Abstract: Reaction products of polyamines with sulfonated oleic acid or sulfonated tall oil fatty acids are disclosed which give emulsions capable of producing cationic medium set mixing grade asphalt emulsions, as well as rapid set asphalt emulsions. Solventless asphalts as well as asphalts containing up to 15% by volume of a hydrocarbon oil can be used for emulsification.

Abstract: A process for air blowing asphalt in the presence of organic sulfonic acids and an asphalt composition comprising a major amount of asphalt and a minor but effective amount of organic sulfonic acid.

Abstract: A novel sulfur-based adduct formed by reacting sulfur with a diene-containing by-product hydrocarbon mixture available from petrochemical operations and/or from coal processing. The adduct is a reaction product of sulfur and each of the dienes contained in the by-product mixture. Also disclosed is a road surface composition containing this adduct as an asphalt extender or as a replacement for asphalt, and there are also disclosed other compositions containing this adduct such as sulfur cements, sulfur concretes, coatings, foams, structural materials and insulators.

Abstract: An improved process for forming an acoustical or thermal insulating fibrous glass product is provided, wherein the binder employed is asphalt and the asphalt is converted into a substantially insolubilized form.

Abstract: Bituminous binders are disclosed which contain at least one silane and show excellent improvement of adhesion. The bituminous binder containing silane is manufactured by heating The bituminous binder to a temperature of 120.degree.-230.degree. C. and stirring in the silane. All known silanes can be used as the silane. The resulting compositions can be used for the production of street surfacings, industrial floors, floorings, building protective paints, roof coating masses, undercoatings for motor vehicles and rail vehicles, and cable covering compounds.

Abstract: A novel sulfur-based adduct formed by reacting sulfur with a diene-containing by-product hydrocarbon mixture available from petrochemical operations and/or from coal processing. The adduct is a reaction product of sulfur and each of the dienes contained in the by-product mixture. Also disclosed is a road surface composition containing this adduct as an asphalt extender or as a replacement for asphalt, and there are also disclosed other compositions containing this adduct such as sulfur cements, sulfur concretes, coatings, foams, structural materials and insulators.

Abstract: In a stockpile asphalt emulsion composition an improved asphalt phase comprises 50-98% of paving grade asphalt, 1-10% added sulfur, and 1-35% liquid hydrocarbon.

Abstract: Propane-precipitated asphalt is heated with 1-15 wt. % elemental sulfur at 140.degree. to 300.degree. C. until hydrogen sulfide evolution ceases. The sulfur-treated asphalt base material having an increased softening point of about 65.degree.-300.degree. C., is blended with 5-60 wt. % liquid petroleum fraction, such as vacuum gas oil or extract oil, having an equivalent atmospheric boiling point of 370.degree.-500.degree. C., to yield a quality paving grade asphalt cement composition meeting ASTM standards.

Abstract: Propane-precipitated asphalt is contacted with a stream of air at 200.degree. C. and above to increase the softening point of the asphalt. The resulting asphalt base, having a softening point of about 65.degree.-300.degree. C., is then blended with 5-60 weight percent liquid sulfur-treated petroleum fraction, having an equivalent atmospheric boiling point range of 370.degree.-500.degree. C., to yield paving grade quality asphalt cement composition.

Abstract: A waterproofing composition is made by admixing primary sludge produced by pulp and paper mill operations with tall oil pitch. The composition may include particulate wood by-products as fillers and a material such as lime for raising the softening point of the tall oil pitch.

Abstract: This invention relates to a new process for the preparation of improved polymeric bitumens.The process is characterized by preparing a first composition by admixing a petroleum fraction (160.degree.-230.degree. C.), while stirring, at a temperature of from 80.degree. C. to 120.degree. C., with a copolymer made of styrenic blocks and dienic blocks such as a styrenebutadiene disequenced or multisequenced or statistical copolymer having a molecular weight varying between 30,000 and 300,000 and crystallized sulfur which is not chemically bound.When homogeneity is obtained, a portion of said first composition is admixed for at least 15 minutes at a temperature of from 130.degree. C. to 230.degree. C., with a conventional bitumen (penetration 20-220) to form a fluid polymeric bitumen.The fluid polymeric bitumen obtained by the process of the present invention is an excellent product characterized by superior properties and this product can be used in conventional spreading means when applying coatings onto roads.

Abstract: Spent asphaltic concrete is recycled by crushing, heating and admixing with sulfur at elevated temperature.

Abstract: A sulfur-bituminous composite binder material consisting essentially of 60-75% by weight sulfur and 25-40% by weight bituminous material. Optionally a small amount of a fibrous or flake reinforcing material and usually a filler material can be added. The binder is suitable for use as a self-compacting road or pothole repair material. A feature of the composite binder is the presence of two continuous phases which is achieved by mixing solid particulate sulfur with a softened bituminous material at a temperature in the range 120.degree.-150.degree. C. or by mixing liquid sulfur with liquid asphalt with a sufficient shearing mixing action to produce an emulsion of the liquid sulfur in the asphalt which, on cooling produces a continuous, rigid, crystaline and porous sulfur skeleton in the composite.

Abstract: Asphaltic compositions are obtained by heating solvent refined coal and sulfur to a temperature of 250.degree. F. to 800.degree. F. to provide asphaltic pitch-like compositions which are useful as paving binders and coating compositions.

Abstract: In a stockpile asphalt emulsion composition an improved asphalt phase comprises 40-70% of paving grade asphalt, 10-50% sulfur, and 5-30% liquid hydrocarbon.

Abstract: Asphaltic compositions comprising waste material are obtained by heating a mixture of solid organic waste, sulfur, and a liquefaction solvent to a temperature of 300.degree. F. to 1000.degree. F. to provide asphaltic pitch-like compositions which are useful as paving binders and coating compositions. The method for producing paving compositions is compatible with current petroleum refining technology and affords a low-cost method of waste disposal.

