With Bituminous Material Or Tarry Residue Patents (Class 106/269)
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Patent number: 12163294Abstract: Pavement aging can be reduced by applying to an asphalt-containing pavement a topcoat layer or a surface treatment containing asphalt binder with sterols.Type: GrantFiled: December 21, 2022Date of Patent: December 10, 2024Assignees: A.I.M. HOLDING COMPANY, ERGON ASPHALT & EMULSIONS, INC.Inventors: Gerald H. Reinke, Gaylon L. Baumgardner, Andrew Hanz
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Patent number: 11912874Abstract: Disclosed are binders and methods for making such binders with crude sterols. The crude sterols improve various rheological properties of the binders. The disclosure provides a method for slowing the aging rate of aged asphalt binder comprising adding a crude sterol to an asphalt binder, wherein the asphalt binder comprises both virgin asphalt binder, and reclaimed asphalt binder material comprising asphalt pavement (RAP), asphalt shingles (RAS) or combinations of RAP and RAS.Type: GrantFiled: December 5, 2016Date of Patent: February 27, 2024Assignees: A.L.M. Holding Company, Ergon Asphalt & Emulsions, Inc.Inventors: Gerald H. Reinke, Gaylon L. Baumgardner, Andrew Hanz
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Patent number: 10683421Abstract: A process for the transportation and/or storage of road bitumen under cold conditions, including at least one chemical additive chosen from: a general formula compound (I): R1—(COOH)z wherein R1 is a linear or branched, saturated or unsaturated hydrocarbon-based chain including 4 to 68 carbon atoms, and z is an integer ranging from 1 to 4, and a general formula compound (II): R—(NH)nCONH—(X)m—NHCO(NH)n—R? wherein: R and R?, which are identical or different, contain a saturated or unsaturated, linear or branched, cyclic or acyclic hydrocarbon-based chain having 1 to 22 carbon atoms and optionally including heteroatoms and/or rings having 3 to 12 atoms and/or heterocycles having 3 to 12 atoms; X contains a saturated or unsaturated, linear or branched, cyclic or acyclic hydrocarbon-based chain having 1 to 22 carbon atoms and optionally including one or more heteroatoms and/or rings having 3 to 12 atoms and/or heterocycles having 3 to 12 atoms.Type: GrantFiled: July 29, 2015Date of Patent: June 16, 2020Assignee: TOTAL MARKETING SERVICESInventors: Régis Vincent, Mouhamad Mouazen, Laurence Lapalu
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Patent number: 10683422Abstract: Bitumen pellets including at least one chemical additive chosen from: a compound of general formula (I): R1-(COOH)z in which R1 is a linear or branched, saturated or unsaturated hydrocarbon-based chain including from 4-68 carbon atoms, and z is an integer ranging from a compound of general formula (II): R—(NH)nCONH—(X)m-NHCO(NH)n-R? in which: R and R? are identical or different, contain a saturated or unsaturated, linear or branched, cyclic or acyclic hydrocarbon-based chain having from 1-22 carbon atoms and optionally including heteroatoms and/or rings having from 3-12 atoms and/or heterocycles having from 3-12 atoms; X contains a saturated or unsaturated, linear or branched, cyclic or acyclic hydrocarbon-based chain having from 1-22 carbon atoms and optionally including one or more heteroatoms and/or rings having from 3-12 atoms and/or heterocycles having from 3-12 atoms; n and m are integers having, independently of one another, a value of 0 or of 1.Type: GrantFiled: July 29, 2015Date of Patent: June 16, 2020Assignee: TOTAL MARKETING SERVICESInventors: Sophie Mariotti, Regis Vincent
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Patent number: 10654752Abstract: Enhanced crack filler materials, systems, and methods for filling and repairing cracks in asphalt surfaces, such as asphalt roadways. The enhanced crack filler material includes crack filler and a silane additive. The silane additive includes organosilane, benzyl alcohol, and ethylene glycol. The crack filler, when combined with the silane additive, provides an enhanced crack filling material having a lower viscosity and a greater ability to penetrate cracks when compared to conventional crack filler materials.Type: GrantFiled: July 1, 2019Date of Patent: May 19, 2020Inventor: Matthew Paul Elam
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Patent number: 10370296Abstract: Enhanced crack filler materials, systems, and methods for filling and repairing cracks in asphalt surfaces, such as asphalt roadways. The enhanced crack filler material includes crack filler and a silane additive. The silane additive includes organosilane, benzyl alcohol, and ethylene glycol. The crack filler, when combined with the silane additive, provides an enhanced crack filling material having a lower viscosity and a greater ability to penetrate cracks when compared to conventional crack filler materials.Type: GrantFiled: October 8, 2018Date of Patent: August 6, 2019Inventor: Matthew Paul Elam
