulations as, for example, emulsifier.Type: GrantFiled: February 11, 2015Date of Patent: October 3, 2017Assignee: Evonik Degussa GmbHInventors: Achim Friedrich, Jürgen Meyer, Jan Marian von Hof, Oliver Springer, Peter Muss
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Patent number: 9776952Abstract: The present invention relates to polymerizable compounds, to processes and intermediates for the preparation thereof, to the use thereof for optical, electro-optical and electronic purposes, in particular in liquid-crystal (LC) media and LC displays having a polymer-stabilized blue phase, and in LC media for LC displays of the PS or PSA type (“polymer sustained” or “polymer sustained alignment”), and to LC media and LC displays comprising these compounds.Type: GrantFiled: February 5, 2016Date of Patent: October 3, 2017Assignee: Merck Patent GmbHInventors: Axel Jansen, Thorsten Kodek, Helmut Haensel, Erdal Durmaz
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Patent number: 9776953Abstract: The present invention relates to a new process for the isolation and purification of 6-aminocaproic acid, which is a known inhibitor of enzymes responsible for fibrinolysis and is used in the treatment of coagulopathies and severe post-operative bleedings.Type: GrantFiled: August 4, 2016Date of Patent: October 3, 2017Assignee: Dipharma Francis S.r.l.Inventors: Massimo Magnani, Enrico Brunoldi, Gabriele Razzetti, Alessandro Restelli
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Patent number: 9776954Abstract: The present invention relates to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer [in the formula, Y1 to Y8 are a chemical single bond, —O—, —O—C(?O)—, —C(?O)—O—, or the like; G1 and G2 are a divalent aliphatic group having 1 to 20 carbon atoms, or the like; Z1 and Z2 are an alkenyl group having 2 to 10 carbon atoms, or the like; A1 is a tetravalent aromatic group, or the like; A2 and A3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, or the like; A4 and A5 are a divalent aromatic group having 4 to 30 carbon atoms, or the like; Ax1 and Ax2 are an organic group having 2 to 30 carbon atoms that includes an aromatic ring, or the like; Ay1 and Ay2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; Q1 and Q2 are a hydrogenType: GrantFiled: October 16, 2013Date of Patent: October 3, 2017Assignee: ZEON CORPORATIONInventors: Kei Sakamoto, Satoshi Kiriki, Kumi Okuyama
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Patent number: 9776955Abstract: A method for preparing N,N?-bis(2-cyanoethyl-1,2-ethylenediamine involves using glycol ether as a catalyst for synthesis reaction in which ethylenediamine and acrylonitrile at a molar ratio of 1:1.9-2.1 are reactant that react at 20-70°C to prepare N,N?-bis(2-cyanoethyl)-1,2-ethylenediamine; the method improves the yield to 98.15-98.98%; and the used glycol ether may be filtered and recycled, thereby saving costs and reducing environmental pollution.Type: GrantFiled: November 18, 2016Date of Patent: October 3, 2017Assignee: NAN YA PLASTICS CORPORATIONInventors: Te-Chao Liao, Jung-Jen Chuang, Zhi-Ming Huang, Shun-Chi Chen, Tzu-Chiang Lin
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Patent number: 9776956Abstract: A method for preparing N,N?-bis(2-cyanoethyl)-1,2-ethylenediamine involves using strongly acidic cation exchange resin as a catalyst for synthesis, and is advantageous for not only eliminating the need of distillation for purification and thereby reducing reaction time, but also improving the yield of N,N?-bis(2-cyanoethyl)-1,2-ethylenediamine to 97.70-98.08%; and the method benefits simplified process and reduced costs and helps to save water significantly, thereby minimizing environmental pollution.Type: GrantFiled: November 18, 2016Date of Patent: October 3, 2017Assignee: NAN YA PLASTICS CORPORATIONInventors: Te-Chao Liao, Jung-Jen Chuang, Zhi-Ming Huang, Shun-Chi Chen, Tzu-Chiang Lin
