Carboxylic Acid, Ester, Alcohol Or Sulfur Or Metal Derivative Patents (Class 106/14.13)
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Patent number: 12043705Abstract: Described herein is a polymeric pigment dispersant, a process for preparation of the polymeric pigment dispersant and a pigment dispersion including the pigment dispersant that is used for coating and in printing ink, automotive basecoat, auto-motive clearcoat, mill base, furniture coatings and wood coatings.Type: GrantFiled: August 9, 2019Date of Patent: July 23, 2024Assignee: BASF COATINGS GMBHInventors: Shampa R. Samanta, Chintankumar Patel, Qingling Zhang, Karel Hartlieb, Benjamin Georg Robert Mohr
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Patent number: 11708444Abstract: There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.Type: GrantFiled: May 10, 2021Date of Patent: July 25, 2023Assignee: PPG Industries Ohio, Inc.Inventors: Adam Bradley Powell, William H. Retsch, Jr., Edward R. Millero, Jr., John M. Dudik, Christopher P. Kurtz, Michael Olah, Anand K. Atmuri
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Patent number: 11060043Abstract: The present disclosure relates to a formulation of diesel additive comprising 2-ethylhexanoic acid, at least one alkylene glycol and at least one alkanolamine which at specific weight ratios, is able to enhance the lubricity of a fuel. Also provided are the methods of preparation and usage of the same. It further relates to the fuel composition comprising the fuel, and the formulation of present disclosure, and the method of preparing the fuel composition.Type: GrantFiled: May 4, 2018Date of Patent: July 13, 2021Assignee: Hindustan Petroleum Corporation LimitedInventors: Sandip Bhowmik, Chintalapati Siva Kesava Raju, Raghava Krishna Kanala, Ganagalla Srinivasa Rao, Ramkumar Mangala, Peddy Venkata Chalapathi Rao, Nettam Venkateswarlu Choudary, Gandham Sriganesh
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Patent number: 10920324Abstract: Disclosed are pretreatment compositions and associated methods for treating metal substrates with pretreatment compositions, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The pretreatment composition includes: a Group IIIB and/or IVB metal; free fluoride; and molybdenum. The methods include contacting the metal substrates with the pretreatment composition.Type: GrantFiled: October 5, 2018Date of Patent: February 16, 2021Assignee: PPG Industries Ohio, Inc.Inventors: Michel Sudour, Aline Wozniak, Philippe Maintier
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Patent number: 10801112Abstract: The coating film-forming composition is a solution of pH 4 to 10 and includes an aromatic compound having an amino group and an aromatic ring in one molecule, a polybasic acid having two or more carboxy groups, and an oxidizing agent. As the oxidizing agent, hypochlorous acid, chlorous acid, chloric acid, perchloric acid, persulfuric acid, percarbonic acid, hydrogen peroxide, organic peroxides, or the like is used. The aromatic compound preferably contains a nitrogen-containing aromatic ring, and more preferably contains a primary amino group or a secondary amino group. The coating film-forming composition is used for, for example, forming a coating film on surface of a metal member.Type: GrantFiled: December 15, 2017Date of Patent: October 13, 2020Assignee: MEC COMPANY LTD.Inventors: Daisaku Akiyama, Itsuro Tomatsu, Yasutaka Amitani, Keisuke Joko, Tokuya Satomi
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Patent number: 10760164Abstract: A method includes providing a workpiece with at least one surface having an anodized aluminum coating and a trivalent chromium sealant. The at least one surface of the workpiece is submerged in a post-treatment sealant solution for 0.5 to 20 minutes. The sealant composition consists essentially of a corrosion inhibitor formulation, a water soluble polymer, an organic complexing agent, and an oxidant. The corrosion inhibitor formulation is formulated from at least one anodic corrosion inhibitor compound, at least one cathodic corrosion inhibitor compound, or a combination thereof. A concentration of each of the corrosion inhibitor formulation, the water soluble polymer, the organic complexing agent, and the oxidant is each in a range of 1-50 mM.Type: GrantFiled: December 19, 2018Date of Patent: September 1, 2020Assignee: Hamilton Sundstrand CorporationInventors: Zhongfen Ding, Weilong Zhang, Blair A. Smith, Mark R. Jaworowski, Georgios S. Zafiris
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Patent number: 10669429Abstract: The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry primer compositions and coatings, the compositions comprising one or more carboxylic acid compounds that contain one of a benzothiazole, benzoxazole, or benzimidazole group, preferably, that contain a benzothiazole group, one or more hydrophobic sulfonic acid catalyst, one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane coating having improved humidity and corrosion resistance.Type: GrantFiled: August 29, 2018Date of Patent: June 2, 2020Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Nahrain E. Kamber, John N. Argyropoulos, Paul J. Popa, Scott A. Murray