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Patent number: 10093578Abstract: Roadway maintenance and repair, and, in particular, to enhanced crack filler materials, systems, and methods for filling and repairing cracks in asphalt surfaces, such as asphalt roadways. The enhanced crack filler material includes crack filler and a silane additive. The silane additive includes organosilane, benzyl alcohol, and ethylene glycol. The crack filler can be a conventional crack filler material that, when combined with the silane additive, provide an enhanced crack filling material that enables improved crack filling operations, cleaning, and repair durability beyond conventional crack filler materials alone.Type: GrantFiled: June 29, 2017Date of Patent: October 9, 2018Inventor: Matthew Paul Elam
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Patent number: 9994485Abstract: The present application discloses an asphalt binder additive composition comprising a carrier matrix and an agent selected from the group consisting of a curing agent and a masked curing agent. Also described are methods for improving or enhancing the paving or re-paving of asphalt mixture to road surfaces comprising combining the disclosed asphalt binder additive composition with an asphalt binder.Type: GrantFiled: November 10, 2014Date of Patent: June 12, 2018Assignee: COLLABORATIVE AGGREGATES, LLCInventors: John C. Warner, Laura Rose Muollo, Rowan Lewis Walker, Jason R. Bianchini
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Patent number: 9982135Abstract: The aim of the invention is to provide, at a lower cost, novel primary mixtures that can be used for preparing polymer bitumens. For this purpose, the primary mixture according to the invention comprises: (a) at least 25% by weight, preferably 25 to 80% by weight, of polymer, (b) at least one thermoplastic tackifying resin having an average molecular mass of 100 to 3,000 g/mol, (c) and/or one or more mono-alkyl—preferably methyl—esters of fatty acids at C16-C18, in particular sunflower oil, linseed oil, rapeseed oil, soybean oil, and/or sunflower oil that is optionally isomerized; the ester (c) necessarily being present when the tackifying resin (b) has an acid value measured according to standard NF EN ISO 660 of less than 50 mg KOH/g. The invention also concerns the polymer bitumens, emulsions and coatings/coated products obtained from this primary mixture, as well as the methods for preparing same.Type: GrantFiled: January 21, 2015Date of Patent: May 29, 2018Assignee: EIFFAGE INFRASTRUCTURESInventor: Frédéric Loup
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Patent number: 9416274Abstract: An asphalt binder blend includes a mixture of new and/or recycled asphalt cement and brown grease, wherein the brown grease has a free fatty acid (FFA) level greater than about 40% w/w, preferably greater than about 75% w/w. A volatile fraction of the brown grease may be removed, and the brown grease may be polymerized. An asphalt pavement material and a method of preparation thereof, wherein the asphalt pavement material includes a mixture of new and/or recycled aggregate and the asphalt binder blend including brown grease.Type: GrantFiled: May 13, 2014Date of Patent: August 16, 2016Assignee: RAP Technologies, LLCInventor: Robert E. Frank
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Publication number: 20140338565Abstract: Asphalt compositions comprising reclaimed asphalt and a rejuvenating agent are disclosed. The reclaimed asphalt comprises aggregate and an aged binder. The rejuvenating agent, which has a cyclic content of at least 5 wt. %, comprises an ester or ester blend derived from an acid selected from aromatic acids, fatty acids, fatty acid monomers, fatty acid dimers, fatty acid trimers, rosin acids, rosin acid dimers, and mixtures thereof. The rejuvenating agent revitalizes the aged bitumen binder of reclaimed asphalt and restores its physical properties to those of the original performance-grade bitumen. Improvements include desirable softening, low-temperature cracking resistance, better fatigue cracking resistance, good elevated temperature performance, improved miscibility, and restored temperature sensitivity.Type: ApplicationFiled: April 25, 2013Publication date: November 20, 2014Applicant: ARIZONA CHEMICAL COMPANY, LLCInventors: Rachel Severance, William Lewis Grady, David Jan Cornelius Broere, Laurent Porot, Tresha Overstreet
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Patent number: 8840717Abstract: The present invention generally relates to an additive package for warm-mix asphalt formulations for the pavement of road surfaces, said additive package comprising a) surfactant component, and b) an asphalt rheology modifying component, wherein said asphalt rheology modifying component comprises at least one of a i) a wax component and ii) a resin component. The invention also relates to a warm mix asphalt having improved compaction at lower temperatures, and to a pavement made from said warm mix asphalt.Type: GrantFiled: May 2, 2013Date of Patent: September 23, 2014Assignee: Akzo Nobel N.V.Inventors: Premnathan Naidoo, Sundaram Logaraj, Alan Duncan James