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Patent number: 9776957Abstract: Disclosed is a method for the production of urea allowing a substantial reduction, even down to zero, of the continuous emission of ammonia conventionally resulting from such a process. According to a preferred embodiment of the invention, the urea-forming reaction from carbon dioxide and ammonia is conducted in a synthesis section that does not require passivation by oxygen. As a result of the absence of oxygen, a hydrogen-rich gas stream results from the synthesis section, that can be used as a fuel in an incinerator. In the incinerator, ammonia-comprising gas streams from the urea production process are combusted.Type: GrantFiled: March 30, 2012Date of Patent: October 3, 2017Assignee: STAMICARBON B.V.Inventors: Johannes Henricus Mennen, Barbara Cucchiella
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Patent number: 9776958Abstract: The present application relates to a sulfonate-based compound and a method for preparing the same.Type: GrantFiled: June 18, 2015Date of Patent: October 3, 2017Assignee: LG CHEM, LTD.Inventors: Hyungsam Choi, Joong Jin Han, Chong Kyu Shin, Youngjea Kim, Esder Kang
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Patent number: 9776959Abstract: The present invention provides crystal forms of the compound of (3R,4S)-4-(4-hydroxyphenyl)-3-[3-(4-fluorophenyl)-4-hydroxybut-2(Z)-enyl]-1-(4-fluorophenyl)-2-azetidinone (formula A). The crystal forms can be characterized by X-ray powder diffraction (XRPD) spectra, differential scanning calorimetry (DSC) spectra, infrared absorption spectra and so on. Meanwhile, the present invention also provides methods for preparing the crystal forms of the compound of formula A, pharmaceutical compositions and uses thereof.Type: GrantFiled: December 21, 2016Date of Patent: October 3, 2017Assignee: Zhejiang Hisun Pharmaceutical Co., Ltd.Inventors: Hongyuan Wei, Chongjun Liu, Xuyang Zhao, Xiaojie Xu, Hua Bai, Yuncai Zhang
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Patent number: 9776960Abstract: Provide herein are compounds and pharmaceutical compositions suitable as modulators of hemoglobin, methods and intermediates for their preparation, and methods for their use in treating disorders mediated by hemoglobin and disorders that would benefit from tissue and/or cellular oxygenation.Type: GrantFiled: August 26, 2015Date of Patent: October 3, 2017Assignee: Global Blood Therapeutics, Inc.Inventors: Qing Xu, Zhe Li
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Patent number: 9776961Abstract: The present invention provides a production intermediate of an atropisomer of a pyrrole derivative having excellent mineralocorticoid receptor antagonistic activity, a method for producing the same, and a crystal thereof. A method for producing an atropisomer of a pyrrole derivative including a step of resolving a compound represented by the following general formula (I) [wherein R1 represents a methyl group or a trifluoromethyl group, R2 represents a hydrogen atom or a C1-C3 alkoxy group, and n represents an integer selected from 1 to 3] into its atropisomers, characterized by using an optically active amine having a cinchonine skeletal formula, and a crystal of (S)-1-(2-hydroxyethyl)-4-methyl-N-[4-(methylsulfonyl)phenyl]-5-[2-(trifluoromethyl)phenyl]-1H-pyrrole-3-carboxamide.Type: GrantFiled: April 28, 2017Date of Patent: October 3, 2017Assignee: Daiichi Sankyo Company, LimitedInventors: Masashi Watanabe, Takahiro Okachi, Michiaki Kawahara, Hiroshi Nagasawa, Noritada Sato, Takashi Takita, Gen Hasegawa
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Patent number: 9776962Abstract: Provided is a novel aromatic ring compound having a GPR40 agonist activity and a GLP-1 secretagogue action. A compound represented by the formula: wherein each symbol is as described in the DESCRIPTION, or a salt thereof has a GPR40 agonist activity and a GLP-1 secretagogue action, is useful for the prophylaxis or treatment of cancer, obesity, diabetes, hypertension, hyperlipidemia, cardiac failure, diabetic complications, metabolic syndrome, sarcopenia and the like, and affords superior efficacy.Type: GrantFiled: August 8, 2014Date of Patent: October 3, 2017Assignee: TAKEDA PHARMACEUTICAL COMPANY LIMITEDInventors: Jumpei Aida, Yayoi Yoshitomi, Yuko Hitomi, Naoyoshi Noguchi, Yasuhiro Hirata, Hideki Furukawa, Akito Shibuya, Koji Watanabe, Yasufumi Miyamoto, Tomohiro Okawa, Nobuyuki Takakura, Seiji Miwatashi