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Patent number: 10323136Abstract: The present invention relates to the use of N-hydroxybenzotriazole derivatives, in particular N-hydroxybenzotriazole salts and/or N-hydroxyindazoles, in particular N-hydroxyindazole salts as flame retardant for plastic materials. The present invention relates in addition to a flame-retardant plastic material molding compound which comprises N-hydroxybenzotriazole derivatives and/or N-hydroxyindazole derivatives as flame retardant.Type: GrantFiled: May 28, 2015Date of Patent: June 18, 2019Assignee: Fraunhofer-Gesellschaft zur förderung der angewandten Forschung e.V.Inventors: Rudolf Pfaendner, Markus Mazurowski
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Patent number: 10131813Abstract: The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry primer compositions and coatings, the compositions comprising one or more carboxylic acid compounds that contain one of a benzothiazole, benzoxazole, or benzimidazole group, preferably, that contain a benzothiazole group, one or more hydrophobic sulfonic acid catalyst, one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane coating having improved humidity and corrosion resistance.Type: GrantFiled: July 20, 2016Date of Patent: November 20, 2018Assignees: Dow Global Technologies LLC, Rhm and Haas CompanyInventors: Nahrain E. Kamber, John N. Argyropoulos, Paul J. Popa, Scott A. Murray
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Patent number: 9771336Abstract: Disclosed are corrosion inhibitor compounds and compositions useful for preventing or inhibiting corrosion of surfaces found in cooling water applications. In some embodiments, the surfaces may include mild steel, aluminum, brass, copper, galvanized steel, a copper alloy, admirality brass, or any combination thereof. Also disclosed are methods of using the compounds and compositions as corrosion inhibitors. In some embodiments, the corrosion inhibitor compounds and compositions are used in cooling water applications.Type: GrantFiled: December 2, 2014Date of Patent: September 26, 2017Assignee: ECOLAB USA INC.Inventors: Jothibasu Seetharaman, Edouard Andre Reny, Donald A. Johnson, Kailas B. Sawant, Vaideeswaran Sivaswamy
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Patent number: 9475954Abstract: A high-hardness clear coating material capable of improving hardness and corrosion resistance of an aluminum material surface includes, in % by weight, 10 to 20% of a melamine curing agent, 10 to 15% of silica, 1 to 5% of a phenol resin, and a remainder of an acrylic resin and other unavoidable impurities.Type: GrantFiled: May 11, 2015Date of Patent: October 25, 2016Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATIONInventor: Chang Yeol Yoo
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Patent number: 9249370Abstract: The invention relates to the use of an O/W emulsion, in particular a PIT emulsion, for lubricating conveyor belt systems in food industries as well as a lubricant concentrate based on an O/W emulsion, in particular a PIT emulsion, of wax esters.Type: GrantFiled: May 14, 2014Date of Patent: February 2, 2016Assignee: Ecolab USA Inc.Inventors: Stefan Küpper, Christina Kohlstedde, Michael Schneider
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Patent number: 9200168Abstract: A tin or tin alloy plating film surface treatment aqueous solution that can reduce whiskers on the surface of a tin or tin alloy plating film, and can provide a favorable tin or tin alloy plating film using a simple method for tin or tin alloy plating films that are used on electronic components.Type: GrantFiled: July 1, 2013Date of Patent: December 1, 2015Inventor: Yutaka Morii
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Patent number: 9108888Abstract: A method to apply nano-crystalline diamond onto a selected substrate, including preparing Nanodiamond slurry of nanodiamond particles dispersed in a medium. The medium may include a liquid or a sol-gel. The selected substrate is immersed in the Nanodiamond slurry for a predetermined period of time. Then the substrate is removed from the slurry. The substrate is then dried with a flow of inert gas. The substrate is left coated with a coating of the nanodiamond particles that are highly adherently held by van der Waals forces.Type: GrantFiled: July 20, 2009Date of Patent: August 18, 2015Inventors: Suneeta S. Neogi, Jayant Neogi
