Patents Issued in October 3, 2017
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Patent number: 9777118Abstract: A method for the manufacture of a metal salt of a hydroxy-substituted aromatic compound comprises: contacting a hydroxy-substituted aromatic compound with a base comprising a metal cation in molten diphenyl sulfone or sulfolane to provide a mixture comprising water, diphenyl sulfone or sulfolane, and a metal salt of the hydroxy-substituted aromatic compound; and removing water from the mixture in the absence of an azeotrope solvent to provide the metal salt of the hydroxy-substituted aromatic compound that contains less than 3,000 ppm of water.Type: GrantFiled: April 15, 2015Date of Patent: October 3, 2017Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Mani Raj Chaulagain, Farid Fouad Khouri
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Patent number: 9777119Abstract: The present invention relates to a process for the production of a polyaryl ether sulfone polymer (P), comprising the following steps: (I) provision of a solution (PL) which comprises the polyaryl ether sulfone polymer (P) and comprises an aprotic polar solvent (L), (II) separation of the solution (PL) into droplets, (III) transfer of the droplets into a precipitation bath (F) which comprises water, with the result that the polyaryl ether sulfone polymer (P) is obtained in the form of particles, and (IV) isolation of the polyaryl ether sulfone polymer (P) where the temperature of the solution (PL) in step (II) is in the range from 50 to <80° C.Type: GrantFiled: June 26, 2014Date of Patent: October 3, 2017Assignee: BASF SEInventors: Martin Weber, Christian Maletzko, Bastiaan Bram Pieter Staal, Joerg Erbes
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Patent number: 9777120Abstract: The present invention relates to alkoxyalkylsilane-modified polysiloxanes, to processes for the production thereof, and to the use thereof.Type: GrantFiled: April 7, 2015Date of Patent: October 3, 2017Assignee: CHT R. BEITLICH GMBHInventors: Petr Schurek, Friedhelm Nickel
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Patent number: 9777121Abstract: Provided are a Gemini-type alkyl-polyoxyalkylene-modified silicone suitable for use in preparing a silicone emulsion; a production method of thereof; and a defoaming agent composition containing such Gemini-type alkyl-polyoxyalkylene-modified silicone. The Gemini-type alkyl-polyoxyalkylene-modified silicone is expressed by the following general formula (A): wherein each of R1, R2, R3, R4, R5 and R6 represents an alkyl group or the like; n represents an integer of 0 to 300; and (B) represents a group expressed by the following general formula (1) or general formula (2): wherein each of R7 and X represents a hydrocarbon group; R8 represents a hydrogen atom, a hydrocarbon group, a formyl group or an acyl group; and a and b represent numbers satisfying 2?a?200 and 0?b?200, provided that a+b=2 to 200.Type: GrantFiled: October 23, 2014Date of Patent: October 3, 2017Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Takato Sakurai
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Patent number: 9777122Abstract: A silicone polymer is provided, modified with at least one functional group from the class of anthraquinone amide groups; anthraquinone sulfonamide groups; thioxanthone amide groups; or thioxanthone sulfone amide groups. The polymer can be combined with a hydrocarbon solvent or with supercritical carbon dioxide (CO2), and is very effective for increasing the viscosity of either medium. A process for the recovery of oil from a subterranean, oil-bearing formation is also described, using supercritical carbon dioxide modified with the functionalized silicone polymer. A process for extracting natural gas or oil from a bedrock-shale formation is also described, again using the modified silicone polymer.Type: GrantFiled: April 10, 2015Date of Patent: October 3, 2017Assignee: General Electric CompanyInventors: Michael Joseph O'Brien, Robert James Perry, Robert Michael Enick, Jason Jiwoo Lee
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Patent number: 9777123Abstract: Low molecular weight sulfated beta-O4 lignin (SbO4L) are potent inhibitors of coagulation with high selectivity.Type: GrantFiled: May 29, 2014Date of Patent: October 3, 2017Assignee: Virginia Commonwealth UniversityInventors: Umesh R. Desai, Jay Thakkar, Akul Mehta
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Patent number: 9777124Abstract: A method includes heating a sulfonated polyester resin in an organic-free solvent, adding a solution of silver (I) ion to the heated resin in water to form a mixture, reducing silver (I) to silver(0) by heating the mixture from about 65° C. to about 90° C., thereby forming an emulsion of composite particles comprising a sulfonated polyester matrix and a plurality of silver nanoparticles disposed within the sulfonated polyester matrix, and allowing the silver nanoparticles to agglomerate into a silver nanodendrite structure.Type: GrantFiled: October 18, 2016Date of Patent: October 3, 2017Assignee: XEROX CORPORATIONInventors: Valerie M. Farrugia, Alana Desouza, Sandra J. Gardner
