Abstract: Described herein is a polymerized biorenewable, petroleum based, previously modified, or functionalized oil, comprising a polymeric distribution having about 2 to about 80 wt % oligomer content, a polydispersity index ranging from about 1.0 to about 5.0, and sulfur content ranging from 0.001 wt % to about 8 wt %. Methods of manufacturing the polymerized oil as well as its incorporation into asphalt paving, roofing, and coating applications are also described.

Abstract: The composition for stabilizing clay-loam soils in the form of a liquid solution includes at least one multifunctional organic compound in the form of derivatives of aromatic or heterocyclic, or alicyclic, or aliphatic compounds, in an amount of 20-40% by weight of the total composition. There is at least one acidic surfactant in an amount of 2-10% by weight of the total composition. There is at least one trivalent metal compound in an amount of 1.0-2.5% by weight of the total composition. There is also sulphuric acid, in an amount of up to 100% by weight of the total composition. The method of preparation and the method of stabilizing clay-loam soils involve the composition.

Abstract: Plastomer-modified asphalt binders meeting MSCR specifications, asphalt paving materials with such asphalt binders, and methods for fabricating such asphalt binders are provided. The asphalt binder contains a base asphalt and a plastomer. If the plastomer has a drop point no greater than about 139° C., the asphalt binder further contains sulfur; sulfur-containing compounds, such as hydrocarbyl polysulfides and thiuram disulfides; phenolic resins; metal oxides; or a combination thereof. The asphalt binder is substantially free of elastomer.

Abstract: Disclosed is a bituminous composition in the form of granules, each granule including a core and a coating and having a mass for approximately one hundred particles of from 0.5 g to 2 g, the core including from 40 wt. % to 60 wt. % of a binder matrix; from 30 wt. % to 40 wt. % of a polymer; from 4 wt. % to 6 wt. % of a compatibilizing agent; and from 2 wt. % to 15 wt. % of an anti-adhesive filler; and the coating including an anti-sticking agent. The invention relates also to a method for preparing the composition, and to the use thereof in bitumen plants.

Abstract: A method of reducing the swell potential of an expansive clayey soil comprising expansive clay mineral(s) at a proportion of the total weight of the expansive clayey soil (PECM). The method includes (a) calculating a first amount of a swelling reduction agent to be incorporated into the expansive clayey soil to form a first swelling reduction agent incorporated expansive clayey soil with a reduced swell potential no greater than a pre-set level T with a nano-level constitutive modeling based on the water content and the CEC of the expansive clayey soil and PECM. The swelling reduction agent is at least one selected from calcite, gypsum, potassium chloride, a composition comprising exchangeable K+, a composition comprising exchangeable Ca2?, and/or a composition comprising exchangeable Mg2+, and (b) incorporating the first amount of the swelling reduction agent into the expansive clayey soil to form the first swelling reduction agent incorporated expansive clayey soil.

Abstract: The present invention relates to an apparatus for producing foamed bitumen for a road construction machine, comprising at least one mixing device having a reaction chamber, in which hot bitumen and at least one reaction fluid can be mixed together via an inlet device comprising at least one inlet nozzle and can be discharged from the mixing device via an outlet device, with at least one compressed-air device being provided, via which the inlet device and/or the outlet device can be subjected to a compressed-air stream for testing and/or cleaning purposes. The present invention further also relates to a method for maintaining such an apparatus.

Abstract: The present invention relates to a preparation method for a UV-shielding material based on Mg—Al Layered Double Hydroxide. The material with multi-layered overlay structure is made from Mg—Al double hydroxide layers and interlayer carbonate, its molecular composition is: Mg1-xAlx(OH)2(CO3)x/2.mH2O. The inorganic layers of this material can play a physical shielding role against UV, and the metal elements dispersed on the layer as well as the interlayer anion can play a great role in the chemical absorbing. In addition, by controlling the particle size and the amount of the layers, UV light can be effectively shielded by multi-level reflection and absorption of the multi-level layered structure. Therefore, the material with multi-level chemical and physical shielding properties has a good UV barrier effect for the anti-ageing asphalt, and could significantly increase its UV resistance properties.

