Abstract: The disclosure relates to an active energy ray-curable inkjet ink composition comprising at least a monomer and a pigment, wherein the monomer comprises at least 2-(2-vinyloxyethoxy)ethyl acrylate and dipropylene glycol diacrylate. A content of 2-(2-vinyloxyethoxy)ethyl acrylate is 36 to 65% by weight in a total weight of the ink. A content of dipropylene glycol diacrylate is 31 to 63% by weight in the total weight of the ink. A content of the pigment is 1 to c % by weight in the total weight of the ink, wherein the c is the pigment concentration at which the average absorbance at 320-380 nm in 2,000-fold dilution of the ink composition with dipropylene glycol diacrylate is 1.

Abstract: Provided is an ink set including black ink and color ink, in which the black ink contains carbon black having a carboxyl group on a surface thereof, a resin particle having a carboxyl group on a surface thereof, betaine, an alkali ion, and water, the alkali ion contains a potassium ion, a sodium ion, and an organic alkali compound, and a content of the potassium ion is the largest among the alkali ions.

Abstract: Provided are metal nanoparticle composite body whose multiple properties, such as a good metal nanoparticle control property, high dispersion stability, a good low-temperature firing property, and ease of purifying and separating metal nanoparticles, are intentionally added and controlled so that practical electrical conductivity can be exhibited, a metal colloidal solution in which the metal nanoparticle composite body is dispersed, and methods for producing these. A metal nanoparticle composite body includes a nitrogen-containing compound (A) and a metal nanoparticle (B), in which the nitrogen-containing compound (A) contains an oxidized nitrogen atom. A metal colloidal solution is obtained by dispersing the metal nanoparticle composite body in a medium. A method for producing a metal colloidal solution is characterized in that metal ions are reduced in a medium in the presence of a nitrogen-containing compound (A) containing an oxidized nitrogen atom so as to form metal nanoparticles (B).

Abstract: A process for depositing a metal on a substrate involves the use of two reduction reactions in a bottom-up based tandem manner starting from a substrate surface and working upward. A first reduction reaction starts on the substrate surface at ambient temperature, and a second reduction reaction, which is initiated by the reaction heat of the first reduction reaction, occurs in a reactive ink solution film coated on top, which becomes solid after the reaction. Gas and other small molecules generated from the reduction reactions, and the solvent, can readily escape through the upper surface of the film before the solid metal layer is formed or during post-treatment, with no or few voids left in the metal film. Thus, the process can be used to form highly conductive films and features at ambient temperature on various substrates.

Abstract: This present invention relates to oxidized, discrete carbon nanotubes in dispersions, especially for use in printing inks. The dispersions can include materials such as elastomers, thermosets and thermoplastics or aqueous dispersions of open-ended carbon nanotubes with additives. A further feature of this invention relates to the development of a dispersion of oxidized, discrete carbon nanotubes that are electrically conductive.

Abstract: A plastic panel suitable for use in an automotive vehicle or other structure is provided wherein the plastic panel includes a polycarbonate substrate, a PMMA layer and a scratch resistant coating. The polycarbonate substrate may have a thickness approximately between 2.0 mm and approximately 6.0 mm. The PMMA layer may be disposed onto the polycarbonate substrate and the PMMA layer may have a thickness approximately between 0.25 mm and approximately 3.0 mm. The scratch resistant coating is applied to both the PMMA layer and the PC substrate.

Abstract: Disclosed herein is a hard coating composition used in forming a hard coating film exhibiting high hardness and excellent properties. The hard coating composition can be used to prepare a hard coating film exhibiting high impact resistance, high scratch resistance and high transparency and having excellent processability.

Abstract: An ink includes a pigment a quinacridone compound represented by Chemical formula 1, and a copolymer including the structure unit represented by Chemical formula 2 or Chemical formula 3. In Chemical formula 1, R1, R2, R3, and R4 each, independently represent hydrogen atoms, halogen atoms, or alkyl groups having 1-4 carbon atoms, R5, R6, and R7 each, independently represent alkyl groups having 1-4 carbon atoms or alkylene groups having 1-4 carbon atoms, and m represents 1 or 2, In Chemical formula 2, R8 represents a hydrogen atom or a methyl group and L1 represents an alkylene group having 2-16 carbon atoms, In Chemical formula 3, R9 represents a hydrogen atom or a methyl group, L2 represents a single bond or —(CH2)n—O— and n represents an integer of 2-16.