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Patent number: 9777125Abstract: This invention is related to a method for producing polymer latex particle coated with silver nanoparticles. First, a polymer latex particle suspension is mixed with a silver nitrate solution in a weight ratio of 10:1 to 1:10 at 50° C. to 90° C. for 10 to 120 minutes to form a mixed solution. After the temperature of the mix solution is cooled to 50° C. to 85° C., a sodium citrate solution is added to react with the mixed solution for 10 to 240 minutes to form a polymer latex particle coated with silver nanoparticles, which has antibacterial activity.Type: GrantFiled: November 27, 2015Date of Patent: October 3, 2017Assignees: Nerd Skincare Inc., Chia-Fen LeeInventors: Ying-Tung Chen, Chia-Fen Lee, Yu-Syuan Chang, Kuen-Lin Leu
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Patent number: 9777126Abstract: The invention provides new composite materials containing aerogels blended with thermoplastic polymer materials at a weight ratio of aerogel to thermoplastic polymer of less than 20:100. The composite materials have improved thermal insulation ability. The composite materials also have better flexibility and less brittleness at low temperatures than the parent thermoplastic polymer materials.Type: GrantFiled: July 12, 2010Date of Patent: October 3, 2017Assignee: The United States of America as Represented by the Administrator of NASAInventors: Martha K. Williams, Trent M. Smith, James E. Fesmire, Luke B. Roberson, LaNetra M. Clayton
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Patent number: 9777127Abstract: The purpose of the present invention is to provide a carbon fiber bundle for resin reinforcement purposes, which is produced using a sizing agent that can exert satisfactory interface adhesiveness to both of a carbon fiber bundle and a thermoplastic resin in the production of a carbon-fiber-reinforced thermoplastic resin, and which has satisfactory emulsion stability. One embodiment of the present invention is a carbon fiber bundle for resin reinforcement purposes, which comprises a carbon fiber bundle and a polymer adhered onto the carbon fiber bundle, wherein the polymer is produced by binding an acid-modified polyolefin having a polyolefin structure and an acidic group in the molecular structure thereof to a hydrophilic polymer having a weight average molecular weight (Mw) of 450 or more, and wherein the ratio of the mass of the polyolefin structure to the mass of the acidic group in the acid-modified polyolefin is 100:0.Type: GrantFiled: September 4, 2013Date of Patent: October 3, 2017Assignee: Mitsubishi Chemical CorporationInventors: Tadashi Ohtani, Akira Harada, Shoya Yoda, Atsushi Takahashi
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Patent number: 9777128Abstract: A method and system for the production of fibers for use in biocomposites is provided that includes the ability to use both retted and unretted straw, that keeps the molecular structure of the fibers intact by subjecting the fibers to minimal stress, that maximizes the fiber's aspect ratio, that maximizes the strength of the fibers, and that minimizes time and energy inputs, along with maintaining the fibers in good condition for bonding to the polymer(s) used with the fibers to form the biocomposite material. This consequently increases the functionality of the biocomposites produced (i.e. reinforcement, sound absorption, light weight, heat capacity, etc.), increasing their marketability. Additionally, as the disclosed method does not damage the fibers, oilseed flax straw, as well as all types of fibrous materials (i.e. fiber flax, banana, jute, industrial hemp, sisal, coir) etc., can be processed in bio composite materials.Type: GrantFiled: February 24, 2015Date of Patent: October 3, 2017Assignee: CNH Industrial Canada, Ltd.Inventors: James Henry, Satyanarayan Panigrahi, Radhey Lal Kushwaha
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Patent number: 9777129Abstract: The present invention is directed to articles of manufacture, including fibers and films, and methods of making thereof. In accordance with the present invention, the article includes a binder impregnated with or encapsulating a filler. The binder is a polyvinyl alcohol (PVOH), cellulose nanofibrils, or a combination of the PVOH and cellulose nanofibrils. The filler is deinking waste solids comprising ash and cellulose fines.Type: GrantFiled: April 2, 2015Date of Patent: October 3, 2017Assignee: Georgia-Pacific Consumer Products LPInventors: Daniel W. Sumnicht, Thomas Schulze, Frank-Gunther Niemz
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Patent number: 9777130Abstract: Polyphenylene sulfide microparticles have a linseed oil absorption amount of 40 to 1,000 mL/100 g and a number average particle diameter of 1 to 200 ?m. The porous PPS microparticles have a large specific surface area and therefore promote fusion of particles when molded into various molded bodies by applying thermal energy, thus enabling formation or molding of a coating layer of particles at a lower temperature in a shorter time. The porous PPS microparticles have a porous shape and therefore enable scattering light in multiple directions and suppression of specific reflection of reflected light in a specific direction, thus making it possible to impart shading effect and matte effect when added to a medium.Type: GrantFiled: December 17, 2014Date of Patent: October 3, 2017Assignee: Toray Industries, Inc.Inventors: Takahiko Otsubo, Itaru Asano, Yoko Wakahara, Hiroshi Takezaki