Abstract: The invention provides a bituminous composition comprising a bitumen in an amount ranging from 20 to 90% wt, a carboxylic additive in an amount of from 0.25 to 5% wt, and sulphur in an amount of 5 to 75% wt, all percentages based on the weight of bitumen, carboxylic additive and sulphur, wherein the carboxylic additive is selected from carboxylic acids, carboxylic esters and carboxylic anhydrides. It further provides a process for making this composition and asphalt compositions comprising such bituminous composition.

Abstract: An asphalt composition comprising aggregate, bitumen, sulphur and an anionic surfactant is disclosed, wherein the amount of anionic surfactant is from 0.05 wt % to 10 wt %, based upon the weight of the sulphur. Methods of preparing asphalt compositions and asphalt pavements are also disclosed.

Abstract: A process for manufacturing asphalt is disclosed. The process comprises the steps of: (i) heating bitumen; (ii) heating aggregate; and (iii) mixing the hot bitumen with the hot aggregate in a mixing unit to form asphalt. From 10 to 200 wt % of sulphur, based upon the weight of the bitumen, is added in at least one of the steps (i), (ii) or (iii) and from 0.1 to 20 wt % of a compound of formula A, based upon the weight of the bitumen, is added in at least one of the steps (i), (ii) or (iii). R1 and R2 are independently chosen from C6-C30 alkyl or alkenyl.

Abstract: The method of production of granulated polymer-asphalt binder and sulphur concrete with the participation of sulfur polymer obtained through solvent-borne modification of waste sulfur at the temperature of 135-150° C. consists in composing this sulfur polymer with other ingredients. At the production of granulated polymer-asphalt binder the content of the sulfur polymer amounts to 40-60% by weight which, after heating to the temperature of 135-150° C., is mixed (mixer 2) with 20-40% by weight of waste phosphogypsum and after they are mixed, 15-20% by weight of D-50 road asphalt is dosed, which dissolves in this mixture reacting partly with the sulfur polymer. Next, this mixture is cooled to plastic form and granules of polymer-asphalt binder are formed in the extruder, which fall into 5% solution of silicone emulsion where they are cooled and covered with a layer of silicone emulsion. At the production of sulfur concrete at the temperature of 135-150° C.

Abstract: A method of making a sulfur-extended asphalt mixture with a minimum of hydrogen sulfide gas release into the atmosphere by using sulfur granules with specific physical properties and which are made by successively coating a starting sulfur seed particle with liquid sulfur that is solidified between coatings to thereby build up the a sulfur particle of a desired size. The sulfur granules are used to in the preparation of a sulfur, bitumen and aggregate mixture to provide the sulfur-extended asphalt.

Abstract: The invention provides a bituminous composition comprising a bitumen in an amount ranging from 20 to 90% wt, a carboxylic additive in an amount of from 0.25 to 5% wt, and sulphur in an amount of 5 to 75% wt, all percentages based on the weight of bitumen, carboxylic additive and sulphur, wherein the carboxylic additive is selected from carboxylic acids, carboxylic esters and carboxylic anhydrides. It further provides a process for making this composition and asphalt compositions comprising such bituminous composition.

Abstract: A method of operating a paving system includes establishing a plan for paving a work area which is based on a positional temperature model. The method further includes receiving temperature data for paving material and comparing the temperature data with data predicted by the positional temperature model. Operation of the paving system is adjusted where actual data differs from model predicted data. A paving system and control system are provided having an electronic control unit configured to compare electronic temperature data with a positional temperature model for paving material. The electronic control unit can control machines of the paving system based on comparing actual data with model predicted data, and can further update either or both of a plan for paving a work area and the positional temperature model itself based on differences between actual data and model predicted data.