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Patent number: 9039821Abstract: The present invention relates to methods and compositions for coating aluminum substrates. In an embodiment, the invention includes a method of applying a coating on an aluminum substrate including contacting the aluminum substrate with a first solution. The first solution can include a zinc metal salt, a sugar acid or alkali metal salt thereof, and an alkali metal hydroxide. The method can also include contacting the aluminum substrate with a second solution. The second solution can include a molybdate salt, an alkanolamine, and a fluorine acid. Other embodiments are also included herein.Type: GrantFiled: February 28, 2014Date of Patent: May 26, 2015Assignee: BIRCHWOOD LABORATORIES LLCInventors: William V. Block, David J. Halverson, John T. Nguyen
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Publication number: 20150125610Abstract: Aqueous seal coat compositions useful for sealing a pretreated metal surface, comprise water, at least two organo-functional silanes, and optionally a pH-adjusting agent. A process for sealing a pretreated metal surface includes contacting the metal surface with such an aqueous seal coat composition. Preferably, the pH of the seal coat compositions is greater than 5.5.Type: ApplicationFiled: November 1, 2013Publication date: May 7, 2015Applicant: Bulk Chemicals, Inc.Inventor: Richard J. Church
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Publication number: 20150053111Abstract: The invention relates to corrosion inhibitors, and more specifically corrosion inhibitors for coating compositions. The invention provides for coating compositions that have improved corrosion properties, including reduced flash rust during the application of the coating composition to a metal surface, and even improved corrosion inhibition in the resulting dried coating. The invention also provides for methods of making and using the described the compositions and the corrosion inhibitors thereof.Type: ApplicationFiled: March 1, 2013Publication date: February 26, 2015Inventors: Britt A. Minch, Gregory E. Moran, David Boothe, Daniel W. Hunt, Ben Faber, Pedro J. Velis
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Publication number: 20140314967Abstract: The present invention relates to a water-based pore sealing agent enhancing PCB coating anti-oxidation and anti-corrosion properties, consisting of, by weight, 4-12 parts of a corrosion inhibitor, 15-25 parts of a mixed surfactants system, 10-20 parts of an ion chelating agent, 6-15 parts of a pH regulator, 20-40 parts of a builder, and the rest being purified water. When used to perform pore sealing on a PCB, the water-based pore sealing agent is diluted with purified water first to be diluted 10-100 times, preferably, 100/8-100/3 times. The pH value is 7-11, and is preferably 7.5-9.5. The surface tension is 18-28 dyn/cm. The pore sealing treatment uses a immersion process, and preferably ultrasonic waves are added at the same time to assist in cleaning the pores. For the pore sealing treatment, the temperature is 20-60° C., and the time is 60-150 seconds. After pore sealing, the temperature for drying the coated piece is 80-150° C., and the time is 60-120 seconds.Type: ApplicationFiled: November 14, 2011Publication date: October 23, 2014Applicant: TANTZ ENVIRONMENTAL TECHNOLOGIES LTD.Inventors: Xiaoming Wu, Yong Lu, Hong Liu, Yinfeng Wu, Qianyuan Liu
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Publication number: 20140272155Abstract: A coating composition and a method for coating metallic substrates for corrosion resistance. In at least one embodiment, the coating composition comprises acid, metal acetate, epoxy silane, aminosilane and water.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: HENKEL AG & CO. KGAAInventors: Kirk Kramer, Lisa Salet
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Publication number: 20140262461Abstract: The present invention provides a printed circuit board comprising a metal surface, such as a final finish, that has been coated with a self-assembled monolayer. The self-assembled monolayer forms a coating on the metal surface that is resistant to corrosion, thus preserving the solderability of the metal surface. The present invention also provides a solution of an alkanethiol and a non-organic solvent that can be used for forming a self-assembled monolayer on a metal substrate. The present invention also provides a process for depositing a self-assembled monolayer on a metal substrate by applying a solution of an alkanethiol and a non-organic solvent to a metal substrate, such as a surface of a printed circuit board.Type: ApplicationFiled: March 7, 2014Publication date: September 18, 2014Applicant: OMG Electronic Chemicals, Inc.Inventors: Jim Trainor, Yubing Wang
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Patent number: 8609762Abstract: An aqueous coating composition containing (i) a polymer having one or more acetoacetyl-functional groups; and (ii) an acid-functional polymer, which may be the same as or distinct from the polymer comprising acetoacetyl-functional groups, wherein a nitrogen-free base has been used to neutralize or partially neutralize the acid-functionality on the polymer.Type: GrantFiled: January 30, 2006Date of Patent: December 17, 2013Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, James M. Bohannon, Shaobing Wu, Frank Chen