Abstract: A small amount of an organosiloxane polymer stabilizes an emulsion of sulphur and a bituminous material in which the bituminous material is a continuous phase and the sulphur is a dispersed phase; the stabilized emulsion serves as a binder for mineral aggregates in the manufacture of paving mixtures.

Abstract: A corrosion resistant coating composition is provided which is a one-quart system. The composition is an asphaltic-base material containing a petroleum sulfonate and a sufficient amount of an organic solvent to impart the desired viscosity. A source of amine groups, such as a polyamide resin, is added and the resulting composition has improved adherence to the metallic substrate.

Abstract: The disclosure describes built-up roofing having improved resistance to spreading of fire, fabricated from two or more layers of felt impregnated with asphalt based saturant with asphalt based coating spread on top of each felt layer; the saturant asphalt or coating asphalt or both are blends of 90 - 45% asphalt with 10 - 55% sulfur. The roofing is built-up in the conventional manner by "mopping" fluid asphalt based coating onto felt layers impregnated with asphalt based impregnant. A protective layer of inert mineral aggregate (e.g. gravel) optionally covers the top coating.

Abstract: An asphalt composition having high ductility at low temperatures is obtained by hot-mixing asphalt and 3 to 7 wt. % of sulfur, based on the weight of asphalt, at temperatures below 300.degree. F. Small amounts of rubber further increase the ductility.

Abstract: New polythiols-polyesters and corresponding polysulphides in the --SH group wherein sulphur is contained in the alcohol residue after the formation of esters. These polyesters are derived from aliphatic polyacids, saturated or not, wherein the molecule contains a minimum of 15 atoms of carbon. They are formulated by the action of a mercapto-alcanol on the corresponding polyacid, in a liquid which gives an azeotropic mixture with water. These products are useful as additives to asphalts, bituminous products, coatings, mastics and cements.

Abstract: A process for producing an infusible and insoluble granular sulfurized material by reacting a petroleum heavy material and sulfur with stirring in the presence of a reaction medium and further in the presence of, if necessary, an infusible and insoluble solid material, and, further, a process for producing granular carbon comprising carbonizing the granular sulfurized material produced above or alternatively a process for producing granular activated carbon comprising carbonizing and activating the granular sulfurized material.

Abstract: A sulfur-based aggregate-asphalt composition prepared by a process comprising mixing aggregate with asphalt and a molten sulfur system, wherein the molten sulfur system is made by a method comprising heating a mixture of sulfur and a sulfur plasticizer. Dicyclopentadiene is a preferred material for plasticizing the sulfur. Preferably the sulfur system contains, in addition to the sulfur plasticizer, a fibrous filler such as glass fiber or asbestos, and an inorganic filler such as talc powder.

Abstract: Vulcanized compositions of matter obtained by heating a mixture of bitumen, an olefin polymer, sulfur and a sulfur-containing vulcanization accelerator to a temperature of 80.degree. to 250.degree. C.

Abstract: Disclosed is a soil stabilizing agent consisting of a source of calcium, such as calcium carbonate, and a spent sulfuric acid having at least about 45% H.sub.2 SO.sub.4, in a water solution and a method for applying the same. Certain chloride and sulfate materials, such as aluminum and ferric chloride and aluminum and ferrous sulfate, may be added to the soil with the stabilizing agent to provide enhanced results in particular soils. The stabilizing agent is applied with sufficient water to thoroughly wet the soil and thus disperse the agent through the soil and the treated soil is then worked to accomplish thorough mixing.

Abstract: Disclosed is a soil stabilizing agent consisting of a source of calcium, such as calcium carbonate, and a source of sulfuric acid, in a water solution and a method for applying the same. Certain chloride and sulfate materials, such as aluminum and ferric chloride and aluminum and ferrous sulfate, may be added to the soil with the stabilizing agent to provide enhanced results in particular soils. The stabilizing agent is applied with sufficient water to thoroughly wet the soil and thus disperse the agent through the soil and the treated soil is then worked to accomplish thorough mixing.

Abstract: Process for dispersing molten sulphur in a hydrocarbon material, such as asphalt, tar and more particularly bitumen. The dispersion is effected in such a way as to produce an emulsion of sulphur in very fine particles, with dimensions not exceeding 10 microns, in the hydrocarbon material. A turbine with a gap or clearance of about 0.1 to 2.25 mm. is very useful for this purpose. The emulsions obtained are particularly suitable for road surfaces.

Abstract: When cast sulfur-asphalt compositions, e.g., sulfur-asphalt-aggregate pavements and construction articles, are being prepared by mixing and/or heating mixtures comprising sulfur and asphalt at elevated temperatures not exceeding 175.degree.C, the evolution of hydrogen sulfide is substantially reduced by carrying out the mixing and/or heating step in the presence of a hydrogen sulfide suppressant selected from the class consisting of free radical inhibitors and redox (oxidation-reduction) catalysts.

Abstract: Surface hardening or skin formation on asphalts stored at temperatures in excess of 170.degree.C is inhibited by the addition of (a) dodecylphenoxypoly(ethyleneoxy)ethanol; (b) calcium petroleum sulfonate; (c) 2,6-ditertiarybutyl-p-phenol; or (d) 2,6-ditertiarybutyl-p-phenol in combination with stearic acid.

Abstract: A method of producing granular or lumpy hard raw materials for activated carbon with a high yield by reacting a petroleum heavy material, such as a petroleum heavy oil or heavy residue, with a sulfonating agent in a reaction solvent thereby converting the petroleum heavy material into a carbonized material.