Abstract: A method of making a sulfur-extended asphalt mixture with a minimum of hydrogen sulfide gas release into the atmosphere by using sulfur granules with specific physical properties and which are made by successively coating a starting sulfur seed particle with liquid sulfur that is solidified between coatings to thereby build up the a sulfur particle of a desired size. The sulfur granules are used to in the preparation of a sulfur, bitumen and aggregate mixture to provide the sulfur-extended asphalt.

Abstract: The invention provides a sulphur pellet comprising at least one H2S-suppressant, comprising in the range of from 60 to 100 wt % elemental sulphur, based on the total weight of the pellet. The invention further provides a process for the manufacture of sulphur pellets comprising at least one H2S-suppressant, comprising the steps of: (a) mixing elemental sulphur, one or more H2S-suppressants and optionally a filler in a mixing unit to obtain a mixture; (b) shaping and/or palletizing the mixture obtained in step (a) in a palletizing unit to obtain H2S-suppressant-comprising sulphur pellets. The invention further provides a process for the manufacture of a sulphur-comprising asphalt paving mixture comprising the steps of: (i) preheating bitumen at a temperature of between 140 and 180° C.; (ii) preheating aggregate at a temperature of between 140 and 180° C.

Abstract: The present invention provides a functionally dry warm mix asphalt binder composition modified with lubricating agents or additives that can be mixed with aggregate and compacted at temperatures substantially below asphalt binder compositions that do not contain the disclosed lubricating additives.

Abstract: The present invention provides a functionally dry warm mix asphalt binder composition modified with lubricating agents or additives that can be mixed with aggregate and compacted at temperatures substantially below asphalt binder compositions that do not contain the disclosed lubricating additives.

Abstract: A process for manufacturing an asphalt paving mixture is disclosed. The process comprises the steps of: (i) heating bitumen at a temperature of from 100 to 200° C.; (ii) heating aggregate at a temperature of from 100 to 200° C.; and (iii) mixing the hot bitumen with the hot aggregate in a mixing unit. From 10 to 200 wt % of sulphur pellets, based upon the weight of the bitumen, are added in at least one of the steps (i), (ii) or (iii). The sulphur pellets comprise from 1 to 50 wt % of a monovinyl aromatic compound, based upon the weight of the sulphur pellets.

Abstract: Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications.

Abstract: The present invention provides a functionally dry warm mix asphalt binder composition modified with lubricating agents or additives that can be mixed with aggregate and compacted at temperatures substantially below asphalt binder compositions that do not contain the disclosed lubricating additives.

Abstract: Hydrogen sulfide evolution from asphalt may be reduced or eliminated using an additive to act as a scavenger. Zinc oxide, when present in the form of nano-particles is an effective component is preventing or mitigating the evolution of hydrogen sulfide from asphalt. Zinc sulfonate may also be used. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.

Abstract: Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications.

Abstract: Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications.

Abstract: Disclosed is a high performance asphalt comprising a mixture of low to moderate performance asphalt with linear or branch chain alkyl substituted aromatic sulfonic acid. The high performance asphalt is made by mixing the low to moderate performance asphalt with 1 to 10 wt % linear or branched chain C8–C48 alkyl substituted aromatic sulfonic acid at a temperature of 175° C. and less.

Abstract: Sulfur, useable in as an additive to asphalt in the preparation of asphalt binders can be plasticized by addition of carbon and further treated with amyl acetate. This plasticized sulfur can be formed into solid particles and then added to asphalt as either a minority or majority component to create desired paving binder compositions. The solid plasticized sulfur has non-stick non-flow properties within a wide range of ambient temperatures, and it can be stored solid for subsequent use in paving applications.

Abstract: A slurry mixture of sulfur in a liquid carrier comprising an ester derived from vegetable oils or animals fats such as biodiesel is disclosed. Also disclosed is a method of preparing a mixture of asphalt, polymer and sulfur comprising blending together, at asphalt blending conditions, the asphalt and a slurry of sulfur particles in a biodiesel liquid carrier comprising an ester derived from vegetable oils or animal fats.

Abstract: A composition of asphaltic concrete and the method of making the same are disclosed. The asphaltic concrete has asphalt cement, sulfuric acid and citrus stripper oil admixed together. This admixture is mixed with some aggregate and then packed and consolidated. The resulting paved surface resists rutting and requires less maintenance.