Abstract: It is an object of the present invention to provide a urethane (meth)acrylate that enables formation of a cured layer having a low reflectance and excellent excoriation resistance, a curable composition produced by using the same, and an antireflective film. In particular, there is provided a fluorine-containing urethane (meth)acrylate represented by General Formula (I) and having a fluorine atom content ranging from 25 to 60 mass % (where R1 and R2 each represent a specific fluorinated alkyl group, R3 and R4 each represent a hydrogen atom or a methyl group, A represents a trivalent linking group represented by any of Structural Formulae (A1) to (A4), and X and Y each independently represent a divalent linking group represented by any of Structural Formulae (a) to (c)) [in Structural Formula (c), R5 represents an alkyl group having 1 to 6 carbon atoms].

Abstract: The present invention relates to a coating composition comprising at least one thermoplastic acrylonitrile-butadiene-styrene copolymer in a content of at least 30% by weight of the solids content of the coating composition, at least one UV-curable reactive diluent in a content of at least 30% by weight of the solids content of the coating composition, at least one photoinitiator in a content of ?0.1 to ?10 parts by weight of the solids content of the coating composition and at least one organic solvent, where the proportion of ethylenically unsaturated groups is at least 3 mol per kg of the solids content of the coating composition. This is used to provide films and moldings coated therewith, having a metallizable, scratch-resistant and solvent-resistant surface.

Abstract: Described is an insulating layer-forming composition, which contains a binder based on epoxy-thiol. The inventive composition, its rate of expansion ratio is relatively high, allows coatings having the layer thickness, required for the respective period of fire resistance, to be applied in a simple and fast manner, while at the same time the layer thickness is reduced to a minimum and yet a high insulating effect can be achieved. The composition of the invention is particularly suitable for fire protection, in particular as a coating of metallic and non-metallic substrates, such as steel components, like columns, beams, trusses, in order to increase the period of fire resistance.

Abstract: The invention relates to a thiol-functional organic compound having on average at least 3.1 thiol groups per molecule, and having carbon atoms, oxygen atoms, and sulfur atoms, and optionally further heteroatoms, and wherein the ratio of the number of carbon atoms (C) to the sum of the number of heteroatoms (HA), (C/HA) is at least 2.0, and wherein the thiol groups are derived from 2-mercapto acetic acid, 2-mercapto propionic acid, or 3-mercapto propionic acid, or esters thereof; and to a liquid coating composition comprising the thiol-functional compound and a thiol-reactive crosslinker.

Abstract: Provided is a binder composition and its use in aqueous based paints and coatings and other applications. The binder composition comprises: a polyurethane dispersion containing water and a polyurethane polymer, wherein the polyurethane polymer is prepared by reacting a nitroalcohol compound, a polyol compound, a polyisocyanate compound, and optionally chain extenders, wherein the nitroalcohol compound is of formula I, wherein R, R1, and Z are as defined herein.

Abstract: A method for producing a composite material, including an assembly of one or a plurality of synthetic reinforcement fibers, impregnated with at least one thermoplastic polymer having a vitreous transition temperature Tg greater than or equal to 80° C. including: i) a step of impregnating said assembly with a precursor composition in the molten state and including: a) at least one prepolymer P(X)n of said thermoplastic polymer, including a molecular chain P having, at the ends n thereof, identical reactive functions X, said prepolymer having a semiaromatic and/or semi-cycloaliphatic structure, b) at least one chain extender including two identical functions Y, which are reactive with at least one of said functions X; ii) a step of polymerization by mass (poly)addition, in the molten state, of said prepolymer with said chain extender, with said thermoplastic polymer of the thermoplastic matrix being the result of said polymerization by mass polyaddition.

Abstract: A protective flowable or spreadable composition. The protective composition optionally and preferably features a base material according to various embodiments and aerogel, dispersed in an acrylic dispersion. Preferably the protective composition further comprises one or more of chopped glass fibers and titanium dioxide. Water or an aqueous solution is preferably added to determine the degree of viscosity, for example to apply the composition in flowable form (paint, sprayable material, coating and so forth) or in spreadable form.

Abstract: An underlayer film-forming composition used for an underlayer for a self-assembled film, including a polysiloxane and a solvent. The polysiloxane may be a hydrolysis-condensation product of a silane containing a phenyl group-containing silane, or a hydrolysis-condensation product of a silane containing a silane of Formula (1) in a ratio of 10 to 100% by mol relative to the total silane, or a hydrolysis-condensation product of silanes containing the silane of Formula (1), silane of Formula (2) [R4Si(R3)3 (2)], and silane of Formula (3) [Si(R5)4 (3)] in a ratio of silane of Formula (1): silane of Formula (2): silane of Formula (3) of 10 to 100:0 to 90:0 to 50 in terms of % by mol relative to the total silane.