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Patent number: 8591638Abstract: A tin or tin alloy plating film surface treatment aqueous solution that can reduce whiskers on the surface of a tin or tin alloy plating film, and can provide a favorable tin or tin alloy plating film using a simple method for tin or tin alloy plating films that are used on electronic components.Type: GrantFiled: September 22, 2009Date of Patent: November 26, 2013Assignee: Rohm and Haas Electronic Materials LLCInventor: Yutaka Morii
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Patent number: 8461253Abstract: Disclosed are coating compositions that can be one-component, ambient curable, and waterborne. The coating compositions comprise acrylic copolymer resin particles comprising carbonyl functional groups and a crosslinking agent comprising functional groups, such as hydrazide groups, that are reactive with carbonyl groups.Type: GrantFiled: January 15, 2010Date of Patent: June 11, 2013Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Mark S. Gaston, Brian K. Rearick, Irina G. Schwendeman, Venkateshwarlu Kalsani, Hongying Zhou, Michael J. Ziegler
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Patent number: 8430973Abstract: The present invention relates to a process for improving the heat and corrosion resistance of stainless steel by means of a novel passivation process. This process comprises a chemical treatment with an aqueous solution comprising a complexing agent combination of at least one oxidant, a subsequent rinsing and a subsequent treatment at elevated temperature in an oxygen-containing atmosphere. The stainless steel surfaces obtained according to the invention have a homogeneous passive layer having increased chemical resistance and resistance to thermal discoloration.Type: GrantFiled: February 22, 2008Date of Patent: April 30, 2013Assignee: Poligrat GmbHInventors: Olaf Böhme, Siegfried Piesslinger-Schweiger
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Patent number: 8304092Abstract: An aqueous surface-treatment liquid is a treatment liquid containing a water-soluble zirconium compound, water-dispersive particulate silica, a silane coupling agent, a vanadic acid compound, a phosphoric acid compound, a nickel compound, and an acrylic resin emulsion in particular proportions. A surface-treated galvanized steel sheet produced using the treatment liquid is a galvanized steel sheet having a surface-treatment coating on a surface thereof, and the coating contains a zirconium compound, particulate silica, a silane-coupling-agent-derived component, a vanadic acid compound, a phosphoric acid compound, a nickel compound, and an acrylic resin in particular proportions. The amount of coating on a zirconium basis is 10 to 200 mg/m2. This surface-treated galvanized steel sheet is chromate-free and has superior flat-portion corrosion resistance, blackening resistance, and appearance and corrosion resistance after press forming.Type: GrantFiled: December 10, 2007Date of Patent: November 6, 2012Assignee: JFE Steel CorporationInventors: Kazuhisa Okai, Rie Umebayashi, Etsuo Hamada, Akira Matsuzaki, Satoru Ando
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Patent number: 8293029Abstract: Chromium-free conversion coating treatment solutions and processes for depositing a colored layer on zinc or galvanized steel, aluminum, magnesium or their alloys, are provided comprising: hexafluorotitanate and/or hexafluorozirconate ions; molybdate and/or tungstate ions; one or more chelating complex formers; and a copolymer of alkylene phosphonic or alkylene phosphinic acid and one or more unsaturated carboxylic acids.Type: GrantFiled: January 31, 2006Date of Patent: October 23, 2012Assignee: Henkel AG & Co. KGaAInventors: Ulrich Jueptner, Joerg Becker
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Patent number: 8273189Abstract: The invention relates to a method for the carboxylation conversion of a metal surface under oxidizing conditions in relation to the metal, consisting in bringing the metal into contact with a hydro-organic or aqueous bath containing a mixture of organic acids. The invention is characterized in that; the organic acids comprise saturated linear carboxylic acids having between 10 and 18 carbon atoms; the mixture comprises a binary or ternary mixture of such acids; the respective proportions of said acids are such that (i) for a binary mixture x±5%?y±5%, wherein x and y represent the respective proportions, in molar percentages, of the two acids in a mixture with the composition of the eutectic and (ii) for a ternary mixture x±3%?y±3%?z±3%, wherein x, y and z represent the respective proportions, in molar percentages, of the three acids in a mixture with the composition of the eutectic; and the concentration of the mixture in the bath is greater than or equal to 20 g/l.Type: GrantFiled: April 9, 2009Date of Patent: September 25, 2012Assignees: ArcelorMittal France, Total FranceInventors: Herve Derule, Lydia Rachiele, Sophie Jacques, Nicole Genet, Jean Steinmetz, Emmanuel Rocca
