Oxidized Starch Patents (Class 106/208.1)
  • Patent number: 8790494
    Abstract: The invention provides a three layered reprographic paper having improved strength, stiffness and curl resistance properties, and a method for making same. The paper has a central core layer made largely of cellulose and bulked with a bulking agent such as a diamide salt. A starch-based metered size press coating is pressed on both sides of the core layer, wherein the starch has a high solid content. The coating forms a three layered paper having an I-beam arrangement with high strength outer layers surrounding a low density core.
    Type: Grant
    Filed: May 31, 2013
    Date of Patent: July 29, 2014
    Assignee: International Paper Company
    Inventors: Agne Swerin, Jay C. Song, Ladislav Bednarik, Peter F. Lee, Michael C. Herman, Sen Yang
  • Patent number: 8460512
    Abstract: The invention provides a three layered reprographic paper having improved strength, stiffness and curl resistance properties, and a method for making same. The paper has a central core layer made largely of cellulose and bulked with a bulking agent such as a diamide salt. A starch-based metered size press coating is pressed on both sides of the core layer, wherein the starch has a high solid content. The coating forms a three layered paper having an I-beam arrangement with high strength outer layers surrounding a low density core.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: June 11, 2013
    Assignee: International Paper Company
    Inventors: Agne Swerin, Michael Herman, Jay C Song, Sen Yang, Peter F Lee, Ladislav Bednarik
  • Patent number: 8357237
    Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.
    Type: Grant
    Filed: January 10, 2012
    Date of Patent: January 22, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
  • Publication number: 20110146524
    Abstract: The present inventor has discovered a new combination composition using modified oxidized starches blended with shortening oil FL30™ and vegetables oil or combination of modified oxidized starches with polyethylene glycol attributed improvement in enhanced water soluble dye for encapsulation into impact ruptured projectile capsules. In a preferred embodiment of the enhanced composition, the aforesaid improvement over prior art of manufacturing native starches mixed with vegetables oil or polyethylene glycol is relates to significant chemical binding stability in the present of carbonyl and carboxylic groups, acetylation, cross-linked, physically modified, enzymatically modified, acid or alkaline treated and hydroxypropylation processes that can reduce retrogradation and syneresis, increased swelling power and solubility in free flowing attribution for greater splattering effect and completely washable solubility.
    Type: Application
    Filed: December 17, 2009
    Publication date: June 23, 2011
    Inventor: Tornee Pang
  • Patent number: 7931778
    Abstract: The present disclosure relates to lecithin containing starch compositions. The disclosure also relates to processes for preparing the lecithin-containing starch compositions. Further, the disclosure relates to uses of the lecithin-containing compositions in the preparation of paper products that have oil and grease resistant properties, and/or have release properties. Further, the disclosure relates to paper products that include lecithin-containing compositions and to paper products resulting from the processes herein.
    Type: Grant
    Filed: October 25, 2006
    Date of Patent: April 26, 2011
    Assignee: Cargill, Incorporated
    Inventors: Ki-Oh Hwang, Jagannadh V. Satyavolu, Kevin Ray Anderson, James Donald Steinke
  • Patent number: 7381300
    Abstract: The present invention relates to a process for applying optical brightening agent (OBA) to a sheet of paper or paperboard substrate. The process comprises applying the composition comprising a cooked starch and a powdered optical brightener to at least one surface of a paper or paperboard substrate at the size press in a paper or paperboard manufacturing process to form a sized paper or paperboard substrate; and drying the sized paper or paperboard substrate to form a dried sized paper or paperboard substrate.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: June 3, 2008
    Assignee: International Paper Company
    Inventors: Benny J Skaggs, Chris Wilson
  • Patent number: 7255732
    Abstract: Starch can be gelatinised more efficiently by a thermomechanical treatment, if a dialdehyde polysaccharide with a relatively low degree of oxidation is added to the starch. This thermomechanical treatment can be carried out at a temperature below 115 DEG C., or even below 100 DEG C., and with a high throughput rate. With this treatment a granulate or other semi-finished product is obtained that can be shaped to produce an article that has excellent dimensional stability in water. By adding dialdehyde polysaccharide with a low degree of oxidation to starch it is possible to blow transparent films based on thermoplastic starch which have improved mechanical properties.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: August 14, 2007
    Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
    Inventors: Sabine Fischer, Eric G. M. Craenmehr, Jan J. De Vlieger, Theodoor M. Slaghek
  • Patent number: 7025821
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Grant
    Filed: October 7, 2004
    Date of Patent: April 11, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 7022174
    Abstract: The present invention relates to compositions of starch. The compositions consist of an anionic and a cationic starch wherein at least one of the starches is waxy. The compositions are surprisingly not resulting in an agglomerated product when cooked. The compositions are used in paper or cardboard preparation. The compositions are cooked and added at the wet end of the paper production process. This results in a high possible addition level and the use of the size press is abolished. The resulting paper and board are shown to have better characteristics than the paper and board prepared with the same components which have not been mixed prior to addition but which are added separately.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: April 4, 2006
    Assignee: Cerestar Holding B.V.