Abstract: A hybrid material for light emitting diodes, comprising a) an organopolysilazane material, comprising repeating units of formulae (I) and (II) [—SiR1R2—NR3—]x??(I) [—SiHR4—NR5—]y??(II) wherein the symbols and indices have the following meanings: R1 is C2-C6-alkenyl or C4-C6-alkadienyl; R2 is H or an organic group; R3 is H or an organic group; R4 is H or an organic group; R5 is H or an organic group; x is 0.001 to 0.2; and y is 2x to (1?x), with the proviso that x+y?1 and that y can be 0 if R2 is H, and b) inorganic nanoparticles having a mean diameter in the range of from 1 to 30 nm, which are surface modified with a capping agent comprising a C1-C18-alkyl and/or C1-C18-alkenyl group, is useful as encapsulation material for LEDs.

Abstract: Fibrous insulation products have an aqueous binder composition that includes a carbohydrate and a crosslinking agent. In exemplary embodiments, the carbohydrate-based binder composition may also include a catalyst, a coupling agent, a process aid, a crosslinking density enhancer, an extender, a moisture resistant agent, a deducting oil, a colorant, a corrosion inhibitor, a surfactant, a pH adjuster, and combinations thereof. The carbohydrate may be natural in origin and derived from renewable resources. Additionally, the carbohydrate polymer may have a dextrose equivalent (DE) number from 2 to 20. In at least one exemplary embodiment, the carbohydrate is a water-soluble polysaccharide such as dextrin or maltodextrin and the crosslinking agent is citric acid. Advantageously, the carbohydrates have a low viscosity and cure at moderate temperatures. The environmentally friendly, formaldehyde-free binder may be used in the formation of insulation materials and non-woven chopped strand mats.

Abstract: A multilayer film includes a protective layer, a color layer and an adhesive layer, with a molding film disposed between either of the adjoining pairs of layers or on an opposite surface of the protective layer to the color layer, wherein the protective layer contains a polyurethane resin (U) formed at least from an active hydrogen component (A) and an organic isocyanate component (B) and having a polycarbonate skeleton with an alicyclic hydrocarbon group and conditions (1) and/or (2) are satisfied: (1): the polyurethane resin (U) is a polyurethane resin (U1) having an alkoxysilyl and/or a silanol group in a molecule, (2): the protective layer contains a compound (X) having a glycidyl ether and an alkoxysilyl and/or a silanol group, and the polyurethane resin (U) is a polyurethane resin (U2) having an amino group or a carboxyl group and/or a salt thereof.

Abstract: [Problem] This is to provide an adhesive sheet having curved surface followability and chemical resistance. [Means for solving] The adhesive sheet is an adhesive sheet having at least a substrate and an adhesive layer, a load at the time of 5% elongation of the substrate is 15 N/cm or less, a stress relaxation rate of the substrate by elongating to 10%, stopping the elongation at that state and after lapsing 600 seconds is 40% or more and 100% or less, and a chemical weight increased ratio of the substrate is 60% or less.

Abstract: The subject matter of the invention is a method for the production of a cladding (1) for elongated material (2), in particular a sheath for cable sets. In this context, two adhesive tapes (3, 4) that are provided at least on one side with an adhesive coating (3) are axially spaced apart from one another by means of a carrier tape (5) are joined to form a laminate (3, 4, 5). For this purpose, both adhesive tapes (3, 4) arc each joined, on the side thereof with the adhesive coating, with the carrier tape (5), in the longitudinal direction, while defining a free region (6) limited by both adhesive tapes (3, 4). According to the invention, the carrier tape (5) is configured free of adhesive coating and is only provided with an own adhesive coating (7) at least in the free region (6) after the laminate (3, 4, 5) has been produced.

Abstract: A conductive composition that is sinterable comprises (i) micron- or submicron-sized silver flakes or powders and (ii) a fluxing agent, or an oxygenated solvent, or a peroxide. The composition can be used to adhere semiconductor dies with silver backing to copper-, silver-, or gold lead-frames at sintering temperatures of ?250° C. without the application of pressure.