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Patent number: 8092618Abstract: The invention provides a method and apparatus for controlling the formation of foulant deposits on petroleum processing equipment. The invention involves a first mixture comprising an acid phosphate ester. The first mixture is applied to the surface of the petroleum processing equipment at a high temperature. Then a second mixture comprising a metal salt is applied also at a high temperature. The result is sufficient to provide an effective coating that prevents the formation of foulant deposits on the petroleum processing equipment. The second mixture reacts with any polyphosphate in the coating to prevent any contamination of petroleum materials within the petroleum processing equipment.Type: GrantFiled: October 21, 2009Date of Patent: January 10, 2012Assignee: Nalco CompanyInventors: Ron Sharpe, Christopher Russell, Simon Crozier
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Patent number: 8083842Abstract: Disclosed is an aqueous solution of a chromium salt, in which the oxalic acid content is 8% by weight or less relative to chromium. In the aqueous solution of the chromium salt, the total organic carbon content is 4% by weight or less relative to chromium. The chromium salt is preferably a chromium chloride, a chromium phosphate, or a chromium nitrate. The chromium chloride preferably contains a basic chromium chloride represented by the composition formula Cr(OH)xCly (wherein 0<x?2, 1?y<3, and x+y=3). The chromium phosphate is preferably one represented by the composition formula Cr(H3?3/nPO4)n (wherein n is a number satisfying 2?n?3). The chromium nitrate is preferably a basic chromium nitrate represented by the composition formula Cr(OH)x(NO3)y (wherein 0<x?2, 1?y<3, and x+y=3).Type: GrantFiled: December 23, 2009Date of Patent: December 27, 2011Assignee: Nippon Chemical Industrial Co., Ltd.Inventors: Hideki Kotaki, Tomohiro Banda, Takashi Hara, Nobuo Takagi
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Patent number: 7985790Abstract: A fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; water; less than 15% wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising: at least one alcohol solvent [solvent (A)]; at least one glycol derivative solvent having a boiling point of at least 100° C. [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl groups, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond.Type: GrantFiled: December 4, 2006Date of Patent: July 26, 2011Assignee: Solvay Solexis, S.p.A.Inventors: Fabio Polastri, Tiziana Poggio, Julio A. Abusleme
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Patent number: 7968007Abstract: A trace amount of a tungstate added together with an ortho-phosphate and/or phosphonite is disclosed for inhibiting corrosion by a nitrogen fertilizer solution. In particular, an ammonium nitrate fertilizer solution is in contact with ferrous metal storage tanks, piping, and equipment surfaces. Tungstate added with an iron stabilizer including a dispersant polymer is also effective for inhibiting corrosion.Type: GrantFiled: June 18, 2008Date of Patent: June 28, 2011Assignee: Nalco CompanyInventors: Craig W. Myers, Steven R. Hatch, Donald A. Johnson, Phillip E. Bureman
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Patent number: 7960519Abstract: A method of treating biologic material with a composition containing at least one fatty acid derivative and/or at least one fatty alcohol, a buffer, and a salt to result in protein partitioning into an aqueous phase and an organic phase. The protein may be a membrane protein. The cells may be plant cells and/or animal cells. The proteins can be thereafter be used for downstream applications.Type: GrantFiled: May 30, 2006Date of Patent: June 14, 2011Assignee: Pierce Biotechnology, Inc.Inventors: Valerie J. O'Sullivan, Edward J. Conklin
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Patent number: 7905964Abstract: Process for the passivation of metallic surfaces, in particular of strip metals, by treatment of the surface with an acidic, aqueous preparation which comprises at least one water-soluble acid group-containing polymer and at least one wax.Type: GrantFiled: June 13, 2006Date of Patent: March 15, 2011Assignee: BASF SEInventors: Helmut Witteler, Walter Bertkau, Thomas Heidenfelder, Alexander Göthlich
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Patent number: 7824482Abstract: The present invention relates to new substance combinations as vapor phase corrosion inhibitors for protecting a broad range of customary utility metals, including iron, chromium, nickel, tin, zinc, aluminum, copper, magnesium and their alloys, against corrosion in humid climates. Said substance combinations comprise (1) at least one C6 to C10 aliphatic monocarboxylic acid, (2) at least one C6 to C10 aliphatic dicarboxylic acid, and (3) a primary aromatic amide. Preferably they further comprise (4) an aliphatic ester of hydroxybenzoic acid, in particular of 4-hydroxybenzoic acid, and/or (5) a bemzimidazole, in particular a benzimidazole substituted on the benzene ring.Type: GrantFiled: December 11, 2008Date of Patent: November 2, 2010Assignee: EXCOR Korrosionsforschung GmbHInventors: Georg Reinhard, Urte Ludwig, Gerhard Hahn