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Patent number: 9776963Abstract: The invention provides for compounds of formula I: wherein Z is absent or (CRARB)nW; each RA and RB is independently (i) H, alkyl, alkenyl, alkynyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, aralkyl, heteroaralkyl, haloalkyl, each of which may be optionally substituted; (ii) OH, ORc, NH2, NHRc, NRcRc, SH, S(O)mRc; or (iii) RA and RB together form C(O); W is absent, C(O), C(O)O, C(O)NRcRc, O, S(O)m, or NRcRc; Y is an optionally substituted heterocyclic, optionally substituted heteroaryl, optionally substituted cycloalkyl, optionally substituted aryl, or NRXRY; wherein Rx and Ry are each independently H, alkyl or aryl; X1 is selected from the group consisting of halogen, methyl, and hydroxyl; X2 is a halogen; each Rc is independently alkyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, aralkyl, or heteroaralkyl, each of which may be optionally substituted; m is O, 1, or 2; and n is 1, 2, 3, 4, 5, or 6; and pharmaceutically acceptable salts thereof.Type: GrantFiled: November 10, 2009Date of Patent: October 3, 2017Assignees: The Trustees of the University of Pennsylvania, Dana-Farber Cancer Institute, Inc., The Johns Hopkins University, Bryn Mawr College, The Trustees of Columbia University in the City of New YorkInventors: Joseph G. Sodroski, Navid Madani, Arne Schön, Judith M. LaLonde, Joel R. Courter, Takahiro Soeta, Danny Ng, Ernesto Freire, Amos B. Smith, III, Amy M. Princiotto, Matthew Le-Khac, Wayne A. Hendrickson
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Patent number: 9776964Abstract: The present invention provides a compound of the Formula (I): wherein X, R, R1, R2, R3, R4, R5, R6, R7, R8, and R9 are as defined herein, or a pharmaceutically acceptable salt thereof.Type: GrantFiled: December 11, 2014Date of Patent: October 3, 2017Assignee: Eli Lilly and CompanyInventors: Matthew Joseph Fisher, Steven Lee Kuklish, Peter Rudolph Manninen, Matthew Allen Schiffler, Alan M Warshawsky, Jeremy Schulenburg York
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Patent number: 9776965Abstract: The N-oxide forms, the pharmaceutically acceptable addition salts and the stereochemically isomeric forms thereof, wherein n is 1 or 2; L represents a C1-3alkyl linker optionally substituted with one or two substituents selected from C1-4alkyl, C1-3alkyloxy-C1-4alkyl-, hydroxy-C1-4alkyl, hydroxy, C1-3alkyloxy- or phenyl-C1-4alkyl; M represents a direct bond or a C1-3alkyl linker optionally substituted with one or two substituents selected from hydroxy, C1-4alkyl or C1-4alkyloxy; R1 and R2 each independently represent hydrogen, halo, cyano, hydroxy, C1-4alkyl optionally substituted with halo, C1-4alkyloxy- optionally substituted with one or where possible two or three substituents selected from hydroxy, Ar1 and halo; or R1 and R2 taken together with the phenyl ring to which they are attached form naphtyl or 1,3-benzodioxolyl, wherein said naphtyl or 1,3-benzodioxolyl are optionally substituted with halo; R3 represents hydrogen, halo, C1-4alkyl, C1-4alkyloxy-, cyano or hydroxy; R4 represents hydrogen, halo,Type: GrantFiled: February 24, 2016Date of Patent: October 3, 2017Assignee: JANSSEN PHARMACEUTICA NVInventors: Libuse Jaroskova, Joannes Theodorus Maria Linders, Christophe Francis Robert Nestor Buyck, Louis Jozef Elisabeth Van Der Veken, Vladimir Dimtchev Dimitrov, Theo Teofanov Nikiforov
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Patent number: 9776966Abstract: Provided herein are processes and intermediate compounds useful for the preparation of 2-carboxamide cycloamino urea derivatives, and useful intermediates therefore.Type: GrantFiled: April 6, 2017Date of Patent: October 3, 2017Assignee: Novartis AGInventors: Bernhard Erb, Isabelle Sylvie Gallou, Florian Karl Kleinbeck
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Patent number: 9776967Abstract: Disclosed are compounds of formula (I) which possess pesticidal, especially nematicidal properties wherein in the structural elements have the meaning as indicated in the description.Type: GrantFiled: October 10, 2014Date of Patent: October 3, 2017Assignee: BAYER ANIMAL HEALTH GMBHInventors: Hans-Georg Schwarz, Anne Decor, Martin Füβlein, Ulrich Görgens, Kerstin Ilg, Claudia Welz, Peter Lümmen, Adeline Köhler, Kirsten Börngen