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Patent number: 9777131Abstract: A method enabling a used superabsorbent polymer recovered from used absorbent, etc., to be readily and inexpensively recovered without using acids or alkalies. The used superabsorbent polymer is treated with an aqueous solution of a multivalent metal salt such as calcium chloride, etc., the superabsorbent polymer treated with the aqueous solution of a multivalent metal salt is treated with an aqueous solution of an alkali metal salt such as sodium chloride, etc., the superabsorbent polymer treated with the aqueous solution of an alkali metal salt is washed with water, and the superabsorbent polymer washed with water is then dried.Type: GrantFiled: March 22, 2013Date of Patent: October 3, 2017Assignee: Unicharm CorporationInventors: Naoyuki Funamizu, Ken Ushijima, Nowaki Hijikata, Hiroki Yoshikawa, Takayoshi Konishi, Toru Oba
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Patent number: 9777132Abstract: A nanostructure that includes a multi-layered fullerene-like nano-structure composed of a plurality of layers each having a metal chalcogenide composition that has a molecular formula of MX2, in which M is a metallic element selected from the group consisting of titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), zirconium (Zr), niobium (Nb), molybdenum (Mo), technetium (Tc), ruthenium (Ru), rhodium (Rh), palladium (Pd), silver (Ag), cadmium (Cd), hafnium (Hf), tantalum (Ta), tungsten (W), rhenium (Re), osmium (Os), iridium (Ir), platinum (Pt), gold (Au), mercury (Hg) and combinations thereof, and X is a chalcogen element selected from the group consisting of sulfur (S), selenium (Se), tellurium (Te), oxygen (O) and combinations thereof. An outer layer of the multi-layered fullerene-like structure includes at least one sectioned portion that extends along a direction away from the curvature of the multi-layered fullerene-like nano-structure.Type: GrantFiled: September 19, 2016Date of Patent: October 3, 2017Assignee: NANOTECH INDUSTRIAL SOLUTIONS, INC.Inventors: Eugene Kverel, George Diloyan
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Patent number: 9777133Abstract: The present invention relates to an additive for hydraulically setting compositions, comprising a colloidally disperse preparation of at least one water-soluble salt of a polyvalent metal cation, at least one compound capable of releasing an anion which forms a sparingly soluble salt with the polyvalent metal cation, and at least one polymeric dispersant which comprises anionic and/or anionogenic groups and polyether side chains.Type: GrantFiled: February 26, 2014Date of Patent: October 3, 2017Assignee: Construction Research & Technology, GmbHInventors: Torben Gädt, Harald Grassl, Alexander Kraus, Luc Nicoleau, Martin Winklbauer
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Patent number: 9777134Abstract: The invention relates to a powdery composition for use in the layer by layer manufacturing of three-dimensional molded bodies. The composition comprises at least one powder made of an aliphatic thermoplastic polyurethane (TPU) and is characterized in that the TPU powder has a melting temperature of less than 135° C. and a melting viscosity at 150° C. of at most 800 Pa·s.Type: GrantFiled: December 2, 2014Date of Patent: October 3, 2017Assignee: Timur UenlueInventor: Timur Uenlue
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Patent number: 9777135Abstract: Provided is an epoxy-amine adduct that offers high reactivity, contributes to better adhesion between a resin and a reinforcing fiber in a fiber-reinforced composite material, and can be easily blended with another component such as a resin. The epoxy-amine adduct has two or more amino groups per molecule and is obtained by a reaction of an epoxy compound (A) having two or more alicyclic epoxy groups per molecule with an amine compound (B) having two or more amino groups per molecule.Type: GrantFiled: June 23, 2016Date of Patent: October 3, 2017Assignee: DAICEL CORPORATIONInventor: Masanori Sakane
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Patent number: 9777136Abstract: A rubber composition according to the present invention includes at least a rubber component, which includes an ethylene propylene diene rubber, a peroxide crosslinking agent, and amorphous silica and further includes not less than 0.3 parts by mass of a quaternary ammonium salt with respect to 100 parts by mass of the amorphous silica. A rubber molded article according to the present invention is constituted of the rubber composition.Type: GrantFiled: August 18, 2015Date of Patent: October 3, 2017Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventor: Masashi Hamakubo
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Patent number: 9777137Abstract: Objects of the present invention are: to obtain a polyimide that is excellent in heat resistance, transparency, and optical isotropy and is soluble in an organic solvent; to provide, by using either a polyimide or a polyamic acid which is a precursor or the polyimide, a product or a member that is highly required to have heat resistance and transparency; and particularly to provide a product and a member both of which are obtained by applying a polyamic acid solution and a polyimide solution of the present invention to the surface of an inorganic substance such as glass, metal, metal oxide, or a single crystal silicon. These objects can be attained by a polyimide acid and a polyimide which are each prepared from an alicyclic tetracarboxylic dianhydride and a monomer having a fluorene structure.Type: GrantFiled: June 12, 2012Date of Patent: October 3, 2017Assignee: KANEKA CORPORATIONInventors: Mari Fujii, Shinji Ozawa