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Patent number: 7820076Abstract: The invention relates to an oleaginous mildew and corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion and mildew. The composition comprises, in parts by weight, from about 20 to 60 parts of an oleaginous material such as a lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.0 to 5.0 parts of a water-displacing compound, an effective amount of a mildew-inhibiting compound, and from 0.0 to 1.0 part of a heterocyclic metal deactivator.Type: GrantFiled: December 20, 2005Date of Patent: October 26, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: El Sayed S. Arafat, Craig A. Matzdorf, James A. Whitfield
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Patent number: 7811391Abstract: This invention comprises an acidic aqueous solution for treating metal substrates to improve the adhesion bonding and corrosion protection of the metal surface which comprises effective amounts of water soluble trivalent chromium compounds, fluorozirconates, effective amounts of at least one corrosion inhibitors such as benzotriazole, fluorometallic compounds, zinc compounds, thickeners, surfactants, and at least about 0.001 mole per liter of the acidic solution of a polyhydroxy and/or carboxylic compound as a stabilizing agent for the aqueous solution.Type: GrantFiled: April 21, 2005Date of Patent: October 12, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: Craig A. Matzdorf, William C. Nickerson, Jr.
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Patent number: 7794531Abstract: An organic solderability preservative (OSP) composition comprising an alkyl cyclic alcohol and an azole compound having enhanced composition stability against crystallization of the azole compound.Type: GrantFiled: January 8, 2007Date of Patent: September 14, 2010Assignee: Enthone Inc.Inventors: Joseph A. Abys, Shenliang Sun
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Patent number: 7776233Abstract: The invention relates to an oleaginous corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion. The composition comprises, in parts by weight, from about 20 to 60 parts of lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.1 to 5.0 parts of a water-displacing compound and from 0.0 to 1.0 part of a metal deactivator.Type: GrantFiled: October 27, 2005Date of Patent: August 17, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: El Sayed Arafat, Judy Butler-Kowalik, Kenneth Clark, David L. Gauntt
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Patent number: 7686980Abstract: Compositions for actively inhibiting corrosion are described herein that include at least one active corrosion inhibitor compound, and at least one conventional corrosion inhibitor compound. In addition, methods for producing a composition that actively reduces corrosion are described herein and include providing at least one active corrosion inhibitor, providing at least one conventional corrosion inhibitor compound or corrosion protection compound, and blending the at least one active corrosion inhibitor and the at least one conventional corrosion inhibitor compound or corrosion protection compound to form the composition. In addition, a composition for actively inhibiting corrosion is described herein that includes at least one active corrosion inhibitor compound, wherein the at least one active corrosion inhibitor compound comprises a derivative or salt of a thio-, thia- or dithiocarbarnic acid, or a combination thereof and at least one conventional corrosion inhibitor compound.Type: GrantFiled: September 30, 2005Date of Patent: March 30, 2010Assignee: Teledyne Scientific & Imaging, LLCInventors: Martin Kendig, Melitta Hon, Les Warren
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Patent number: 7678184Abstract: Coatings containing particulate metal alloy are disclosed. The coatings provide corrosion protection to a substrate, such as a metal substrate. The coatings contain zinc-metal-containing alloy in flake form, most particularly an alloy flake of zinc and aluminum. The coating can be from compositions that are water-based or solvent-based. The compositions for providing the coating may also contain a substituent such as a water-reducible organofunctional silane, or a hexavalent-chromium-providing substance, or a titanate polymer, or a silica substance constituent. the coating may desirably be topcoated.Type: GrantFiled: October 14, 2008Date of Patent: March 16, 2010Assignee: Metal Coatings International Inc.Inventors: Etienne G. Maze, Gilbert L. Lelong, Terry E. Dorsett, Donald J. Guhde, Toshio Nishikawa