Abstract: The present invention relates to thermally curable adhesives that are suitable for use as electrically conductive materials in the fabrication of electronic devices, integrated circuits, semiconductor devices, passive components, solar cells, solar modules, and/or light emitting diodes. The thermally curable adhesives comprise at least one thermosetting resin, electrically conductive particles having an average particle size of 1 ?m to 50 ?m, and at least one metal precursor, wherein the metal precursor decomposes substantially to the corresponding metal during the thermal curing of the thermally curable adhesive.

Abstract: The spray can with pre-mixed fiberglass and resin is a prepackaged application system for fiberglass, which can be used for repair or for new applications. The spray can with pre-mixed fiberglass and resin is a chemical formulation that contains a combination of fiberglass and resin that can be applied in a single coat or a multiple coat in a manner similar to applying paint through a spray paint can. The spray can with pre-mixed fiberglass and resin comprises fiberglass, a solvent, a resin, and a propellant.

Abstract: The invention relates to a composition for a structural acrylic adhesive that comprises an adhesion promoter including a phosphate ester and a high molecular-weight polyamine as a polymerization accelerator.

Abstract: The invention relates to an adhesive composition wherein such composition comprises at least one polypropylene copolymer and wherein such adhesive composition has improved overall bond performance. It further relates to an article comprising said adhesive composition, as well as to a process for producing such article. It even further relates to the use of the adhesive composition in the preparation of an article.

Abstract: Compositions and methods are described for a temporary adhesive with adjustable adhesion force to affix a thin solid material onto a carrier whereby the force of adhesion is defined by choosing and adjusting the polymeric resin components to provide sufficient adhesion to support a manufacturing process, and upon completion, the thin solid material is removed by an external applied force of a given value that overcomes the adhesive force without harm to the thin solid material. The temporary adhesive provides a tunable adhesion force that is lower than the tensile strength of the thin solid material, preferably less than 50%, more preferably less than 25%, and most preferably less than 10% of the tensile strength of the thin solid material. The temporary adhesive may be applied and cured in a variety of ways that meet the needs of the form of the thin solid material and objectives of the manufacturing process.

Abstract: A method of forming a shaped abrasive particle includes applying a mixture into a shaping assembly within an application zone and directing an ejection material at the mixture in the shaping assembly under a predetermined force, removing the mixture from the shaping assembly and forming a precursor shaped abrasive particle.

Abstract: A method includes: providing a mold having a plurality of mold cavities, wherein each mold cavity is bounded by a plurality of faces joined along common edges; filling at least some of the mold cavities with a sol-gel composition that includes a release agent dispersed therein; at least partially drying the sol-gel composition thereby forming shaped ceramic precursor particles; calcining at least a portion of the shaped ceramic precursor particles to provide calcined shaped ceramic precursor particles; and sintering at least a portion of the calcined shaped ceramic precursor particles to provide ceramic shaped abrasive particles. A sol-gel composition, shaped ceramic precursor particles, and ceramic shaped abrasive particles associated with practice of the method are also disclosed.

Abstract: Ice-resistant paint comprising an ice-resistant base component that in turn comprises a main component entailing a high solid paint with a synthetic polyurethane-based binding component dissolved in a main organic solvent, and a hydrophobe component consisting of hydrophobic ice-resistant functional nanoparticles selected from among nanoparticles functionalized with a polymer and nanoparticles functionalized in sol-gel, where the ice-resistant paint comprises a mixture of the main component with a dispersion of functional nanoparticles dispersed in a dispersing composition constituting the main solvent and a dispersant, and forms a base matrix, where the dispersing composition and functional nanoparticles form a dispersion of nanoparticles in which the functional nanoparticles are in the base matrix, and the dispersion of dispersing nanoparticles mixed with the main component to form an ice-resistant base component of the ice-resistant paint.

Abstract: Provided is a phenolic resin composition containing: an epoxy resin curing agent that contains a hydroxybenzene derivative represented by the following Formula (I) and a phenol resin having at least one partial structure selected from the group consisting of the following Formulae (IIa), (IIb), (IIc) and (IId); and an epoxy resin. In these Formulae, each of R1, R2, R3, R4 and R5 independently represents a hydroxy group, a hydrogen atom or an alkyl group; at least two of R1, R2, R3, R4 and R5 are hydroxy groups; each Ar independently represents at least one group selected from the group consisting of the following Formulae (IIIa) and (IIIb); each of R11 and R14 independently represents a hydrogen atom or a hydroxy group; and each of R12 and R13 independently represents a hydrogen atom or an alkyl group.