    Inventors: Detlev Glittenberg, Peter Leonhardt
  • Patent number: 6896725
    Abstract: The invention concerns the use of a water-soluble or water-dispersible polymer having a molecular weight of at least 800, containing at least 5 aldehyde groups per molecule and at least 1 carboxyl group per molecule, the ratio of aldehyde groups to carboxyl groups being higher than 0.75:1, as a wet strength additive. The invention also discloses novel cationic derivatives thereof.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: May 24, 2005
    Assignee: SCA Hygiene Products Zeist B.V.
    Inventors: Jeffrey Wilson Thornton, Dorine Lisa Van Brussel-Verraest, Arie Besemer, Sussan Sandberg
  • Patent number: 6811599
    Abstract: A biodegradable thermoplastic material comprising a natural polymer, a plasticizer and an exfoliated clay having a layered structure and a cation exchange capacity of from 30-250 milliequivalents per 100 grams and a process of preparing a biodegradable thermoplastic material comprising preparing a suspension of clay, combining said suspension with a natural polymer and a plasticizer and extruding the resultant composition at a temperature of 35-200° C.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: November 2, 2004
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventors: Hartmut Rudolf Fischer, Sabine Fischer
  • Patent number: 6802895
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: October 12, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 6723160
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: April 20, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 6710175
    Abstract: According to the present disclosure, starch/polymer combinations are provided. The preferred starch/polymer combinations are usable as paper additives, in the wet end of a papermaking process. Typical and preferred starch/polymer combinations of this type, result from combining a starch, having a polymer reactive carbonyl functionality, with a polymer, having a carbonyl reactive functionality, under conditions that allow for covalent interaction between the two. Typically usable components comprise oxidized starch and polymer having reactive primary or reactive secondary amine groups. Also provided are methods of preparing such combinations, methods of use, preferred papers including such combinations, and, analytical techniques usable in preparation of such combinations.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: March 23, 2004
    Inventors: Kevin Ray Anderson, Anton Esser, Lawrence Edward Fosdick, Ki-Oh Hwang, Norbert Mahr, John Thomas McDonald, Jr., Dogan Sahin Sivasligil, Andreas Stange, Sarah Veelaert, Martin Wendker
  • Publication number: 20030141637
    Abstract: The invention relates to the field of processing starch. In particular, the invention relates to a process for extruding starch to obtain a starch product having a certain intrinsic viscosity when dissolved or dispersed in water, which process requires less specific mechanical energy input than conventional extrusions of starch.
    Type: Application
    Filed: December 2, 2002
    Publication date: July 31, 2003
    Inventors: Ronald Peter W Kesselmans, Berend Venema, Egbert Hadderingh
  • Patent number: 6398912
    Abstract: The object of the invention is an additive for paper making by means of which the dusting tendency of paper can be reduced. The agent is based on starch, the molecular size of which has been reduced, and which has been cationized to a charge of less than 1.5 mEkv/g with a quaternary nitrogen compound. The agent is added to the fiber pulp for paper making prior to web formation.
    Type: Grant
    Filed: January 9, 2001
    Date of Patent: June 4, 2002
    Assignee: Raisio Chemicals Ltd.
    Inventors: Tapio Vihervaara, Kari Luukkonen, Veikko Niinivaara
  • Patent number: 6228158
    Abstract: A dry preblended carrier starch for corrugating adhesive compositions comprising modified starch and a dry alkali, the modified starch being preferably oxidized starch and the dry alkali being sodium metasilicate or trisodium phosphate. The dry preblended carrier starch for corrugating adhesives has improved viscosity stability over time and temperature fluctuations, eliminates the need for added caustic at end use or at the corrugator and does not require additional silicate compounds in the corrugating adhesive.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: May 8, 2001
    Assignee: Corn Products International, Inc.
    Inventor: Roman Skuratowicz
  • Patent number: RE41622
    Abstract: The present invention relates to compositions of starch. The compositions consist of an anionic and a cationic starch wherein at least one of the starches is waxy. The compositions are surprisingly not resulting in an agglomerated product when cooked. The compositions are used in paper or cardboard preparation. The compositions are cooked and added at the wet end of the paper production process. This results in a high possible addition level and the use of the size press is abolished. The resulting paper and board are shown to have better characteristics than the paper and board prepared with the same components which have not been mixed prior to addition but which are added separately.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: September 7, 2010
    Assignee: Cerestar Holding B.V.
    Inventors: Detlev Glittenberg, Peter Leonhardt