H Or Alkyl Directly Bonded To Si Patents (Class 106/287.14)
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Patent number: 11884778Abstract: The object of the present invention is to provide a silicone composition which provides a release coating having excellent adhesion to a substrate, in particular a plastic film substrate, such as a polyester film. Further, an object of the present invention is to provide a release sheet having a cured coating of the silicon composition. It is also an object of the present invention to provide a silicone composition which has improved storage stability and does not cause separation of the functional compound during long-term storage or transportation. The present invention provides a silicone composition comprising the following components (A) to (C): (A) an organopolysiloxane having at least two alkenyl groups each bonded to a silicon atom in a molecule, having a viscosity at 25 degrees C.Type: GrantFiled: June 27, 2019Date of Patent: January 30, 2024Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Ataru Kobayashi, Ken Nakayama, Toshiaki Ihara
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Patent number: 11289666Abstract: A display has a plurality of pixels in a matrix, the pixels each comprising a liquid crystal layer and/or light emitting diode layer, a plurality of substrates, at least a first substrate being optically transmissive to visible light, an electrode formed on one of the substrates and having electrically conductive material that has an electrical resistivity of less than 200 ?/sq and that comprises a siloxane material and particles having an average particle size of less than 10 microns.Type: GrantFiled: October 10, 2016Date of Patent: March 29, 2022Assignee: Inkron OyInventors: Juha Rantala, Jarkko Heikkinen, Janne Kylmä
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Patent number: 11166456Abstract: A deposition aid is provided, comprising a low molecular weight, low viscosity polysiloxane, combined with a crop oil concentrate or esterified seed oil concentrate. Combinations including the modified silicone can improve spreading and/or adhesion to foliage. Adding about 5% to about 20% of the modified silicone can provide more than a proportional increase in spreading and/or adhesion.Type: GrantFiled: October 4, 2018Date of Patent: November 9, 2021Assignee: Momentive Performance Materials Inc.Inventors: William L. Brown, George A. Policello, Jeferson A. Naue
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Patent number: 10995012Abstract: The present disclosure relates to methods of preparing sols of titanium dioxide nanoparticles that are photoactive, neutral, and in a substantially concentrated form. The methods particularly provide for concentrated sols in light of washing and dewatering under low cation concentrations and utilizing rapid peptizing through addition of the filter case to the peptizing agent. Concentrated acid may be utilized to maintain high TiO2 concentration while still avoiding precipitation of the colloidal TiO2. Concentrated photoactive, neutral titanium dioxide sols are also provided as well as compositions thereof and photoactive coatings formed therewith.Type: GrantFiled: December 9, 2016Date of Patent: May 4, 2021Assignee: Tronox LLCInventor: Julie Kerrod
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Patent number: 10925813Abstract: The present invention provides a sunscreen composition comprising two or more oil-soluble ultraviolet absorbers and composite silicone particles having an average particle diameter of 10 ?m or less.Type: GrantFiled: January 25, 2013Date of Patent: February 23, 2021Assignee: OTSUKA PHARMACEUTICAL CO., LTD.Inventors: Masahiko Tanaka, Miyoko Ogihara, Junko Kako
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Patent number: 10919919Abstract: Novel epoxy-functional alkoxysilanes have, for example, formulae II, III, IV, V, and VI.Type: GrantFiled: September 26, 2018Date of Patent: February 16, 2021Assignee: Evonik Operations GmbHInventors: Markus Rudek, Susann Witzsche, Stefan Bade, Burkhard Standke, Reiner Störger
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Patent number: 10882275Abstract: A gas barrier film with a protective layer including inorganic particles is provided. A gas barrier effect of the gas barrier film is improved by including inorganic nanoparticles in a protective layer when a protective coating is performed to protect a gas barrier layer.Type: GrantFiled: November 29, 2013Date of Patent: January 5, 2021Assignee: LG CHEM, LTD.Inventors: Sang Uk Ryu, Dong Ryul Kim, Jong Min Moon