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Patent number: 7670415Abstract: Systems and methods for enhanced moisture vapor barrier performance for concrete-containing materials and surfaces are disclosed. Treatment modalities that include addition of the disclosed materials, compositions and systems to pre- and post-construction concrete-containing materials and surfaces are provided. Moisture vapor barrier properties are effected over an extended period of time as compared to control systems. The disclosed compositions and systems also yield reductions in the rate and/or impact of corrosion are achieved for concrete-containing structures and surfaces and, despite the water soluble properties of the compositions and systems, the treatments are effective in delivering an advantageous level of liquid moisture resistance to the treated concrete-containing structure and/or surface. The composition is synthesized from a feedstock that includes C9 to C16 branched hydrocarbons of varying structures.Type: GrantFiled: August 31, 2007Date of Patent: March 2, 2010Assignee: Hycrete, Inc.Inventors: David Rosenberg, David C. Darwin, John de Mars, Eugene B. Humphrey, Todd B. Humphrey, legal representative, Michael S. Rhodes, Philip S. Rhodes, legal representative, Philip S. Rhodes, James R. Humphrey, Leonid Izrailev, John Wojakowski, Jason Tuerack
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Patent number: 7662241Abstract: A corrosion-inhibiting composition for application to a metal substrate, such as aluminum or steel, and in connection with a paint, and the synthesis of the composition. The active inhibitor constituent of the composition can be selected from the group consisting of 2,5-dimercapto-1,3,4 thiadiazole (DMTD), 2,4-dimercapto-s-triazolo-[4,3-b]-1,3-4-thiadiazole, trithiocyanuric acid (TMT), and derivatives of DMTD and TMT, including various N— or S— and N, N—, S— and N—,S-substituted derivatives of DMTD, including salts of DMTD of the general formula: M(DMTD)n, where n=1,2 or 3, and M is a metal cation and preferably M=Zn(II), Bi(III), Co(II), Ni(II), Cd(II), Pb(II), Ag(I), Sb(III), Cu(II), Li(I), Ca(II), Sr(II), Mg(II), La(III), Ce(III), Pr(III), Al(III) or Zr(IV). DMTD, TMT, and their derivatives may also be combined with phosphates, molybdates, borates, silicates, tungstates, phosphotungstates, phosphomolybdates, cyanamides, carbonates, SiO2 and mixtures thereof.Type: GrantFiled: February 23, 2004Date of Patent: February 16, 2010Assignee: Wayne Pigment Corp.Inventor: John Sinko
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Patent number: 7651556Abstract: A protective coating is formed on a metallic material surface by applying a treating agent comprising water, an alkali silicate, and, optionally, a lubricating component to the surface and drying the treating agent. The coating film thereby formed has excellent anti-galling and rust preventive properties. If a lubricating component is present, the coating film also has excellent self-lubricating properties.Type: GrantFiled: January 26, 2004Date of Patent: January 26, 2010Assignee: Henkel AG & Co. KGaAInventors: Shinobu Komiyama, Yugo Tsuiki, Akihiro Seo
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Patent number: 7641721Abstract: Disclosed is an aqueous solution of a chromium salt, in which the oxalic acid content is 8% by weight or less relative to chromium. In the aqueous solution of the chromium salt, the total organic carbon content is 4% by weight or less relative to chromium. The chromium salt is preferably a chromium chloride, a chromium phosphate, or a chromium nitrate. The chromium chloride preferably contains a basic chromium chloride represented by the composition formula Cr(OH)xCly (wherein 0<x?2, 1?y<3, and x+y=3). The chromium phosphate is preferably one represented by the composition formula Cr(H3-3/nPO4)n (wherein n is a number satisfying 2?n?3). The chromium nitrate is preferably a basic chromium nitrate represented by the composition formula Cr(OH)x(NO3)y (wherein 0<x?2, 1?y<3, and x+y=3).Type: GrantFiled: November 22, 2004Date of Patent: January 5, 2010Assignee: Nippon Chemical Industrial Co., Ltd.Inventors: Hideki Kotaki, Tomohiro Banda, Takashi Hara, Nobuo Takagi
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Patent number: 7625439Abstract: The ferrous metal chemical conversion coating is comprised of mixed oxides and organometallic compounds of aluminum and iron. A ferrous metal substrate is immersed for a period of time in a bath composition, at a temperature, at a pH, and at a concentration for each constituent of the bath composition, that will form a coating with the desired characteristics. The bath composition comprises water, aluminum salt, oxalic acid, and an oxidizer. The conversion coating is amorphous in nature and can be formed as thin as 1 micron with a coating weight in the range of about 40-250 milligrams per square foot. When sealed with an appropriate rust preventive material, the coating enhances corrosion resistance of the ferrous metal substrate. It is an effective absorbent base for paint finishes. When top coated with a lubricant, the conversion coating aids (a) assembly of parts, (b) break-in of sliding surfaces, and (c) anti-galling.Type: GrantFiled: September 27, 2006Date of Patent: December 1, 2009Assignee: Birchwood Laboratories, Inc.Inventors: Bryce D. Devine, William V. Block