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Patent number: 9777138Abstract: A latent additive which is represented by general formula (1). (In the formula, A represents a five-membered or six-membered aromatic ring or heterocyclic ring; each of R1 and R2 independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an optionally substituted alkyl group having 1-40 carbon atoms, an aryl group having 6-20 carbon atoms, an arylalkyl group having 7-20 carbon atoms or a heterocyclic ring-containing group having 2-20 carbon atoms; and R4 represents an alkyl group having 1-20 carbon atoms, an alkenyl group having 2-20 carbon atoms, an aryl group having 6-20 carbon atoms, an arylalkyl group having 7-20 carbon atoms, a heterocyclic ring-containing group having 2-20 carbon atoms or a trialkylsilyl group.Type: GrantFiled: June 21, 2013Date of Patent: October 3, 2017Assignee: ADEKA CORPORATIONInventors: Mitsuhiro Okada, Tomoyuki Ariyoshi
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Patent number: 9777139Abstract: Reactive antioxidants, antioxidant-containing prepolymers, compositions containing reactive antioxidants and antioxidant-containing prepolymers, methods of synthesizing reactive antioxidants and reactive antioxidant-containing prepolymers and the use of reactive antioxidants and antioxidant-containing prepolymers in aerospace sealant applications are disclosed. Reactive antioxidants and antioxidant-containing prepolymers can be added to a curable composition and react with a curing agent to become incorporated into the cured polymer network. Antioxidant-containing prepolymers have antioxidants incorporated into the backbone of the prepolymer. Cured sealant compositions comprising reactive antioxidants and antioxidant-containing prepolymers exhibit enhanced thermal resistance.Type: GrantFiled: October 26, 2015Date of Patent: October 3, 2017Assignee: PRC-DeSoto International, Inc.Inventors: Chandra Rao, Juexiao Cai, Renhe Lin
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Patent number: 9777140Abstract: The present invention relates to a composite material obtained by in situ polymerization of a thermoplastic resin with a fibrous material. More particularly the present invention relates to a polymeric composite material obtained by in-situ polymerization of a thermoplastic (meth) acrylic resin and a fibrous material containing long fibers and its use, a process for making such a composite material and manufactured mechanical or structured part or article comprising this polymeric composite material.Type: GrantFiled: October 19, 2012Date of Patent: October 3, 2017Assignee: Arkema FranceInventors: Pierre Gerard, Michel Glotin, Gilles Hochstetter
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Patent number: 9777141Abstract: A silica-containing resin composition, characterized by containing a resin and silica particles in an amount of 5 to 300 parts by mass, with respect to 100 parts by mass of the resin, wherein the silica particles satisfy the following requirements (a) to (c): (a) the silica particles have a specific surface area, as determined through a nitrogen absorption method, of 20 to 500 m2/g; (b) the silica particles have a percent moisture absorption of 5.0 mass % or less at a relative humidity of 50%; and (c) the silica particles contain substantially no metallic impurity or halogen.Type: GrantFiled: June 5, 2014Date of Patent: October 3, 2017Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Keiko Yoshitake, Ichitaro Kikunaga, Ai Miyamoto, Megumi Shimada
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Patent number: 9777142Abstract: The present invention relates to a polyolefin composition comprising two heterophasic propylene copolymers which differ in the intrinsic viscosity of their xylene soluble fractions.Type: GrantFiled: August 18, 2014Date of Patent: October 3, 2017Assignee: BOREALIS AGInventors: Martina Sandholzer, Susanne Kahlen, Georg Grestenberger
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Patent number: 9777143Abstract: The present invention is directed to an article of manufacture, which can be a fiber and or a film. In one aspect, the fiber or the film comprises a polyvinyl alcohol (PVOH) and an inorganic filler comprising particles having an average diameter of less than about 20 micrometers. The PVOH has a degree of hydrolysis of greater than about 95% and is present in a range between about 20 wt. % and about 99 wt. % based on the total fiber weight. Methods of making the fibers and films are also disclosed.Type: GrantFiled: April 2, 2015Date of Patent: October 3, 2017Assignee: Georgia-Pacific Consumer Products LPInventors: Daniel W. Sumnicht, Thomas Schulze, Frank-Gunther Niemz
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Patent number: 9777144Abstract: A method of production of an aqueous dispersion of hollow polymer particles including forming, on the outer layers of core polymer particle (A) on which inside shell layer (B) and intermediate shell layer (C) are formed, outside shell layer (D) obtained by using a monomer mixture (d) with a ratio of content of an acidic group-containing monomer controlled to 0.15 wt % or less and adding a base to an aqueous dispersion of the obtained polymer particle to make the pH of the aqueous dispersion 7 or more is provided.Type: GrantFiled: March 13, 2014Date of Patent: October 3, 2017Assignee: ZEON CORPORATIONInventor: Atsushi Yamaguchi