Abstract: Disclosed herein are compositions, preparation methods, and use of thermally conductive materials comprising silicone composition curable by hydrosilylation, thermally conductive fillers, and phthalocyanine. The novel composition retains its desirable pliability after cure even when kept at an elevated temperature for an extended period.

Abstract: The present invention relates to hollow hydrogel capsules. In various embodiments, the present invention provides a method of treating a subterranean formation with a hollow hydrogel capsule including a hydrogel shell including a hydrolyzed and crosslinked polymerized composition. The hollow hydrogel capsule also includes a hollow interior including at least one component of a downhole composition for subterranean petroleum or water well drilling, stimulation, clean-up, production, completion, abandonment, or a combination thereof. In various embodiments, the present invention provides compositions comprising the hollow hydrogel capsules and methods of making the hollow hydrogel capsules.

Abstract: A method of drilling a subterranean well may include drilling the subterranean well while circulating a wellbore fluid in the subterranean well, wherein the wellbore fluid includes a base fluid; and a ground weight material comprising barite and quartz and having a d50 between about 4 and 8 microns and a d90 between about 15-25 microns.

Abstract: Crosslinked sulfonate-containing polymers may be stable in high density, monovalent brines, which may render such polymers particularly useful in drilling fluids in general and, especially, in the subclass of drilling fluids known as drill-in fluids. For example, a drilling fluid may include a crosslinked sulfonate-containing polymer dispersed in a monovalent brine having a density of about 8 lb/gal to about 20 lb/gal, wherein the crosslinked sulfonate-containing polymer comprises: reactants of a first repeating unit and a crosslinker that react to form the crosslinked sulfonate-containing polymer, wherein the first repeating unit is a sulfonic acid-containing monomer present from 50% to 99.99% by weight of the reactants, and wherein the crosslinker comprises at least two olefinic bonds.

Abstract: The present invention relates to the well drilling field in petroleum industry, in particular to a drilling fluid additive composition that contains a lubricant, an emulsifier, and a rheological modifier, wherein, the lubricant contains: graphite oxide and a biquaternary ammonium salt compound in which the cation part is represented by formula (1); the emulsifier is one or more of compounds represented by formula (I); the rheological modifier is a dimer acid-organic amine copolymer comprising structural units from dimer acid, structural units from alkylamine and structural units from arylamine. The present invention further provides an oil-based drilling fluid containing the composition and a use thereof.

Abstract: Disclosed are traceable polymeric additives that comprise a tagging material and methods of using the traceable polymeric additives in subterranean applications, such as cementing. An embodiment discloses a well treatment composition comprising a base fluid and a traceable polymeric additive comprising a polymer and a tagging material.

Abstract: Methods of treating a well bore within an underground formation are disclosed. These methods include: (a) preparing a treatment composition by mixing a polyol-containing component and a polyisocyanate-containing component; and (b) introducing the treatment composition into the well bore. The polyol-containing component includes a polymeric polyol having a viscosity at 25° C. of no more than 1000 mPa·s and the isocyanate-containing component includes an unblocked (cyclo)aliphatic polyisocyanate polymer including allophanate groups and having a viscosity at 25° C. and at least 99% solids of no more than 1000 mPa·s.

Abstract: Methods, compositions, and techniques for enhancing the production of hydrocarbons such as crude oil from subterranean hydrocarbon bearing formations are disclosed. In some embodiments, the invention relates to processes for evaluating enhanced oil recovery mechanisms in carbonate based reservoirs at both the rock-fluid and oil-water interfaces using spectroscopic and interfacial techniques. In further embodiments, the spectroscopic and interfacial techniques include microscopic, rheometric and tensiometric measurements. In preferred embodiments, the disclosed methods and techniques provide reservoir based details at that allow for optimized “smart water” flooding practices and correspondingly higher oil recovery rates.

Abstract: The invention relates to a hydrocarbon recovery composition comprising an anionic surfactant, wherein said composition is in the solid state, and to a shaped article comprising said composition. Preferably, said composition is in the form of a powder. Further, the invention relates to a process for treating a hydrocarbon containing formation comprising the steps of a) transporting said composition or shaped article to the location of the hydrocarbon containing formation; b) dissolving said composition or shaped article in water thereby forming an aqueous fluid containing the hydrocarbon recovery composition; c) providing the aqueous fluid containing the hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation; and d) allowing the hydrocarbon recovery composition to interact with the hydrocarbons in the hydrocarbon containing formation.