Abstract: A method for manufacturing modified asphalt is characterized by adding a dispersion agent such as furfural or vegetable oil to a modifier material and then mixing the modifier material with asphalt. The dispersion agent facilitates dispersion of the modifier through the asphalt to form a homogeneous mixture. A first activator is added to the mixture to produce a devulcanized and stabilized asphalt material having improved rheological, separation and solubility characteristics. A micro activator is also added to the mixture to improve the ductility of the modified asphalt. The modifier material comprises granular crumb rubber or polymer.

Abstract: A sulfur in oil in asphalt blend is disclosed. A polymer-free slurry of solid, elemental, sulfur in liquid oil is used to add sulfur to asphalt. Addition of a slurry of solid sulfur in oil, or oil containing sulfur compounds, permits rapid and effective dispersion of the sulfur component in the asphalt. Uneven mixing, which can occur when sulfur is separately added as a solid, or in molten forms to the asphalt, is avoided. The method is safer because formation of explosive clouds of sulfur dust is avoided.

Abstract: An asphalt composition is provided which contains i) an asphalt component containing solvent-deasphalted bottoms, ii) a rerefined lube bottoms fraction, iii) an optional fluxing component, and iv) an optional vacuum bottoms component. The invention further relates to a method of preparing the asphalt composition and a paving composition containing same.

Abstract: A method is provided for preparing asphalt composition, e.g., solvent deasphalting (SDA)-produced asphalt composition comprising a mixture containing SDA bottoms with or without vacuum tower bottoms and lube plant extract, which method comprises treating the asphalt composition with 0.05 to 0.5 wt % reactive sulfur under conditions sufficient to improve rheological properties of said composition as measured by increased complex shear modulus relative to a corresponding untreated mixture. The invention further relates to such asphalt composition and paving composition containing same.

Abstract: A modified asphalt composition having improved low-temperature fracture properties is obtained by devulcanizing crumb rubber, preferably ground rubber tire. The devulcanization is effected without the use of harsh oxidizing treatments or the addition of potentially hazardous solvents, by fractional distillation of a mixture of the rubber and crude oil to a temperature at which substantially complete devulcanization occurs and harmful volatiles are driven off, around 300.degree. C. The resulting compositions are relatively inexpensive and simple to produce and, not having been oxidized, may be expected to show better long-term aging and fatigue performance compared to air-blown asphalts and the like. They are also preferable, on grounds of health and safety, to prior paving asphalts containing significant proportions of volatile organic aliphatic or aromatic hydrocarbons.

Abstract: The present invention provides a method of making storage-stable road paving binders by blending a minor amount of an unsaturated polymer (e.g., having at least one diene monomer) with a major amount of asphalt at an elevated temperature such that the components are sufficiently fluid to blend; treating the asphalt-polymer blend with a sulfonating agent; and stripping the treated asphalt-polymer blend at an elevated temperature with sufficient stripping gas to remove strippable sulfur moieties and to stabilize the resulting stripped, treated blend. The invention also provides asphaltic compositions made by the method. The asphaltic compositions are useful as binders in road paving applications.

Abstract: A process is described for preparing a water-soluble sulphonated dispersant from a petroleum hydrocracking residue comprising: contacting a petroleum hydrocracking residue boiling above 524.degree. C. with concentrated sulphuric acid, oleum or sulphur trioxide to form a sulphonated mixture containing water soluble and water insoluble products, and separating the water soluble sulphonated product from the mixture. The mixture of water soluble and water insoluble sulphonated products is neutralized with alkali and evaporated to dryness, after which the dried mixture is extracted with alcohol to leave a water soluble product. The product can be used as a water reducer or superplasticizer in concrete.