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Patent number: 10858540Abstract: A composition that includes an amino-functional compound having at least one silane group, a fluorinated compound represented by formula Rf{—X—[Si(Y)3-x(R)x]y}z, and a non-fluorinated organic solvent having a flashpoint of at least 40° C. A method of making a treated article having a metal surface using a composition that includes an amino-functional compound having at least one silane group, a fluorinated compound represented by formula Rf{—X—[Si(Y)3-x(R)x]y}z, and an organic solvent having a flashpoint of at least 40° C. is also disclosed. Another method includes treating the metal surface with a primer composition including an amino-functional compound having at least one silane group to provide a primed metal surface and subsequently treating the primed metal surface with a treatment composition including a fluorinated compound represented by formula Rf{—X—[Si(Y)3-x(R)x]y}z. The compositions each include up to one percent by weight of an organic solvent having a flashpoint up to 40° C.Type: GrantFiled: September 21, 2016Date of Patent: December 8, 2020Assignee: 3M Innovative Properties CompanyInventors: Frans A. Audenaert, Christoph T. R. Schuell, Inge Nuyts
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Patent number: 10754069Abstract: The present invention relates to an ophthalmic lens whose front and rear faces are differentiated with respect to their hydrophobic properties. Said lens comprising a substrate having a hydrophobic front main face, and a rear main face whose external surface has a receding contact angle with water greater than or equal to 80°, the external surface of said front main face having a receding contact angle with water lower than that of the rear main face. The invention presents various means for preparing such lenses, which may notably be obtained after deposition and then removal of temporary layers with different thicknesses on the two faces of the lens.Type: GrantFiled: July 3, 2015Date of Patent: August 25, 2020Assignee: Essilor InternationalInventors: Aude Lapprand, Pascale Lacan, Christophe Valenti
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Patent number: 10703940Abstract: A method of making an adhesive article comprises three steps. First, the method includes providing a liner having first and second opposed major surfaces with respective first and second silicone release layers disposed thereon. The second silicone release layer comprises a partially cured hydrosilation-crosslinkable silicone mixture comprises a first silicone polymer having at least three Si—H groups and second silicone polymer have at least two vinyl, and has an extractables content of 5 to 25 weight percent. Second, an adhesive layer is disposed onto the first silicone release layer. Third, the adhesive layer is exposed to E-beam radiation within a process chamber thereby providing a crosslinked adhesive layer. The second silicone release layer is exposed to oxygen during crosslinking of the adhesive layer. Adhesive articles made according to the method also disclosed.Type: GrantFiled: August 24, 2017Date of Patent: July 7, 2020Assignee: 3M Innovative Properties CompanyInventors: Maria A. Appeaning, Marie A. Boulos, David J. Kinning, Georgiy Teverovskiy, Michael L. Steiner, Sai Vang
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Patent number: 10597566Abstract: An organopolysiloxane emulsion composition for release paper or a release film, said composition being produced by dispersing a mixture comprising components (A) to (D) as mentioned below in water: (A) an alkenyl-group-containing diorganopolysiloxane having at least two alkenyl groups per molecule and having a viscosity of 1,000 Pa·s or less at 25° C., in an amount of 100 parts by mass; (B) an organohydrogenpolysiloxane having at least two Si—H groups per molecule and having a viscosity of 1 Pa·s or less at 25° C., in such an amount that the number of moles of an Si—H group can become 0.5 to 10 times the number of moles of an alkenyl group in the component (A); (C) a curing catalyst, in an amount of 0.01 to 3 parts by mass; and (D) a polyether-modified and/or polyol-modified organosilicon compound, in an amount of 0.01 to 10 parts by mass.Type: GrantFiled: March 17, 2016Date of Patent: March 24, 2020Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Kenji Yamamoto, Tsutomu Nakajima
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Patent number: 10570020Abstract: A silica particle has a compression and aggregation degree of from 60% to 95% and a particle compression ratio of from 0.20 to 0.40.Type: GrantFiled: January 20, 2016Date of Patent: February 25, 2020Assignee: FUJI XEROX CO., LTD.Inventors: Hiroyoshi Okuno, Satoshi Inoue, Yoshifumi Iida, Tomohito Nakajima, Yuka Zenitani, Yoshifumi Eri, Yasuo Kadokura, Yasuhisa Morooka, Shunsuke Nozaki, Takeshi Iwanaga, Sakae Takeuchi
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Patent number: 10557066Abstract: The present invention relates to an adhesive composition capable of improving adhesion force between two interfaces through thermal crosslinking and photo-crosslinking of a substrate and a resin, or a resin and a resin, in processes for optical devices and electronic devices, and a preparation method thereof. Specifically, the present invention relates to an adhesive composition capable of adhering an interface between a substrate and a photocurable resin, and a method of adhering an interface using the same.Type: GrantFiled: October 6, 2016Date of Patent: February 11, 2020Assignee: Chem Optics Inc.Inventors: Hyung-Jong Lee, Nam Seob Baek, Jonghwi Lee, Yun Jung Seo, Jin-Kwon Jeong