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Patent number: 8815004Abstract: A process for treating a tailings stream comprises (a) contacting (1) a gelling agent and (2) an activator with said tailings stream to produce a gel; (b) entrapping solids including sand and clay, and other solid particles with the gel; and (c) allowing the gel to strengthen and solidify to produce a trafficable deposit; wherein the tailings stream comprises water and solids, which solids comprise sand, clay and other solids particles, and wherein 5% by volume to 100% by volume of the solids have a particle size less than 0.05 mm, based on the total volume of the solids. The process may further comprises spreading the gel produced in step (a) or the trafficable deposit produced in step (c) over a surface. The present invention is particularly useful to treat tailings streams produced in processes to extract bitumen from oil sands ores.Type: GrantFiled: December 19, 2011Date of Patent: August 26, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Robert Harvey Moffett, Peter Andrin
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Publication number: 20140154009Abstract: An asphalt composition comprising aggregate, bitumen, sulphur and an anionic surfactant is disclosed, wherein the amount of anionic surfactant is from 0.05 wt % to 10 wt %, based upon the weight of the sulphur. Methods of preparing asphalt compositions and asphalt pavements are also disclosed.Type: ApplicationFiled: May 23, 2012Publication date: June 5, 2014Inventors: Sunil Ashtekar, Franciscus Gondulfus Anton Van Den Berg, Majid Jamshed Chughtai, Marinus Johannes Reynhout, Govind Wagle
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Patent number: 8741052Abstract: The present invention relates to a bitumen or asphalt formulation for the pavement of road surfaces, said formulation comprising a mixture of bitumen and aggregates, and an additive package evenly distributed therein, said additive package comprising from about i) 10 to 60% by weight of an amine or modified amine surfactant, ii) from about 20 to 90% of an asphalt rheology modifying component.Type: GrantFiled: February 18, 2013Date of Patent: June 3, 2014Assignee: Akzo Nobel N.V.Inventors: Premnathan Naidoo, Sundaram Logaraj, Alan Duncan James
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Patent number: 8608845Abstract: Cut back asphalt compositions and product wherein the cutting solvent comprises a tall oil based solvent and optionally other renewable solvents.Type: GrantFiled: January 8, 2009Date of Patent: December 17, 2013Assignee: PVS Meridian Chemicals, Inc.Inventors: Terry Naidoo, William E. Sonnier, Rick Billings
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Publication number: 20130160674Abstract: A method of forming an asphalt mixture can include mixing a bio-asphalt and a bitumen source material different from the bio-asphalt. The bio-asphalt can be formed by mixing a bio-source material with a liquid catalyst. Particles can be added to the asphalt mixture. In an embodiment, the bitumen source material can have a softening point of at least approximately 93° C. and a penetration distance no greater than approximately 25 dmm. In another embodiment, the roofing-grade asphalt mixture can have a softening point of at least approximately 104° C., a penetration distance no greater than approximately 12 dmm, a viscosity of at least approximately 3000 cps at a temperature of 204° C., or any combination thereof. The asphalt mixture can be applied to a base material to form a roofing product. The asphalt mixture can be applied as a pavement product.Type: ApplicationFiled: December 21, 2012Publication date: June 27, 2013Inventors: Keith C. Hong, Gregory F. Jacobs
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Patent number: 8440011Abstract: The present invention generally relates to an additive package for warm-mix asphalt formulations for the pavement of road surfaces, said additive package comprising a) surfactant component, and b) an asphalt rheology modifying component, wherein said asphalt rheology modifying component comprises at least one of a i) a wax component and ii) a resin component. The invention also relates to a warm mix asphalt having improved compaction at lower temperatures, and to a pavement made from said warm mix asphalt.Type: GrantFiled: November 11, 2008Date of Patent: May 14, 2013Assignee: Akzo Nobel N.V.Inventors: Premnathan Naidoo, Sundaram Logaraj, Alan Duncan James
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Publication number: 20120315088Abstract: A method for recycling or renovating old pavements, wherein a rejuvenating binder is used including at least one compound based on fatty substances of natural origin including hydrocarbon fatty chains, these fatty substances of natural origin having undergone at least one chemical functionalization reaction through which at least one oxygenated functional group has been introduced. The rejuvenating binders and rejuvenating binder emulsions especially suitable to the method, and asphalt mixes based on regenerated reclaimed asphalt pavement are also disclosed.Type: ApplicationFiled: June 10, 2011Publication date: December 13, 2012Applicant: COLASInventors: Christine DENEUVILLERS, Roger HAYNER, Jean-Paul FORT