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Patent number: 9777145Abstract: Disclosed are compositions comprising a copolymer comprising copolymerized units of ethylene and copolymerized units of a comonomer providing an amine-reactive site combined with a short chain polymer having from about 5 to 50 repeat units and containing one primary amine active amine site, which have a combination of enhanced gas transmission and absorption properties and antifog properties. Films and laminate structures comprising these compositions have excellent gas (e.g. oxygen, water vapor, etc.) absorption and transmission and antifogging properties.Type: GrantFiled: December 18, 2014Date of Patent: October 3, 2017Assignee: E. I. DU PONT DE NEMOURS AND COMPANYInventor: Richard T Chou
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Patent number: 9777146Abstract: Provided is a thermoplastic resin composition in which filler such as glass fiber is incorporated to enhance rigidity, and which is further improved in hand touch feeling and occurrence of squeaking noise. The thermoplastic resin composition comprises a rubber-reinforced aromatic vinyl resin (A, B), a crystalline thermoplastic resin (C), and a fibrous or layered filler (D), wherein the thermoplastic resin composition has melting points, as measured according to JIS K7121-1987, between 0 and 100° C. and between 170 and 280° C., and a bending elastic modulus of 3,000 MPa or higher. The component (A) preferably comprises an ethylene/?-olefin rubbery polymer (a1) having a melting point of 0 to 100° C. as measured according to JIS K7121-1987. The component (C) preferably has a melting point of 170 to 280° C. as measured according to JIS K7121-1987, and is preferably at least one selected from the group consisting of a polyester resin and a polyamide resin.Type: GrantFiled: April 23, 2014Date of Patent: October 3, 2017Assignee: TECHNO POLYMER CO., LTD.Inventors: Isamu Mochizuki, Kazuya Egawa
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Patent number: 9777147Abstract: Provided is a thermoplastic resin composition [X] for reduction of squeaking noises containing a rubber-reinforced vinyl resin [A] obtained by polymerizing a vinyl monomer [b1] in the presence of an ethylene-?-olefin rubber polymer [a1] having Tm (melting point) of 0° C. or higher, wherein an amount of silicon contained in the thermoplastic resin composition [X] is 0.15% by mass or less based on 100% by mass of the thermoplastic resin composition [X]. According to the present invention, a structure can be provided, which is characterized in that squeaking noises that are generated when members rub against each other is remarkably reduced, that an effect of reducing squeaking noises is maintained without deterioration even when placed under high temperature for a long time, and that impact resistance and molded appearance are superior.Type: GrantFiled: April 28, 2016Date of Patent: October 3, 2017Assignee: TECHNO POLYMER CO., LTD.Inventors: Isamu Mochizuki, Kazuya Egawa
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Patent number: 9777148Abstract: A biodegradable composite material or device including at least one biodegradable polymer matrix material and at least one filler component. The material or device has an initial shape and at least one evolved shape. The evolved shape is different from the initial shape. The initial shape is adapted to change towards the evolved shape. The filler component is adapted to accelerate and/or amplify the transformation from the initial shape towards the evolved shape when the external stimulus for transformation is given by physiological conditions. Also a method to control the shape transformation rate of a composite material or device.Type: GrantFiled: May 11, 2010Date of Patent: October 3, 2017Assignee: BIORETEC OYInventors: Kaarlo Paakinaho, Harri Heino, Pertti Törmälä
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Patent number: 9777149Abstract: A polyester resin composition according to the present invention includes a polyester polyol having a glycerol skeleton and a curing agent, wherein 5 percent by mass or more of glycerol residue of the polyester polyol is contained in the polyester resin composition. The resin composition can provide an adhesive exhibiting an excellent adhesive force. The adhesive has a gas barrier property or a water vapor barrier property and, therefore, a gas barrier or water vapor barrier film can be provided by using the adhesive.Type: GrantFiled: December 24, 2013Date of Patent: October 3, 2017Assignee: DIC CORPORATIONInventors: Hiroyuki Takeda, Hiroyuki Kagaya, Masanori Hayashi, Michiya Nakashima, Hidekazu Miyano
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Patent number: 9777150Abstract: A polyester composition is suitable for food and beverage packaging. The polyester composition is obtained by blending: (a) 90-97 wt. % of a thermoplastic polyester selected from polyethylene terephthalate, polyethylene naphthalene, and mixtures thereof, (b) 2-6 wt. % of MXD6, (c) 1-5000 ppm of a cobalt salt, (d) 0.1-1000 ppm ethylene glycol (EG), and (e) 0.1-1000 ppm of pyromellitic dianhydride (PMDA).Type: GrantFiled: September 23, 2014Date of Patent: October 3, 2017Assignee: Anheuser-Busch InBev S.A.Inventors: Daniel Peirsman, Vanessa Valles, Ajay Godara