Abstract: The present invention provides for a method of making storage stable road paving binders by blending a minor amount of a polymer having at least one diene monomer with a major amount of asphalt containing at least 0.3% by weight of total nitrogen at an elevated temperature such that the components are sufficiently fluid to blend; treating the asphalt-polymer blend using not more than 250 meq of a sulfonating agent per 100 g of asphalt-polymer blend to introduce the corresponding acid functionality into the blend; maintaining the sulfonated asphalt-polymer blend at a sufficiently elevated temperature and stripping the sulfonated blend with sufficient chemically unreactive gas to remove a major fraction of the acid functionality introduced by sulfonation. The invention also provides for the compositions made by the process. These are useful as binders in road paving applications.

Abstract: A pitch based impregnant for a carbon or graphite body and a method of impregnation. The method involves forming a liquid solution of a substantially solids free pitch having a Q.I. of less than 1% dissolved in furfural and containing an acid catalyst with the solution having a viscosity of less than 150 cps at room temperature and heating the impregnated body to between 150.degree.-200.degree. C. until the impregnant is cured.

Abstract: The improved composition for use in the production of composite carbon materials comprises a mesophase pitch containing at least 80% of an optical anisotropic phase and having a softening point of no higher than 250.degree. C., and sulfur present in an amount of 6-35 parts by weight per 100 parts by weight of said mesophase pitch. Said composition may be heated together with an aggregate and subsequently shaped to yield a composite carbon material. The improved process for producing a composite carbon material comprises impregnating an aggregate with said composition as it is melted, shaping the mixture in a temperature range of 150.degree.-350.degree. C, and then carbonizing the shaped part.

Abstract: A process for preparing a sulfonated dispersant from a petroleum asphalt fraction, comprising:establishing contact between the asphalt fraction dissolved in an inert solvent and liquid or gaseous sulfur trioxide at a temperature equal to or less than 60.degree. C., to obtain a sulfonated asphalt fraction;salifying the sulfonated asphalt fraction thus obtained by contact with an aqueous solution of a hydroxide of an alkaline metal, alkaline earth metal or ammonium and recovering the sulfonated salt from the reaction mixture.This process provides water-soluble sulfonated salts of petroleum asphalt fractions, which can be used as fluidifying and stabilizing agents for aqueous dispersions of solids, such as aqueous dispersions of coal or cement.

Abstract: Paving binders, especially hot mix paving mixtures, having excellent storage stability, reduced binder runoff, and high temperature viscosity are formed by adding a copolymer of ethylene with an alkyl acrylate or vinyl acetate and a neutralized sulfonated polymer to the asphalt. Preferably, the alkyl acrylate is methyl acrylate and the neutralized sulfonated polymer is a terpolymer of ethylene, propylene, and a diene monomer.

Abstract: The present invention discloses a process for producing a formed carbon products which comprises the steps of mixing a pitch or a pitch precursor and at least one kind of polymer becoming compatible with the pitch or the pitch precursor by heat-treating and having an aromatic ring and at least one sulfur, oxygen or nitrogen atom in its repeating unit; of heat-treating the mixture to convert it to a raw material pitch and thereafter of at least forming, infusibilizing and carbonizing and which succeeded to simplify a production apparatus and to reduce an energy comsumption by reducing an infusibilizing time without deteriorating physical properties of the carbon products.

Abstract: There is disclosed a method for chemically stabilizing cohesive soils. Sulfuric acid, citrus stripper oil, and water are admixed to the soil. Then the soil is packed to consolidate the soil particles.

Abstract: A new composition is disclosed which comprises pellets of asphalt coated with a solid layer of sulfur. The sulfur shell provides a meltable container for the asphalt core while protecting it from contact with the atmosphere. The relative quantities of sulfur and asphalt in the pellets of the invention may be varied over a wide range to provide sulfur-to-asphalt ratios commonly used in both sulfur-asphalt-sand mixes and sulfur-extended asphalt binders. The advantages of pelletizing are virtual elimination of the danger of dealing with hot materials and significant reduction in energy costs associated with keeping asphalt and sulfur hot and pumpable. To produce an asphalt paving mix, the sulfur-coated asphalt pellets may simply be mixed with heated aggregate.