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Patent number: 8088210Abstract: A bituminous composition including, based on total weight of the bituminous composition, (a) hard bitumen in an amount of 0.5% to 7.5% by weight, the hard bitumen being characterized by a penetration number of 100 dmm or less at 25° C. as determined according to the American Association of State Highway and Transportation Officials (AASHTO) Method T49; (b) emulsifier in an amount of 0.0005% to 0.2% by weight, wherein the emulsifier has a Hildebrand solubility parameter of at least 19 (MPa)1/2; (c) water; and (d) aggregate in an amount of 90% to 99% by weight, the aggregate having an aggregate surface that is wetted with the hard bitumen, wherein the bituminous composition is at a temperature ranging from 50° C. to 140° C.Type: GrantFiled: May 26, 2011Date of Patent: January 3, 2012Assignee: MeadWestvaco CorporationInventors: Everett Crews, Tom Girardeau, Iain Jack
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Patent number: 8034172Abstract: Asphalt compositions and products in which the binder comprises tall oil materials possibly previously subjected to distillation, and/or oxidation, and/or combined with a polymer, the tall oil materials having a softening point in the range of 75 F to 400 F, a Needle Penetration value (0.1 mm) at 25 C of at least 1, a Rotational Viscosity at 275 F in the range of 650 cps to 8,000 cps, and a water solubility of less than 10 percent.Type: GrantFiled: December 17, 2008Date of Patent: October 11, 2011Assignee: Foris Technologies, L.L.C.Inventors: Prenathan Naidoo, William E Sonnier, Rick A. Billings
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Publication number: 20110213040Abstract: A method of producing volatilized fatty acids by heating a feedstock comprising at least one fat or oil in a reactor under inert vacuum to volatilize fatty acids, and removing volatilized fatty acids from bottoms residue comprising cross-linked oil. A system for stripping fatty acids from triglycerides, the system comprising a reactor, heating apparatus and a vacuum pump capable of pulling a vacuum in the range of from 1 kPa to 50 kPa on the reactor. A system for producing a hydrogenated product including a reactor comprising an inlet for a stream comprising triglycerides, an outlet for volatilized fatty acids, and an outlet for a cross-linked product, heating apparatus, a vacuum pump capable of pulling a vacuum in the range of from 1 kPa to 50 kPa on the reactor, and a hydrogenation reactor, wherein an inlet of the hydrogenation reactor is fluidly connected to the outlet for cross-linked product.Type: ApplicationFiled: May 10, 2011Publication date: September 1, 2011Applicant: H R D CorporationInventors: Abbas Hassan, Ebrahim Bagherzadeh, Rayford G. Anthony, Gregory Borsinger, Aziz Hassan
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Patent number: 7972429Abstract: This invention relates to bituminous compositions and methods of producing the same. More particularly, the invention relates to the production of bituminous compositions formulated with performance-graded bitumen-containing solvent-free bitumen emulsions which exhibit controllable, temperature-dependent interfacial rheology. When employed in paving applications, these bituminous compositions develop adhesive strength and load-bearing strength properties at rates comparable to traditional hot mix paving compositions and at rates faster than traditional cold mix paving compositions.Type: GrantFiled: October 15, 2010Date of Patent: July 5, 2011Assignee: MeadWestvaco CorporationInventors: Everett Crews, Tom Girardeau, Iain Jack
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Patent number: 7951238Abstract: A method for preparing a fluxing oil, having an iodine number ranging from 50 to 200, based on fatty substances of natural origin having been chemically functionalized by oxidation, includes the steps of: i) providing a fatty substance or a mixture of fatty substances of natural origin, ii) subjecting the fatty substance or the mixture of fatty substances of natural origin to at least one transesterification or esterification reaction by at least one alkanol or mono-alcohol, iii) subjecting the compound or mixture of compounds obtained at step ii) to at least one chemical functionalization reaction by oxidation introducing at least one functional group selected from carboxylic acid, epoxy, peroxide, aldehyde, ether, ester, alcohol and ketone groups, and iv) collecting the fluxing oil.Type: GrantFiled: October 10, 2006Date of Patent: May 31, 2011Assignees: Colas, Valagro, Centre de Valorisation Industrielle des AgroressourcesInventors: Christine Deneuvillers, Lê Chiên Hoang
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Publication number: 20110041728Abstract: The disclosure relates to cold asphalt coatings, in particular cold-poured asphalt coatings. The cold asphalt coatings according to the disclosure include one or more polymerized fatty acids. The cold asphalt coatings, prepared using a bitumen emulsion, have a pre-breakage mixing time that imparts good workability thereto. The cold asphalt coatings, and particularly cold-poured asphalt coatings, have increased cohesion that enables the same to be used under high-speed traffic. Finally, the cold asphalt coatings have good mechanical resistance.Type: ApplicationFiled: April 15, 2009Publication date: February 24, 2011Applicant: TOTAL RAFFINAGE MARKETINGInventors: Charlotte Godivier, Joël Herault, Sophie Mariotti, Maurice Bourrel, Jean-Philippe Gingras, Stéphane Jouenne