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Patent number: 10134942Abstract: The present invention relates to a novel process for the preparation of printable, high-viscosity oxide media, and to the use thereof in the production of solar cells.Type: GrantFiled: December 18, 2013Date of Patent: November 20, 2018Assignee: MERCK PATENT GMBHInventors: Ingo Koehler, Oliver Doll, Sebastian Barth
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Patent number: 10125291Abstract: A composition for promoting the release of bituminous materials and other adhesive materials from a substrate and methods of use thereof. More particularly, a composition comprising a silicone oil-in-water emulsion, which is stabilized by an alkoxylated polysiloxane surfactant, for use as a release agent that can be applied to a substrate, such as a truck bed, prior to use for promoting the free release of a bituminous material, such as asphalt, from the substrate.Type: GrantFiled: June 6, 2016Date of Patent: November 13, 2018Assignee: Troxler Electronics Laboratories Inc.Inventor: Robert Ernest Troxler
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Patent number: 9874661Abstract: A wavelength conversion member may include a first substrate and a second substrate that overlaps the first substrate. The wavelength conversion member may further include a wavelength conversion layer disposed between the first substrate and the second substrate in a first direction. The wavelength conversion member may further include a first hydrophobic membrane that overlaps at least one of the first substrate, the second substrate, and the wavelength conversion layer in a second direction perpendicular to the first direction.Type: GrantFiled: June 2, 2014Date of Patent: January 23, 2018Assignee: SAMSUNG DISPLAY CO., LTD.Inventors: Sang Hyuk Lee, Seok Hyun Nam
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Patent number: 9730325Abstract: A substrate with built-in passive element includes passive elements and a substrate. The passive elements include at least one of a capacitor, an inductor, a resistor, a signal transmission element or an optical waveguide element. The capacitor, the inductor, the resistor, the signal transmission element or the optical waveguide element has a functional element filled in a groove-like or hole-like element forming region provided in the substrate along a thickness direction thereof. The functional element has a Si—O bond region obtained by reacting Si particles with an organic Si compound.Type: GrantFiled: January 15, 2014Date of Patent: August 8, 2017Assignee: NAPRA CO., LTD.Inventors: Shigenobu Sekine, Yurina Sekine, Kazutoshi Kamibayashi
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Patent number: 9675905Abstract: Defoamer compositions are described and the use of defoamer compositions in paper and pulp mills is described, especially for use at the brown stock washing steps in a pulp mill. The defoamer composition comprises: a) about 20 wt % to about 90 wt % of at least one organophosphorous component (e.g., compound or polymer, n-tributoxyethyl phosphate); b) about 1 wt % to about 10 wt % of at least one silane treated silica; c) about 0.5 wt % to about 10 wt % of at least one surfactant that is anionic or non-ionic; and d) optionally, water or an aqueous liquid.Type: GrantFiled: March 19, 2015Date of Patent: June 13, 2017Assignee: Buckman Laboratories International, Inc.Inventor: Glenn Mudaly
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Patent number: 9620367Abstract: A diffusion agent composition including an impurity-diffusing component (A); a binder resin (B) that thermally decomposes and disappears below a temperature at which the impurity-diffusing component (A) begins to thermally diffuse; SiO2 fine particles (C); and an organic solvent (D) that contains an organic solvent (D1) having a boiling point of at least 100° C.Type: GrantFiled: August 18, 2010Date of Patent: April 11, 2017Assignee: TOKYO OHKA KOGYO CO., LTD.Inventors: Takaaki Hirai, Atsushi Murota, Katsuya Tanitsu
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Patent number: 9608143Abstract: The composition for forming an n-type diffusion layer in accordance with the present invention contains a glass powder and a dispersion medium, in which the glass powder includes an donor element and a total amount of the life time killer element in the glass powder is 1000 ppm or less. An n-type diffusion layer and a photovoltaic cell having an n-type diffusion layer are prepared by applying the composition for forming an n-type diffusion layer, followed by a thermal diffusion treatment.Type: GrantFiled: November 10, 2013Date of Patent: March 28, 2017Assignee: Hitachi Chemical Co., Ltd.Inventors: Youichi Machii, Masato Yoshida, Takeshi Nojiri, Kaoru Okaniwa, Mitsunori Iwamuro, Shuichiro Adachi, Tetsuya Sato, Keiko Kizawa