Abstract: Crushed sulfur is melted by and is mixed with hot liquid asphalt at a manufacturing plant, after which the mixture is formed into sulfur-asphalt pellets. The sulfur added to the asphalt prevents a mass of the pellets from flowing and conglomerating at ambient temperatures. The pellets thus may be shipped in bulk form and without special temperature control from the manufacturing plant site to a remote site where the pellets are mixed with heated aggregate and are melted to form a sulfur-extended bituminous concrete paving composition for application to a roadway. By mixing a fine mineral filler such as calcium hydroxide with the crushed sulfur and the hot liquid asphalt at the manufacturing plant, temperature-stable pellets may be produced while using a lower ratio of sulfur to asphalt in the mixture. If desired, aggregate also may be added to the mixture at the manufacturing plant to form briquettes and avoid the need of mixing the pellets with aggregate at the paving site.

Abstract: A method of producing high quality, homogenous asphalt comprising the steps of mixing and heating a hydrocarbon feedstock not normally suited for asphalt production with elemental sulfur and agitating the resulting mixture. A halide catalyst may be added to the mixture to promote the reaction of the hydrocarbon feedstock with the sulfur. If desired, the agitated mixture may be air blown in any conventional manner to increase its hardness.

Abstract: A simpler and new process for the polycondensation of a sulfonated coal tar fraction comprising: sulfonating a coal tar fraction having a distillation range of 200.degree. to 240.degree. at normal pressure, with an excess of 20-30% mole of sulfuric acid, as opposed to 105% in the prior art, for 4-8 hours at a temperature of 160.degree. C..+-.10.degree. C. under reflux. The product is diluted with water to render it fluid at about 80.degree. C. and molar ratio of formaldehyde per mole of the sulfonated coal tar fraction is then added gradually at a temperature of about 85.degree. C..+-.5.degree. C., then gradually heated for about 1 to 4 hours at 100.degree. to 106.degree. C., and then further raised to 106.degree. C.-120.degree. C. for 2 to 4 hours. The product is then cooled and neutralized. With this process, new polycondensates with improved properties are produced. The polycondensation including neutralization is completed within 16 hours from the time the formaldehyde is added.

Abstract: Disclosed is a one-step method of producing an industrial asphalt from a bituminous material which comprises mixing together without air-blowing:(a) a feed material comprising a bituminous material having a viscosity of at least 50 centistokes at 350 degrees Fahrenheit and wherein the feed petroleum residuum forms a single phase when mixed with 5 percent of paratoluene sulfonic acid; and(b) from about 0.1 to 20.0 percent by weight of an organic sulfonic acid, said mixing being done at a temperature in the range of 351 to 600 degrees Fahrenheit, whereby the softening point of the feed is substantially increased and the penetration is significantly decreased.

Abstract: An asphaltic composition having improved temperature susceptibility and a method of manufacturing the improved asphaltic composition are disclosed. The improvement is directed at the addition of a stabilizing agent selected from the group consisting of Group IA sulfates, Group IIB sulfates and mixtures thereof.

Abstract: Disclosed is a one-step method of producing an industrial asphalt from a bituminous material which comprises mixing together without air-blowing:(a) a feed material comprising a bituminous material having a viscosity of at least 50 centistokes at 350 degrees Fahrenheit and wherein the feed petroleum residuum forms a single phase when mixed with 5 percent of 98 percent sulfuric acid; and(b) from about 0.1 to 20.0 percent by weight of sulfuric acid, said mixing being done at a temperature in the range of 351 to 600 degrees Fahrenheit, whereby the softening point of the feed is substantially increased and the penetration is significantly decreased.

Abstract: Sulfur, useable in as an additive to asphalt in the preparation of asphalt binders can be plasticized by addition of carbon and further treated with amyl acetate. This plasticized sulfur can be formed into solid particles and then added to asphalt as either a minority or majority component to create desired paving binder compositions. The solid plasticized sulfur has non-stick non-flow properties within a wide range of ambient temperatures, and it can be stored solid for subsequent use in paving applications.