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Publication number: 20100212546Abstract: A bituminous cold glue for cold gluing of construction material and comprising at least 35% by weight of bitumen and at least 10% by weight of oil, and further comprising clay and a dispersing agent, said oil being a vegetable oil compound, based on a carbon chain comprising at least one of the C6 to C12 carbon atoms and further comprising between 0.1 and 5% by weight of a solvent.Type: ApplicationFiled: January 15, 2010Publication date: August 26, 2010Inventors: Hans Aerts, Eric Bertrand, Michel Getlichermann
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Publication number: 20100199885Abstract: The present invention relates to a bitumen or asphalt formulation for the pavement of road surfaces, said formulation comprising a mixture of bitumen and aggregates, and an additive package evenly distributed therein, said additive package comprising from about i) 10 to 60% by weight of an amine or modified amine surfactant, ii) from about 20 to 90% of an asphalt rheology modifying component.Type: ApplicationFiled: July 24, 2008Publication date: August 12, 2010Applicant: AKZO NOBEL N.V.Inventors: Premnathan Naidoo, Sundaram Logaraj, Alan Duncan James
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Publication number: 20090137705Abstract: The present invention relates to a hot-melt binder based on asphalt or bitumen, comprising at least one additive for lowering the production temperature of the asphalt product relative to that of the base product, said additive being a triglyceride of saturated fatty acids. The present invention likewise relates to processes for preparing an asphalt or bituminous product coated material, in which the mixing temperature is lowered. The present invention finally relates to an asphalt product or coated bituminous material comprising a hot-melt binder according to the invention.Type: ApplicationFiled: November 20, 2008Publication date: May 28, 2009Inventors: Stephane FAUCON DUMONT, Frederic Delfosse, Thomas Gianetti
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Publication number: 20090012214Abstract: An asphalt material having improved paving characteristics and processes for its preparation. An asphalt base material is heated in a mixing chamber to a temperature sufficient to melt the asphalt so that it can be stirred. A water-insoluble heavy metal soap is incorporated into the chamber in an amount effective to reduce the PAV-DSR temperature of the asphalt base material by an incremental amount of at least 1° C. Thereafter, the asphalt material is recovered from the mixing chamber to provide an asphalt product containing the heavy metal soap which exhibits a PAV-DSR temperature which is less than the PAV-DSR temperature for the corresponding base material without the addition of the heavy metal soap. The water-insoluble soap is a C14-C18 heavy metal soap such as a C16-C18 zinc- or calcium-based soap including zinc stearate, zinc oleate and zinc palmitate. The heavy metal soap is added to the mixing chamber in an amount within the range of 0.05-3.0 wt.Type: ApplicationFiled: June 27, 2008Publication date: January 8, 2009Applicant: Fina Technology, Inc.Inventors: James Butler, Paul Buras, William Lee
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Publication number: 20080194738Abstract: The present invention relates to bituminous compositions suitable for use in paving applications containing water-in-oil bitumen dispersion of paving grade bitumen such as penetration-graded, viscosity-graded and/or penetration-graded varieties that is substantially free of volatile solvents and made by controlling temperature-dependent interfacial rheology through the use of selected surfactants. The invention paving compositions are suitable for use in the construction of load-bearing, high-traffic pavements at a temperature range lower than that required for conventional hot-mix bituminous paving compositions, yet with similar or superior compaction to densities property and at least equal cure rate.Type: ApplicationFiled: March 26, 2007Publication date: August 14, 2008Applicant: MeadWestvaco CorporationInventors: Everett Crews, Tom Girardeau, Iain Jack
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Patent number: 7384468Abstract: An asphalt/aggregate composition having enhanced adhesion characteristics and its preparation. An asphalt base material is heated to a molten state in order to permit mixing of the asphalt with added components. A heavy metal soap is incorporated into the asphalt base material to enhance the adhesion of the asphalt base material with an aggregate component which is mixed with the asphalt base material to provide an asphalt/aggregate blend. The asphalt and aggregate can be blended together in a mixing chamber to provide a fluid asphalt/aggregate concrete which is then dispensed on a substrate surface or the asphalt base material and aggregate components can be separately applied to the substrate surface to provide the ultimate asphalt/aggregate concrete. The heavy metal soap is a C14-C18 heavy metal soap such as zinc stearate. Zinc oxide may also be added to the asphalt base material in an amount which is less than the amount of zinc stearate.Type: GrantFiled: December 13, 2004Date of Patent: June 10, 2008Assignee: Fina Technology, Inc.Inventors: James R. Butler, William Lee, Paul Buras