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Patent number: 9556359Abstract: Provided is a method of producing a member for electrophotography capable of providing a high-quality electrophotographic image.Type: GrantFiled: September 5, 2013Date of Patent: January 31, 2017Assignee: CANON KABUSHIKI KAISHAInventors: Noriko Suzumura, Noriyuki Doi, Hiroki Masu, Masataka Kodama, Masahiro Kurachi, Noriaki Kuroda
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Patent number: 9528036Abstract: Low-VOC compositions of dialkyl-functional siloxane oligomers, especially of methylalkylalkoxysiloxanes, and processes for producing them are provided. Additionally methods for hydrophobizing porous mineral substrates employing the low-VOC compositions, in the course of which few or no volatile organic compounds are released, are provided.Type: GrantFiled: February 23, 2015Date of Patent: December 27, 2016Assignee: Evonik Degussa GmbHInventors: Christopher Studte, Spomenko Ljesic
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Patent number: 9493615Abstract: The invention provides a composition comprising a polyolefin and a polyorganosiloxane in which at least 50 mole % of the siloxane units are D units as herein defined and which contains at least one unsaturated group, characterized in that the unsaturated group is group of the formula —X—CH?CH—R? (I) or —X—C?C—R? (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH?CH— or —C?C— bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH?CH—R? or with the acetylenic unsaturation of —X—C?C—R? and R? represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH?CH— or —C?C— bond.Type: GrantFiled: December 22, 2010Date of Patent: November 15, 2016Assignee: Dow Corning CorporationInventors: Michael Backer, Francois De Buyl, Damien Deheunynck, Valerie Smits
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Patent number: 9394461Abstract: Radiation curable composition for preparing a hybrid sol-gel layer on a surface of a substrate, wherein said composition comprises at least one radically radiation curable material; at least one non-reactive organofunctional silane; at least one reactive organofunctional silane; at least one cationic photoinitiator; and at least one radical photoinitiator. Method for preparing a hybrid sol-gel layer on a surface of a substrate using said composition and hybrid sol-gel layer so prepared. Substrate comprising at least one surface coated with said hybrid sol-gel layer.Type: GrantFiled: May 16, 2013Date of Patent: July 19, 2016Assignees: UNIVERSITE DE HAUTE-ALSACE, SOCOMOREInventors: Céline Croutxe-Barghorn, Abraham Chemtob, Lingli Ni, Nadia Moreau, Thierry Bouder
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Patent number: 9387270Abstract: A method to condition the air in a bowling alley utilizes an oil mixture which is dispensed by conditioning apparatus which down and up a synthetic bowling lane. The oil mixture comprises original lane oil and a fragrance composition which admixed to the oil mixture to produce a fragrant lane oil which has at 1700 cm?1 a % T which is generally equivalent to the % T of the original lane oil.Type: GrantFiled: January 3, 2013Date of Patent: July 12, 2016Inventor: Elizabeth K Piper
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Patent number: 9382402Abstract: The flame-retardant silicone resin composition of the present invention comprises: an inorganic oxide particle-containing condensation-reactive silicone resin (A) comprising a crosslinking structure in which inorganic oxide particles dispersed in a polysiloxane resin having a condensation-reactive group are crosslinked with the polysiloxane resin by chemical bonds; and inorganic particles (B). The inorganic oxide particles are preferably at least one type of inorganic oxide particles selected from the group consisting of silica, alumina, glass frit, and antimony-doped tin oxide.Type: GrantFiled: April 9, 2013Date of Patent: July 5, 2016Assignee: NITTO DENKO CORPORATIONInventors: Kohei Doi, Kunio Nagasaki, Yusuke Sugino, Takafumi Hida, Yusuke Nakayama, Keisuke Hirano
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Patent number: 9358579Abstract: A composition for promoting the release of bituminous materials and other adhesive materials from a substrate and methods of use thereof. More particularly, a composition comprising a silicone oil-in-water emulsion, which is stabilized by an alkoxylated polysiloxane surfactant, for use as a release agent that can be applied to a substrate, such as a truck bed, prior to use for promoting the free release of a bituminous material, such as asphalt, from the substrate.Type: GrantFiled: September 14, 2012Date of Patent: June 7, 2016Assignee: Troxler Electronics Laboratories, Inc.Inventors: Nael Naguib Zaki, Robert Ernest Troxler
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Patent number: 9232650Abstract: A surface treated copper foil which is well bonded to a resin and allows the resin to have excellent transparency after removal of the copper foil by etching, and a laminate using the same are provided. A surface treated copper foil having at least one surface with a skewness Rsk of ?0.35 to 0.53, comprising an Sv defined by the following expression (1) of 3.5 or more based on a brightness curve: Sv=(?B×0.Type: GrantFiled: November 11, 2013Date of Patent: January 5, 2016Assignee: JX Nippon Mining & Metals CorporationInventors: Hideta Arai, Atsushi Miki, Kohsuke Arai, Kaichiro Nakamuro