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Patent number: 9777151Abstract: A polymer resin composition capable of providing a synthetic resin showing physical properties of improved heat resistance or impact resistance is provided, in which the polymer resin composition includes a polyester tetrapolymer containing a residue of a dicarboxylic acid component containing terephthalic acid and a residue of a diol component containing dianhydrohexitol, and one or more terpolymers selected from the group consisting of an unsaturated nitrile-diene-based rubber-aromatic vinyl graft terpolymer, an alkyl methacrylate-diene-based rubber-aromatic vinyl graft terpolymer, and an alkyl methacrylate-silicone/alkyl acrylate graft terpolymer.Type: GrantFiled: February 6, 2014Date of Patent: October 3, 2017Assignee: SK CHEMICAL CO., LTDInventors: Dong-Cheol Sohn, Byung-Woo Ahn, Jong-Wook Shin, Jong-Ryang Kim
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Patent number: 9777152Abstract: To provide a polycarbonate resin composition excellent in surface hardness and impact strength. A polycarbonate resin composition comprising at least a polycarbonate resin (a) and a polycarbonate resin (b) having structural units different from the polycarbonate resin (a), which satisfies the requirements: (i) the pencil hardness of the polycarbonate resin (a) as specified by ISO15184 is higher than the pencil hardness of the polycarbonate resin (b) as specified by ISO15184; (ii) the weight ratio of the polycarbonate resin (a) to the polycarbonate resin (b) in the polycarbonate resin is from 1:99 to 45:55; (iii) the pencil hardness of the polycarbonate resin composition as specified by ISO15184 is higher by at least two ranks than the pencil hardness of the polycarbonate resin (b) as specified by ISO15184; and (iv) the Charpy impact strength of the polycarbonate resin composition is higher than the Charpy impact strength of the polycarbonate resin (a).Type: GrantFiled: October 1, 2012Date of Patent: October 3, 2017Assignees: Mitsubishi Chemical Corporation, Mitsubishi Engineering-Plastics CorporationInventors: Tatsuya Hitomi, Ryouhei Nishihara, Masanori Yamamoto, Michio Nakata, Tetsurou Nobuyasu, Ryuuji Uchimura, Kazuyuki Takahashi, Kenji Tsuruhara, Tomonari Yokoyama
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Patent number: 9777153Abstract: A polyalkylene carbonate resin composition with interpenetrating network structure includes an aliphatic polycarbonate obtained through a reaction of carbon dioxide with at least one epoxide compound selected from the group consisting of (C2-C10)alkylene oxide substituted or unsubstituted with halogen or alkoxy, (C4-C20)cycloalkylene oxide substituted or unsubstituted with halogen or alkoxy, and (C8-C20)styrene oxide substituted or unsubstituted with halogen, alkoxy, alkyl or aryl, at least one compound selected from a polyol compound, an epoxy compound and an acryl compound, and a curing agent for polymerization or networking.Type: GrantFiled: May 3, 2013Date of Patent: October 3, 2017Assignees: SK Innovation Co., Ltd., SK Global Chemical Co., Ltd.Inventors: Seung Gweon Hong, Jae Young Park, Hye Lim Kim, Ji Yeon Choi, Kwang Jin Chung, Myung Ahn Ok
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Patent number: 9777154Abstract: Gels and gel-containing materials, including hydrogels, are described. A gel can be formed by blending polyacrylic acid (PAA) and a polyglycol, such as polytetramethylene ether glycol (PTMEG) at room temperature and, in some cases, without using a catalyst. The blend material can be used to form soft or hard materials, films and particles. The blend material can be combined with vinyl monomers and polymerize to form a hydrogel. The hydrogel can have a high mechanical strength and high water absorbency.Type: GrantFiled: November 8, 2011Date of Patent: October 3, 2017Inventors: Naihong Li, Michael C. Williams
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Patent number: 9777155Abstract: The embodiments herein relate to a benzoxazine resin composition, a prepreg, and a carbon fiber-reinforced composite material. More specifically, the embodiments herein relate to a benzoxazine resin composition that provides a carbon fiber-reinforced composite material that is suitable for use as a manufacture material due to its superior mechanical strength in extreme use environments, such as high temperature and high moisture, as well as a prepreg, and a carbon fiber-reinforced composite material. An embodiment comprises a benzoxazine resin composition having a multifunctional benzoxazine resin; a multifunctional epoxy resin that is a liquid at 40° C. and has three or more glycidyl groups; a sulfonate ester; and optionally at least one thermoplastic resin. The resin may include an interpenetrating network structure after curing.Type: GrantFiled: June 27, 2013Date of Patent: October 3, 2017Assignee: TORAY INDUSTRIES, INC.Inventors: Atsuhito Arai, Jeffrey A Satterwhite, Johnathan C Hughes, Hiroaki Sakata, Kenichi Yoshioka