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Patent number: 7252755Abstract: A low-viscosity, high-softening point heavy hydrocarbon material having a viscosity-reducing amount of at least one biodiesel material dissolved in a heavy hydrocarbon, and a method for producing such low-viscosity, high-softening point heavy hydrocarbon material are disclosed.Type: GrantFiled: April 7, 2003Date of Patent: August 7, 2007Assignee: Marathon Ashland Petroleum Co.Inventors: Melvin D. Kiser, David C. Boyer
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Patent number: 7008670Abstract: This composition sealant relates to rejuvenating, sealing, and preserving asphalt pavements and concrete surfaces. More specifically, the sealant composition includes soy products and other vegetable products. More specifically, the agricultural sealant composition is a combination of soybean oil, alkyl esters of soybean oil, and at least one of d-limonene or other terpine hydrocarbons. In another embodiment, the composition is a mixture of bitumen and soy product.Type: GrantFiled: April 19, 2004Date of Patent: March 7, 2006Inventor: Michael Freisthler
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Patent number: 6667382Abstract: The present invention provides an amine or polyamine, which has a surface activity not inferior to a solid tallow-based amine and an excellent workability. A salt of the amine is suited for emulsifying asphalt and the like, and also provides an asphalt emulsion composition which is obtained by using the salt and which has a quick setting property. Namely, the prevent invention provides a polyamine represented by the formula (1), a process for producing the amine, and an asphalt emulsion composition containing a water-soluble salt of the amine. wherein R is a straight or branched hydrocarbon group having 8 to 22 carbon atoms; x is a number of 1 to 5; and each of y and z is a number of 0 to 5 with the proviso that both of y and z are not 0 at the same time.Type: GrantFiled: November 1, 2000Date of Patent: December 23, 2003Assignee: Kao CorporationInventors: Kazuo Isobe, Ryoichi Tamaki, Keiichiro Tomioka, Wataru Yoshida, Tetsuaki Fukushima, Uichiro Nishimoto
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Publication number: 20030212168Abstract: Liquefied biomass (16) obtained from direct liquefaction and/or fast-pyrolysis is reacted with mixtures of fatty acids (24) in the presence of an oxidizer (28) and with various reactive monomer and polymer additives (46, 48, 50) to create tailored compatibilizer-like bio-additives (34) that are compatible with petroleum asphalts. By judiciously selecting appropriate additives and additional constituent, such as non-reactive (18) and reactive diluents (30), these bio-additives can be tailored to modify low-temperature properties, high-temperature properties, compatibility with aggregate materials, application characteristics, and other properties of petroleum asphalts for paving, roofing and sealing uses.Type: ApplicationFiled: October 9, 2002Publication date: November 13, 2003Inventors: Donald H. White, Barry A. Cooper
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Patent number: 6514332Abstract: Coating compositions containing a bituminous material and an effective amount of a methyl/ethyl ester diluent for coating bulk solids are disclosed. The coating compositions of the present invention are particularly suited to reduce dust formation and cake formation in fertilizer and coal.Type: GrantFiled: January 22, 2002Date of Patent: February 4, 2003Assignee: Arr-Maz Products, LP, a division of Process Chemicals, LLCInventors: Glen R. Varnadoe, Stacy K. Spence
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Patent number: 6514331Abstract: Coating compositions containing a bituminous material and an effective amount of a methyl/ethyl ester diluent for coating bulk solids are disclosed. The coating compositions of the present invention are particularly suited to reduce dust formation and cake formation in fertilizers.Type: GrantFiled: February 15, 2001Date of Patent: February 4, 2003Assignee: Arr-Maz Products, LP a division of Process Chemical, LLCInventors: Glen R. Varnadoe, Stacy K. Spence
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Patent number: 6261356Abstract: The present invention provides an additive for asphalt which causes an improvement in anti-stripping effect of asphalt from aggregates, and exhibits the effect quickly. That is, the present invention provides an asphalt-additive composition comprising (A) a specific acidic phosphoric acid compound, and (B) at least one member selected from the group consisting of mineral oil, alcohol having 8 to 18 carbon atoms, carboxylic acid having 8 to 18 carbon atoms and triglyceride thereof; with the proviso that the amount of the (B) component is 25-400 parts by weight per 100 parts by weight of the (A) component.Type: GrantFiled: September 10, 1999Date of Patent: July 17, 2001Assignee: Kao CorporationInventors: Kazuo Isobe, Ryoichi Tamaki, Keiichiro Tomioka