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Patent number: 9200248Abstract: The invention relates to a bioreactor for cultivating phototrophic organisms in an aqueous culture medium. The reactor parts and/or fittings that come into contact with the culture medium are entirely or partially coated with a silicone layer, and the surface of the silicone layer has a contact angle to the water of at least 100°.Type: GrantFiled: August 6, 2010Date of Patent: December 1, 2015Assignee: Wacker Chemie AGInventors: Christoph Müller-Rees, Rupert Pfaller
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Patent number: 9200247Abstract: The invention relates to a bioreactor for cultivating phototrophic organisms in an aqueous culture medium, the reactor parts that come into contact with the culture medium being entirely or partially produced from silicone materials. The invention is characterized in that the silicone materials are produced from addition-crosslinked silicones, and the surface of the silicone materials has a contact angle to the water of at least 100°.Type: GrantFiled: August 6, 2010Date of Patent: December 1, 2015Assignee: Wacker Chemie AGInventors: Christoph Müller-Rees, Rupert Pfaller
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Patent number: 9169122Abstract: A method for the manufacture of crystallite particles, said method comprising the steps of: a) reacting a reaction solution comprising a silicate, a micelle forming agent, an alkane, a salt under stirring at pH 2 or lower, wherein the reaction solution comprises HCI in a concentration of at least 1.5 M, wherein the stirring is performed not more than 10 minutes, and b) treating the obtained material to remove the micelle forming agent with one method selected from i) heat treating the material above 300° C., ii) treating the material with at least one selected from H2O2, and H2SO4, iii) treating the material with microwaves to digest the micelle forming agent. An advantage is that the time for the synthesis is shortened considerably compared to the prior art.Type: GrantFiled: September 21, 2011Date of Patent: October 27, 2015Assignee: Nanolith Sverige ABInventors: Magnus Odén, Emma Björk
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Patent number: 9156740Abstract: A ceramic boron-containing dopant paste is disclosed. The ceramic boron-containing dopant paste further comprising a set of solvents, a set of ceramic particles dispersed in the set of solvents, a set of boron compound particles dispersed in the set of solvents, a set of binder molecules dissolved in the set of solvents. Wherein, the ceramic boron-containing dopant paste has a shear thinning power law index n between about 0.01 and about 1.Type: GrantFiled: May 3, 2011Date of Patent: October 13, 2015Assignee: Innovalight, Inc.Inventors: Maxim Kelman, Elena Rogojina, Gonghou Wang
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Patent number: 9110313Abstract: There are provided a display in which a sealing section is prevented from being spread and the sealing section is allowed to be provided in a desired region, and an electronic unit including the display. The display includes: a substrate including a sealing region and a step section, the sealing region surrounding a display region, and the step section surrounding the sealing region from outside; a display layer provided in the display region; and a sealing section provided in the sealing region.Type: GrantFiled: July 17, 2012Date of Patent: August 18, 2015Assignee: Sony CorporationInventors: Hirofumi Nakamura, Nobuhide Yoneya, Toru Tanikawa, Shota Nishi, Shin Akasaka, Satoshi Kumon
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Patent number: 9045647Abstract: A surface treatment composition comprises a polyfluoropolyether silane. The polyfluoropolyether silane and the surface treatment composition are produced by reacting a perfluoropolyether-containing compound and a hydrosilane in the presence of a hydrosilylation catalyst and an isomer reducing agent.Type: GrantFiled: November 10, 2011Date of Patent: June 2, 2015Assignees: DOW CORNING CORPORATION, DAIKIN INDUSTRIES, LTD.Inventors: Don Lee Kleyer, Yasushi Sugiura, Mamoru Tachikawa, Yoshinori Taniguchi, Peter Hupfield, Yasuo Itami, Masahiko Maeda, Tetsuya Masutani, Tomohiro Yoshida