Abstract: Filamentous polymer particles are added to fluids that are used in oil, condensate or gas recovery from subterranean locations as stimulation fluids injected in wells. The wells serve also as producing wells for the hydrocarbons initially present in the subterranean formations. Such fluids include hydraulic fracturing fluids, diverting fluids, fluids that make it possible to improve the distribution and the flow profiles of the fluids or products injected (referred to as conformance fluids) or permeability control fluids, sand control gravel pack placement fluids, acid fracturing fluids, and the like.

Abstract: The present invention relates to lightweight high strength microsphere containing ceramic particles having controlled microsphere placement and/or size and microsphere morphology, which produces an improved balance of specific gravity and crush strength such that they can be used in applications such as proppants to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more microsphere containing ceramic particles of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the microsphere containing ceramic particles of the present invention are further disclosed, as well as methods of making the microsphere containing ceramic particles.

Abstract: Methods of creating variably tacky proppants and providing such proppants into a subterranean formation are provided. The variably tacky proppants can be non-tacky at a first set of conditions and tacky at a second set of conditions. As such, the variably tacky proppants can be pumped into a subterranean formation and caused to enter fractures in the formation while the proppants are non-tacky. Subsequently, natural or induced conditions in the well bore can cause the proppants to become tacky. The tacky proppants inhibit the movement of proppants in the fractures when pressure is reduced in the formation and inhibit the migration of fines towards the wellbore.

Abstract: A method of treating a treatment zone of a subterranean formation penetrated by a wellbore of a well, the method including the steps of: (A) forming a treatment fluid comprising: (i) an aqueous phase comprising water having at least 1,000 ppm total dissolved inorganic salts; (ii) a carboxymethyl hydroxyethyl cellulose, wherein: (a) the carboxymethyl hydroxyethyl cellulose has a carboxymethyl degree of substitution is in the range of about 0.3 to about 0.45 per glucopyranose unit in the polymer; and (b) the carboxymethyl hydroxyethyl cellulose has a hydroxyethyl molecular substitution is in the range of about 2.1 to about 2.8 per glucopyranose unit in the polymer; and (iii) a breaker for the carboxymethyl hydroxyethyl cellulose; and (B) introducing the treatment fluid into the treatment zone. In embodiments, the carboxymethyl hydroxyethyl cellulose may or may not be crosslinked.

Abstract: Methods and compositions comprising an emulsion or a microemulsion for use in various aspects of the life cycle of an oil and/or gas well are provided. In some embodiments, the emulsion or the microemulsion comprises water, a solvent, and a surfactant, and optionally, one or more additives.

Abstract: The invention relates to compounds which can be used in electronic devices, and to electronic devices, in particular organic electroluminescent devices, containing said compounds.

Abstract: A method of manufacturing a fluoride phosphor, the method comprising: preparing a hydrofluoric (HF) solution in which a first source material and a fluoride containing Mn4+ are dissolved; and forming fluoride particles by introducing a second source material to the HF solution in each of a plurality of instances.

Abstract: A light-emitting ceramic that contains, as a major component thereof, a pyrochlore compound represented by ABOw, wherein A includes at least one element selected from the group consisting of La, Y, Gd, Yb and Lu, B includes Bi and at least one element selected from the group consisting of Zr, Sn and Hf, and W is a positive number.

Abstract: The invention relates to co-activated magnesium alumosilicate based phosphors, to a process of its preparation, the use of these phosphors in electronic and electro optical devices, such as light emitting diodes (LEDs) and solar cells and especially to illumination units comprising said magnesium alumosilicate-based phosphors.

Abstract: In one embodiment, a method includes forming a powder having a composition with the formula: AhBiCjO12, where h is 3±10%, i is 2±10%, j is 3±10%, A includes one or more rare earth elements, B includes aluminum and/or gallium, and C includes aluminum and/or gallium. The method additionally includes consolidating the powder to form an optically transparent ceramic, and applying at least one thermodynamic process condition during the consolidating to reduce oxygen and/or thermodynamically reversible defects in the ceramic. In another embodiment, a scintillator includes (Gd3-a-cYa)x(Ga5-bAlb)yO12Dc, where a is from about 0.05-2, b is from about 1-3, x is from about 2.8-3.2, y is from about 4.8-5.2, c is from about 0.003-0.3, and D is a dopant, and where the scintillator is an optically transparent ceramic scintillator having physical characteristics of being formed from a ceramic powder consolidated in oxidizing atmospheres.