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Patent number: 9777156Abstract: A composition [composition (C)] comprising from 1 to 90% by weight (wt. %) of at least one poly(aryl ether ketone) [(PAEK) polymer, herein after], from to 25 wt. % of at least one polyphenylsulfone polymer [(PPSU) polymer, herein after], from 1 to 90% wt. % of at least one poly(aryl ether sulfone) polymer [(P1) polymer, herein after], selected from a group consisting of at least one high temperature poly(aryl ether sulfone) polymer [(PAESHT) polymer, herein after] and at least one polyethersulfone polymer [(PESU) polymer, herein after]; from 0 to 50% wt. % of at least one reinforcing filler, and wherein all % are based on the total weight of the composition (C).Type: GrantFiled: November 8, 2013Date of Patent: October 3, 2017Assignee: SOLVAY SPECIALTY POLYMERS USA, LLC.Inventors: Mohammad Jamal El-Hibri, Keshav Gautam, Ahmed Khan
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Patent number: 9777157Abstract: A fluorosilicone rubber composition comprising (A) an alkenyl-rich fluorosilicone gum, (B) an alkenyl-poor fluorosilicone gum, (C) reinforcing silica, and (D) a curing catalyst cures into a product which experiences little change of physical strength even after immersion in alcohol-containing fuel oil.Type: GrantFiled: March 12, 2015Date of Patent: October 3, 2017Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Osamu Hayashida, Takao Uno, Kazuhiro Oishi, Atsuhito Kashima
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Patent number: 9777158Abstract: This invention is based upon the discovery that hydroxylated carboxylic acids which contain at least 17 carbon atoms and zinc, aluminum or alkaline earth metal salts thereof, such as zinc ricinoleate, act effectively as deodorants in asphalt and asphalt containing compositions. The present invention more specifically discloses an asphalt additive composition which is comprised of (1) an asphalt, (2) 0.05 weight percent to about 4 weight percent of a partitioning agent, and (3) at least 0.1 weight percent of a deodorant selected from the group consisting of (a) a hydroxylated carboxylic acid which contains at least 17 carbon atoms and (b) an aluminum, zinc, or alkaline earth metal salt of a hydroxylated carboxylic acid which contains at least 17 carbon atoms. In many applications it is beneficial for the asphalt additive composition to further include 0.5 weight percent to about 50 weight percent of a polymer additive.Type: GrantFiled: October 7, 2016Date of Patent: October 3, 2017Assignee: Flow Polymers, LLCInventors: Aaron S. Puhala, Michael S. Ivany, James W. Hoover
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Patent number: 9777159Abstract: A pyrolysis device and process to convert a carbonaceous feedstock to a carbon solid and pyrolysis gas, and processes for refining the resulting carbon solid and pyrolysis gases. The pyrolysis process may include introducing a carbonaceous feedstock into a pyrolysis processor having a vertical rotary tray processor, heating the feedstock to a temperature above about 790° F., removing a carbon material from a bottom of the pyrolysis processor, and removing a pyrolysis gas from a top of the pyrolysis processor.Type: GrantFiled: November 14, 2014Date of Patent: October 3, 2017Assignee: Reklaim, Inc.Inventors: Joel Horn, Daniel F. Kapral, William J. Langley, Jr., Thomas A. Reynolds
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Patent number: 9777160Abstract: The invention relates to copper-containing metal pigments, wherein the copper-containing metal pigments have an elemental copper content of at least 50 wt.-%, relative to the total weight of the uncoated copper-containing metal pigment, wherein the copper-containing metal pigments have at least one enveloping metal oxide layer and at least one enveloping chemically non-reactive plastic layer, wherein the sum of the amounts of the at least one chemically non-reactive plastic layer and of the at least one metal oxide layer lies in a range of from 10 to 50 wt.-%, relative to the weight of the uncoated metal pigment, and the weight ratio of the at least one metal oxide layer to the at least one chemically non-reactive plastic layer lies in a range of from 1:2 to 1:20. The invention furthermore relates to a method for producing these pigments and the use thereof.Type: GrantFiled: March 21, 2012Date of Patent: October 3, 2017Assignee: ECKART GMBHInventors: Oliver Struck, Phu Qui Nguyen, Dirk Schumacher, Sebastian Hoefener
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Patent number: 9777161Abstract: Treated, mesoporous aggregates comprising a plurality of coated particles that comprise an inorganic oxide core having a surface area of about 50 to about 500 square meters per gram and a shell or coating consisting of an array of fluoroalkyl molecular chains covalently bonded to the core at a density of at least one chain per square nanometer. The aggregates are formed by the chemical attachment of fluoroalkyl-alkylsilanes after exposure to an alkylamine and followed by an extraction to remove any unbound organic material. The dense packing of molecular chains in the fluoroalkyl shell combined with a mesoporous structure imparts a very low surface energy, a very high specific surface area, and surface texture over a wide range of length scales. Such features are highly desirable for the creation of, for example, superhydrophobic and superoleophobic surfaces, separation media, and release films.Type: GrantFiled: April 18, 2014Date of Patent: October 3, 2017Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Raymond Campos, Andrew Guenthner, Timothy Haddad, Joseph M. Mabry