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Patent number: 7531022Abstract: A liquid for the preparation of powder mixtures on the basis of hard metals, comprising water and an inhibitor, wherein the inhibitor is in the form of at least one of the following materials: polyvinyllactam or wax emulsion, or the inhibitor is in the form of at least one of the following materials: carboxylic acid, amines or their derivatives.Type: GrantFiled: October 13, 2005Date of Patent: May 12, 2009Assignee: Zschimmer & Schwarz GmbH & Co. KG Chemische FabrikenInventors: Peter Quirmbach, Michael Hölzgen, Alfred Vuin
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Patent number: 7513948Abstract: Systems and methods for enhanced autogenous healing of cracks that are formed or are present in concrete-containing materials and surfaces are disclosed. Treatment modalities that include addition of the disclosed materials, compositions and systems to pre- and post-construction concrete-containing materials and surfaces are provided. Autogenous healing is effected at a greater rate and to a larger degree as compared to control systems. The disclosed compositions and systems also yield reductions in the rate and/or impact of corrosion are achieved for concrete-containing structures and surfaces and, despite the water soluble properties of the compositions and systems, the treatments are effective in delivering an advantageous level of moisture resistance to the treated concrete-containing structure and/or surface. The composition is synthesized from a feedstock that includes C9 to C16 branched hydrocarbons of varying structures.Type: GrantFiled: August 31, 2007Date of Patent: April 7, 2009Assignee: Hycrete, Inc.Inventors: Todd B Humphrey, legal representative, Philip S. Rhodes, legal representative, Philip S. Rhodes, James R. Humphrey, Leonid Izrailev, David Rosenberg, John Wojakowski, Jason Tuerack, Eugene B. Humphrey, Michael S. Rhodes
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Patent number: 7498090Abstract: A combination includes a composition providing corrosion resistance for application to a post-construction material, and a post-construction material, wherein the composition is applied to at least one surface of the post-construction material after the post-construction material has hardened. The composition may include an effective amount of a thinning agent, e.g., isopropyl alcohol, ethanol, xylene or similar composition. The composition may be an aqueous solution of a metal salt of a dioic acid. The post-construction material may be reinforced or unreinforced concrete. The post-construction material may be a concrete-containing structure, and the composition may be applied to an exterior surface thereof.Type: GrantFiled: August 21, 2007Date of Patent: March 3, 2009Assignee: Hycrete, Inc.Inventors: Philip S. Rhodes, David Rosenberg, John Wajakowski
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Patent number: 7485177Abstract: A corrosion inhibiting mixture is disclosed comprising a carrier, a volatile corrosion inhibitor and a tracing agent which absorbs light in the ultraviolet and violet region of the electromagnetic spectrum, and re-emits light in the blue region of the electromagnetic spectrum.Type: GrantFiled: July 20, 2007Date of Patent: February 3, 2009Assignee: SKS IndustriesInventors: Robin McConnell, Wesley Raymond Measel, Jr.
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Patent number: RE42384Abstract: Water soluble materials, compositions and systems for use in treating concrete-containing materials and surfaces are disclosed. Treatment modalities that include addition of the disclosed materials, compositions and systems to pre- and post-construction concrete-containing materials and surfaces are provided. Reductions in the rate and/or impact of corrosion are achieved for concrete-containing structures and surfaces. In addition, despite the water soluble properties of the material, composition or system, the treatments are effective in delivering an advantageous level of moisture resistance to the treated concrete-containing structure and/or surface. The composition is synthesized from a feedstock that includes C9 to C16 branched hydrocarbons of varying structures.Type: GrantFiled: August 4, 2010Date of Patent: May 24, 2011Assignee: Hycrete, Inc.Inventors: Eugene B. Humphrey, Todd B. Humphrey, legal representative, Michael S. Rhodes, Philip S. Rhodes, legal representative, James R. Humphrey, Leonid Izrailev, David Rosenberg, John Wojakowski, Jason S. Tuerack