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Publication number: 20150132494Abstract: A vanadium dioxide coating for intelligent temperature control is formed by mixing a vanadium dioxide powder slurry, a polymer emulsion, and coating additives, and then coating the mixture onto a substrate. The vanadium dioxide powdery slurry comprises vanadium dioxide composite powders and a dispersion medium, the composite powders comprising vanadium dioxide nanopowders having a chemical composition of V1?xMxO2, and the surface of the vanadium dioxide nanopowders being attached to organic modified long-chain molecules, wherein M is a doped element, and 0?x?0.5. Through using the vanadium dioxide powders and the slurry thereof having an organic modified surface, the coating has higher visible light transmittance, can almost completely screen ultraviolet rays, and simultaneously intelligently adjust infrared rays.Type: ApplicationFiled: March 7, 2012Publication date: May 14, 2015Applicants: SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES., FSPG HI-TECH CO., LTD.Inventors: Hongjie Luo, Yiliao Liu, Yanfeng Gao, Zhaohui Cai, Yuwei Lin, Chuanxiang Cao, Shaobo Wang, Minoru Kanehira
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Patent number: 9028603Abstract: A xerogel film exhibiting antifouling properties. The films are made using long-chain alkyltrialkoxysilanes, short-chain alkyltrialkoxysilanes, aminoalkyltrialkoxysilanes, alkylaminoalkyltrialkoxysilanes, dialkylaminoalkyltrialkoxysilanes, and perfluororalkyltrialkoxysilanes as sol-gel precursors. The films can be used as coatings on surfaces to reduce or eliminate fouling resulting from attachment and/or growth of biofoulants such as algae, diatoms, bacteria, barnacles, and biofilms.Type: GrantFiled: June 11, 2012Date of Patent: May 12, 2015Assignee: The Research Foundation of State University of New YorkInventors: Michael Ray Detty, Frank V. Bright, Stephanie Marie Bennett, Anastasiya Sokolova
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Publication number: 20150124327Abstract: A coating material for forming an optical coating film, which constitutes a reflection preventing film provided on a lens base material, includes a solvent (A), a compound (B) which contains a polymerizable functional group, and a metal oxide particle (C), in which the solvent (A) contains at least one solvent (A1) selected from the group consisting of propylene glycol monopropyl ether, propylene glycol monomethyl ether, and propylene glycol monomethyl ether acetate, and the compound (B) contains a compound (B1) which contains two or more urethane bonds in one molecule, or metal alkoxide (B2).Type: ApplicationFiled: January 12, 2015Publication date: May 7, 2015Inventor: TAKAYOSHI TOZUNE
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Patent number: 9011586Abstract: The invention relates to a binding agent comprising an aqueous, film-forming, polymeric siloxane. The invention also relates to a coating agent that is produced using said binding agent and to a workpiece that is coated with said coating agent.Type: GrantFiled: March 21, 2005Date of Patent: April 21, 2015Assignee: Ewald Dörken AGInventors: Thomas Kruse, Bettina Werner, Gerhard Reusmann
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Patent number: 9011592Abstract: A sol to form an inorganic-organic hybrid coating having a thick highly transparent hard coating is described. The hybrid coating is formed from a combined aqueous sol with least one hydrolyzable silane and at least one hydrolyzable metal oxide precursor where the only organic solvents present are those liberated upon hydrolysis of the silanes and metal oxide precursors. In one embodiment an inorganic-organic hybrid coating is formed by combination of a sol, prepared by the hydrolysis of tetraethoxysilane and ?-glycidoxypropyltrimethoxysilane with an excess of water, and a sol, prepared by the hydrolysis of titanium tetrabutoxide and ?-glycidoxypropyltrimethoxysilane with a deficiency of water. A plastic substrate can be coated with the combined sol and the combined sol gelled to a thickness of at least 5 ?m with heating to less than 150° C.Type: GrantFiled: April 2, 2014Date of Patent: April 21, 2015Assignee: University of Florida Research Foundation, Inc.Inventors: Masahiro Asuka, Wolfgang M. Sigmund
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Patent number: 9011591Abstract: Compositions for use in microelectronic applications: Ra comprises one or more multiple bonds, provided that, if Ra comprises more than one multiple bond, these multiple bonds are not in a conjugated configuration; and R1, R2, R3 are independently selected from alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl; and Rb is selected from H or a saturated group comprising alkyl, alkylene, or alkylidene; and R4, R5, R6 are independently alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl; and Rc comprises more than one multiple bond, and these multiple bonds are in a conjugated configuration; and R7, R8, R9 are independently alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl; and R10, R11, R12, R13 are independently alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl.Type: GrantFiled: August 28, 2012Date of Patent: April 21, 2015Assignees: Dow Global Technologies LLC, Rohm and Haas Electronic Materials LLCInventors: Yuanqiao Rao, Robert L. Auger, John D. Weaver, Paul J. Popa, Roxanne M. Jenkins, Christopher P. Sullivan, Jessica P. Evans, Cecilia W. Kiarie, Yasmin N. Srivastava, Jeffrey L. Fenton, Jr.