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Patent number: 9777162Abstract: To provide a waterborne curable resin composition that is advantageous for environmental protection measures, can be applied without use of a film-forming assistant and can improve the dispersion stability of the emulsion, and also improve physical properties of the coat such as curability, durability, and stain resistance. A waterborne curable resin composition having an acrylic emulsion produced by emulsion polymerization, wherein the acrylic emulsion contains a curable monomer and/or oligomer in emulsion particles.Type: GrantFiled: October 2, 2006Date of Patent: October 3, 2017Assignee: Nippon Shokubai Co., Ltd.Inventors: Yoshiyuki Yokota, Masaya Uchida
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Patent number: 9777163Abstract: The method consists of the formation of a layer over a stone substrate to increase its hardness, chemical resistance, wear and scratch resistance, comprising applying on the substrate a coating matrix incorporating an organic material and fillers including inorganic nanoparticles and/or microparticles; chemically binding said matrix to the substrate, by a self-assembly process and/or a binding process by covalent bonding, electrostatic bonding, van der Waals bonding or hydrogen bonds; and finally drying said matrix. The mentioned organic material is selected from organosilanes, organophosphates, polycarboxylic compounds, compounds based on triazine heterocycles and said nanoparticles are nanoparticles of oxides, carbides, borides, nitrides of metals or of semimetals.Type: GrantFiled: December 15, 2010Date of Patent: October 3, 2017Assignee: SILICALIA, SLInventors: Erik Schoneveld, Francisco Antonio Sanchis Brines, Amaya Ortega Murguialday, Julio Gómez Cordón, Maria Dolores Lorente Aroca, Diana Cordero Etchaberry
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Patent number: 9777164Abstract: An allergen reducing agent is provided that contains a terpenoid polymer or copolymer as an active component, and that functions to reduce allergens such as mites and pollen, and is capable of suppressing coloring.Type: GrantFiled: September 26, 2014Date of Patent: October 3, 2017Assignee: Panasonic Intellectual Property Management Co., Ltd.Inventors: Kenji Sakamoto, Shigeharu Fukuzawa, Hiroyuki Omura, Shoichi Nakamoto, Kazumasa Rokushima
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Patent number: 9777165Abstract: The present invention relates to an alkaline aqueous composition on the basis of water glass and organosilanes with non-hydrolysable substituents which have a primary amino group in the substituents, for providing corrosion-protected coatings on metal surfaces which convey good reshaping properties in metal processing. For the desired functionality, the compositions according to the invention contain the organosilane and the water glass in a predetermined ration. The invention further relates to a method for pre-treating metal surfaces using the alkaline aqueous compositions, which method provides excellent results with regard to corrosion protection, varnish adhesion and reshapability, particularly on aluminum and on steel strips provided with aluminum alloy metal coatings.Type: GrantFiled: March 19, 2015Date of Patent: October 3, 2017Assignee: Henkel AG & Co. KGaAInventors: Juergen Stodt, Michael Wolpers, Marcel Roth
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Patent number: 9777166Abstract: The present invention provides aqueous caulk or sealant compositions that are substantially free of any plasticizer comprising an aqueous emulsion copolymer having a broad measured glass transition temperature by differential scanning calorimetry (DSC), soft phases and hard phases, and two separate Tan Delta transition temperatures as measured by dimensional mechanical analysis (DMA), (ii) one or more filler in a filler to binder ratio of up to 4:1, and (iii) from 0.2 to 5 wt. % as solids, based on the total weight of the composition, of one or more thickener or rheology modifier. In addition, the invention provides methods of making the composition comprising polymerizing by gradually adding from a flask into a polymerization vessel a soft monomer composition, and, after feeding at least 20 wt. % of such composition in the vessel, gradually adding into the flask a hard comonomer composition, feeding all flask contents into the vessel and polymerizing.Type: GrantFiled: December 12, 2013Date of Patent: October 3, 2017Assignee: Rohnm and Haas CompanyInventors: Willie Lau, Karl Allen Bromm, Victoria A. Demarest, Catheryn L. Jackson, Audrey B. Liss
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Patent number: 9777167Abstract: A formulation for application to a substrate including a mixture of a liquid having a first viscosity and an amine-acid adduct. The mixture has a second viscosity greater than the first viscosity. The amine-acid adduct is evaporative and substantially completely removed from the mixture in a functionally dry state as applied as a deposit on the substrate. In particular, the general nature of the formulation is that of a mixture that includes a viscosity control agent, such as an amine-acid adduct that forms a carbamate, and the formulation is for use in coating or printing wherein the final coated product includes little or no viscosity control agent.Type: GrantFiled: May 19, 2005Date of Patent: October 3, 2017Assignee: FLEXcon Company, Inc.Inventors: Yan Bielek, Philip R. Emery