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Patent number: 6156113Abstract: Use is made, as thinner or fluxing oil in an anhydrous or emulsified bituous binder, of methyl esters of fatty acids which are obtained in particular by transesterification of vegetable oils. The hardening of the binder after spreading is obtained no longer by evaporation but by crosslinking of the thinner in the presence of atmospheric oxygen and of a catalyst.Type: GrantFiled: December 14, 1998Date of Patent: December 5, 2000Assignee: Societe Anonyme d'Application des Derives de l 'Asphalte - S.A.A.D.A.Inventor: Michel Pasquier
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Patent number: 6046260Abstract: A zinc oxide dispersion for use in rubber compounds having at least 40, preferably 74-92, weight percent zinc oxide powder and at least five weight percent of a binder selected from the group consisting of asphalt and terpene tackifiers. The dispersion also preferably includes at least 0.5 weight percent stearifying agent such as stearic acid.Type: GrantFiled: January 13, 1998Date of Patent: April 4, 2000Assignee: Flow Polymers, Inc.Inventor: James W. Hoover
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Patent number: 5925182Abstract: A stable liquid suspension composition comprising a liquid carrier, a solid fatty acid or a salt thereof, and a solid particulate is disclosed wherein said liquid carrier is selected from the group consisting of oils, olefins, terpenes, glycols, esters, ethers, alcohols, and combinations of any two or more thereof and said liquid carrier, solid fatty acid or salt thereof, and solid particulate are each present in said composition in a stabilizing amount sufficient to produce a stable liquid suspension. Also disclosed is a stable liquid composition comprising a liquid carrier, an oil-soluble polymer, and a solid particulate wherein said liquid carrier is selected from the group consisting of olefins, terpenes, esters, and combinations of any two or more thereof and said liquid carrier, oil-soluble polymer, and solid particulate are each present in said composition in a stabilizing amount sufficient to effect the formation of a stable liquid suspension.Type: GrantFiled: July 16, 1998Date of Patent: July 20, 1999Assignee: Phillips Petroleum CompanyInventors: Bharat B. Patel, Marshall D. Bishop
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Patent number: 5494510Abstract: This invention provides for a method of producing an asphalt product which includes initially shredding scrap tires within a shredder system (14) where at least partially vulcanized rubber composition is formed into particulates less than approximately 2.0 mm in dimension. Metal is removed from the scrap tires and the resulting composition leaving the shredder system (14) is mixed in particular weight percentages with a chemical composition for insertion into a masticator system (28) which includes a first zone (42), a second zone (44), and a third zone (46). The masticator system (28) heats the composition entering to a temperature approximating 485.degree. F. in the first zone (42). The composition is then cooled to a temperature within the approximating range of 230.degree. F.-250.degree. F. in second zone (44) and then slightly re-heated to a temperature within the range of 290.degree. F.-350.degree. F. in the third zone (46).Type: GrantFiled: January 30, 1995Date of Patent: February 27, 1996Inventor: John Kuc, Sr.
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Patent number: 5421876Abstract: An organoclay in which a quaternary long chain fatty amine is ionically bonded to clay platelets is found to function both as a filler or thickener as well as a compatibilizer in an asphaltic polyurethane (PUR) dispersion. When a PUR prepolymer is mixed into a homogenized blend of asphalt and organoclay under high shear, a phase inversion occurs the result of which is that a microdispersion of asphalt particles (preferably 1 .mu.m-44 .mu.m) becomes the dispersed phase which is uniformly scattered throughout the PUR prepolymer (the continuous phase). This dispersion is found to be an excellent adhesive, particularly for roofing components which can be secured without using conventional fasteners, and it is stable and moisture-curable to afford, when cured, an elastomer having excellent adhesion to surfaces exposed outdoors. It is also user-friendly because it is solvent-free. The asphalt is treated to react all functional groups it may have because they may react with a functional group of the PUR prepolymer.Type: GrantFiled: October 18, 1993Date of Patent: June 6, 1995Assignee: Tremco, Inc.Inventor: Ronald J. Janoski