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Solution comprising propyl-functional alkali siliconates, silicates and method of production thereof
Patent number: 8999053Abstract: The invention relates to a solution and to methods for producing the solution comprising propylfunctional alkaline siliconates, silicates and, optionally, the cocondensation products thereof.Type: GrantFiled: February 27, 2012Date of Patent: April 7, 2015Assignee: Evonik Degussa GmbHInventors: Manuel Friedel, Spomenko Ljesic, Christian Waβmer, Susanne Zölitz -
Patent number: 8999052Abstract: Fine mesoporous silica particles are provided by which not only the functions of low reflectance (Low-n), low dielectric constant (Low-k) and low thermal conductivity but also improved strength of a molded article are achieved. The fine mesoporous silica particles are manufactured by a process including a surfactant composite fine silica particle preparation step and a mesoporous particle formation step. In the silica fine particle preparation step, a surfactant, water, an alkali and a hydrophobic part-containing additive including a hydrophobic part for increasing the volume of micelles are mixed with a silica source to thereby prepare surfactant composite fine silica particles. In the mesoporous particle formation step, the mixture is mixed with an acid and an organosilicon compound to thereby remove the surfactant and hydrophobic part-containing additive from the surfactant composite fine silica particles and provide the surface of each silica fine particle with an organic functional group.Type: GrantFiled: May 18, 2010Date of Patent: April 7, 2015Assignees: Panasonic Corporation, The University of TokyoInventors: Hiroki Yabe, Takeyuki Yamaki, Yasuto Hoshikawa, Tatsuya Okubo, Atsushi Shimojima
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Publication number: 20150090026Abstract: The present application relates to an anti-fingerprint coating material. a method for evaluating a surface property. More particularly, the present application relates to a non-fluorinated coating materials with anti-fingerprint property, as well as a method for manufacturing thereof, and evaluating an anti-fingerprint properties of the coating materials surface and non-fluorinated coating materials with anti-fingerprint property.Type: ApplicationFiled: September 27, 2013Publication date: April 2, 2015Applicant: National Taiwan University of Science and TechnologyInventors: Toyoko Imae, Ampornphan Siriviriyanun
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Publication number: 20150087743Abstract: Fluids incorporated into intraocular lenses and their methods of use. In some embodiments the fluids are silicone oils, and in some embodiments they are used in accommodating intraocular lenses.Type: ApplicationFiled: November 26, 2014Publication date: March 26, 2015Inventors: David J. ANVAR, Andrew GOODWIN, David CHAZAN
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Patent number: 8980960Abstract: Process for preparing a dispersion comprising silicon dioxide particles and cationizing agents, by dispersing 50 to 75 parts by weight of water, 25 to 50 parts by weight of silicon dioxide particles having a BET surface area of 30 to 500 m2/g and 100 to 300 ?g of cationizing agent per square meter of the BET surface area of the silicon dioxide particles, wherein the cationizing agent is obtainable by reacting at least one haloalkyl-functional alkoxysilane, hydrolysis products, condensation products and/or mixtures thereof with at least one aminoalcohol and water; and optionally removing the resulting hydrolysis alcohol from the reaction mixture. Also the process for preparing the dispersion, wherein the cationizing agent comprises one or more quaternary, aminoalcohol-functional, organosilicon compounds of formula III and/or condensation products thereof, wherein Ru and Rv are independently C2-4 alkyl group, m is 2-5 and n is 2-5.Type: GrantFiled: May 23, 2011Date of Patent: March 17, 2015Assignee: Evonik Degussa GmbHInventors: Stefan Scharfe, Andrea Heuschen, Christoph Batz-Sohn, Burkhard Standke, Christian Wassmer, Heinz Lach
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Patent number: 8961672Abstract: Solid alkali metal salts of organosilanols and/or their hydrolysis/condensation products are prepared by hydrolysis of organosilanes in water and in the presence of a basic alkali metal salt. The products contain predominately methyl and ethyl organic groups, and C4 or higher hydrocarbon groups as well. The solid salts effectively hydrophobe building materials, while being easily mixed with water.Type: GrantFiled: May 7, 2012Date of Patent: February 24, 2015Assignee: Wacker Chemie AGInventors: Michael Stepp, Dominik Auer, Karl-Heinz Felix, Daniel Schildbach
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Publication number: 20150048356Abstract: Provided are an adhesive film, and an organic electronic device (OED) encapsulation product using the same. Dimensional stability, lifespan, and durability may be enhanced even when a panel of an organic electronic device is large-sized and formed as a thin film by controlling dimensional tolerance and edge angular tolerance of the adhesive film, thereby ensuring long-term reliability, and process yields may be enhanced when the adhesive film is applied to an automation process.Type: ApplicationFiled: October 29, 2014Publication date: February 19, 2015Inventors: Seung Min LEE, Suk Ky CHANG, Hyun Jee YOO, Jung Sup SHIM, Yoon Gyung CHO, Kyung Yul BAE
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Patent number: 8951342Abstract: A chemical vapor deposition method for producing a porous organosilica glass film comprising: introducing into a vacuum chamber gaseous reagents including at least one precursor selected from the group consisting of an organosilane and an organosiloxane, and a porogen that is distinct from the precursor; applying energy to the gaseous reagents in the vacuum chamber to induce reaction of the gaseous reagents to deposit a preliminary film on the substrate, wherein the preliminary film contains the porogen; and removing from the preliminary film substantially all of the porogen to provide the porous film with pores and a dielectric constant less than 2.6.Type: GrantFiled: November 1, 2011Date of Patent: February 10, 2015Assignee: Air Products and Chemicals, Inc.Inventors: Raymond Nicholas Vrtis, Mark Leonard O'Neill, Jean Louise Vincent, Aaron Scott Lukas, Mary Kathryn Haas
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Publication number: 20150037570Abstract: The disclosure discloses abrasion resistant, persistently hydrophobic and oleophobic, anti-reflective and anti-soiling coatings for glass. The coatings described herein have wide application, including for example the front cover glass of solar modules. Methods of applying the coatings using various apparatus are disclosed. Methods for using the coatings in solar energy generation plants to achieve greater energy yield and reduced operations costs are disclosed. Coating materials are formed by combinations of hydrolyzed silane-base precursors through sol-gel processes. Several methods of synthesis and formulation of coating materials are disclosed.Type: ApplicationFiled: September 17, 2014Publication date: February 5, 2015Inventors: Brenor L. Brophy, Vinod Nair, Bakul Champaklal Dave
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Publication number: 20150020878Abstract: An anti-reflective coating film is formed from a coating solution composition that includes a silane-based precursor. When measured via Fourier Transform Infrared (FT-IR) Spectroscopy using a wavelength of 1064 nm, the coating solution composition exhibits a peak intensity ratio IB/IA and a peak intensity ratio IC/IA of equal to or greater than 0.47, respectively. The peak intensity IB is in a range of about 930 cm?1 to about 960 cm?1, the peak intensity IA is in a range of about 1110 cm?1 to about 1130 cm?1, and the peak intensity IC is in a range of about 1020 cm?1 to about 1050 cm?1. A solar cell including the anti-reflective coating film, and a method of predicting the strength of the anti-reflective coating film for the solar cell have been disclosed.Type: ApplicationFiled: January 6, 2014Publication date: January 22, 2015Applicant: SAMSUNG SDI CO., LTD.Inventors: Soo-Youn Park, Sang-Hyun Eom, Do-Young Park, Hye-Jin Park, Sung-Su Kim, Chun-Gyoo Lee, Jong-Hwan Park, Ji-Won Lee