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Patent number: 5352285Abstract: A rapid set microsurfacing system which comprises 36% water, 2% of the quaternized or unquaternized emulsifier, 1.5% acid (HCl), 56.5% asphalt residue, and 4% latex polymer [1.5% water and 2.5% rubber]. The quaternized or unquaternized emulsifier comprising an amidoamine and imidazoline mixture prepared from the combination of a tall oil fatty acid rosin mixture with a rosin content between 8 to 40 percent and a polyamine of either ethylenediamine, diethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylene pentamine, or aminoethylethanolamine. The break control agent used can be a hydrophilic, alkylated vinylpyrrolidone polymer (commercially available as Ganex.RTM.Type: GrantFiled: September 7, 1993Date of Patent: October 4, 1994Assignee: Asphalt Technology and ConsultingInventor: Dennis Krivohlavek
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Patent number: 5242492Abstract: A rapid set microsurfacing system which comprises 36% water, 2% of the quaternized or unquaternized emulsifier, 1.5% acid (HCl), 56.5% asphalt residue, and 4% latex polymer [1.5% water and 2.5% rubber]. The quaternized or unquaternized emulsifier comprising an amidoamine and imidazoline mixture prepared from the combination of a tall oil fatty acid rosin mixture with a rosin content between 8 to 40 percent and a polyamine of either ethylenediamine, diethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylene pentamine, or aminoethylethanolamine. The break control agent used can be a hydrophilic, alkylated vinylpyrrolidone polymer (commercially available as Ganex.RTM.Type: GrantFiled: May 13, 1991Date of Patent: September 7, 1993Assignee: Asphalt Technology & Consulting, Inc.Inventor: Dennis Krivohlavek
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Patent number: 4876130Abstract: A bituminous composition comprising:(a) from 99 to 85% w of a mixture of:(1) 45 to 99.8% w of a bituminous component having a penetration of at least 800 dmm at 25.degree. C.;(2) 0.1 to 30% w of a lithium salt of a C.sub.10-40 fatty acid or hydroxy fatty acid;(3) 0.1 to 25% w of an elastomer; and(b) from 1 to 15% w of an amorphous silica filler.Type: GrantFiled: August 25, 1986Date of Patent: October 24, 1989Assignee: Shell Oil CompanyInventors: Willem C. Vonk, Gerrit van Gooswilligen
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Patent number: 4801332Abstract: A paving composition formed of aggregate and asphalt cement in which the asphalt cement is treated with a combination of a primary catalyst comprising a compound chosen from the group consisting of asphalt cement soluble organic-manganese, organic-cobalt, and organic-copper compounds, or a mixture of two or more thereof, and a secondary catalyst comprising an asphalt cement soluble organic-iron compound.Type: GrantFiled: June 15, 1987Date of Patent: January 31, 1989Assignee: Chemcrete International Corp.Inventors: Philip T. Selfridge, John B. Leonard, Jr., Patrick K. Clancey
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Patent number: 4576648Abstract: Cationic emulsions of bituminous binders of the type consisting of an organic phase formed of a bituminous binder dispersed in an aqueous phase containing a cationic emulsifying agent and an acid.The bituminous binder is a bitumen-polymer type binder and the acid present in the aqueous phase is a possibly hydroxylated mono or polycarboxylic acid, used in sufficient quantity that the pH of the said aqueous phase is comprised between 1 and 7.The bituminous binders of the bitumen-polymer type having passed through the said emulsions present an excellent aging behavior.Type: GrantFiled: June 7, 1985Date of Patent: March 18, 1986Assignee: Elf FranceInventors: Francis Demangeon, Germain Hagenbach, Paul Maldonado
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Patent number: 4450011Abstract: Reaction products of polyamines with sulfonated oleic acid or sulfonated tall oil fatty acids are disclosed which give emulsions capable of producing cationic medium set mixing grade asphalt emulsions, as well as rapid set asphalt emulsions. Solventless asphalts as well as asphalts containing up to 15% by volume of a hydrocarbon oil can be used for emulsification.Type: GrantFiled: September 20, 1982Date of Patent: May 22, 1984Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4376651Abstract: The invention relates to a protective coating for foundry implements which are in contact particularly with molten aluminium alloys, comprising from 10 to 60 weight parts of extraction oil obtained by deasphalting and dewaxing heavy oils left after the vacuum distillation of crude oil having a kinematic viscosity of from 37 to 53 mm.sup.2.sec..sup.-1 at 100.degree. C. and an open cup flash point of at least 285.degree. C.; further from 5 to 30 weight parts of a mixture of light and middle oils obtained by the vacuum distillation of crude oils having a flash point of at least 150.degree. C. and a viscosity of from 16 to 22 mm.sup.2.sec..sup.-1 at 50.degree. C., from one to 15 weight parts of graphite, or from 0.1 to 5 weight parts of wool fat, and from 0.1 to 3 weight parts of ethoxylated fatty alcohols having from 12 to 18 carbon atoms and from 10 to 20 ethylene oxide units in the molecule, the coating being characterized in that it additionally contains from 20 to 65 weight parts of titanium dioxide.Type: GrantFiled: February 11, 1982Date of Patent: March 15, 1983Assignee: Vyzkumny ustav keramikyInventors: Igor Lanik, Otakar Havelka, Dusan Pirochta